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Fatigue strength and microstructure evaluation of Al 7050 alloy wires recycled by spray forming,extrusion and rotary swaging

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Transactions of Nonferrous Metals Society of China 2020年第12期30卷 3195-3209页

作者： joão g.j.de salvo Conrado RMAFoNSo Programa de Pós-graduação em Ciência e Engenharia de Materiais(PPg-CEM) Universidade Federal de São Carlos(UFSCar)Rod.Washington LuizKm 23513565-905 São Carlos-SPBrazil Divisão de Materiais Instituto de Aeronáutica e EspaçoCTAPraça Marechal Eduardo Gomes5012228-904 São Josédos Campos-SPBrazil departamento de Engenharia de Materiais(deMa) Universidade Federal de São Carlos(USFCar)Rod.Washington LuizKm 23513565-905 São Carlos-SPBrazil

Recycled high-strength aluminum alloys have limited use as structural materials due to poor mechanical properties. Spray forming remelting followed by hot extrusion is a promising route for reprocessing 7 xxx alloys. The 7050 alloy machining chips were spray formed, hot extruded, rotary swaged and heat-treated in order to improve mechanical properties. Microstructures, tensile properties and fatigue strength results for a 2.7 mm-diameter recycled wire are presented. Secondary phases and precipitates were investigated by XRD, SEM, EBSD, TEM and DSC. As-swaged and heat-treated(solution and aging) conditions were evaluated. Mechanical properties of both conditions outperformed AA7050 aerospace specification. Substantial grain refinement resulted from the extensive plastic deformation imposed by rotary swaging. Refined micrometric and sub-micrometric Al grains, as well as coarse and fine intermetallic precipitates were observed. Subsequent solution treatment resulted in a homogeneous, recrystallized and equiaxed microstructure with grain size of 9 μm. Nanoscale gP(I) zones and η′ phase precipitates formed after aging at 120 ℃, imparting higher tensile(586 MPa) and fatigue(198 MPa) strengths.

关键词： Al−Zn−Mg−Cu alloy spray forming thermomechanical processing microstructure fatigue

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Low-Cost and Biodegradable Thermoelectric devices Based on van der Waals Semiconductors on Paper Substrates

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Energy & Environmental Materials 2024年第01期7卷 205-210页

作者： gulsum Ersu Carmen Munuera Federico j.Mompean Daniel Vaquero jorge Quereda jo?o Elias F.S.Rodrigues jose A.Alonso Eduardo Flores jose R.Ares Isabel j.Ferrer Abdullah M.Al-Enizi Ayman Nafady Sruthi Kuriakose joshua o.Island Andres Castellanos-gomez Materials Science Factory Instituto de Ciencia de Materiales de Madrid (ICMM-CSIC) Nanotechnology group USAL–Nanolab Univesidad de Salamanca gISC Departamento de Física de Materiales Universidad Complutense de Madrid departamento de Física Aplicada Centro de Investigación y Estudios Avanzados MIRE group Departamento de Física de Materiales Universidad Autónoma de Madrid Instituto Nicolás Cabrera Universidad Autónoma de Madrid department of Chemistry College of Science King Saud University department of Physics and Astronomy University of Nevada Las Vegas

We present a method to fabricate handcrafted thermoelectric devices on standard office paper *** devices are based on thin films of WS2,Te,and BP（P-type semiconductors） and TiS3and TiS2（N-type semiconductors）,depo... 详细信息

关键词： paper-based electronics Seebeck effect semiconductors thermoelectrics van der Waals materials

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Supercritical fluid technology as a sustainable alternative method for textile dyeing:An approach on waste,energy,and Co_(2)emission reduction

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journal of Environmental Sciences 2024年第6期140卷 123-145页

作者： Carlos Rafael Silva de oliveira Patrícia Viera de oliveira Leandro Pellenz Catia Rosana Lange de Aguiar Afonso Henrique da Silva júnior Federal University of Santa Catarina Textile Engineering Department2514 João Pessoa St.BlumenauSC89036-004Brazil Federal University of Santa Catarina Chemical Engineering DepartmentS/n Biotério Central St.FlorianópolisSC88040-900Brazil

