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Highly efficient ternary organic solar cells with excellent open-circuit voltage and fill factor via precisely tuning molecular stacking and morphology

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Science China Chemistry 2024年第3期67卷 963-972页

作者： Dinghong Sun Zhenyu Chen jianfeng zhang Wei Song Jingyu Shi Jintao Zhu Yuanyuan Meng Fei Jin Shuncheng Yang Ziyi Ge Faculty of Electrical Engineering and Computer Science Ningbo UniversityNingbo 315211China Faculty of Material Science and Chemical Engineering Ningbo UniversityNingbo 315211China Zhejiang Provincial Engineering Research Center of Energy Optoelectronic Materials and Devices Ningbo Institute of Materials Technology&EngineeringChinese Academy of SciencesNingbo 315201China Center of Materials Science and Optoelectronics Engineering University of Chinese Academy of Sciences Beijing 100049China Department of Chemical and Environmental Engineering University of Nottingham NingboNingbo 315100China

The micro-morphology and molecular stacking play a key role in determining the charge transport process and nonradiative energy loss, thus impacting the performances of organic solar cells(OSCs). To address this issue, a non-fullerene acceptor PhC6-IC-F with alkylbenzene side-chain, possessing optimized molecular stacking, complementary absorption spectra and forming a cascade energy level alignment in the PM6:BTP-eC9 blend, is introduced as guest acceptor to improve efficiency of ternary OSCs. The bulky phenyl in the side-chain can regulate crystallinity and optimizing phase separation between receptors in ternary blend films, resulting in the optimal phase separations in the ternary films. As a result, high efficiencies of 18.33% as photovoltaic layer are obtained for PhC6-IC-F-based ternary devices with excellent fill factor(FF) of 78.92%. Impressively, the ternary system produces a significantly improved open circuit voltage(V_(oc)) of 0.857 V compared with the binary device,contributing to the reduced density of trap states and suppressed non-radiative recombination result in lower energy loss. This work demonstrates an effective approach for adjusting the aggregation, molecular packing and fine phase separation morphology to increase V_(oc) and FF, paving the way toward high-efficiency OSCs.

关键词： alkylbenzene side-chain morphology regulation ternary blends organic solar cells

19.3% Efficiency ternary organic solar cells enabled by the alkyl side-chain effect of guest non-fullerene acceptors

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Science China Chemistry 2024年第8期67卷 2686-2693页

作者： Hongqian Wang Sijian Wu Daobin Yang Xueliang Yu Shuncheng Yang Pengfei Ding Pengyu Yan Zaifei Ma jianfeng zhang Ziyi Ge School of Materials Science and Chemical Engineering Ningbo UniversityNingbo 315211China Zhejiang Engineering Research Center for Energy Optoelectronic Materials and Devices Ningbo Institute of Materials Technology and EngineeringChinese Academy of SciencesNingbo 315201China State Key Laboratory for Modification of Chemical Fibers and Polymer Materials Center for Advanced Low-dimension MaterialsCollege of Materials Science and EngineeringDonghua UniversityShanghai 201620China Center of Materials Science and Optoelectronics Engineering University of Chinese Academy of SciencesBeijing 100049China

The effect of side-chain engineering of conjugated molecules on the morphology and device performance in binary organic solar cells has been widely investigated. However, this relationship has hardly been studied in the guest components of ternary organic solar cells. In this study, a family of non-fullerene guest acceptors, namely XY-3, XY-5 and XY-7, with hydrogen substituent,straight and branched alkyl chains on the bithiophene units, respectively, were designed and synthesized to understand their effects on aggregation properties and device performance. The straight and branched alkyl chains on the bithiophene units result in sightly blue-shifted absorption compared to the hydrogen substituent and the XY-7 demonstrates the most appropriate phase separation scale and the most balanced charge transport. Consequently, the OSCs based on D18:e C9:XY-7 achieve a high shortcircuit current density(JSC) and fill factor(FF), while maintaining the enhancement of the open-circuit voltage(VOC) achieving an efficiency of 19.32%, exceeding those of D18:e C9, D18:e C9:XY-3, D18:e C9:XY-5(PCE:18.28%, 19.04%, 18.75%, respectively). These results highlight that the side-chain engineering of Y series non-fullerene acceptors as the guest acceptors has great potential in optimizing morphology properties and promoting photovoltaic performance.

