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Journal of Energy Chemistry 2024年第1期88卷 461-468,I0011页

作者： Yahui Zhang Yafeng Li Ruixiang Peng Yi Qiu jingyu Shi Zhenyu Chen Jinfeng Ge Cuifen Zhang Zheng Tang Ziyi Ge School of Materials Science and Engineering Shanghai UniversityShanghai 200444China Zhejiang Business Technology Institute Ningbo 315012ZhejiangChina Zhejiang Provincial Engineering Research Center of Energy Optoelectronic Materials and Devices Ningbo Institute of Materials Technology and EngineeringChinese Academy of SciencesNingbo 315201ZhejiangChina Center for Advanced Low-dimension Materials College of Materials Science and EngineeringDonghua UniversityShanghai 201620China

Phenazine-based non-fullerene acceptors(NFAs)have demonstrated great potential in improving the power conversion efficiency(PCE)of organic solar cells(OSCs).Halogenation is known to be an effective strategy for increasing optical absorption,refining energy levels,and improving molecular packing in organic ***,a series of NFAs(Pz IC-4H,Pz IC-4F,Pz IC-4Cl,Pz IC-2Br)with phenazine as the central core and with/without halogen-substituted(dicyanomethylidene)-indan-1-one(IC)as the electron-accepting end group were synthesized,and the effect of end group matched phenazine central unit on the photovoltaic performance was systematically *** photophysical and morphological analyses revealed that the PM6:Pz IC-4F blend involves efficient exciton dissociation,higher charge collection and transfer rates,better crystallinity,and optimal phase ***,OSCs based on PM6:Pz IC-4F as the active layer exhibited a PCE of 16.48%with an open circuit voltage(Voc)and energy loss of 0.880 V and 0.53 e V,***,this work demonstrated a promising approach by designing phenazine-based NFAs for achieving high-performance OSCs.

关键词： Organic solar cells Non-fullerene acceptor Phenazine Central core End group

A nonradical oxidation process initiated by Ti-peroxo complex showed high specificity toward the degradation of tetracycline antibiotics

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Chinese Chemical Letters 2024年第5期35卷 366-370页

作者： Jian Peng Yue Jiang Shuangyu Wu Yanran Cheng jingyu Liang Yixin Wang Zhuo Li Sijie Lin College of Environmental Science and Engineering Biomedical Multidisciplinary Innovation Research InstituteShanghai East HospitalTongji UniversityShanghai 200092China Key Laboratory of Yangtze River Water Environment Shanghai Institute of Pollution Control and Ecological SecurityTongji UniversityShanghai 200092China

Nonradical oxidation has received wide attention in advanced oxidation processes for environmental *** the relationship between material characteristics and their ability to initiate nonradical oxidation processes is the key to better material design and ***,a novel titanium-based metal-organic framework MIL-125-Ti/H_(2)O_(2) system was established to show a highly selective degradation efficacy toward tetracycline ***-125-Ti with the abundance of TiO6 octahedra units was found to effectively activate H_(2)O_(2) under dark conditions by forming an oxidative Ti-peroxo *** presence of the Ti-peroxo complex,confirmed by UV-visible spectrophotometer,fourier transform infrared spectroscopy,and X-ray photoelectron spectroscopy characterizations,showed superior degradation(>95%removal rate)of oxytetracycline hydrochloride(OTC),doxycycline hydrochloride,chlortetracycline hydrochloride,and *** functional theory calculations were performed to assist the elucidation on the mechanism of H_(2)O_(2) activation and antibiotics *** MIL-125-Ti/H_(2)O_(2) system was highly resistant to halogens and background organics,and could well maintain its original catalytic activity in actual water *** retained the ability to degrade 75%of OTC within ten test *** study provides new insight into the nonradical oxidation process initiated by the unique Ti-peroxo complex of Ti-based MOF.

