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CFB灰-钢渣粉-矿渣-脱硫石膏全固废公路下伏采空区注浆材料特性研究

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中国公路学报 2024年第6期37卷 193-206页

作者：肖杰刘财壮刘志勇何建刚常锦张红日长沙理工大学交通运输工程学院湖南长沙410114 山西省交通科技研发有限公司黄土地区公路建设与养护技术交通行业重点实验室太原山西030006 交通运输部公路科学研究所道路结构与材料交通运输行业重点实验室北京100088 同济大学上海市轨道交通结构耐久与系统安全重点实验室上海201804 同济大学道路与交通工程教育部重点实验室上海201804 湖南人健宝固高新科技发展有限公司湖南长沙410201 长沙学院土木工程学院湖南长沙410022 广西交科集团有限公司广西南宁530007

为解决传统水泥基注浆材料成本高、能耗和污染大等问题,基于固废材料协同效应,以CFB粉煤灰(CFBFA)、钢渣微粉(SS)、高炉矿渣(BFS)和脱硫石膏(FGD)为原材料制备新型绿色环保的公路路基及桥隧下伏采空区全固废注浆材料。通过系列室内试验... 详细信息

为解决传统水泥基注浆材料成本高、能耗和污染大等问题,基于固废材料协同效应,以CFB粉煤灰(CFBFA)、钢渣微粉(SS)、高炉矿渣(BFS)和脱硫石膏(FGD)为原材料制备新型绿色环保的公路路基及桥隧下伏采空区全固废注浆材料。通过系列室内试验,研究了不同CFBFA掺量(80%、60%、50%、40%、20%)、水固比(1∶1.3、1∶1.4、1∶1.5、1∶1.6)及SS与BFS质量比(8∶2、6∶4)等因素对浆料的密度、流动度、析水率、结石率以及结石体单轴抗压强度(UCS)的影响,并结合XRD、TG、SEM等微观试验,分析了水化作用机理。研究结果表明:水固比相同时,随CFBFA掺量的增加,浆料流动度、结石率增大,而密度、析水率和UCS减小;原材料配比相同时,随水固比增大,浆料析水率增加,流动度、密度、结石率及UCS减小;水固比与CFBFA掺量相同时,随SS与BFS比值增大,浆料密度与析水率增大,流动度、结石率与UCS减小;CFBFA掺量、水固比对浆料工作性能的影响均显著,且CFBFA、BFS掺量对UCS影响大;结石体28 d UCS试件中仅有A1组的小于0.6 MPa,且最大值达16.71 MPa。综合考虑浆料工作、力学性能,同时结合经济性,提出了公路路基、桥隧下伏采空区注浆材料的施工建议配合比。浆料水化产物主要为C—S—(A)—H、AFt及Ca(OH)2,减小水固比、增加SS与BFS掺量、提高试件养护龄期均可使水化产物(C—S—(A)—H、AFt)数量增多,试件更密实,UCS更高,且BFS掺量增加有助于Ca(OH)2二次水化和AFt等水化产物的生成。实际应用中,通过调整CFBFA、SS、BFS与FGD全固废注浆材料配合比,其工作性能及UCS均能满足相关规范的要求,用于采空区注浆是切实可行的。

关键词：路基工程 CFB灰-钢渣粉-矿渣水化反应机理注浆材料

New sustainable polymers with on-demand depolymerization property

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Science China Chemistry 2024年第9期67卷 2803-2841页

