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In-situ construction of high-mechanical-strength and fast-ion-conductivity interphase for anode-free Li battery

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Journal of Energy Chemistry 2023年第5期80卷 207-214,I0006页

作者： Yangfan Lin Juner Chen Han Zhang jianhui Wang Key Laboratory of 3D Micro/Nano Fabrication and Characterization of Zhejiang Province School of EngineeringWestlake UniversityHangzhou 310024ZhejiangChina Institute of Advanced Technology Westlake Institute for Advanced StudyHangzhou 310024ZhejiangChina Department of Chemistry Zhejiang UniversityHangzhou 310027ZhejiangChina

The solid electrolyte interphase(SEI)with strong mechanical strength and high ion conductivity is highly desired for Li metal batteries,especially for harsh anode-free batteries.Herein,we report a pragmatic approach to the in-situ construction of high-quality SEI by applying synergistic additives of Li NO_(3)and ethylene sulfite(ES)in the electrolyte.The obtained SEI exhibits a high average Young’s modulus(9.02GPa)and exchanging current density(4.59 mA cm^(-2)),which are 3.0 and 1.2 times as large as those using the sole additive of LiNO_(3),respectively.With this improved SEI,Li-dendrite growth and side reactions are effectively suppressed,leading to an ultra-high Coulombic efficiency(CE)of 99.7%for Li plating and stripping.When applying this improved electrolyte in full cells,it achieves a high capacity retention of 89.7%for over 150 cycles in a LiFePO_(4)||Li battery(~12 mg cm^(-2)cathode,50μm Li)and of 44.5%over 100 cycles in a LiFePO_(4)||Cu anode-free battery.

关键词： Anode-free Li battery Solid electrolyte interphase Additive Lithiu mnitrate Ethylene sulfite

A dilute fluorine-free electrolyte design for high-voltage hybrid aqueous batteries

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Journal of Energy Chemistry 2023年第2期77卷 180-190,I0005页

作者： Rui Lin Jiahao Chen Changming Ke Shi Liu jianhui Wang School of Materials Science&Engineering Zhejiang UniversityHangzhou 310024ZhejiangChina Key Laboratory of 3D Micro/Nano Fabrication and Characterization of Zhejiang Province School of EngineeringWestlake UniversityHangzhou 310024ZhejiangChina Institute of Advanced Technology Westlake Institute for Advanced StudyHangzhou 310024ZhejiangChina Key Laboratory for Quantum Materials of Zhejiang Province Department of PhysicsSchool of ScienceWestlake UniversityHangzhou 310030ZhejiangChina Institute of Natural Sciences Westlake Institute for Advanced StudyHangzhou 310024ZhejiangChina

Fluorinated salts and/or high salt concentrations are usually necessary to produce protective films on the electrodes for high-voltage aqueous batteries,yet these approaches increase the cost,toxicity and reaction resistances of battery.Herein,we report a dilute fluorine-free electrolyte design to overcome this dilemma.By using the LiClO_(4) salt and polyethylene glycol dimethyl ether(PED)solvent and optimizing the LiClO_(4)/PED/H_(2)O molar ratio,we formulate a 1 mol kg^(-1)3 V-class hybrid aqueous electrolyte that enables reversible charge/discharge of 2.5 V LiMn_(2)O_(4)|Li_(4)Ti_(5)O_(12) full cell at both low(0.5C,92.4%capacity retention in 300 cycles)and high(5C,80.4%capacity retention in 2000 cycles)rates.This excellent performance is reached even without the generation of protective film on either anode or cathode as identified by in/ex situ characterizations.The selection of appropriate ingredients that have both high stability and strong interactions with water is critical to widen the potential window of electrolyte while suppressing parasitic reactions on the electrodes.This work suggests that expensive and toxic fluorinate salts are no longer necessary for 3 V-class aqueous electrolytes,boosting the development of low-cost,environmentally-friendly,high-power and high-energy-density aqueous batteries.