关键词： Nonradical oxidation Metal-organic frameworks Advanced oxidation process Ti-peroxo complex Antibiotics degradation

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超低浓度甲烷流态化催化燃烧特性与模型验证

工程热物理学报 2015年第7期36卷 1496-1500页

作者：杨仲卿杨鹏王恒远张力冉景煜郭名女低品位能源利用技术及系统教育部重点实验室(重庆大学) 重庆400030 重庆大学动力工程学院重庆400030

采用实验研究和理论分析相结合的方法研究了体积分数为0.15~3%超低浓度甲烷在0.5%Pd/Al_2O_3（质量分数）催化颗粒鼓泡流态化状态下的催化燃烧特性,根据其在密相区和稀相区的流动及反应特点,建立了低浓度甲烷催化燃烧反应模型,并在不同... 详细信息

采用实验研究和理论分析相结合的方法研究了体积分数为0.15~3%超低浓度甲烷在0.5%Pd/Al_2O_3（质量分数）催化颗粒鼓泡流态化状态下的催化燃烧特性,根据其在密相区和稀相区的流动及反应特点,建立了低浓度甲烷催化燃烧反应模型,并在不同温度、进气甲烷浓度、床层高度等工况下进行了模型预测及与实验数据的对比分析。研究结果表明：考虑了稀相区中催化颗粒飞溅,模型计算数据与实验数据吻合较好,误差在5%以内;反应器出口无量纲甲烷浓度随着床层温度的升高、进气甲烷浓度的降低以及床层高度的升高而降低;通过与活塞流,全混流反应模型的对比分析,进一步验证了所建立的数学模型能够较好地反映超低浓度甲烷在鼓泡流态化状态下的催化燃烧特性。

关键词：超低浓度甲烷催化燃烧鼓泡流态化反应数学模型

湿法脱硫塔入口烟气调温耦合余热回收工艺系统节能分析比较

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中国电机工程学报 2020年第23期40卷 7667-7674页

作者：邓庆波冉景煜杨仲卿蒲舸闫云飞牛俊天低品位能源利用技术及系统教育部重点实验室(重庆大学) 重庆市沙坪坝区400044

火力发电厂中脱硫系统能耗较高,脱硫塔前烟气具有较大余热回收潜力,合理的脱硫塔入口烟气参数可提高脱硫性能并降低水耗。为此,文中提出了4种将烟气调温与余热回收进行耦合的系统方案,并计算了系统能耗、投资以及投入运行后机组的节煤... 详细信息

火力发电厂中脱硫系统能耗较高,脱硫塔前烟气具有较大余热回收潜力,合理的脱硫塔入口烟气参数可提高脱硫性能并降低水耗。为此,文中提出了4种将烟气调温与余热回收进行耦合的系统方案,并计算了系统能耗、投资以及投入运行后机组的节煤量。在此基础上,结合能量汇入温差最小的?损分析原则,在保证高脱硫效率的前提下,提出了优化的分级烟气调温与余热回收方案,可将余热分别回收至机组第六、七级低加,能使系统?损百分比降低为1.05%,机组供电标准煤耗降低3.29g/(k W·h)。

关键词：湿法脱硫余热回收烟气调温 [火用]损节煤量

Discussion on the Implications of Expansion in Postgraduate Education

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Journal of Contemporary Educational Research 2024年第6期8卷 128-134页

作者： jingyu Zhu Shandong Xiandai University Jinan 250104Shandong ProvinceChina

This paper explores the development of postgraduate education in China,including the overall situation of postgraduate education,the trend in enrollment expansion in professional degrees as well as in various academic fields;it also triggers the impact and discussion about the postgraduate enrollment expansion,such as over-education and credential inflation,as well as the concerns about the quality of education and talent cultivation and so *** the expansion brings various problems,the challenges may also become new opportunities for higher education reform,this paper also provides some suggestions on the expansion of postgraduate education.

关键词： Expansion of postgraduate education Over-education Credential inflation Implications Employment crisis Education quality

Securing multi-chain consensus against diverse miner behavior attacks in blockchain networks

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Frontiers of Information Technology & Electronic Engineering 2024年第4期25卷 540-554页

作者： Wenbo ZHANG Tao WANG Chaoyang ZHANG jingyu FENG School of Cyberspace Security Xi’an University of Posts and TelecommunicationsXi’an 710121China Postal Savings Bank of China Xi’an 710000China