The clothing industry is considered one of the most polluting industries on the planet due to the high consumption of water,energy,chemicals/dyes,and high generation of solid waste and *** with environmental concerns,the textile ennoblement sector is the most critical of the textile production chain,especially the traditional dyeing *** an alternative to current problems,dyeing with supercritical Co_(2)(scCo_(2))has been presented as a clean and efficient process for a sustainable textile *** fluid dyeing(SFD)has shown a growing interest due to its significant impact on environmental preservation and social,economic,and financial *** main SFD benefits include economy and reuse of non-adsorbed dyes;reduction of process time and energy expenditure;capture of atmospheric Co_(2)(greenhouse gas);use and recycling of Co_(2)in SFD;generation of carbon credits;water-free process;effluent-free process;reduction of Co_(2)emission and auxiliary *** being still a non-scalable and evolving technology,SFD is the future of *** review presented a comprehensive overview of the environmental impacts caused by traditional processes and confronted the advantages of *** SFD technique was introduced,along with its latest advances and future *** and environmental gains were also discussed.

关键词： Textile industry Supercritical dyeing Sustainable processes Water free dyeing Energy saving Cleaner production

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Response to Commentary by Dr. Matthew j. Clarkson on

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journal of Sport and Health Science 2024年第5期13卷 670-671页

作者： Hugo de Luca Corrêa Lysleine Alves deus Dahan da Cunha Nascimento Nicholas Rolnick Rodrigo Vanerson Passos Neves Andrea Lucena Reis Thais Branquinho de Araújo Carmen Tzanno-Martins Fernanda Silveira Tavares Luiz Sinésio Silva Neto Cláudio Avelino Rodrigues Santos Paolo Lucas Rodrigues-Silva Fernando Honorato Souza Vitória Marra da Motta Vilalva Mestrinho Rafael Lavarini dos Santos Rosangela Vieira Andrade jonato Prestes Thiago dos Santos Rosa Post-graduate Program of Physical Education Catholic University of BrasıliaBrasılia 71966-700Brazil The Human Performance Mechanic Lehman CollegeNew YorkNY 10011USA Clinical group Home Dialysis Center and RenalClass Sao Paulo 01239-040Brazil department of Medicine Catholic University of BrasıliaBrasılia 71966-700Brazil Faculty of Medicine Federal University of TocantinsTocantins 77001-090Brazil Embrapa genetic Resources and Biotechnology Brasılia 70770-917Brazil g graduate Program of genomic Sciences and Biotechnology Brasılia 71966-700Brazil

dear editor:We sincerely thank Matthew *** for his insightful commentary1 on our recent publication in the journal of Sport and Health Science.2 Clarkson's pioneering work in the development and application of blood flow restriction (BFR) exercise protocols has undeniably laid the groundwork for subsequent investigations in this field,including our own.(3-6)His commentary not only highlights the relevance and timeliness of our study but also offers valuable perspectives on refining safety considerations for intradialytic BFR exercise among hemodialysis patients.

关键词： patients application flow

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defect Engineering in Earth-Abundant Cu2ZnSnSe4 Absorber Using Efficient Alkali Doping for Flexible and Tandem Solar Cell Applications

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Energy & Environmental Materials 2024年第2期7卷 253-260页

作者： Muhammad Rehan Ara Cho Inyoung jeong Kihwan Kim Asmat Ullah jun-Sik Cho joo Hyung Park Yunae jo Sung jun Hong Seung Kyu Ahn Sejin Ahn jae Ho Yun jihye gwak Donghyeop Shin Photovoltaics Research department Korea Institute of Energy Research (KIER) department of Renewable Energy Engineering University of Science and Technology (UST) Korea Institute of Energy Technology (KENTECH)

To demonstrate flexible and tandem device applications, a low-temperature Cu2ZnSnSe4（CZTSe） deposition process, combined with efficient alkali doping, was developed. First, high-quality CZTSe films were grown at480 °C by a single co-evaporation, which is applicable to polyimide（PI）substrate. Because of the alkali-free substrate, Na and K alkali doping were systematically studied and optimized to precisely control the alkali distribution in CZTSe. The bulk defect density was significantly reduced by suppression of deep acceptor states after the（Na F + KF） PDTs. Through the low-temperature deposition with（Na F + KF） PDTs, the CZTSe device on glass yields the best efficiency of 8.1% with an improved VoCdeficit of646 m V. The developed deposition technologies have been applied to *** the first time, we report the highest efficiency of 6.92% for flexible CZTSe solar cells on PI. Additionally, CZTSe devices were utilized as bottom cells to fabricate four-terminal CZTSe/perovskite tandem cells because of a low bandgap of CZTSe（～1.0 e V） so that the tandem cell yielded an efficiency of 20%. The obtained results show that CZTSe solar cells prepared by a low-temperature process with in-situ alkali doping can be utilized for flexible thin-film solar cells as well as tandem device applications.