关键词： High-voltage hybrid aqueous batteries Fluorine-free electrolyte design Interphase chemistry Polyethylene glycol dimethyl ether

Activating copper oxide for stable electrocatalytic ammonia oxidation reaction via in-situ introducing oxygen vacancies

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Nano Research 2022年第7期15卷 5987-5994页

作者： Jingjing Huang Zhe Chen Jinmeng Cai Yongzhen Jin Tao wang jianhui Wang Department of Chemistry Zhejiang UniversityHangzhou 310027China Key Laboratory of 3D Micro/Nano Fabrication and Characterization of Zhejiang Province School of EngineeringWestlake UniversityHangzhou 310024China Institute of Advanced Technology Westlake Institute for Advanced StudyHangzhou 310024China Center of Artificial Photosynthesis for Solar Fuels School of ScienceWestlake UniversityHangzhou 310024China Green Catalysis Center College of ChemistryZhengzhou UniversityZhengzhou 450001China School of Science Westlake Institute for Advanced StudyHangzhou 310024China

Electrocatalytic ammonia oxidation reaction(EAOR)provides an ideal solution for on-board hydrogen supply for fuel cells,while the lack of efficient and durable EAOR catalysts has been a long-standing obstacle for its practical application.Herein,we reported that the defect engineering via in-situ electrochemically introducing oxygen vacancies(Vo)not only turns the inactive CuO into efficient EAOR catalyst but also achieves a high stability of over 400 h at a high current density of~200 mA·cm^(−2).Theoretical simulation reveals that the presence of Vo on the CuO surface induces a remarkable upshift of the d-band center of active Cu site closer to the Fermi level,which significantly stabilizes the reaction intermediates(*NHx)and efficiently oxidizes NH3 into N2.This Vo-modulated CuO shows a different catalytic mechanism from that on the conventional Pt-based catalysts,paving a new avenue to develop inexpensive,efficient,and robust catalysts,not limited to EAOR.

关键词： electrocatalysis ammonia oxidation reaction oxygen vacancy CuO stability

Voltage Stability Constrained Optimal Power Flow for Unbalanced Distribution System Based on Semidefinite Programming

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Journal of Modern Power Systems and Clean Energy 2022年第6期10卷 1614-1624页

作者： Yanling Lin Xiaohu Zhang jianhui Wang Di Shi Desong Bian GEIRI North America San JoseUSA Southern Methodist University DallasUSA

This paper proposes a voltage stability constrained optimal power flow(VSC-OPF)for an unbalanced distribution system with distributed generators(DGs)based on semidefinite programming(SDP).The AC optimal power flow(ACOPF)for unbalanced distribution systems is formulated as a chordal relaxation-based SDP model.The minimal singular value(MSV)of the power flow Jacobian matrix is adopted to indicate the voltage stability margin.The Jacobian matrix can be explicitly expressed by ACOPF state variables.The nonlinear constraint on the Jacobian MSV is then replaced with its maximal convex subset using linear matrix inequality(LMI),which can be incorporated in the SDP-based ACOPF formulation.A penalty technique is leveraged to improve the exactness of the SDP relaxation.Case studies performed on several IEEE test systems validate the effectiveness of the proposed method.

关键词： Voltage stability semidefinite programming Jacobian matrix optimal power flow

Optimization of Gas-Flooding Fracturing Development in Ultra-Low Permeability Reservoirs

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Fluid Dynamics & Materials Processing 2024年第3期20卷 595-607页

作者： Lifeng Liu Menghe Shi jianhui Wang Wendong wang Yuliang Su Xinyu Zhuang Tight Oil Research Institute PetroChina Research Institute of Petroleum Exploration&DevelopmentBeijing100083China Key Laboratory of Unconventional Oil&Gas Development China University of Petroleum(East China)Qingdao266580China Oil&Gas Technology Research Institute Changqing Oilfield CompanyXi’an710018China

Ultra-low permeability reservoirs are characterized by small pore throats and poor physical properties, which areat the root of well-known problems related to injection and production. In this study, a gas injection floodingapproach is analyzed in the framework of numerical simulations. In particular, the sequence and timing of fracturechanneling and the related impact on production are considered for horizontal wells with different fracturemorphologies. Useful data and information are provided about the regulation of gas channeling and possible strategiesto delay gas channeling and optimize the gas injection volume and fracture parameters. It is shown that inorder to mitigate gas channeling and ensure high production, fracture length on the sides can be controlled andlonger fractures can be created in the middle by which full gas flooding is obtained at the fracture location in themiddle of the horizontal well. A Differential Evolution (DE) algorithm is provided by which the gas injectionvolume and the fracture parameters of gas injection flooding can be optimized. It is shown that an improvedoil recovery factor as high as 6% can be obtained.

