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二硫化钼和碳纳米管复合物电极用于盐差能转换

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电化学（中英文） 2024年第6期30卷 32-44页

作者：李家俊张伟彬刘鑫宇杨静蕾尹易杨泽钦马雪婧成都理工大学材料与化学化工学院四川成都610059

海洋占地球水资源总量的97%,地表面积的70%以上。随着化石燃料等不可再生能源的持续消耗与可再生能源的快速发展,人们对海洋资源的利用越来越重视。海洋能包括潮汐能、波浪能、温差能和盐差能等。其中盐差能是海水和淡水相互作用产生的... 详细信息

海洋占地球水资源总量的97%,地表面积的70%以上。随着化石燃料等不可再生能源的持续消耗与可再生能源的快速发展,人们对海洋资源的利用越来越重视。海洋能包括潮汐能、波浪能、温差能和盐差能等。其中盐差能是海水和淡水相互作用产生的能量,是以化学能形式存在的海洋能,这种能量较多产生在河口处。目前,压力延迟渗透技术、反电渗析技术和电容混合技术是转换盐差能的三种主要技术。本文构建了一种基于电容混合技术的新型盐差电池,使用二硫化钼和多壁碳纳米管复合物电极作为阳极,活性炭作为阴极。将两种不同离子储存机制的材料复合在一起,二硫化钼具有类似石墨烯的层状结构,层间间距约为石墨烯的两倍,是一种可以与钠离子发生插层反应的电池电极材料。多壁碳纳米管具有典型的双电层效应,放电时在其表面吸附钠离子的同时,可以帮助钠离子更快地进入二硫化钼层间,加快离子传输效率和盐差能的转换效率。对该复合材料进行物理和电化学表征,并与活性炭电极组装的盐差电池,测试其盐差能转换能力。浓度响应电压150 mV,经过一个完整的四步循环后,转换能量密度可达6.96 J·g^(-1)。该器件原材料价格较低,并且不使用离子膜,更加环保,为转换盐差能的研究提供了一种新途径。

关键词：盐差量电化学转化转换效率二硫化钼碳纳米管

CeO_(2)-clay composites for ultra-long cycle life electrochemical capacitive energy storage application

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Journal of Rare Earths 2023年第5期41卷 728-739,I0004页

作者： Shan-Shan Chai Wei-Bin Zhang jing-Lei Yang Lun Zhang Xiong-Wei Han Myat Myintzu Theint xue-jing ma College of materials and Chemistry&Chemical Engineering Chengdu University of TechnologyChengdu 610059China Mineral Development Section for the International Relation Department of MinesMinistry of Natural Resources and Environmental ConversationNay Pyi Taw15011Myanmar

The lattice expansion caused by the reduction of Ce(Ⅳ)to Ce(Ⅲ)impeded the development of the CeO_(2)as an effective electrode material for electrochemical ***,we prepared CeO_(2)-clay composites through a one-step hydrothermal *** interlayer structures of clays efficiently accommodate volume changes induced by crystal lattice expansion to achieve ultra-long cycle *** 60000 charge-discharge cycles,the capacitance retention rate of the assembled asymmetric supercapacitors is as high as~-100%.The key findings of this work reveal the potential application of clays in achieving ultralong cycle stability of the CeO_(2)electrode material,paving the way for further application of the CeO_(2)in electrochemical energy storage.

关键词： Cerium dioxide Clay mineral Cycle life Electrochemical supercapacitor Rareearths

Hydroxysafflor Yellow A Promotes HaCaT Cell Proliferation and Migration by Regulating HBEGF/EGFR and PI3K/AKT Pathways and Circ_0084443

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Chinese Journal of Integrative Medicine 2024年第3期30卷 213-221页

作者： ZHANG Yue XIAO Yan-wei ma jing-xin WANG Ao-xue Department of Dermatology the Second Hospital of Dalian Medical UniversityDalianLiaoning Province116021China Department of Cell Biology Dalian Medical UniversityDalianLiaoning Province116044China