关键词： alkali doping Earth-abundant Cu2ZnSnSe4 flexible solar cells four-terminal tandem cells low-temperature process

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Vertical plane depth-resolved surface potential and carrier separation characteristics in flexible CZTSSe solar cells with over 12% efficiency

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Carbon Energy 2024年第3期6卷 36-52页

作者： Dae-Ho Son Ha Kyung Park Dae-Hwan Kim jin-Kyu Kang Shi-joon Sung Dae-Kue Hwang jaebaek Lee Dong-Hwan jeon Yunae Cho William jo Taeseon Lee junHo Kim Sang-Hoon Nam Kee-jeong Yang Division of Energy Technology DGISTDaeguRepublic of Korea Research Center for Thin Film Solar Cells DGISTDaeguRepublic of Korea department of Physics Ewha Womans UniversitySeoulRepublic of Korea department of Physics Incheon National UniversityIncheonRepublic of Korea department of Mechanical Engineering Massachusetts Institute of TechnologyCambridgeMassachusettsUSA

Cu2ZnSn(S,Se)4(CZTSSe)solar cells have resource distribution and economic *** main cause of their low efficiency is carrier loss resulting from recombination of photo-generated electron and *** overcome this,it is important to understand their electron-hole behavior *** determine the carrier separation characteristics,we measured the surface potential and the local current in terms of the absorber *** elemental variation in the intragrains(Igs)and at the grain boundaries(gBs)caused a band edge shift and bandgap(Eg)*** the absorber surface and subsurface,an upward Ec and Ev band bending structure was observed at the gBs,and the carrier separation was *** the absorber center,both upward Ec and Ev and downward Ec-upward Ev band bending structures were observed at the gBs,and the carrier separation was *** improve the carrier separation and suppress carrier recombination,an upward Ec and Ev band bending structure at the gBs is desirable.

关键词： carrier separation CZTSSe flexible solar cell local current surface potential

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A Quasilinear System Related with the Asymptotic Equation of the Nematic Liquid Crystal’s Director Field

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Chinese Annals of Mathematics,Series B 2021年第2期42卷 163-172页

作者： joão-Paulo DIAS departamento de Matemática and CMAFcIo Faculdade de Ciências da Universidade de LisboaCampo GrandeEdificio C61749-016 LisboaPortugal

In this paper, the author studies the local existence of strong solutions and their possible blow-up in time for a quasilinear system describing the interaction of a short wave induced by an electron field with a long wave representing an extension of the motion of the director field in a nematic liquid crystal’s asymptotic model introduced in[Saxton, R. A., Dynamic instability of the liquid crystal director. In: Current Progress in Hyperbolic Systems(Lindquist, W. B., ed.), Contemp. Math., Vol.100, Amer. ***., Providence, RI, 1989, pp.325–330] and [Hunter, j. K. and Saxton, R. A., Dynamics of director fields, SIAM j. Appl. Math., 51, 1991, 1498–1521] and studied in [Hunter, j. *** Zheng, Y., on a nonlinear hyperbolic variational equation I, Arch. Rat. Mech. Anal.,129, 1995, 305–353], [Hunter, j. K. and Zheng, Y., on a nonlinear hyperbolic variational equation II, Arch. Rat. Mech. Anal., 129, 1995, 355–383] and in [Zhang, P. and Zheng,Y., on oscillation of an asymptotic equation of a nonlinear variational wave equation,Asymptotic Anal., 18, 1998, 307–327] and, more recently, in [Bressan, A., Zhang, P. and Zheng, Y., Asymptotic variational wave equations, Arch. Rat. Mech. Anal., 183, 2007,163–185].

