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Pt nanoclusters modified porous g-C_(3)N_(4)nanosheets to significantly enhance hydrogen production by photocatalytic water reforming of methanol

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Chinese Journal of Chemical Engineering 2024年第2期66卷 40-50页

作者： Yi-Fei Liang jin-Rong Lu Shang-Kun Tian Wen-Quan Cui Li Liu Hebei Provincial Key Laboratory of Environmental Photocatalytic and Electrocatalytic Materials College of Chemical EngineeringNorth China University of Science and TechnologyTangshan 063210China

For the use of green hydrogen energy,it is crucial to have efficient photocatalytic activity for hydrogen generation by water reforming of methanol under mild *** attention has been paid to gC_(3)N_(4)as a promising photocatalyst for the generation of *** improve the separation of photogenerated charge,porous nanosheet g-C_(3)N_(4)was modified with Pt nanoclusters(Pt/g-C_(3)N_(4))through impregnation and following photo-induced *** catalyst showed excellent photocatalytic activity of water reforming of methanol fo r hydrogen production with a 17.12 mmol·g^(-1)·h^(-1)rate at room temperature,which was 311 times higher than that of the unmodified g-C_(3)N_(4).The strong interactions of Pt-N in Pt/g-C_(3)N_(4)constructed effective electron transfer channels to promote the separation of photogenerated electrons and holes *** addition,in-situ infrared spectroscopy was used to investigate the intermediates of the hydrogen production reaction,which proved that methanol and water eventually turn into H_(2)and CO_(2)via formaldehyde and *** study provides insights for understanding the photocatalytic hydrogen production in the water reforming of methanol.

关键词： Water reforming of methanol Photocatalysis g-C_(3)N_(4) Pt nanoclusters Hydrogen production

Remodeling the tumor microenvironment by vascular normalization and GSH-depletion for augmenting tumor immunotherapy

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Chinese Chemical Letters 2024年第2期35卷 329-334页

作者： jin Wang Qingqing Zhang Yanchen Li Xiaoyan Pan Yuanyuan Shan Jie Zhang School of Pharmacy Health Science CenterXi'an Jiaotong UniversityXi'an 710061China Department of Pharmacy The First Affiliated Hospital of Xi'an Jiaotong UniversityXi'an 710061China

Remodeling tumor microenvironment(TME)is a very promising and effective strategy to enhance the effects of chemotherapy,photodynamic therapy,and *** of tumor vasculature as well as depletion of glutathione(GSH)can improve the ***,we developed a novel therapeutic nanoparticle functional enzyme ultra QDAU5 nanoparticles(FEUQ Nps)based on a fluorescence-on and releasable strategy by combining a vascular normalization inducer,a GSH depleting agent,and an activated *** which the cleavage of disulfide bonds releases active molecules that induce vascular normalization and improve the hypoxic *** addition,it may deplete GSH in cancer cells,thus inducing the production of reactive oxygen species(ROS)and lipid peroxide(LPO)and promoting iron *** may also lead to endoplasmic stress and release of calmodulin,which activates the immune ***,quenched fluorophores are turned on in the presence of galactosidase(GLU)for tumor-specific *** summary,we developed novel therapeutic agent nanoparticles with the function of vascular normalization inducers to achieve specific labeling of hepatocellular carcinoma while exerting efficient antitumor effects in vivo.

关键词： Vascular normalization Tumor microenvironment GSH depletion Ferroptosis Activated immune

Detwinning and Anneal-Hardening Behaviors of Pre-Twinned AZ31 Alloys under Cryogenic Loading

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Acta Metallurgica Sinica(English Letters) 2024年第9期37卷 1551-1563页

作者： Lingyu Zhao Wei Zhu Chao Zhang Yunchang Xin Changjian Yan Yao Cheng Zhaoyang jin School of Mechanical Engineering Yangzhou UniversityYangzhou225127China Key Laboratory for Light-Weight Materials Nanjing Tech UniversityNanjing210009China Institute of Corrosion Science and Technology Guangzhou510070GuangdongChina Jiangsu Key Laboratory of Advanced Structural Materials and Application Technology Nanjing Institute of TechnologyNanjing211167China

Detwinning behavior of a pre-twinned magnesium alloy AZ31 at cryogenic temperature was investigated,also with a focus on the annealing hardening behavior of samples with different fractions of ***-compression along the transverse direction with strains of 1.7%,3.0%,and 6.0% was applied to generated[1012]*** behavior,microstructure,and texture evolution during subsequent tension were *** results show that low temperature did not change the fact that detwinning still pre-dominated in the pre-twinned samples under reverse ***,a relatively harder migration of twin boundaries was found at cryogenic *** annealing hardening of 27-40 MPa was observed in the pre-twinned samples,and such a hardening effect shows a close relation with the fraction of pre-twins or the level of *** annealing hardening effect disappeared if the matrix was consumed by twins along with the increased pre-compression *** corresponding reasons for the annealing hardening behavior were discussed.