Objective:To investigate the effect and possible mechanism of hydroxysafflor yellow A(HSYA) on human immortalized keratinocyte cell proliferation and ***:HaCaT cells were treated with *** proliferation was detected by the cell counting kit-8 assay,and cell migration was measured using wound healing assay and Transwell migration *** mRNA and protein expression levels of heparin-binding epidermal growth factor(EGF)-like growth factor(HBEGF),EGF receptor(EGFR),phosphatidylinositol 3-kinase(PI3K),protein kinase B(AKT),mammalian target of rapamycin(mTOR),and hypoxia-inducible factor-1α(HIF-1α) were detected by quantitative real-time polymerase chain reaction(qRT-PCR) and Western blot,***_0084443-overexpressing HaCaT cells and empty plasmid HaCaT cells were constructed using the lentiviral stable transfection and treated with *** expression of circ_0084443 was detected by ***:HSYA(800 μmol/L) significantly promoted HaCaT cell proliferation and migration(P0.05).Conclusion:HSYA played an accelerative role in HaCaT cell proliferation and migration,which may be attributable to activating HBEGF/EGFR and PI3K/AKT signaling pathways,and had a particular inhibitory effect on the keratinocyte negative

关键词： hydroxysafflor yellow A circ_0084443 heparin-binding epidermal growth factor-like growth factor/epidermal growth factor receptor phosphatidylinositol 3-kinase/protein kinase B

Cracking on a nickel-based superalloy fabricated by direct energy deposition

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China Foundry 2024年第4期21卷 311-318页

作者： xue Zhang Ya-hang Mu Liang ma jing-jing Liang Yi-zhou Zhou Xiao-feng Sun Jin-guo Li School of materials Science and Engineering University of Science and Technology of ChinaShenyang 110016China Shi-changxu Innovation Center for Advanced materials Institute of Metal ResearchChinese Academy of SciencesShenyang 110016China School of materials Science and Engineering Northeastern UniversityShenyang 110819China

Cracks have consistently been a significant challenge limiting the development of additive manufactured nickel-based *** is essential to investigate the location of cracks and their forming *** study extensively examines the impact of solidification process,microstructural evolution,and stress concentration on crack initiation during direct energy deposition(DED).The results emphasize that the crack formation is significantly related to large-angle grain boundaries,rapid cooling *** caused by large-angle grain boundaries and a fast-cooling rate predominantly appear near the edge of the deposited *** cracks are more likely to form near the top of the deposited sample,due to the presence ofγ/γ'*** secondary dendritic arm and the carbides in the interdendritic regions can obstruct liquid flow during the final stage of solidification,which results in the formation of solidification cracks and *** work paves the way to avoid cracks in nickel-based superalloys fabricated by DED,thereby enhancing the performance of superalloys.

关键词： location cracks direct energy deposition nickel-based superalloys

Risk factors for diabetic retinopathy in northern Chinese patients with type 2 diabetes mellitus

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International Journal of Ophthalmology(English edition) 2016年第8期9卷 1194-1199页

作者： Zhi-Peng Yan jing-xue ma Department of Ophthalmology the Third Hospital of Hebei Medical University Department of Ophthalmology the Second Hospital of Hebei Medical University

AIM: To investigate the prevalence and risk factors of diabetic retinopathy (DR) in northern Chinese patients with type 2 diabetes mellitus (T2DM). METHODS: This retrospective cross-sectional study was performed between may 2011 and April 2012. A total of 1100 patients (male/female, 483/617) were included in this study. DR was defined following the Early Treatment Diabetic Retinopathy Study (ETDRS) severity scale. All included patients accepted a comprehensive ophthalmic examination including retinal photographs. Logistic regression models were used to estimate odds ratios (ORs) and 95% confidence interval (CI) after adjusting for age and gender. RESULTS: Retinopathy was present in 307 patients with a prevalence of 27.9%. In univariate logistic analysis, presence of DR was associated with longer duration of diabetes (OR, 5.70; 95% CI, 2.91-12.56), higher concentration of fasting blood glucose (OR, 12.94; 95% CI, 2.40-67.71), higher level of glycosylated hemoglobin HbA1c (OR, 5.50; 95% CI, 3.78-11.97) and insulin treatment (OR, 6.99; 95%Cl, 1.39-35.12). The lifestyle of patients with T2DM including smoking, alcohol consumption and regular exercise seemed not associated with the development of DR. CONCLUSION: Our study suggests that fasting serum glucose concentration, HbA1c level, duration of diabetes and insulin treatment are potential risk factors for DR in northern Chinese patients with T2DM, while the lifestyle of included patients seems not associated with DR.

