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Chinese Chemical Letters 2024年第6期35卷 161-167页

作者： Ya Song Mingxia Zhou Zhu Chen Huali Nie jiao-jing shao Guangmin Zhou School of Materials and Metallurgy Guizhou UniversityGuiyang 550025China Medical College of Guizhou University Guiyang 550025China College of Biological Science and Medical Engineering Donghua UniversityShanghai 201620China Shenzhen Geim Graphene Center Tsinghua Shenzhen International Graduate SchoolTsinghua UniversityShenzhen 518055China

The practical application of high-energy-density lithium-sulfur(Li-S)batteries have been highly praised for energy storage devices,while are largely hindered by the“shuttling effect”.Herein,core-shell carbon spheres composed of interlinked porous core and lamellar shell were designed to restrain the polysulfide *** microporous structure with pore size of around 1 nm effectively trap lithium ***,the interconnected porous core shortens the ion transfer distance and the lamellar carbon shell endows the carbon spheres with fast electron conduction,finally facilitating polysulfide conversion ***,the Li-S batteries with the carbon spheres as the interlayer show high discharge specific capacity of 1002 m Ah/g at 2 C with 574 m Ah/g remaining after 600 cycles,and high areal capacity of 5.48 m Ah/cm^(2) with sulfur loading of 4.67 mg/cm^(2) at 0.1 *** corresponding pouch cells also exhibit stable cycling stability with an initial discharge specific capacity of 1082 m Ah/g at 0.1 C.

关键词： Interlayer Shuttle effect Strong adsorption Porous carbon spheres Lithium-sulfur batteries

Mixed‑Dimensional Assembly Strategy to Construct Reduced Graphene Oxide/Carbon Foams Heterostructures for Microwave Absorption,Anti‑Corrosion and Thermal Insulation

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Nano-Micro Letters 2024年第11期16卷 1-18页

作者： Beibei Zhan Yunpeng Qu Xiaosi Qi Junfei Ding jiao‑jing shao Xiu Gong jing‑Liang Yang Yanli Chen Qiong Peng Wei Zhong Hualiang Lv College of Physics Guizhou Province Key Laboratory for Photoelectrics Technology and ApplicationGuizhou UniversityGuiyang City 550025People’s Republic of China College of Materials and Metallurgy Guizhou UniversityGuiyang City 550025People’s Republic of China National Laboratory of Solid State Microstructures and Jiangsu Provincial Laboratory for NanoTechnology Nanjing UniversityNanjing 210093People’s Republic of China Department of Materials Science and Laboratory of Advanced Materials Fudan UniversityShanghai 200433People’s Republic of China

Considering the serious electromagnetic wave(EMW)pollution problems and complex application condition,there is a pressing need to amalgamate multiple functionalities within a single ***,the effective integration of diverse functions into designed EMW absorption materials still faces the huge ***,reduced graphene oxide/carbon foams(RGO/CFs)with two-dimensional/three-dimensional(2D/3D)van der Waals(vdWs)heterostructures were meticulously engineered and synthesized utilizing an efficient methodology involving freeze-drying,immersing absorption,secondary freeze-drying,followed by carbonization *** to their excellent linkage effect of amplified dielectric loss and optimized impedance matching,the designed 2D/3D RGO/CFs vdWs heterostructures demonstrated commendable EMW absorption performances,achieving a broad absorption bandwidth of 6.2 GHz and a reflection loss of-50.58 dB with the low matching ***,the obtained 2D/3D RGO/CFs vdWs heterostructures also displayed the significant radar stealth properties,good corrosion resistance performances as well as outstanding thermal insulation capabilities,displaying the great potential in complex and variable ***,this work not only demonstrated a straightforward method for fabricating 2D/3D vdWs heterostructures,but also outlined a powerful mixeddimensional assembly strategy for engineering multifunctional foams for electromagnetic protection,aerospace and other complex conditions.