关键词： Ultra-low permeability reservoir gas injection flooding component simulation fracture parameters intelligent optimization differential evolution

A collaborative approach to integrated energy systems that consider direct trading of multiple energy derivatives

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Global Energy Interconnection 2023年第4期6卷 418-437页

作者： jianhui Wang Guangqing Bao Peizhi wang Shoudong Li Department of electrical Engineering and Information Engineering Lanzhou University of TechnologyLanzhou 730000P.R.China School of Electronics and Information Engineering Southwest Petroleum UniversityChengdu 610500P.R.China College of Engineering Northeastern UniversityBoston02101-02117USA

The cooperative model of a multi-subject Regional Integrated Energy System(RIES)is no longer limited to the trading of traditional energy,but the trading of new energy derivatives such as Green Certificates(GC),Service Power(SP),and CO_(2) will be more involved in the energy allocation of the cooperative model.This study was conducted for the multi-entity RIES cooperative model considering the trading of electronics,GC,SP,and CO_(2).First,a cooperative framework including wind-photovoltaic generation system(WG),combined heat and power system(CHP),and power-carbon-hydrogen load(PCH)is proposed,and the mechanism of energy derivatives trading is also analyzed.Then,the sub-models of each agent in the cooperative model are established separately so that WG has the capability of GC generation,CHP has the capability of GC and CO_(2) absorption,and PCH can realize the effective utilization of CO_(2).Then,the WG–CHP–PCH cooperative model is established and equated into two sub-problems of cooperative benefit maximization and transaction payment negotiation,which are solved in a distributed manner by the alternating directed multiplier method(ADMM).Finally,the effectiveness of the proposed cooperative model and distributed solution is verified by simulation.The simulation results show that the WG–CHP–PCH cooperative model can substantially improve the operational efficiency of each agent and realize the efficient redistribution of energy and its derivatives.In addition,the dynamic parameter adjustment algorithm(DP)is further applied in the solving process to improve its convergence speed.By updating the step size during each iteration,the computational cost,the number of iterations,and the apparent oscillations are reduced,and the convergence performance of the algorithm is improved.

关键词： Green certificates Service power CO_(2) Electricity-carbon-hydrogen Cooperative model ADMM

Three-dimensional characteristics of mesoscale eddies simulated by a regional model in the northwestern Pacific Ocean during 2000–2008

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Acta Oceanologica Sinica 2022年第10期41卷 74-93页

作者： Guijing Yang Xiayan Lin Guoqing Han Yu Liu Gengxin Chen jianhui Wang Marine Science and Technology College Zhejiang Ocean UniversityZhoushan316000China State Key Laboratory of Satellite Ocean Environment Dynamics Second Institute of OceanographyMinistry of Natural ResourcesHangzhou310012China Southern Marine Science and Engineering Guangdong Laboratory(Zhuhai) Zhuhai519082China State Key Laboratory of Tropical Oceanography South China Sea Institute of OceanologyChinese Academy of SciencesGuangzhou510301China

