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Roadmap for rechargeable batteries:present and beyond

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Science China Chemistry 2024年第1期67卷 13-42页

作者： Sen Xin Xu Zhang Lin Wang Haijun Yu Xin Chang Yu-Ming zhao Qinghai Meng Pan Xu Chen-Zi zhao Jiahang Chen Huichao Lu Xirui Kong Jiulin Wang Kai Chen Gang Huang Xinbo Zhang Yu Su Yao Xiao Shu-Lei Chou Shilin Zhang Zaiping Guo Aobing Du Guanglei Cui Gaojing Yang Qing zhao Liubing Dong Dong Zhou Feiyu Kang Hu Hong Chunyi Zhi Zhizhang Yuan Xianfeng Li Yifei Mo Yizhou Zhu Dongfang Yu Xincheng Lei jianxiong zhao Jiayi Wang Dong Su Yu-Guo Guo Qiang Zhang Jun Chen Li-Jun Wan CAS Key Laboratory of Molecular Nanostructure and Nanotechnology CAS Research/Education Center for Excellence in Molecular SciencesBeijing National Laboratory for Molecular Sciences(BNLMS)Institute of ChemistryChinese Academy of Sciences(CAS)Beijing 100190China University of Chinese Academy of Sciences.Beijing 100049 China Institute of Advanced Battery Materials and Devices Faculty of Materials and ManufacturingBeijing University of TechnologyBeijing 100124China Key Laboratory of Advanced Functional Materials Ministry of EducationBeijing University of TechnologyBeijing 100124China Beijing Key Laboratory of Green Chemical Reaction Engineering and Technology Department of Chemical EngineeringTsinghua UniversityBeijing 100084China State Key Laboratory of Chemistry and Utilization of Carbon-Based Energy Resources College of ChemistryXinjiang UniversityUrumqi 830046China Department of Chemical Engineering Shanghai Jiao Tong UniversityShanghai 200240China State Key Laboratory of Rare Earth Resource Utilization Changchun Institute of Applied ChemistryChangchun 130022China Institute for Carbon Neutralization College of Chemistry and Materials EngineeringWenzhou UniversityWenzhou 325035China School of Chemical Engineering and Advanced Materials The University of AdelaideAdelaide 5000Australia Qingdao Industrial Energy Storage Research Institute Qingdao Institute of Bioenergy and Bioprocess TechnologyChinese Academy of SciencesQingdao 266101China Frontiers Science Center for New Organic Matter Key Laboratory of Advanced Energy Materials Chemistry(Ministry of Education)College of ChemistryNankai UniversityTianjin 300071China College of Chemistry and Materials Science Jinan UniversityGuangzhou 511443China Tsinghua Shenzhen International Graduate School Tsinghua UniversityShenzhen 518055China Department of Materials Science and Engineering City University of Hong KongHong Kong 999077China Division of Energy Storage Dalian National Laboratory for Clean Energy(DNL)Dalian Institute of Chem

Rechargeable batteries currently hold the largest share of the electrochemical energy storage market,and they play a major role in the sustainable energy transition and industrial decarbonization to respond to global climate *** to the increased popularity of consumer electronics and electric vehicles,lithium-ion batteries have quickly become the most successful rechargeable batteries in the past three decades,yet growing demands in diversified application scenarios call for new types of rechargeable *** efforts are made to developing the next-generation post-Li-ion rechargeable batteries,which include,but are not limited to solid-state batteries,lithium–sulfur batteries,sodium-/potassium-ion batteries,organic batteries,magnesium-/zinc-ion batteries,aqueous batteries and flow *** the great achievements,challenges persist in precise understandings about the electrochemical reaction and charge transfer process,and optimal design of key materials and interfaces in a *** roadmap tends to provide an overview about the current research progress,key challenges and future prospects of various types of rechargeable *** computational methods for materials development,and characterization techniques will also be discussed as they play an important role in battery research.

关键词： energy storage rechargeable batteries battery materials electrochemistry

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云南大理打造世界级绿色食品产业研究

食品安全导刊 2024年第4期 148-150页

作者：赵嫣然赵健雄大理农业科学推广研究院云南大理671000

云南省大理州坚决贯彻新发展理念,大力推动绿色食品产业发展,打造世界一流“绿色食品品牌”。本文结合大理州绿色食品产业发展现状,找出产业发展优势与短板,最后提出加快打造大理州世界级绿色食品产业补短板的建议。

关键词：绿色食品产业建议大理

Study on joint Bayesian model selection and parameter estimation method of GTD model

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Science in China(Series F) 2007年第2期50卷 261-272页

作者： SHI ZhiGuang ZHOU jianxiong zhao HongZhong FU Qiang ATR Laboratory National University of Defence Technoloqy Chanqsha 410073. China

The Bayesian method is applied to the joint model selection and parameter estimation problem of the GTD model. An algorithm based on RJ-MCMC is designed. This algorithm not only improves the model order selection and parameter estimation accuracy by exploiting the priori information of the GTD model, but also solves the mixed parameter estimation problem of the GTD model properly. Its performance is tested using numerical simulations and data generated by electromagnetic code. It is shown that it gives good model order selection and parameter estimation results, especially for low SNR, closely-spaced components and short data situations.