作者： Yangyang Sun Zesheng An Yanshan Gao Rongrong Hu Ye Liu Hua Lu Xiao-Bing Lu Xuan Pang Anjun Qin Yong Shen Youhua Tao Yu-Zhong Wang Junpeng Wang gang Wu Guang-Peng Wu Tie-Qi Xu Xing-Hong Zhang Yuetao Zhang Zhenbiao Zhang jian-Bo Zhu Miao Hong Zhibo Li State Key Laboratory of Organometallic Chemistry Shanghai Institute of Organic ChemistryChinese Academy of SciencesShanghai 200032China State Key Laboratory Base of Eco-Chemical Engineering College of Chemical EngineeringQingdao University of Science and TechnologyQingdao266042China State Key Laboratory of Supramolecular Structure and Materials College of ChemistryJilin UniversityChangchun 130012China State Key Laboratory of Luminescent Materials and Devices Guangdong Provincial Key Laboratory of Luminescence from Molecular AggregatesSouth China University of TechnologyGuangzhou 510640China State Key Laboratory of Fine Chemicals Frontiers Science Center for Smart MaterialsDalian University of TechnologyDalian 116024China Beijing National Laboratory for Molecular Sciences Center for Soft Matter Science and EngineeringKey Laboratory of Polymer Chemistry and Physics of Ministry of EducationCollege of Chemistry and Molecular EngineeringPeking UniversityBeijing 100871China Key Laboratory of Polymer Ecomaterials Changchun Institute of Applied ChemistryChinese Academy of SciencesChangchun 130022China The Collaborative Innovation Center for Eco-Friendly and Fire-Safety Polymeric Materials(MoE) National Engineering Laboratory of Eco-Friendly Polymeric Materials(Sichuan)College of ChemistryState Key Laboratory of Polymer Materials EngineeringSichuan UniversityChengdu 610064China School of Polymer Science and Polymer Engineering the University of AkronAkronOH 44325USA MOE Key Laboratory of Macromolecular Synthesis and Functionalization Department of Polymer Science and EngineeringZhejiang UniversityHangzhou 310027China State and Local Joint Engineering Laboratory for Novel Functional Polymeric Materials Jiangsu Key Laboratory of Advanced Functional Polymer Design and ApplicationSuzhou Key Laboratory of Macromolecular Design and Precision SynthesisCollege of ChemistryChemical Engineering and Materials ScienceSoochow UniversitySuzhou 215123China

To combat the crisis of today's synthetic polymers arising from unsustainable production and disposal,it is essential for the synthetic polymer community to reshape the current polymer industry with sustainable *** an emerging class of sustainable polymers,the development of chemically depolymerizable polymers(CDPs),which can undergo closed-loop depolymerization/repolymerization cycles to reproduce virgin polymers without the loss of properties from recovered monomers,offers an ideal solution to preserve finite natural resources,provides a feasible solution to the end-of-life issue of polymer waste,and thereby establishes a circular materials ***,two grand key challenges have been encountered in the establishment of practically useful CDPs:how to balance polymerization and depolymerization ability and how to unify conflicted depolymerizability and physical ***,this critical review article presents our vision for summarizing feasible strategies to overcome the above two significant challenges and the design principles for constructing an ideal CDP by highlighting selected major progress made in this rapidly expanding field.

关键词： chemically depolymerizable polymers sustainable polymers depolymerization monomer recovery degradation plastics

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潜蚀的局部守恒有限元和有限体积交替解法

岩土力学 2024年第3期45卷 917-926页

作者：王刚邓泽之金伟张建民重庆大学山地城镇建设与新技术教育部重点实验室重庆400045 重庆大学土木工程学院重庆400045 中国电建集团成都勘测设计院有限公司四川成都610072 清华大学土木水利学院北京100084

潜蚀的模拟需要计算土中的渗流过程以及土中细粒随孔隙水流的运移过程。常规有限元法在求解纯运移方程时存在稳定性问题,为此提出了一个采用有限元法求解渗流方程、有限体积法求解细粒运移方程的交替方法。鉴于常规有限元法不能给出满... 详细信息