As cross-chain technologies enable interactions among different blockchains(hereinafter“chains”),multi-chain consensus is becoming increasingly important in blockchain ***,more attention has been paid to single-chain consensus ***-chain consensus schemes with trusted miner participation have not been considered,thus offering opportunities for malicious users to launch diverse miner behavior(DMB)attacks on different *** attackers can be friendly in the consensus process on some chains,called mask chains,to enhance their trust value,while on others,called kill chains,they engage in destructive behaviors on the *** this paper,we propose a multi-chain consensus scheme named Proof-of-DiscTrust(PoDT)to defend against DMB *** idea of distinctive trust(DiscTrust)is introduced to evaluate the trust value of each user across different *** trustworthiness of a user is split into local and global trust values.A dynamic behavior prediction scheme is designed to enforce DiscTrust to prevent an intensive DMB attacker from maintaining strong trust by alternately creating true or false blocks on the kill *** trusted miner selection algorithms for multi-chain environments can be implemented to select network miners,chain miners,and chain miner leaders,*** results show that PoDT is secure against DMB attacks and more effective than traditional consensus schemes in multi-chain environments.

关键词： Blockchain Cross-chain Trust mechanism Multi-chain consensus

THE HEAT TranSFER CHARACTERISTIC OF THE GAS BAKING METHOD FOR HEATING ELECTROLYTIC CELL

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THE HEAT TRANSFER CHARACTERISTIC OF THE GAS BAKING METHOD FO...

Highly efficient ternary organic solar cells with excellent open-circuit voltage and fill factor via precisely tuning molecular stacking and morphology

国际能源转换及利用学术会议

作者： Zhang Li Wu Chengbo Pan Liangming ran jingyu Xin Mingdao The Institute of Engineering Thermophysics Chongqing University Chongqing, 400044 P. R. China

This paper has numerically investigated the relationship between opportune heating process and temperature distribution of Hall cell baking using non-steady three dimensional heat transfer mode. We found that when the cell was heated in ultimate or fast speed(heating the cell up in 33 to 50 hours), it would cause high thermal gradients that lead to objectionable thermal stress in the cathode which can result in thermal-shock cracking, although the cathode can be raised to desired temperature;if completed the heating in 70 hours with the step speed, considering the moisture transpiration and the carbonization of cathodic material, thermal gradients were lowed to 100℃/m in cross section, and the surface gradients were lowed to 30℃/m. the temperature distribution is substantially unilbrmly. In real practice, we have gotten excellent results by using this method. In this paper, we also investigated the least time requirement to heat cell, and the utmost high temperature of the cathode bottom.

关键词： prebaked aluminum electrolytic cell gas heating method heat-transfer characteristic

来源： cnki会议评论

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Science China Chemistry 2024年第3期67卷 963-972页

作者： Dinghong Sun Zhenyu Chen Jianfeng Zhang Wei Song jingyu Shi Jintao Zhu Yuanyuan Meng Fei Jin Shuncheng Yang Ziyi Ge Faculty of Electrical Engineering and Computer Science Ningbo UniversityNingbo 315211China Faculty of Material Science and Chemical Engineering Ningbo UniversityNingbo 315211China Zhejiang Provincial Engineering Research Center of Energy Optoelectronic Materials and Devices Ningbo Institute of Materials Technology&EngineeringChinese Academy of SciencesNingbo 315201China Center of Materials Science and Optoelectronics Engineering University of Chinese Academy of Sciences Beijing 100049China Department of Chemical and Environmental Engineering University of Nottingham NingboNingbo 315100China

The micro-morphology and molecular stacking play a key role in determining the charge transport process and nonradiative energy loss, thus impacting the performances of organic solar cells(OSCs). To address this issue, a non-fullerene acceptor PhC6-IC-F with alkylbenzene side-chain, possessing optimized molecular stacking, complementary absorption spectra and forming a cascade energy level alignment in the PM6:BTP-eC9 blend, is introduced as guest acceptor to improve efficiency of ternary OSCs. The bulky phenyl in the side-chain can regulate crystallinity and optimizing phase separation between receptors in ternary blend films, resulting in the optimal phase separations in the ternary films. As a result, high efficiencies of 18.33% as photovoltaic layer are obtained for PhC6-IC-F-based ternary devices with excellent fill factor(FF) of 78.92%. Impressively, the ternary system produces a significantly improved open circuit voltage(V_(oc)) of 0.857 V compared with the binary device,contributing to the reduced density of trap states and suppressed non-radiative recombination result in lower energy loss. This work demonstrates an effective approach for adjusting the aggregation, molecular packing and fine phase separation morphology to increase V_(oc) and FF, paving the way toward high-efficiency OSCs.