关键词： organic solar cells side chain engineering ternary strategy non-fullerene energy losses

The Chinese guideline for management of snakebites

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World Journal of Emergency Medicine 2024年第5期15卷 333-355页

作者： Rongde Lai Shijiao Yan Shijun Wang Shuqing Yang zhangren Yan Pin Lan Yonggao Wang Qi Li Jinlong Wang Wei Wang Yuefeng Ma Zijing Liang jianfeng zhang Ning Zhou Xiaotong Han Xinchao zhang Mao zhang Xiaodong Zhao Guoqiang zhang Huadong Zhu Xuezhong Yu Chuanzhu Lyu Emergency Department the First Affi liated Hospital of Guangzhou Medical UniversityGuangzhou 510120China School of Public Health Hainan Medical UniversityHaikou 571199China Surgery Department of Traditional Chinese Medicine the Affi liated People’s Hospital of Fujian University of Traditional Chinese MedicineFuzhou 350004China Emergency Department Chongqing University Central Hospital/Chongqing Emergency Medical CenterChongqing 400014China Department of Surgery of Traditional Chinese Medicine Affi liated Hospital of Jiangxi University of Chinese MedicineNanchang 330006China Department of Emergency Medicine the Fifth Affi liated Hospital of Wenzhou Medical University/Lishui Central HospitalLishui Hospital of Zhejiang UniversityLishui 323000China General Surgery Department the First Affi liated Hospital of Zhejiang Chinese Medical UniversityHangzhou 310006China Emergency Department Shengli Clinical Medical College of Fujian Medical UniversityFuzhou 350001China Emergency Department Chongqing University Fuling HospitalChongqing UniversityChongqing 408000China Emergency Department the First Affi liated Hospital of Guangxi Medical UniversityNanning 530021China Emergency Department the Second Affi liated Hospital of Zhejiang University School of MedicineHangzhou 310009China Emergency Department Wuming Hospital of Guangxi Medical UniversityNanning 530021China Emergency Department Central People's Hospital of ZhanjiangZhanjiang 524037China Emergency Department Hunan Provincial People's HospitalChangsha 410005China Emergency Department National Geriatrics Center of Beijing HospitalBeijing 100020China Emergency Department the Fourth Medical Center of the PLA General HospitalBeijing 100048China Emergency Department China-Japan Friendship HospitalBeijing 100029China Emergency Department Peking Union Medical College HospitalBeiJing 100730China Emergency Department Sichuan Academy of Medical Sciences/Sichuan Provincial People's HospitalChengdu 610072China Research Unit of Island Emergency

In 2009,the World Health Organization included snakebite on the list of neglected tropical diseases,acknowledging it as a common occupational hazard for farmers,plantation workers,and others,causing tens of thousands of deaths and chronic physical disabilities every *** guideline aims to provide practical information to help clinical professionals evaluate and treat snakebite *** recommendations are based on clinical experience and clinical research *** guideline focuses on the following topics:snake venom,clinical manifestations,auxiliary examination,diagnosis,treatments,and prevention.

关键词： Snakebite Envenomation Management Prevention

Comparative Study on Microstructure and Mechanical Properties of Coarse-grained WC-based Cemented Carbides Sintered with Ultrafine WC or (W+C) as Additives

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Journal of Wuhan University of Technology(Materials Science) 2024年第2期39卷 399-409页

作者：于淞百闵凡路 LI De NOUDEM Guillaume Jacques zhang Hailong MA Jichang ZHAO Kui YAO Zhanhu 张建峰 College of Mechanics and Materials Hohai UniversityNanjing 210098China Key Laboratory of Geomechanics and Embankment Engineering Hohai UniversityMinistry of EducationNanjing 210098China CRISMAT-ENSICAEN(UMR-CNRS 6508) Universitéde Caen-Basse-NormandieF-14050 CaenFrance Shaanxi Aeronautic Carbide Tool Co.Ltd. Hanzhong 724200China CCCC Tunnel Engineering Co.Ltd. Beijing 100102China

The effects of ultrafine WC(WC_(UF),0.5μm) or W(1μm) and C(0.3μm)(W+C)_(UF) additives on the densification,microstructure and mechanical properties of coarse-grained cemented carbides were compared ***,the cemented carbides with WC_(UF)/(W+C)_(UF) additives are almost fully densification to be higher than 99%,and the average grain size is kept above 2.8μ*** WC_(UF) additive assists grains to(truncated)trigonal prism shape by two dimensional(2D) growth,whereas the(W+C)_(UF) additive assists grains to rounded shape by three dimensional(3D) growth,lowers WC contiguity and increases face-centered-cubic *** hardness and bending strength of(75WC_(C)-15WC_(UF))-10Co are 86.6 HRA and 2 272 MPa,respectively,both higher than those of(75WC_(C)-15(W+C)_(UF))-10Co,which could be ascribed to the enhanced densification and unblemished ***,the fracture toughness of the(75WC_(C)-15(W+C)_(UF))-10Co is 23.5 MPa·m^(1/2),higher than that of the(75WC_(C)-15WC_(UF))-10Co due to the uniform WC-Co structure and flexible binder phase.