关键词： diabetic retinopathy type 2 diabetes mellitus risk factors lifestyle

The Forecast Skills and Predictability Sources of marine Heatwaves in the NUIST-CFS1.0 Hindcasts

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Advances in Atmospheric Sciences 2024年第8期41卷 1589-1600页

作者： jing ma Haiming XU Changming DONG jing-Jia LUO Collaborative Innovation Center on Forecast and Evaluation of Meteorological Disasters/KLME/ILCEC/Institute of Climate and Application Research(ICAR) Nanjing University of Information Science and TechnologyNanjingJiangsu 210044China

Using monthly observations and ensemble hindcasts of the Nanjing University of Information Science and Technology Climate Forecast System(NUIST-CFS1.0) for the period 1983–2020, this study investigates the forecast skill of marine heatwaves(MHWs) over the globe and the predictability sources of the MHWs over the tropical oceans. The MHW forecasts are demonstrated to be skillful on seasonal-annual time scales, particularly in tropical oceans. The forecast skill of the MHWs over the tropical Pacific Ocean(TPO) remains high at lead times of 1–24 months, indicating a forecast better than random chance for up to two years. The forecast skill is subject to the spring predictability barrier of El Nino-Southern Oscillation(ENSO). The forecast skills for the MHWs over the tropical Indian Ocean(TIO), tropical Atlantic Ocean(TAO), and tropical Northwest Pacific(NWP) are lower than that in the TPO. A reliable forecast at lead times of up to two years is shown over the TIO, while a shorter reliable forecast window(less than 17 months) occurs for the TAO and ***, the forecast skills for the TIO, TAO, and NWP are seasonally dependent. Higher skills for the TIO and TAO appear in boreal spring, while a greater skill for the NWP emerges in late summer-early autumn. Further analyses suggest that ENSO serves as a critical source of predictability for MHWs over the TIO and TAO in spring and MHWs over the NWP in summer.

关键词： marine heatwaves NUIST-CFS1.0 hindcasts forecast skill predictability source ENSO

Interlayer material technology of manganese phosphate toward and beyond electrochemical pseudocapacitance over energy storage application

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Journal of materials Science & Technology 2021年第12期71卷 109-128页

作者： Xu Bao Wei-Bin Zhang Qiang Zhang Lun Zhang xue-jing ma Jianping Long College of materials and Chemistry&Chemical Engineering Chengdu University of TechnologyChengdu 610059China

manganese phosphates have shown excellent performances and great potential in electrochemical energy storage,which are demonstrated by research works published in recent *** manganese phosphates,the open-framework structures with large channels and cavities endow them with good ion conductivity and charge storage *** this review,we present the recent progress on manganese phosphates,by focusing on their advantages/disadvantages and potential applications as a new class of electrode materials in *** structural characteristics,synthesis methods,and mineral sources to prepare these manganese phosphates are investigated,together with the modification,as they strongly affect the electrochemical energy storage *** are paid to those hybrid-type materials,where strong synergistic effects *** the summary,interlayer engineering for the manganese phosphates and hybrid-types are proposed and discussed.

关键词： manganese phosphate Layer structure Interlayer technology Pseudocapacitance Supercapacitor Energy storage

Interdecadal Variations of ENSO Impacts over the Indo-Northwest Pacific Region and the Related Mechanisms

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Journal of Meteorological Research 2024年第2期38卷 235-248页

作者： Hongxia LAN jing ma Haiming XU jingjia LUO Collaborative Innovation Center on Forecast and Evaluation of Meteorological Disasters(CIC-FEMD)/Key Laboratory of Meteorological Disaster Ministry of Education/Joint International Research Laboratory of Climate and Environment Change(KLME/ILCEC)Nanjing University of Information Science&TechnologyNanjing 210044 School of Atmospheric Sciences Nanjing University of Information Science&TechnologyNanjing 210044