关键词： Multifunctionality Reduced graphene oxide/carbon foams 2D/3D van der Waals heterostructures Electromagnetic wave absorption Thermal insulation

Two-dimensional silica enhanced solid polymer electrolyte for lithium metal batteries

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Particuology 2024年第2期85卷 146-154页

作者： Zhihong Luo Weiyong Li Chong Guo Ya Song Mingxia Zhou Yan Shi jing Xu Long Li Bin Shi Quansheng Ouyang jiao-jing shao Guangmin Zhou School of Materials and Metallurgy Guizhou UniversityGuiyang550025China State Key Laboratory of Advanced Chemical Power Sources Zunyi563003China Graphene Materials Engineering Research Center of Guizhou Colleges and Universities Guiyang550025China Tsinghua-Berkeley Shenzhen Institute&Tsinghua Shenzhen International Graduate Schoo Tsinghua UniversityShenzhen518055China

Solid polymer electrolytes(SPEs)are promising substitutes for current flammable liquid electrolytes to achieve high-safety and high-energy-density lithium metal *** oxide(PEO)based solid polymer electrolytes have attracted increasing attention because of their excellent flexibility,manufacturability,light weight,and low-cost processing,while they often suffer from low ionic con-ductivity at room temperature,low lithium transference number and unsatisfactory interfacial resis-tance,which largely restrain their practical ***,two-dimensional holey silica nanosheets(2D-HSN)as the fillers,together with LiNO_(3) as the electrolyte additive,are introduced in a PEO/poly(-vinylidene fiuoride-co-hexafluoropropylene)(PVDF-HFP)blended polymer matrix to obtain a *** incorporation of HSN filler creates supplementary channels for lithium ion migration and lowers the crystallinity of the polymer,thereby facilitating the movement of lithium *** HSN-based SPE demonstrates higher ionic conductivity up to 3.7 x 10-4 S cm-1 at 30℃,larger Li+transference number close to 0.34,and more stable lithium plating/stripping than that without the fillers,and HSN can promote the formation of more stable solid electrolyte interphase(SEI)*** as-assembled LiFePO4||Li batteries deliver a high specific capacity of 159 mA h g-1 with the capacity retention of 95.5%after 200 cycles at 30℃,as well as superior rate performance and cycling stability compared to that using the blank SPE.

关键词： Vermiculite nanosheets Two-dimensional silica Solid polymer electrolytes FillersLithium metal batteries

Rationalizing the impact of oxygen vacancy on polysulfide conversion kinetics for highly efficient lithium-sulfur batteries

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Journal of Energy Chemistry 2023年第12期87卷 51-60,I0003页

作者： Ya Song Huan Li Junfeng Li Jinyu An jiao-jing shao Guangmin Zhou School of Materials and Metallurgy Guizhou UniversityGuiyang 550025GuizhouChina School of Chemical Engineering and Advanced Materials The University of AdelaideAdelaideSA 5005Australia Shenzhen Geim Graphene Center Tsinghua Shenzhen International Graduate SchoolTsinghua UniversityShenzhen 518055GuangdongChina College of Civil Engineering Guizhou UniversityGuiyang 550025GuizhouChina

The“shuttle effect”of lithium polysulfides(LiPSs)is a huge challenge for practical use of high-energydensity lithium-sulfur(Li-S)batteries,and one of the main reasons is the sluggish kinetics of sulfur *** oxides are able to expedite the sulfur electrochemistry,and the structural defects enhance the adsorption-conversion ability of metal oxides for ***,a significant research gap still remains regarding the relationship between the oxygen vacancy concentration and the adsorptivecatalytic performance of metal ***,we establish a correlation between oxygen vacancy concentration and adsorptive-catalytic properties by using tungsten oxide(WO_(x))as model *** is revealed that high-concentration oxygen vacancy is beneficial for enhancing the binding between tungsten oxide and LiPSs,reducing the energy barrier of Li_(2)S decomposition,and promoting polysulfide conversion ***,the Li-S batteries using the tungsten oxide with high-concentration oxygen vacancies deliver high initial discharge capacity of 1169 mA h g^(-1)at 0.2 C and 865 mA h g^(-1)at 2 C,low attenuation rate of 0.064%per cycle over 1100 cycles at 2 *** a high sulfur area loading of 5.34 mg cm^(-2),the Li-S batteries still exhibit high initial gravimetric capacity of 982 mA h g^(-1)at 0.1 C and areal capacity of 5.92 mA h cm^(-2).This work promotes the feasibility of defect engineering on metal oxides as an effective mean to enhance the practicality of Li-S batteries.