关键词： RJ-MCMC GTD model scattering centers parameter estimation model order selection ESPRIT CRB

Interface synergistic effects induced multi-mode luminescence

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Nano Research 2022年第5期15卷 4457-4465页

作者： Ronghua Ma Chunfeng Wang Wei Yan Mingzi Sun jianxiong zhao Yuantian Zheng Xu Li Longbiao Huang Bing Chen Feng Wang Bolong Huang Dengfeng Peng Laboratory of Optoelectronic Devices and Systems of Ministry of Education and Guangdong Province College of Physics and Optoelectronic EngineeringShenzhen UniversityShenzhen 518060China Department of Applied Biology and Chemical Technology The Hong Kong Polytechnic UniversityHung HomKowloonHong Kong SAR 999077China Department of Materials Science and Engineering City University of Hong Kong83 Tat Chee AvenueHong KongHong Kong SAR 999077China

Mechanoluminescence(ML)has become the most promising material for broad applications in display and sensing devices,in which ZnS is the most commonly studied one due to its stable and highly repetitive ML *** this work,we have successfully prepared the biphase ZnS on a large scale through the facile in-air molten salt protection *** obtained biphase has the best ML properties,which is mainly attributed to the synergistic effects of piezo-photonic,defect,and interface *** calculations have confirmed that the defects activate the local S and Zn sites and reduce the energy barrier for electron *** much stronger X-ray induced luminescence than the commercial scintillator is also *** application of ZnS particles in both papers and inks delivers superior ***,ZnS particles based screen printing ink is able to directly print on paper,plastic and other carriers to form clear *** proposed paper and ink hold great potentials in applications of information security and anti-counterfeiting based on the multi-mode luminescence *** work provides a new avenue to understand and realize the high-performance multi-mode luminescence,inspiring more future works to extend on other ML materials and boosting their practical applications.

关键词： interface synergetic effects multi-mode luminescence mechanoluminescence biphase engineering anti-counterfeiting

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弥沙乡森林防火工作的思考及对策

科学之友 2012年第2期 126-127页

作者：赵剑雄剑川县弥沙乡农业综合服务中心

陈旧的思想、传统的耕种模式和群众防火观念的淡薄使弥沙乡的森林火灾年年不断,管理手段和常规的工作套路已很难适应当前的森林防火工作。文章结合弥沙乡实际,简要的对森林防火工作中存在的困难和问题进行了思考,并有针对性的提出了几... 详细信息

陈旧的思想、传统的耕种模式和群众防火观念的淡薄使弥沙乡的森林火灾年年不断,管理手段和常规的工作套路已很难适应当前的森林防火工作。文章结合弥沙乡实际,简要的对森林防火工作中存在的困难和问题进行了思考,并有针对性的提出了几点具体的应对措施。

关键词：森林防火工作思考对策

扶正抑瘤汤对肿瘤细胞端粒酶活性及血液流变学影响的研究

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北京师范大学学报（自然科学版） 2008年第3期44卷 334-336页

作者：张玉红柴巍中赵键雄北京师范大学医院北京100875 北京大学公共卫生学院北京100083 兰州大学医学院中西医结合研究所兰州730030

用S180瘤株接种昆明种小鼠建成S180实体瘤模型,采用扶正抑瘤汤中药灌胃治疗,用端粒酶试剂盒检测肿瘤细胞端粒酶活性,用全自动血液流变仪检测全血黏度.结果显示:各中药治疗组肿瘤细胞端粒酶活性较NS荷瘤组明显降低,P<0.001;荷瘤模型组呈... 详细信息

用S180瘤株接种昆明种小鼠建成S180实体瘤模型,采用扶正抑瘤汤中药灌胃治疗,用端粒酶试剂盒检测肿瘤细胞端粒酶活性,用全自动血液流变仪检测全血黏度.结果显示:各中药治疗组肿瘤细胞端粒酶活性较NS荷瘤组明显降低,P<0.001;荷瘤模型组呈高血黏状态,各治疗组全血黏度明显降低,P<0.001.说明肿瘤细胞端粒酶的活性被抑制,是扶正抑瘤汤影响癌细胞的增殖周期,同时有效改善荷瘤小鼠高血黏状态,发挥了抗肿瘤作用.