关键词： coarse-grained WC-based cemented carbide ultrafine WC ultrafine(W+C) microstructure mechanical properties

高压直流输电保护定值整定依据及配合关系探讨

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电力系统自动化 2024年第17期48卷 181-189页

作者：王俊生蒲莹张建锋南京南瑞继保电气有限公司江苏省南京市211102 国网经济技术研究院有限公司北京市102209

在中国30余年的高压直流输电工程实践中形成了一套高压直流输电保护系统定值体系。文中结合近年来在应用中出现的复杂案例,对以下保护的定值整定依据开展了进一步探讨:阀短路保护启动定值需避开与换流阀并联的阻容回路的充电电流;换流... 详细信息

在中国30余年的高压直流输电工程实践中形成了一套高压直流输电保护系统定值体系。文中结合近年来在应用中出现的复杂案例,对以下保护的定值整定依据开展了进一步探讨:阀短路保护启动定值需避开与换流阀并联的阻容回路的充电电流;换流器过流保护过负荷段定值整定依据是直流控制系统失控造成直流运行电流超过控制的过负荷目标值,以及控制目标电流超过所设定的运行时间;直流低电压保护阈值及延时定值的整定需兼顾保护的后备功能,不确保与换相失败保护双桥原理长延时段配合。另外,深入探讨了交直流系统间、金属回线运行方式下直流保护间,以及高压线路再启动与低压再启动间的定值配合问题。最后,提出了高压直流输电保护系统的定值及定值间的配合应有一定的规范性和适度的灵活性的建议。

关键词：高压直流输电保护定值短路保护过流保护再启动

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无人机天钩回收航迹控制系统设计与实现

火力与指挥控制 2024年第2期49卷 56-62页

作者：张剑锋王朋飞西安爱生技术集团有限公司西安710065

天钩回收无人机在回收时对于航迹偏差等的控制精度要求苛刻,这对控制系统提出了挑战。提出一种用于无人机天钩回收航迹控制的新方法,设计无人机天钩回收航迹控制策略与流程,给出控制系统组成,基于某型无人机风洞试验数据,构建天钩回收... 详细信息

天钩回收无人机在回收时对于航迹偏差等的控制精度要求苛刻,这对控制系统提出了挑战。提出一种用于无人机天钩回收航迹控制的新方法,设计无人机天钩回收航迹控制策略与流程,给出控制系统组成,基于某型无人机风洞试验数据,构建天钩回收无人机的线性化和非线性模型,利用优化L1航迹控制方法设计了航迹控制律,并在实际飞行试验中得到了应用,验证了所设计控制系统的正确性与工程实现性,最终的飞行试验结果表明,无人机能够在控制系统作用下实现精确天钩回收,且具有良好的动态特性。

关键词：无人机天钩回收风洞试验数据 L1航迹控制

FGH4096粉末高温合金保载低周疲劳性能研究

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航空制造技术 2024年第12期67卷 44-50页

作者：鲁亮张剑锋徐瑶杨璟中国航发商用航空发动机有限责任公司上海200241

对FGH4096粉末高温合金在700℃下进行了总应变范围控制的低周疲劳试验和拉伸应变保载低周疲劳试验,研究了保载时间对滞回环特征、应力松弛、循环应力响应和疲劳寿命的影响及其产生作用的损伤机理。结果表明,保载时间的引入可导致FGH409... 详细信息

对FGH4096粉末高温合金在700℃下进行了总应变范围控制的低周疲劳试验和拉伸应变保载低周疲劳试验,研究了保载时间对滞回环特征、应力松弛、循环应力响应和疲劳寿命的影响及其产生作用的损伤机理。结果表明,保载时间的引入可导致FGH4096合金疲劳寿命降低,随保载时间的延长,疲劳寿命降低速率逐渐减小;在总应变范围0.9%下,不同保载时间下FGH96合金均表现出循环软化特征;在拉伸应变保持期间发生应力松弛现象,拉伸应变保持初始阶段,应力急剧下降,之后随保持时间延长而趋于平缓。微观组织分析表明,低周疲劳断口和保载低周疲劳断口均由疲劳源区、疲劳裂纹扩展区和瞬断区组成,疲劳源区均位于试样表面,扫描电镜下观察两种试样断口均未发现明显的蠕变断裂特征。

