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Journal of Rare Earths 2024年第8期42卷 1447-1457,I0002页

作者： jiantong wang Changshuai Gong Sihan Yang Qi Zhu Xuejiao wang Ji-Guang Li College of Chemistry and Materials Engineering Bohai UniversityJinzhou121007China Key Laboratory for Anisotropy and Texture of Materials(Ministry of Education) School of Materials Science and EngineeringNortheastern UniversityShenyang110819China Research Center for Electronic and Optical Materials National Institute for Materials ScienceTsukubaIbaraki 305-0044Japan

Phosphor-converted near-infrared light-emitting diodes(NIR pc-LEDs) are finding applications in various fields including food quality analysis,biomedical imaging,night vision,and *** crucial factor in the development of NIR pc-LEDs devices lies in the advancement of high-performance broadband NIR phosphors,In this work,novel Cr^(3+)-activated silicate phosphors NaRESi_(3)O_(9)(RE=Y,Lu,Sc) are *** silicate has a special 3D network structure in which RE has four different sites,forming four octahedrons and providing suitable occupation sites for Cr^(3+).The phosphors demonstrate a wide emission spectrum ranging from 750 to 1450 nm when excited by light at 468 *** full width at half maximum(FWHM),which benefits from the presence of Cr^(3+)ions occupying multiple sites,is measured to be 203 ***,the strongest emission peak is observed at a longer wavelength of 984 nm compared to most other systems activated by Cr^(3+).The Na_(3)ScSi_(3)O_(9) lattice provides a weak crystal field(Dq/B=1.97) and weak phonon-photon coupling for Cr^(3+),and the integrated emission intensity of Na_(3)ScSi_(3)O_(9):0,03Cr^(3+)is 4.66 times stronger than that of Na_(3)YSi_(3)O_(9):0.03Cr^(3+).

关键词： Rare earths Broadband near-infrared Silicate Photoluminescence Cr^(3+)

宽带绿色荧光粉(Lu_(0.99-x)La_(x)Bi_(0.01))_(2)WO_(6)的制备、光致发光及性能调控

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稀有金属 2024年第3期48卷 355-364页

作者：龚长帅薛绪岩王渤文王建通冯晓雯王雪娇渤海大学化学与材料工程学院辽宁锦州121013

宽带绿光荧光粉在克服荧光粉转换白光LED(pc-WLED)蓝绿(青色)470~510 nm波段的缺失问题,实现高显色指数白光照明中有重要应用。采用普适的高温固相法合成一种以Bi^(3+)为激活剂的发射宽带绿光荧光粉(Lu_(0.99)Bi_(0.01))_(2)WO_(6)。采... 详细信息

宽带绿光荧光粉在克服荧光粉转换白光LED(pc-WLED)蓝绿(青色)470~510 nm波段的缺失问题,实现高显色指数白光照明中有重要应用。采用普适的高温固相法合成一种以Bi^(3+)为激活剂的发射宽带绿光荧光粉(Lu_(0.99)Bi_(0.01))_(2)WO_(6)。采用共掺杂La^(3+)的策略对(Lu_(0.99-x)La_(x)Bi_(0.01))_(2)WO_(6)(x=0~0.25)系列荧光粉的物相、形貌及发光性能进行调控,并采用X射线衍射(XRD)、Rietveld精修、场发射扫描电子显微镜(FE-SEM)、X射线光电子能谱(XPS)及光致发光等检测手段对样品进行了研究。结果表明,La^(3+)掺杂可显著提高(Lu_(0.99-x)La_(x)Bi_(0.01))_(2)WO_(6)样品的结晶性(x≤0.10)及发光强度,并在x>0.20时开始发生相变。La^(3+)掺杂对样品的微观形貌有显著影响,得益于La^(3+)掺杂获得了尺寸均匀分散性较好的微米棒形貌。在346 nm波长激发下,(Lu_(0.99-x)La_(x)Bi_(0.01))_(2)WO_(6)样品在400~800 nm范围内呈现出宽带绿色发射,半峰宽(FWHM)可达135 nm,最强峰位于515 nm处,对应于Bi3+的3P1→1S0跃迁。荧光粉呈现宽带激发,激发范围覆盖了200~400 nm的波长区域,与商用紫外LED匹配良好。采用所得的宽带绿光荧光粉(Lu_(0.94)La_(0.05)Bi_(0.01))_(2)WO_(6)与商用CaAlSiN_(3):Eu^(2+)红色荧光粉、BaMgAl10O17:Eu2+蓝色荧光粉及365 nm商用芯片制作出具有较高的显色指数(R,Ra=93,R1~R15均大于80),较低色温(相关色温(CCT)=3928 K)的暖白光pc-LED器件,表明(Lu_(0.99-x)La_(x)Bi_(0.01))_(2)WO_(6)荧光粉在高质量的暖白光LED照明方向有较大的应用潜力。