关键词： Shuttl eeffect Oxygen vacancy Interlayer Lithium-sulfur batteries

Patterns and drivers of seasonal water sources for artificial sand-fixing plants in the northeastern Mu Us sandy land,Northwest China

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Pedosphere 2024年第1期34卷 63-77页

作者： Yanwu PEI Laiming HUANG Ming'an shao jiao WANG Yinglong ZHANG Yellow River Delta Modern Agricultural Engineering Laboratory Institute of Geographic Sciences and Natural Resources ResearchChinese Academy of SciencesBeijing 100101China College of Natural Resources and Environment Northwest Agriculture and Forestry UniversityYangling 712100China State Key Laboratory of Urban and Regional Ecology Research Center for Eco-Environmental Sciences of Chinese Academy of SciencesBeijing 100085China College of Resources and Environment University of Chinese Academy of SciencesBeijing 100049China Shenmu Ecological Association Shenmu 719399China

Understanding plant water-use patterns is important for improving water-use efficiency and for sustainable vegetation restoration in arid and semi-arid regions. However, seasonal variations in water sources and their control by different sand-fixing plants in water-limited desert ecosystems remain poorly understood. In this study, stable isotopic ratios of hydrogen(δ^(2)H) and oxygen(δ^(18)O) in precipitation, soil water, groundwater, and xylem water were determined to document seasonal changes in water uptake by three representative plant species(Pinus sylvestris var. mongolica Litv., Amygdalus pedunculata Pall., and Salix psammophila) in the northeastern Mu Us sandy land, Northwest China. Based on the depth distribution and temporal variation of measured gravimetric soil water content(SWC), the soil water profile of the three species stands was divided into active(0.01 g g^(-1)45%) layers. Annually, P. sylvestris, A. pedunculata, and S. psammophila obtained most water from deep(59.2%±9.7%, moist layer and groundwater),intermediate(57.4%±9.8%, stable and moist layers), and shallow(54.4%±10.5%, active and stable layers) sources, respectively. Seasonally, the three plant species absorbed more than 60% of their total water uptake from the moist layer and groundwater in the early(June) dry season;then, they switched to the active and stable layers in the rainy season(July–September) for water resources(50.1%–62.5%). In the late(October–November) dry season, P. sylvestris(54.5%–66.2%) and A. pedunculata(52.9%–63.6%) mainly used water from stable and moist layers, whereas S. psammophila(52.6%–70.7%) still extracted water predominantly from active and stable layers. Variations in the soil water profile induced by seasonal fluctuations in precipitation and groundwater levels and discrepancies in plant pheno

关键词： desert ecosystem MixSIAR model plant water uptake soil moisture stable isotopes vegetation restoration water-use efficiency

3-D Tunnel Seismic Advance Prediction Method with Wide Illumination and High-Precision

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Journal of Earth Science 2024年第3期35卷 970-979页

作者： Peng Guan Cuifa shao Yuyong jiao Guohua Zhang Junpeng Zou Fei Tan Faculty of Engineering China University of GeosciencesWuhan 430074China

Tunnel seismic advance prediction can effectively reduce the construction risk during tunnel *** with the 2-D method,the 3-D method is more conducive to describing the spatial characteristics of the geological body by adding the seismic data in the vertical ***,some drawbacks still need improvement in the current 3-D tunnel seismic prediction method.(1)The geometry is complex,which is destructiveness,high cost,and time-consuming,and will delay the tunnel construction schedule.(2)Illumination of the anomalous body is insufficient,and the precision of migration imaging is low.(3)Shot points are far away from the tunnel face,the energy loss at the shot points is more serious.(4)The received signals at the tunnel wall have the surface wave with strong energy when the shot points are placed on the tunnel wall.(5)The geometry is not linear,so the directional filtering method cannot be used to extract the reflection *** overcome the drawbacks of the current prediction method,a new 3-D symmetrical tunnel seismic prediction method is *** geophones are installed on the tunnel wall,two on the left side,two on the right side,and two on the top ***-four shot points are placed on the tunnel face and near both sides of the tunnel wall,twelve shot points on the left side and twelve shot points on the right *** shot points will move along with the forward excavation of the *** wavefield analysis,illumination statistics,and 3-D reverse time migration imaging are used to evaluate the proposed *** result of modeled data indicates that the proposed 3-D geometry has some advantages:(1)the geometry is simple and the geophone installation time is short;(2)it has high illumination energy,wide illumination range,and can improve the prediction distance and imaging accuracy;(3)the proposed 3-D method can better estimate the velocity of surrounding rock and is more conducive to extracting the reflection wave with high resolut

关键词： tunnels excavation geophone shot points migration imaging method engineering ge-ology.