关键词： FGH4096 粉末高温合金保载低周疲劳应力松弛拉伸应变疲劳断口

石墨相氮化碳-硫化铋复合膜的染料分离与自清洁性能

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复合材料学报 2024年第1期41卷 293-306页

作者：李德黄海萌张天蒙李改叶董平 WANG Zhongchang 张建峰河海大学力学与材料学院南京211100 南京水联天下海水淡化技术研究院南京210000 Department Quantum&Energy Material International Iberian Nanotechnology LaboratoryBraga 4715-330Portugal

随着废水零排放的标准与要求不断深化,高效可持续的膜分离水处理技术成为研究热点,但面临着水通量低、易污染等问题。本研究通过石墨相氮化碳(g-C_(3)N_(4))、细菌纤维素(BC)和硫化铋(Bi_(2)S_(3))三者的有机结合,经真空辅助抽滤法制备... 详细信息

随着废水零排放的标准与要求不断深化,高效可持续的膜分离水处理技术成为研究热点,但面临着水通量低、易污染等问题。本研究通过石墨相氮化碳(g-C_(3)N_(4))、细菌纤维素(BC)和硫化铋(Bi_(2)S_(3))三者的有机结合,经真空辅助抽滤法制备得到光催化自清洁复合膜。通过一系列表征手段对粉末及膜材料进行物相结构与元素能态分析,研究了g-C_(3)N_(4)和Bi_(2)S_(3)不同添加量对复合膜染料分离性能的影响规律,探讨了两者在光催化下对染料的降解机制。结果表明,60wt%的g-C_(3)N_(4)、10wt%的BC、30wt%的Bi_(2)S_(3)与复合膜的综合性能最佳,水通量和截留率分别为23.48 L·m^(−2)·h^(−1)和100%,长时间过滤中依然保持16.65 L·m^(−2)·h^(−1)的水通量和90%左右的染料截留,在光照下浸泡3 h后通量恢复率达到96.5%,表明了该膜具有良好的光催化自清洁性能。该研究为高通量、可持续分离膜的设计提供了新的思路及基础探索。

关键词： g-C_(3)N_(4) Bi_(2)S_(3) 膜分离染料降解光催化机制细菌纤维素

自支撑聚吡咙基碳纤维负极材料的制备及其电化学性能

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纺织学报 2024年第6期45卷 23-31页

作者：徐振凯马鸣蔺多佳刘航张剑峰夏鑫新疆大学纺织与服装学院新疆乌鲁木齐830017

为探究聚吡咙基碳纤维作为自支撑负极材料的电化学性能,将聚羧酸铵盐(PCAAS)和不同质量分数的聚氧乙烯(PEO)混合溶液通过静电纺丝技术制备成前驱体纳米纤维,在500℃下亚胺化、环化形成聚吡咙(BBB)纤维,800℃下炭化形成聚吡咙基碳纤维(BC... 详细信息

为探究聚吡咙基碳纤维作为自支撑负极材料的电化学性能,将聚羧酸铵盐(PCAAS)和不同质量分数的聚氧乙烯(PEO)混合溶液通过静电纺丝技术制备成前驱体纳米纤维,在500℃下亚胺化、环化形成聚吡咙(BBB)纤维,800℃下炭化形成聚吡咙基碳纤维(BCF),将BCF作为负极材料装配成锂离子电池,探究不同质量分数PEO对BCF形貌结构和电化学性能的影响。结果表明:当PEO质量分数为6%时,前驱体纳米纤维表面光滑且直径均匀,炭化后的BCF直径减小了24.2%;聚吡咙作为芳杂环聚合物有密集的碳链,经炭化后含碳量高达97.5%;且咪唑和+吡咯的残留N导致较多无序碳的产生,N上的孤对电子作为载体促进电子迁移,并为Li提供了更多活性位点;在恒流充放电循环中,50 mA/g的电流密度下循环100圈后仍具有422.3 mA·h/g的放电比容量。

关键词：静电纺丝聚吡咙碳纳米纤维柔性自支撑电化学性能负极材料