Mesoscale eddies play vital roles in ocean processes.Although previous studies focused on eddy surface features and individual three-dimensional(3D)eddy cases in the northwestern Pacific Ocean,the analysis of unique eddy3D regional characteristics is still lacking.A 3D eddy detection scheme is applied to 9 years(2000-2008)of eddyresolving Regional Ocean Modeling System(ROMS)output to obtain a 3D eddy dataset from the surface to a depth of 1000 m in the northwestern Pacific Ocean(15°-35°N,120°-145°E).The 3D characteristics of mesoscale eddies are analyzed in two regions,namely,Box1(Subtropical Countercurrent,15°-25°N,120°-145°E)and Box2(Southern Kuroshio Extension,25°-35°N,120°-145°E).In Box1,the current is characterized by strong vertical shear and weak horizontal shear.In Box2,the current is characterized by the strong Kuroshio,topographic effect,and the westward propagation of Rossby waves.The results indicate the importance of baroclinic instability in Box1,whereas in Box2,both the barotropic and baroclinic instability are important.Moreover,the mesoscale eddies’properties in Box1 and Box2 are distinct.The eddies in Box1 have larger number and radius but a shorter lifetime.By contrast,Box2 has fewer eddies,which have smaller radius but longer lifetime.Vertically,more eddies are detected at the subsurface than at the surface in both regions;the depth of 650 m is the turning point in Box1.Above this depth,the number of cyclonic eddies(CEs)is larger than that of anticyclonic eddies(AEs).In Box2,the number of CEs is dominant vertically.Eddy kinetic energy(EKE)and mean normalized relative vorticity in Box2are significantly higher than those in Box1.With increasing depth,the attenuation trend of EKE and relative vorticity of Box1 become greater than those of Box2.Furthermore,the upper ocean(about 300 m in depth)contains 68.6%of the eddies(instantaneous eddy).Only 16.6%of the eddies extend to 1000 m.In addition,about87%of the eddies are bowl-shaped eddies in the two regions.Only about 3%are cone-shaped eddies.With in

关键词： three-dimensional structures mesoscale eddies northwestern Pacific Ocean

Deep Learning in Power Systems Research:A Review

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CSEE Journal of Power and Energy Systems 2021年第2期7卷 209-220页

作者： Mahdi Khodayar Guangyi Liu jianhui Wang Mohammad E.Khodayar Global Energy Interconnection Research Institute North America(GEIRI North America) San JoseCAUSA Department of Computer Science at the University of Tulsa TulsaOKUSA Khodayar are with the Department of Electrical and Computer Engineering of Southern Methodist

With the rapid growth of power systems measurements in terms of size and complexity,discovering statistical patterns for a large variety of real-world applications such as renewable energy prediction,demand response,energy disaggregation,and state estimation is considered a crucial challenge.In recent years,deep learning has emerged as a novel class of machine learning algorithms that represents power systems data via a large hypothesis space that leads to the state-of-the-art performance compared to most recent data-driven algorithms.This study explores the theoretical advantages of deep representation learning in power systems research.We review deep learning methodologies presented and applied in a wide range of supervised,unsupervised,and semi-supervised applications as well as reinforcement learning tasks.We discuss various settings of problems solved by discriminative deep models including stacked autoencoders and convolutional neural networks as well as generative deep architectures such as deep belief networks and variational autoencoders.The theoretical and experimental analysis of deep neural networks in this study motivates longterm research on optimizing this cutting-edge class of models to achieve significant improvements in the future power systems research.

关键词： Autoencoder convolution neural network deep learning discriminative model deep belief network generative architecture variational inference

Synthesis and Catalytic Activity of a Grubbs-Hoveyda Pre-catalyst Having a Trimeric Resting State

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中国化学:英文版 2015年第4期33卷 441-445页

作者： Guiyan Liu Bin Wu jianhui Wang Tianjin Key Laboratory of Structure and Performance for Functional Molecules Key Laboratory of Inorganic-Organic Hybrid Functional Material Chemistry(Tianjin Normal University)Ministry of EducationCollege of ChemistryTianjin Normal UniversityTianjin 300387China Department of Chemistry College of ScienceTianjin UniversityTianjin 300072China

A Grubbs-Hoveyda pre-catalyst having a trimeric resting state based on 2,4,6-trichloro-1,3,5-triazine was syn-thesized and the complex was characterized by NMR,HRMS and elemental analysis.The activity of this complex for ring-closing metathesis(RCM)was investigated.The catalytic system possesses high catalytic activity for many different olefin substrates.

关键词： olefin metathesis ruthenium carbene catalyst