Highly active and durable core-shell electrocatalysts for proton exchange membrane fuel cells

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Nano Research 2024年第10期17卷 8772-8784页

作者： Hsiwen Wu Fei Xiao jing Wang Meng Gu Minhua shao Department of Chemical and Biological Engineering The Hong Kong University of Science and TechnologyClear Water BayHong KongChina Department of Materials Science and Engineering Southern University of Science and TechnologyShenzhen 518055China Fok Ying Tung Research Institute The Hong Kong University of Science and TechnologyGuangzhou 511458China Energy Institute and Chinese National Engineering Research Center for Control&Treatment of Heavy Metal Pollution The Hong Kong University of Science and TechnologyClear Water BayHong KongChina

This work presents simple post-treatment methods to selectively and partially remove the Pd core of Pd-Pt core–shell(Pt@Pd/C)*** proton exchange membrane fuel cell with the post-treated Pt@Pd/C cathode(Pt loading:0.10 mg·cm^(-2))delivers an impressive peak power density of 1.2 W·cm^(-2).The partial removal of Pd core endows an ultrahigh oxygen reduction reaction(ORR)mass activity of 0.32 A·g_(PGM)-1 when normalized to the platinum group metal(PGM)mass,or equivalently 0.55 A·mg_(Pt)^(-1) at 0.9 V measured in a fuel *** post-treatment thickens the Pt shells and mitigates the Pd dissolution during potential *** a result,the post-treated core-shell catalyst demonstrates superior durability in ORR mass activity and polarization power density retention than untreated core-shell catalyst and benchmark Pt/***-situ inductively coupled plasmamass spectrometry(ICP-MS)results highlight that the amount of dissolved Pd in post-treated core–shell catalyst is 17-times lower than that of the untreated *** findings highlight the importance of structural tuning of catalysts in enhancing their mass activity and durability.

关键词： core-shell catalyst platinum monolayer proton exchange membrane fuel cell oxygen reduction reaction durability

Unraveling the role of NiSnPH@OOH/CC perovskite hydroxide for efficient electrocatalytic oxidation of methanol to formate

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Nano Research 2024年第4期17卷 2388-2399页

作者： jing shao Yusheng Fang Xiaobing Wu Muhammad Imran Abdullah Youkun Tao College of Chemistry and Environmental Engineering Shenzhen UniversityShenzhen 518060China School of Science Harbin Institute of TechnologyShenzhen 518055China

The sluggish kinetics of oxygen evolution reaction(OER)is the key tailback for hydrogen production from the water *** OER with thermodynamically auspicious methanol oxidation reaction(MOR)can significantly boost the H_(2) and value-added products ***,it is currently challenging to achieve a synergistic manipulation of product selectivity and performance for MOR ***,we report NiSnPH@OOH/CC(CC=carbon cloth)perovskite hydroxide nanosphere as an efficient MOR electrocatalyst with high activity,stability,and selectivity towards methanol oxidation to formate.A surface amorphous layer of defect rich NiOOH was generated in operando by selective Sn leaching with stable perovskite hydroxide bulk structure,which mitigates the oxidative power and optimizes the local coordination environment of the active NiOOH *** situ Raman combined with electrochemical studies further confirm the key active species,NiOOH,generated in operando enhance the MOR and blocking the over oxidation of methanol to CO_(2).As a result,NiSnPH@OOH/CC effectively masks the OER and attains>99%selectivity with 100%Faradic efficiency for *** results of this study show the advances of NiSnPH@OOH/CC as an efficient electrocatalyst for MOR and also suggest its potential applications for various small organic molecules oxidation.