关键词： Bi^(3+)发光稀土钨酸盐宽带发射光致发光

新型硅酸盐型荧光粉K_(3)(Y_(0.88)Yb_(0.10)Ho_(0.02))Si_(2)O_(7)的上转换光致发光及光学测温性能研究

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人工晶体学报 2024年第1期53卷 115-122页

作者：滕雨含王建通龚长帅王渤文薛绪岩王雪娇渤海大学化学与材料工程学院锦州121013

本文采用普适的固相法合成一种新型硅酸盐K_(3)(Y_(0.88)Yb_(0.10)Ho_(0.02))Si_(2)O_(7)荧光粉,并系统研究样品的上转换光致发光和光学测温性能。研究表明,在980 nm激发下,K_(3)(Y_(0.88)Yb_(0.10)Ho_(0.02))Si_(2)O_(7)荧光粉表现出红光发射,主发射峰位于665 nm,归属于Ho^(3+)的^(5)F_(5)→^(5)I_(8)跃迁。通过对发光强度和激发功率的对数变换,研究荧光粉的上转换机制和可能导致的上转换的光子反应,证明(5S4,5F2)→5I8跃迁上转换发光机制为三光子机制,^(5)F_(5)→^(5)I_(8)跃迁则为双光子机制。K_(3)(Y_(0.88)Yb_(0.10)Ho_(0.02))Si_(2)O_(7)荧光粉的^(5)F_(5)/(^(5)F_(4),^(5)S_(2))的非热耦合能级的荧光强度比结果表现出其良好的光学测温潜力,经计算其最大灵敏度约为0.17 K^(-1)(423 K)。

关键词：上转换硅酸盐光学测温稀土发光光致发光固相法

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高速公路收费模式调整对货车车型设计的影响

中国汽车 2024年第1期 28-32页

作者：闫晟煜王建统白昭然王钊龙长安大学汽车学院西安710018 扬州市交通运输综合行政执法支队扬州225009

2020年我国高速公路收费模式由计重收费改为按车(轴)型收费,本文基于此背景,结合近年来高速公路各轴型货车车流量占比变化等数据,揭示收费模式调整给货车空驶、载重、车型结构分布等带来的影响,分析货车车型设计应对收费模式改变的合理... 详细信息

2020年我国高速公路收费模式由计重收费改为按车(轴)型收费,本文基于此背景,结合近年来高速公路各轴型货车车流量占比变化等数据,揭示收费模式调整给货车空驶、载重、车型结构分布等带来的影响,分析货车车型设计应对收费模式改变的合理方案,预测未来我国货车车型的发展趋势。

关键词：高速公路收费模式货车车型设计货车轴型

豫西蒲阵沟铅锌银多金属矿区稀散金属的发现及地质意义

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矿产勘查 2024年第6期15卷 1122-1124页

作者：吴煜李新萍豆贯铭岳涛王建统宋佳伟河南省第一地质矿产调查院有限公司河南洛阳471000 河南省金银多金属成矿系列与深部预测重点实验室河南洛阳471000 自然资源部贵金属分析与勘查技术重点实验室河南洛阳471000