关键词： Mg alloys Detwinning Annealing hardening Cryogenic temperature Mechanical property

A Novel High-Efficiency Transaction Verification Scheme for Blockchain Systems

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Computer Modeling in Engineering & Sciences 2024年第5期139卷 1613-1633页

作者： jingyu Zhang Pian Zhou jin Wang Osama Alfarraj Saurabh Singh Min Zhu School of Computer&Communication Engineering Changsha University of Science&TechnologyChangsha410015China Science and Technology on Information Systems Engineering Laboratory School of Systems EngineeringNational University of Defense TechnologyChangsha410073China Computer Science Department King Saud UniversityRiyadh11437Saudi Arabia Department of Artificial Intelligence and Big Data Woosong UniversityDaejeon34606South Korea College of Information Science and Technology Zhejiang Shuren UniversityHangzhou310015China

Blockchain can realize the reliable storage of a large amount of data that is chronologically related and verifiable within the *** technology has been widely used and has developed rapidly in big data systems across various *** increasing number of users are participating in application systems that use blockchain as their underlying *** the number of transactions and the capital involved in blockchain grow,ensuring information security becomes *** the verification of transactional information security and privacy has emerged as a critical ***-based verification methods can effectively eliminate the need for centralized third-party ***,the efficiency of nodes in storing and verifying blockchain data faces unprecedented *** address this issue,this paper introduces an efficient verification scheme for transaction ***,it presents a node evaluation module to estimate the activity level of user nodes participating in transactions,accompanied by a probabilistic analysis for all ***,this paper optimizes the conventional transaction organization form,introduces a heterogeneous Merkle tree storage structure,and designs algorithms for constructing these heterogeneous *** analyses and simulation experiments conclusively demonstrate the superior performance of this *** verifying the same number of transactions,the heterogeneous Merkle tree transmits less data and is more efficient than traditional *** findings indicate that the heterogeneous Merkle tree structure is suitable for various blockchain applications,including the Internet of *** scheme can markedly enhance the efficiency of information verification and bolster the security of distributed systems.

关键词： Blockchain architecture transaction verification information security heterogeneous Merkle tree distributed systems

Enhancing blocking temperature using inverse hydrogen bonds for non-radical bridged dimeric Dy(Ⅲ)single-molecule magnets

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Science China Chemistry 2024年第10期67卷 3328-3338页

作者： Peng-Bo jin Qian-Cheng Luo Ye-Ye Liu Yan-Zhen Zheng Frontier Institute of Science and Technology State Key Laboratory of Electrical Insulation and Power EquipmentMOE Key Laboratory for Nonequilibrium Synthesis and Modulation of Condensed MatterXi’an Key Laboratory of Electronic Devices and Material Chemistry and School of ChemistryXi’an Jiaotong UniversityXi’an 710054China

Single-molecule magnets(SMMs)are a kind of nanosized magnetic materials that are capable of storing massive bytes of *** coupling the spin centers in a proper manner is a usual approach to promote the working temperature(or blocking temperature)for *** delocalized radicals have been widely employed to accomplish this ***,we show a new manner by using weak but multiple B–H^(δ-)···Dy^(3+)inverse hydrogen bonding(IHB)interactions to control the magnetic couplings in a series of dimeric dysprosiacaborane *** approach leads to a record high T_(B)^(100s)of 10 K among non-radical bridged dimeric SMMs,which is mainly ascribed to strong ferromagnetic coupling(4.38 cm^(-1))and the proper alignment of the magnetic principle axes of the adjacent dysprosium(Ⅲ)*** verifying by theoretical calculations,these results demonstrate that IHB interactions can be used to construct strong axial ferromagnetic coupling and enhancing magnetic blocking temperature for SMMs.

关键词： single-molecule magnets carborane dysprosium ferromagnetic coupling inverse hydrogen bond

Effect of temperature and reaction path interaction on fluidization reduction kinetics of iron ore powder

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Journal of Iron and Steel Research International 2024年第8期31卷 1840-1849页

作者： Guo-min Zhu Ming-wei Hu An-nan Dou jin-yu Huang jing Ding Qi-yan Xu School of Metallurgical Engineering Anhui University of TechnologyMa'anshan 243002AnhuiChina

Due to the instability of FeO at temperatures below 843 K,the fuidization reduction pathway of iron ore powder changes with the reduction ***,the effect of temperature and reaction pathway interaction on the kinetics of fuidization reduction of iron ore powder under low-temperature conditions ranging from 783 to 903 K was investigated to describe the fluidization reduction rate of iron ore powder from three aspects:microstructure change,reaction limiting link,and apparent activation energy of the reaction,exploring their internal *** experimental results revealed that in a temperature range of 783-813 K,the formation of a dense iron layer hindered the internal diffusion of reducing gas,resulting in relatively high gas diffusion *** addition,due to the differences in limiting links and reaction pathways in the intermediate stage of reduction,the apparent activation energy of the reaction *** apparent activation energy of the reaction ranged from 23.36 to 89.13 kJ/mol at temperature ranging from 783 to 813 K,while it ranged from 14.30 to 68.34 kJ/mol at temperature ranging from 873 to 903 K.