关键词： perovskite hydroxide small organic molecules nickel oxy(hydroxide) value-added products methanol oxidation reaction

Nonlinear change of ion-induced secondary electron emission in theκ-Al_(2)O_(3) surface charging from first-principle modelling

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Plasma Science and Technology 2024年第9期26卷 40-50页

作者： Zhicheng jiao Mingrui ZHU Dong DAI Tao shao Buang WANG South China University of Technology Guangzhou 510641People’s Republic of China Institute of Electrical Engineering Chinese Academy of SciencesBeijing 100190People’s Republic of China University of Richmond Richmond 23173United States of America

Secondary electron emission(SEE)induced by the positive ion is an essential physical process to influence the dynamics of gas discharge which relies on the specific surface *** charging has a significant impact on the material properties,thereby affecting the SEE in the plasma-surface ***,it does not attract enough attention in the previous *** this paper,SEE dependent on the charged surface of specific materials is described with the computational method combining a density functional theory(DFT)model from the first-principle theory and the theory of Auger *** effect ofκ-Al2O3 surface charge,as an example,on the ion-induced secondary electron emission coefficient(SEEC)is investigated by analyzing the defect energy level and band structure on the charged *** results indicate that,with the surface charge from negative to positive,the SEEC of a part of low ionization energy ions(such as Ei=12.6 eV)increases first and then decreases,exhibiting a nonlinear changing *** is quite different from the monotonic decreasing tendency observed in the previous model which simplifies the electronic *** irregular increase of the SEEC can be attributed to the lower escaped probability of orbital *** results further illustrate that the excessive charge could cause the bottom of the conduction band close to the valence band,thus leading to the decrease of the orbital energy occupied by the excited *** nonlinear change of SEEC demonstrates a more realistic situation of how the electronic structure of material surface influences the SEE *** work provides an accurate method of calculating SEEC from specific materials,which is urgent in widespread physical scenarios sensitive to surface materials,such as increasingly growing practical applications concerning plasma-surface interactions.

关键词： secondary electron emission charged surface density functional theory defect energy level

Anomalous thermal expansion and enhanced magnetocaloric effect in<001>-textured Mn_(x)Fe_(5-x)Si_(3) alloys

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Rare Metals 2024年第5期43卷 2263-2274页

作者： Yong Gong Xue-Fei Miao Tapas Samanta Chris Taake Jun Liu Feng-jiao Qian Yan-Yan shao Yu-jing Zhang Qing-Yong Ren Luana Caron Feng Xu MIIT Key Laboratory of Advanced Metallic and Intermetallic Materials Technology School of Materials Science and EngineeringNanjing University of Science and TechnologyNanjing210094China Department of Physics Bielefeld University33501BielefeldGermany College of Physics Nanjing University of Aeronautics and AstronauticsNanjing210016China Institute of High Energy Physics Chinese Academy of SciencesBeijing100049China Spallation Neutron Source Science Center Dongguan523803China Guangdong-Hong Kong-Macao Joint Laboratory for Neutron Scattering Science and Technology Dongguan523803China Department of Physics Bielefeld University33501BielefeldGermany Helmholtz-Zentrum Berlin für Materialien und Energie12489BerlinGermany

The development of zero and negative therma expansion(i.e.,ZTE and NTE)materials is of crucial importance to the control of undesirable thermal expansion for high-precision *** the present work,ZTE and NTE were obtained in directionally-solidified Mn_(x)Fe_(5-x)Si_(3)alloys with a strongtexture,in striking contrast to positive thermal expansion in their isotropic counterparts Magnetometry and in-situ X-ray diffraction(XRD)measurements were performed to uncover the origin of the anomalous thermal *** measurements indicate a strong easy-plane magnetocrystalline anisotropy in the textured samples,where the magnetic moments are aligned within the ab plane of the hexagonal structure Temperature-dependent XRD on the x=1 sample reveals a ZTE character in the ab plane that is coupled to a ferromagnetic *** a result,the macroscopic ZTE(~0.22×10^(-6)K^(-1))in the x=1 sample can be attributed to the microscopic magneto volume effect within the ab plane,which is realized by the introduction of the-textured ***,the competition between antiferromagnetic and ferromagnetic exchange coupling leads to NTE in textured x=1.5 and 2 ***,textured x=1 sample displays enhanced magnetocaloric properties as compared to the conventional counterparts with randomly-oriented *** this work demonstrates a new strategy toward the exploration of anomalous thermal expansion properties as well as the enhancement of magnetocaloric properties for materials with a strong magnetocrystalline anisotropy.

关键词： MnFeySis Magnetocaloric effect Magnetic phase transition Negative thermal expansion