研究区位于东秦岭成矿带卢氏多金属矿集区,区内燕山期中酸性岩浆活动强烈,形成了后瑶峪、柳关、八宝山及蒲阵沟等小型斑岩体,围绕这些岩体已发现多处中—小型铁、铜、钼多金属斑岩-矽卡岩型矿床,以银家沟、八宝山、夜长坪及曲里为代表,... 详细信息

研究区位于东秦岭成矿带卢氏多金属矿集区,区内燕山期中酸性岩浆活动强烈,形成了后瑶峪、柳关、八宝山及蒲阵沟等小型斑岩体,围绕这些岩体已发现多处中—小型铁、铜、钼多金属斑岩-矽卡岩型矿床,以银家沟、八宝山、夜长坪及曲里为代表,找矿效果良好。

关键词：找矿效果斑岩体钼多金属秦岭成矿带多金属矿集区银家沟矽卡岩型矿床夜长坪

Application of wastewater-based epidemiological monitoring of COVID-19 for disease surveillance in the city

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Frontiers of Environmental Science & Engineering 2024年第8期18卷 81-87页

作者： Heng Chen Zhenhua Chen Liwen Hu Fengzhu Tang Dan Kuang Jiayi Han Yao wang Xiao Zhang Yue Cheng jiantong Meng Rong Lu Lan Zhang Chengdu Workstation for Emerging Infectious Disease Control and Prevention Chinese Academy of Medical SciencesChengdu 610047China Chengdu Center for Disease Control and Prevention Chengdu 610047China National Key Laboratory of Intelligent Tracking and Forecasting for Infectious Diseases Beijing 100050China National Institute of Environmental Health Chinese Center for Disease Control and PreventionBeijing 100050China

Wastewater-based surveillance serves as a supplementary approach to clinical surveillance of COVID-19 during the *** study aimed to track the prevalence of the disease and the viral genetic variability through wastewater-based surveillance in the post-epidemic *** January to December 2023,samples were collected from the influent lines of two wastewater treatment plants(WWTPs),concentrated using PEG8000,and subjected to detection of the target genes ORF 1ab and N of SARS-CoV-2 via reverse transcriptional quantitative PCR(RT-qPCR).For next-generation sequencing(NGS),high-quality samples from both wastewater and clinical patients were *** analysis were performed using R software to evaluate the correlation between the SARSCoV-2 RNA concentrations in wastewater and positive rate of reported cases,indicating a positive *** diversity patterns of SARS-CoV-2 in wastewater resembled those in the patient source based on Principal Coordinates Analysis(PCoA)with three clusters for different *** rise of RNA concentration in wastewater indicates the growth of cases and the emergence of new variants,serving as an early warning of potential viral mutations,disease outbreaks even possible ***,the genomic surveillance of wastewater could help identify new variants that may not be captured through population monitoring,especially when sample sizes are ***,surveillance of SARS-CoV-2 in municipal wastewater has emerged as a reliable,earlywarning monitoring system for COVID-19 in the post-epidemic era.

关键词： Wastewater-based epidemiology Monitoring COVID-19 Post-epidemic era

Effects of herbicide butachlor application on the growth of periphytic biofilms and nitrogen loss in paddy systems

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Pedosphere 2024年第1期34卷 211-221页

作者： Yanhui ZHAO Mingjun LEI Liandong JING Fan XIA Meixia YAN jiantong LIU Yonghong WU Yunli WU Chenxi WU Ecology and Environment Monitoring and Scientific Research Center Yangtze Basin Ecology and Environment AdministrationMinistry of Ecological and EnvironmentWuhan 430010China College of Chemistry and Environmental Protection Engineering Southwest Minzu UniversityChengdu 610041China State Key Laboratory of Freshwater Ecology and Biotechnology Institute of HydrobiologyChinese Academy of SciencesWuhan 430072China State Key Laboratory of Soil and Sustainable Agriculture Institute of Soil SciencesChinese Academy of SciencesNanjing 210008China