Owing to limited observations,it remains unknown whether the impact of El Niño-Southern Oscillation(ENSO)on the Indian Ocean-Northwest Pacific(IO-NWP)climate showed decadal changes in the early 20th *** multi-source reanalysis and hindcast datasets from the ECMWF and NOAA extending back to 1901,this study investigates interdecadal variations of the impact of ENSO on the IO-NWP climate from 1901 to *** is found that the influence of ENSO on the IO-NWP climate shows“strong-weak-strong”interdecadal change during *** is characterized by much weaker Indian Ocean sea surface temperature(SST)warming and a weaker NWP subtropical anticyclone(NWPSA)in the following summer of El Ni?o during 1946-1967,compared with those in the other two periods(1901-1945 and 1968-2009).Analyses of the datasets indicate that the interdecadal variation is mainly associated with the change in ENSO *** contrast to the period of 1946-1967,a greater SST variance occurred in the central-eastern equatorial Pacific during 1901-1945 and 1968-2009.A stronger El Ni?o tends to generate more significant anticyclonic anomalies over the southeast Indian Ocean through *** northwesterly anomalies to the south of the anticyclone weaken the southeast trade winds and warm the south Indian Ocean SST via wind-evaporation-SST feedback,and the positive south Indian Ocean SST anomalies trigger westward-propagating oceanic Rossby waves to induce stronger warming of the southwest Indian Ocean,leading to a significant asymmetric wind pattern across the equator in *** profound northeastward winds on the north side weaken the southwest monsoon,leading to a“second warming”over the north Indian Ocean in summer,which anchors the eastward-propagating warm Kelvin waves and results in a stronger NWPSA by inducing surface divergence and suppressing deep convection.

关键词： ENSO Indo-Northwest Pacific Northwest Pacific subtropical anticyclone decadal changes

Diverse foraging strategies of breeding Swinhoe's Storm-petrel in the productive marginal sea of the Northwest Pacific

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Avian Research 2024年第1期15卷 27-34页

作者： Yachang Cheng Lei Zhu Lin xue Shisheng ma Nan Jia Shaoping Zang Zhihai Cao jing Yuan Yang Liu State Key Laboratory of Biocontrol School of EcologySun Yat-sen UniversityShenzhen 518107China Guangxi mangrove Research Center Guangxi Marine Academy of SciencesNanning 530021China Qingdao Bird Watch Society Qingdao 266121China Jiangsu Provincial Environmental Monitoring Center Nanjing 210019China marine Science and Engineering Qingdao Agricultural UniversityQingdao 266109China Ministry of Education Key Laboratory for Biodiversity Science and Ecological Engineering Fudan UniversityShanghai 200433China Qingdao marine management and Support Centre Qingdao 266555China management Committee of Lingshan Island Provincial Nature Reserve Qingdao 266428China

Understanding the foraging behavior is essential for investigating seabird ecology and conservation,as well as monitoring the well-being of the marine *** seabirds adopt diverse foraging strategies to maximize energy gains and cope with the intensified challenges of parenting and *** tradeoff may stem from the heterogeneity of food resources and the constraints of central place ***,abundant marine productivity could alleviate the energy limitation for seabirds,resulting in a consistent foraging ***,we investigated the foraging strategy during the breeding season of a cryptic small-sized seabird,Swinhoe’s Storm-petrel(Hydrobates monorhis),in the Yellow Sea,a productive marginal sea of the Northwest *** GPS tracking,we evaluated habitat preference,quantified the foraging strategy,and tested if environmental conditions and individual traits influence foraging *** found that Swinhoe’s Storm-petrels preferred nearshore areas with shallow water and engaged in primarily short foraging *** southeastward and southwestward strategies emerged when combining trip metrics,including foraging direction,duration,and maximum *** bathymetry,proximity to the coastline,and sea surface temperature differed in two foraging *** strategies exhibited flexibility between individuals,potentially explained by wing morphology,in which longer-winged birds are more likely to embark on longer-distance foraging *** findings highlight the impact of environmental factors and individual traits on seabirds’foraging decisions in productive marginal sea *** study also provides valuable insights into the foraging ecology of this Asian endemic storm-petrel.

关键词： Behavioral strategy Biologging Central place foraging marine primary productivity Seabird Sea surface temperature