关键词： Benney system Conservation law Schrödinger equation Nematic liquid crystal Director field

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Chitosan and Carboxymethylchitosan as High Turbidity Water Biocoagulants

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journal of Renewable Materials 2020年第11期8卷 1489-1504页

作者： Raimundo N.Lima júnior joão L.I.o.Almeida jones de Andrade Flávia o.M.S.Abreu Natural Sciences Program State University of Ceará-UECEFortalezaCE 60714-903Brazil Physical-Chemistry department Institute of ChemistryFederal University of Rio Grande do Sul-UFRGSPorto AlegreRS 91501-970Brazil

Biocoagulants emerges as a promising technology in water treatment,in order to exploit renewable and biodegradable *** present work aims to study the coagulant action of chitosan and carboxymethylchitosan on water with very high turbidity(above 300 NTU),contrasting the physicochemical results with those obtained for aluminum *** was produced by the Williamson’s ethers synthesis and characterized by potentiometric titration,FTIR and 1 *** coagulant tests were performed using synthetic water in a jar-test equipment,through the induction of high and low velocity gradients,followed by *** results showed turbidity and color removal efficiencies above 99%for the biocoagulants,by applying dosages much lower than those used for aluminum sulphate;the volume of sedimentable solids obtained at the end of the water treatment process was much lower when chitosan and carboxymethylchitosan were used as coagulants(reduction of 25%when compared to aluminum sulphate).In summary,carboxymethylchitosan is a non-toxic,renewable,biodegradable material with high efficiency as a coagulant for waters with very high turbidity,showing promise for in natura applications.

关键词： Chitosan carboxymethylchitosan biocoagulants colloids and interfaces

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Partition coefficient prediction of Baker's yeast invertase in aqueous two phase systems using hybrid group method data handling neural network

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Chinese journal of Chemical Engineering 2017年第5期25卷 652-657页

作者： Carlos Eduardo de Araújo Padilha Sérgio Dantas de oliveira júnior Domingos Fabiano de Santana Souza jackson Araújo de oliveira gorete Ribeiro de Macedo Everaldo Silvino dos Santos Laboratory of Biochemical Engineering Chemical Engineering DepartmentFederal University of Rio Grande do Norte (UFRN)

A hybrid gMDH neural network model has been developed in order to predict the partition coefficients of invertase from Baker's yeast. ATPS experiments were carried out changing the molar average mass of PEg(1500–6000 Da), p H(4.0–7.0), percentage of PEg(10.0–20.0 w/w), percentage of MgSo_4(8.0–16.0 w/w), percentage of the cell homogenate(10.0–20.0 w/w) and the percentage of MnSo_4(0–5.0 w/w) added as cosolute. The network evaluation was carried out comparing the partition coefficients obtained from the hybrid gMDH neural network with the experimental data using different statistical metrics. The hybrid gMDH neural network model showed better fitting(AARD = 32.752%) as well as good generalization capacity of the partition coefficients of the ATPS than the original gMDH network approach and a BPANN model. Therefore hybrid gMDH neural network model appears as a powerful tool for predicting partition coefficients during downstream processing of biomolecules.

关键词： Partitioning Invertase Aqueous Two Phase System gMDH Neural network

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Neutrino masses,cosmological inflation and dark matter in a variant U(1)B-L model with type II seesaw mechanism

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Chinese Physics C 2021年第2期45卷 621-630页

作者： j.g.Rodrigues A.C.o.Santos j.g.Ferreira jr C.A.de S.Pires departamento de Física Universidade Federal da ParaíbaCaixa Postal 500858051-970João PessoaPBBrasil departamento de Física Universidade Federal do Rio Grande do Norte59078-970NatalRNBrasil

In this study,we implemented the type Ⅱ seesaw mechanism into the framework of the U(l)B-L gauge *** achieve this,we added a scalar triplet,A,to the canonical particle content of the U(l)B-Lgauge *** imposing that the U(l)B-L gauge symmetry be spontaneously broken at TeV scale,we show that the type Ⅱ seesaw mechanism is realized at an intermediate energy scale,more precisely,at approximately 109 *** prevent heavy right-handed neutrinos from disturbing the mechanism,we evoke a Z2 discrete ***,as a result,we have standard neutrinos with mass around eV scale and right-handed neutrinos with mass in TeV scale,with the lightest one fulfilling the condition of dark *** developed all of these in this *** addition,we show that the neutral component of Δ may perform unproblematic non-minimal inflation with loss of unitarity.

关键词： models beyond the standard model particle-theory and field-theory models of the early universe neutrino mass and mixing

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