The application of butachlor as an herbicide in paddy fields is widely practiced,aiming to increase rice yield by directly or indirectly influencing the paddy *** biofilms,which form at the soil-water interface in paddy fields,are complex bioaggregates that play an important role in nitrogen (N) *** objective of this study was to investigate the effect of butachlor on periphytic biofilm growth and N cycling under both light and dark conditions in the *** results revealed that butachlor application hindered the growth of periphytic biofilms and led to the dominance of Cyanobacteria as the primary prokaryotes,while inhibiting the development of eukaryotic ***,the application of butachlor reduced the richness and diversity of prokaryotes,but increased those of eukaryotes in periphytic *** light treatments exhibited higher total N loss because light favored periphytic biofilm growth and enhanced ammonium (NH_(4)^(+)) assimilation and ***,butachlor application resulted in the increased retention of NH_(4)^(+)-N and nitrate (NO_(3)^(-))-N and an increase in N loss via *** abundances of functional genes encoding enzymes such as ammonia monooxygenase,nitrite reductase,and nitrous oxide reductase were increased by butachlor application,favoring nitrification and denitrification ***,the results suggest that butachlor application leads to an increase in total N loss mainly through denitrification in paddy systems,particularly in the presence of periphytic ***,the results may provide valuable insights into the changes in periphytic biofilm growth and N cycling induced by butachlor,and future studies can further explore the potential implications of these changes in paddy soils.

关键词： ammonia-oxidizing bacteria amoA denitrification denitrifying bacteria nirK nitrification nitrogen cycling nosZ volatilization

A graph deep learning method for landslide displacement prediction based on global navigation satellite system positioning

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Geoscience Frontiers 2024年第1期15卷 29-38页

作者： Chuan Yang Yue Yin jiantong Zhang Penghui Ding Jian Liu China Transport Telecommunications and Information Center Beijing 100011PR China China Nuclear Power Engineering Co. LtdBeijing 100011PR China

The accurate prediction of displacement is crucial for landslide deformation monitoring and early *** study focuses on a landslide in Wenzhou Belt Highway and proposes a novel multivariate landslide displacement prediction method that relies on graph deep learning and Global Navigation Satellite System(GNSS)*** model the graph structure of the monitoring system based on the engineering positions of the GNSS monitoring points and build the adjacent matrix of graph *** construct the historical and predicted time series feature matrixes using the processed temporal data including GNSS displacement,rainfall,groundwater table and soil moisture content and the graph *** introduce the state-of-the-art graph deep learning GTS(Graph for Time Series)model to improve the accuracy and reliability of landslide displacement prediction which utilizes the temporal-spatial dependency of the monitoring *** approach outperforms previous studies that only learned temporal features from a single monitoring point and maximally weighs the prediction performance and the priori graph of the monitoring *** proposed method performs better than SVM,XGBoost,LSTM and DCRNN models in terms of RMSE(1.35 mm),MAE(1.14 mm)and MAPE(0.25)evaluation metrics,which is provided to be effective in future landslide failure early warning.

关键词： Landslide displacement prediction GNSS positioning Graph deep learning

(La_(0.88)Yb_(0.10)Ho_(0.02))_(2)W_(2)O_(9)荧光粉的上转换发光及双模式荧光测温

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功能材料 2023年第3期54卷 3179-3186,3200页

作者：龚长帅薛绪岩冯晓雯王建通王渤文王雪娇渤海大学化学与材料工程学院辽宁锦州121013

采用共沉淀法制备了Yb-Ho共掺的La_(2)W_(2)O_(9)纳米晶。采用X射线衍射(XRD),场发射扫描电子显微镜(FE-SEM)和荧光光谱(PL/PLE)对前驱体及产物进行表征。系统地研究了样品包括功率/温度依赖发射光谱、潜在上转换发光机制、主发射的衰... 详细信息