关键词： Reaction limiting link Gas internal diffusion Interface reaction Apparent activation energy Iron ore powder Reaction pathway Fluidization reduction

Active molecule-based theranostic agents for tumor vasculature normalization and antitumor efficacy

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Chinese Chemical Letters 2024年第8期35卷 229-234页

作者： jin Wang Xiaoyan Pan Junyu Zhang Qingqing Zhang Yanchen Li Weiwei Guo Jie Zhang School of Pharmacy Health Science CenterXi’an Jiaotong UniversityXi’an 710061China Center of Advanced Pharmaceuticals and Biomaterials State Key Laboratory of Natural MedicineChina Pharmaceutical UniversityNanjing 210009China

Tumor vascular normalization has emerged as a promising strategy for synergistic therapy *** on the strategy of“fluorescence turn on-controllable release”,a novel bifunctional candidate was con-structed based on previous developed vascular normalization inducer QDAU5,which could self-assemble to form functional enzyme infrared QDAU5 nanoparticles(FEIRQ NPs).Subsequently,biological evaluation demonstrated that the FEIRQ NPs could induce ferroptosis,endoplasmic reticulum stress,and antigen pre-conditioning and maturation of dendritic cells and CD8^(+)T cells,leading to excellent antitumor efficacy in the absence of cytotoxic ***,FEIRQ NPs show high fluorescence intensity upon expo-sure to theβ-galactosidase(β-Gal)enzyme expressed in ovarian cancer,enabling real-time monitoring of therapeutic ***,our findings suggest a prospering strategy to early diagnosis and efficient therapy for ovarian cancer without cytotoxicity.

关键词： Tumor vasculature normalization Diagnosis and treatment Cytotoxicity Depleting glutathione Ferroptosis Immune activation

Fabrication of telechelic DNA-bridged food emulsion gel as edible ink for 3D printing

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Food Quality and Safety 2024年第1期8卷 158-165页

作者： Ruyuan Zhang Hao Huang Rong Ai Dong Li Yanqun Xu Weiwei jin Zisheng Luo College of Biological Chemical Sciences and Engineering Jiaxing UniversityJiaxingChina College of Biosystems Engineering and Food Science Zhejiang UniversityHangzhouChina College of Ecology Lishui UniversityLishuiChina Ningbo Innovation Center Zhejiang UniversityNingboChina Wenzhou Academy of Agriculture Science Liuhongqiao Road 1000WenzhouChina Key Laboratory of Agro-Products Postharvest Handling of Ministry of Agriculture and Rural Affairs Zhejiang Key Laboratory for Agri-Food ProcessingHangzhouChina

Objectives:Interdroplet interactions affect the properties and textures of *** this study,we creatively introduced telechelic DNA to link oil droplets directly at molecular scale to further improve the viscoelastic properties of *** and Methods:A stable emulsion with 70%oil fraction was prepared by adding 40 mg/mL of whey protein isolate and peach gum polysaccharide complex(WPI–PGP complex).The addition of telechelic DNA(0.125–0.375μmol/L)made the emulsion change from a cream-like state to a self-supporting ***:Rheological experiments confirmed that the telechelic DNA could improve the yield stress,storage modulus/loss modulus(Gʹ/Gʹʹ)and apparent viscosity of the emulsion gel in a concentration-dependent manner(0–0.375μmol/L).Inverted fluorescence images clearly showed the interdroplet network of the emulsion gel linked by telechelic *** 3D printing,the emulsion gel with a higher concentration(0.375μmol/L)of telechelic DNA displayed better surface quality and dimensional resolution,indicating improved ***:This study successfully designed a novel telechelic DNA-bridged emulsion gel,which showed great potential as edible ink for 3D printing.

关键词： Telechelic DNA WPI-PGP complex emulsion gel interdroplet interactions 3D printing.

Mitigation of Optical Multipath Interference Algorithms in IM-DD Transmission System

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China Communications 2024年第4期21卷 1-9页

作者： Huo Jiahao Zhu jin Zhu Zuqing Zhang Xiaoying Liu Shaonan Tao Jianlong Wei Huangfu School of Computer and Communication Engineering University of Science and Technology BeijingBeijing 100083China School of Information Science and Technology University of Science and Technology of ChinaHefei 230026China

This paper aimed to propose two algorithms,DA-M and RF-M,of reducing the impact of multipath interference(MPI)on intensity modulation direct detection(IM-DD)systems,particularly for four-level pulse amplitude modulation(PAM4)***-M reduced the fluctuation by averaging the signal in blocks,RF-M estimated MPI by subtracting the decision value of the corresponding block from the mean value of a signal block,and then generated interference-reduced samples by subtracting the interference signal from the product of the corresponding MPI estimate and then weighting *** paper firstly proposed to separate the signal before decision-making into multiple blocks,which significantly reduced the complexity of DA-M and *** results showed that the MPI noise of 28 GBaud IMDD system under the linewidths of 1e5 Hz,1e6 Hz and 10e6 Hz can be effectively alleviated.

关键词： IM-DD multipath interference PAM4