关键词：扶正抑瘤汤端粒酶活性全血黏度抗肿瘤

一种高效制备高性能PLA/PBAT复合材料的方法及其性能研究

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中国塑料 2023年第3期37卷 1-6页

作者：何和智杨以科赵健雄华南理工大学机械与汽车工程学院聚合物成型加工工程教育部重点实验室广东省高分子先进制造技术及装备重点实验室广州510000

为解决聚乳酸(PLA)韧性较差这一问题,人们提出了诸多弹性体填充方案来增韧PLA,但这些方案大多会造成PLA的强度损失,或者引入不可降解的相容剂组分,因此,开发了一种由聚己二酸/对苯二甲酸丁二酯(PBAT)填充,由三螺杆挤出机挤出结合三辊式... 详细信息

为解决聚乳酸(PLA)韧性较差这一问题,人们提出了诸多弹性体填充方案来增韧PLA,但这些方案大多会造成PLA的强度损失,或者引入不可降解的相容剂组分,因此,开发了一种由聚己二酸/对苯二甲酸丁二酯(PBAT)填充,由三螺杆挤出机挤出结合三辊式轧机冷压的方式制备样品。通过对本工艺制备的样品进行表征,在样品的扫描电子显微镜(SEM)照片中发现三辊冷压工艺对于PBAT的拉伸作用,在拉伸作用的诱导下产生了原位成纤现象。同时在差示扫描量热仪(DSC)测试中发现拉伸作用对PLA的结晶有促进作用,在拉伸试验中,证明了原位成纤和结晶度的提高分别对PLA起到了增韧和增强的作用,最后通过热失重(TG)测试对样品的热稳定性进行表征,探究了此工艺对于热稳定性的影响。并将此工艺的增韧机理进行了归纳,为PLA的增韧提供了新的思路。

关键词：聚乳酸增韧冷压原位成纤诱导结晶

心肌酶谱和脑脊液检查诊断手足口病并发SIRS和MODS的价值分析

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重庆医学 2013年第31期42卷 3721-3723页

作者：赵健雄王爱忠贵州省贵阳市第五人民医院重症医学科 550004 上海交通大学附属第六人民医院重症医学科 200233

目的探讨心肌酶谱和脑脊液检查在诊断手足口病(HFMD)并发全身炎症反应综合征(SIRS)和多器官功能障碍综合征(MODS)中的价值。方法对2010年4月至2013年1月于该院就诊的204例HFMD患儿进行回顾性分析,对患儿进行心肌酶谱和脑脊液检查,分析... 详细信息

目的探讨心肌酶谱和脑脊液检查在诊断手足口病(HFMD)并发全身炎症反应综合征(SIRS)和多器官功能障碍综合征(MODS)中的价值。方法对2010年4月至2013年1月于该院就诊的204例HFMD患儿进行回顾性分析,对患儿进行心肌酶谱和脑脊液检查,分析检查结果与SIRS和MODS发生的相关性。结果重型和危重型组SIRS发病率、MODS发病率、病死率均高于普通型组,差异有统计学意义(P<0.05)。SIRS组脑脊液蛋白含量、肌酸激酶同工酶(CK-MB)、乳酸脱氢酶(LDH)和肌钙蛋白T(cTnT)含量高于非SIRS组,差异有统计学意义(P<0.05)。MODS组脑脊液蛋白含量、CK-MB、LDH和cTnT含量高于非MODS组,差异有统计学意义(P<0.05)。Spearman秩相关分析结果显示,脑脊液蛋白、CK-MB、cTnT与SIRS、MODS发病呈正相关(P<0.05)。结论脑脊液和心肌酶谱检查在早期诊断HFMD并发SIRS和MODS中具有较高的价值。

关键词：手足口病全身炎症反应综合征多器官功能衰竭心肌酶谱脑脊液

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一种大电流LDO稳压器的设计

微电子学 2016年第2期46卷 198-201,206页

作者：杨燕赵健雄陈祝成都信息工程大学通信工程学院成都610225

设计了一种最大输出电流为3 A的LDO电路。通过优化误差放大器,并采用两个NMOS管作为调整管,增强了电路上拉和下拉负载电流的能力。采用20μF的陶瓷电容,保证电路具有足够快的负载瞬态响应,在空载时,电路仅消耗80μA的负载电流。该芯片... 详细信息

设计了一种最大输出电流为3 A的LDO电路。通过优化误差放大器,并采用两个NMOS管作为调整管,增强了电路上拉和下拉负载电流的能力。采用20μF的陶瓷电容,保证电路具有足够快的负载瞬态响应,在空载时,电路仅消耗80μA的负载电流。该芯片能够驱动高达3A的负载电流,极大地提高了LDO的带载能力,并保持了良好的系统稳定性,具有快速的瞬态响应和较小的输出纹波。

关键词： LDO 大电流上拉和下拉负载电流