采用共沉淀法制备了Yb-Ho共掺的La_(2)W_(2)O_(9)纳米晶。采用X射线衍射(XRD),场发射扫描电子显微镜(FE-SEM)和荧光光谱(PL/PLE)对前驱体及产物进行表征。系统地研究了样品包括功率/温度依赖发射光谱、潜在上转换发光机制、主发射的衰减动力学、发光颜色等上转换发光特性及荧光测温性能。结果表明在不同功率980 nm光源激发下,(La_(0.88)Yb_(0.1)Ho_(0.02))_(2)W_(2)O_(9)荧光粉在654 nm出现最强发射峰,对应于Ho^(3+)离子的_(5)F_(5)→_(5)I_(8)跃迁。在298-548 K温度范围内的上转换发光性能研究表明所得荧光粉可通过荧光强度比模式(FIR)和荧光寿命模式(FL)实现双模式荧光测温。在980 nm光源激发下,所得荧光粉可基于Ho^(3+)的最强发射峰^(5)F_(5)→^(5)I_(8)(654 nm)与(^(5)F_(4),^(5)S_(2))→^(5)I_(8)(544 nm)和(^(5)F_(4),^(5)S_(2))→^(5)I_(7)(759 nm)两发射峰的荧光强度比(FIR)进行荧光测温。I_(654)/I_(759)荧光强度比模式测温最大绝对灵敏度(S_(A))及相对灵敏度(S_(R))分别为266×10^(-4)和3266×10^(-4)K^(-1),I_(654)/I_(544)荧光强度比模式测温的最大绝对灵敏度(S_(A))为81×10^(-4),最大相对灵敏度(S_(R))为3427×10^(-4)K^(-1)。随着温度的升高,所得荧光粉的发光颜色发生人眼可见的明显变化,从室温的绿色变为高温的橙红色。此外,本工作荧光粉可基于主发射峰的荧光寿命进行测温,在298-548 K范围内主发射峰荧光寿命与温度呈指数减小关系,通过FL模式测温S_(A)、S_(R)最大值分别为997×10^(-4)K^(-1)、1184×10^(-4)K^(-1)。

关键词：钨酸盐上转换发光 La_(2)W_(2)O_(9) 荧光测温

High-rate metal-free MXene microsupercapacitors on paper substrates

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Carbon Energy 2024年第5期6卷 94-104页

作者： Han Xue Po‐Han Huang Lee‐Lun Lai Yingchun Su Axel Strömberg Gaolong Cao Yuzhu Fan Sergiy Khartsev Mats Göthelid Yan‐Ting Sun Jonas Weissenrieder Kristinn BGylfason Frank Niklaus jiantong Li School of Electrical Engineering and Computer Science KTH Royal Institute of TechnologyStockholmSweden School of Engineering Sciences KTH Royal Institute of TechnologyStockholmSweden

MXene is a promising energy storage material for miniaturized microbatteries and microsupercapacitors(MSCs).Despite its superior electrochemical performance,only a few studies have reported MXene-based ultrahigh-rate(>1000 mV s^(−1))on-paper MSCs,mainly due to the reduced electrical conductance of MXene films deposited on ***,ultrahigh-rate metal-free on-paper MSCs based on heterogeneous MXene/poly(3,4-ethylenedioxythiophene)-poly(styrenesulfonate)(PEDOT:PSS)-stack electrodes are fabricated through the combination of direct ink writing and femtosecond laser *** a footprint area of only 20 mm^(2),the on-paper MSCs exhibit excellent high-rate capacitive behavior with an areal capacitance of 5.7 mF cm^(−2)and long cycle life(>95%capacitance retention after 10,000 cycles)at a high scan rate of 1000 mV s^(−1),outperforming most of the present on-paper ***,the heterogeneous MXene/PEDOT:PSS electrodes can interconnect individual MSCs into metal-free on-paper MSC arrays,which can also be simultaneously charged/discharged at 1000 mV s^(−1),showing scalable capacitive *** heterogeneous MXene/PEDOT:PSS stacks are a promising electrode structure for on-paper MSCs to serve as ultrafast miniaturized energy storage components for emerging paper electronics.

关键词： direct ink writing femtosecond laser scribing MXene on-paper microsupercapacitors PEDOT:PSS ultrahigh rate capability