关键词： alkylbenzene side-chain morphology regulation ternary blends organic solar cells

3-Epi-betulinic acid 3-O-β-D-glucopyranoside(eBAG)induces autophagy by activation of AMP-activated protein kinase in hepatocellular carcinoma

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Food Science and Human Wellness 2024年第3期13卷 1453-1464页

作者： Mengjie Liu Xuqiang Liu Kaiyue He Yongping Jian Yujia Li Jinrong Guo jingyu Yang Zhixiang Xu Wenyi Kang School of Life Sciences Henan UniversityKaifeng 475004China National R&D Center for Edible Fungus Processing Technology Henan UniversityKaifeng 475004China Joint International Research Laboratory of Food&Medicine Resource Function Kaifeng 475004China Shenzhen Research Institute of Henan University Shenzhen 518000China

3-Epi-betulinic acid 3-O-β-D-glucopyranoside(eBAG)is a pentacyclic triterpene mainly distributed in food and medicinal plants,which exhibits various pharmacological ***,whether these functions are attributed to eBAG or additional components in these plants remain ***,we report that eBAG exerted an inhibitory activity against hepatocellular carcinoma and esophageal cancer *** induced non-apoptotic cell death in hepatocellular carcinoma *** eBAG-induced cell death was inhibited by knock-down of autophagy related gene(ATG)5 and ATG7,by administration of 3-methyladenine,a selective autophagy inhibitor that suppresses phosphoinositide 3-kinase(PI3K),and by chloroquine,a classic autophagy flux *** demonstrated that eBAG induced an autophagy-mediated cell *** of eBAG mimicked cellular bioenergetics depletion leading to the reduction of intracellular ATP,activation of AMP-activated protein kinase(AMPK),and inhibition of ***-treatment with compound C,an AMPK inhibitor,abrogated cell death induced by *** further validated the anti-tumor effect of eBAG in the murine xenograft model of hepatocellular carcinoma and found that eBAG treatment promoted the induction of autophagy and reduction of tumor growth in *** a functional food ingredient,eBAG is a potential therapeutic agent for the treatment of hepatocellular carcinoma and esophageal cancer.

关键词： eBAG Autophagy ATP AMPK Hepatocellular carcinoma

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挥发性有机废气热氧化技术研究进展

化工进展 2017年第10期36卷 3866-3875页

作者：杨仲卿刘显伟张力冉景煜闫云飞杜学森重庆大学低品位能源利用技术及系统教育部重点实验室重庆400044 重庆大学动力工程学院重庆400044

挥发性有机废气(VOCs)是一种单位体积能量密度低、成分复杂、热值波动大的有毒有害大气污染物。本文分别介绍了吸附浓缩、蓄热氧化和催化燃烧3类VOCs处理工艺,并主要从工程应用与实验研究两方面对当前3类工艺在国内外的最新研究进展进... 详细信息

挥发性有机废气(VOCs)是一种单位体积能量密度低、成分复杂、热值波动大的有毒有害大气污染物。本文分别介绍了吸附浓缩、蓄热氧化和催化燃烧3类VOCs处理工艺,并主要从工程应用与实验研究两方面对当前3类工艺在国内外的最新研究进展进行了回顾,还重点从有机废气性质和工艺特点两方面分析了不同技术的优势和制约各自发展瓶颈。通过分析比较发现吸附浓缩对复杂有机废气的适应性较强,但单位体积吸附材料利用率较低、占地面积大;催化燃烧具有起燃温度低、节能等优点,但运行成本较高且单一催化剂对组分复杂的VOCs适应性差;蓄热燃烧具有较高的热回收率,但浓度低、热值波动大的有机废气限制了其运行的稳定性;组合式工艺相比3类基本工艺综合性能较好,但系统较复杂、稳定性较差以及占地面积大。未来,对不同工艺的优势进行组合与优化将成为经济、高效和安全治理挥发性有机废气最有效的途径之一。

关键词：挥发性有机废气吸附浓缩蓄热催化燃烧热氧化