潜蚀的模拟需要计算土中的渗流过程以及土中细粒随孔隙水流的运移过程。常规有限元法在求解纯运移方程时存在稳定性问题,为此提出了一个采用有限元法求解渗流方程、有限体积法求解细粒运移方程的交替方法。鉴于常规有限元法不能给出满足有限体积法输入要求的流速场,给出了一个基于单元不平衡流量总体再平衡修正单元边界流速的算法。利用该算法对有限元计算的单元边界流速进行局部守恒处理,即可实现在同一有限元网格上利用有限体积法求解细粒运移方程,因此可以方便地和现有的有限元计算程序结合。算例验证表明,所提出的局部守恒处理算法及交替解法计算效率高且具有可接受的精度,是模拟潜蚀问题的一条简单实用的途径。

关键词：潜蚀渗流有限元法有限体积法局部守恒

A typical Riedel Shear Pattern of active faults in the Laolongwan Basin， Northeastern Tibetan Plateau

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Journal of Earth Science 2024年

作者： Kai-Xun WANG Xiao-gang LI Wei SHI Xiang-You FENG Qian YANG Jie LI Zheng-jian XU Zhou-Jun PENG Shao-Hua XU Yi-Xue XIONG Mao LIN School of Petroleum Engineering， Chongqing University of Science and Technology Chongqing Key Laboratory of Complex Oil and Gas Field Exploration and Development， Chongqing University of Science and Technology Geophysics Research Institute of jiangsu Oilfield Company，SINOPEC SinoProbe Laboratory， Chinese Academy of Geological Sciences Academy of Dazu Rock Carvings

Riedel shear system， consists of some different oriented faults and derivative structures， is an important pattern of tectonic activity and stress regulation， which has been widely applied to the interpretation of intracontinental deformation. The Laolongwan Basin， located in the western Haiyuan fault zone at the northeastern Tibetan Plateau， is a key area to study the Cenozoic intracontinental deformation in the northeastern plateau， which formed a complex active fault system during the Cenozoic. However， the activity of these faults and their kinematic mechanism remain unclear. In this contribution， based on detailed structural interpretation of remote sensing image， field observations and OSL dating analysis， we propose a Riedel Shear model of active fault system in the Laolongwan basin. Our observations show that this active fault system is consist of four major faults， including the left strike-slip Hasi Shan Fault and Zihong Shan Fault with thrusting characteristics， the Southern Zihong Shan thrust fault and the Mijia Shan normal fault. The fault offset and OSL dating analyses suggest that the left-lateral slip rate of the Hasi Shan Fault is ～ 2.60-3.01 mm/a since ca. 15 ka， whereas the Zihong Shan Fault is ～ 1.10-1.13 mm/a since ca. 14 ka. Fault-slip vectors analyses indicate that the active fault system related to the Riedel Shear in the Laolongwan Basin was controlled by the regional ENE-WSW compressive stress. This compression also caused the significant left-lateral strike-slip movement along the Haiyuan Fault zone at the same time， which might result from the northeastward continuous expanding of the Tibetan Plateau during the late Cenozoic.

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Stratigraphic framework and sedimentary evolution during the Cryogenian-Ediacaran transition in northeastern Sichuan Basin,South China

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Petroleum Science 2024年第2期21卷 823-835页

作者： Yi Zhang Hong-Wei Kuang Yong-Qing Liu Qiang Shi Dong-Ge Wang Ke-Ning Qi Yu-Chong Wang Da-Wei Qiao Xiao-Shuai Chen Li-Zhi Wu Meng Tian Long Chen Yi Wei Liao-Yuan Song jian Li Zi-gang Wu Yun-Qian Liu Xuan-Chun Liu An-Qing Chen Zhi-Wei Liao Institute of Geology Chinese Academy of Geological SciencesBeijing100037China State Key Laboratory of Coal Mine Disaster Dynamics and Control School of Resources and Safety EngineeringChongqing UniversityChongqing400044China No.205 Geological Team Chongqing Bureau of Geology and Minerals ExplorationChongqing401121China Chongqing Institute of Geological Survey Chongqing401122China Key Laboratory of Deep-time Geography and Environment Reconstruction and Applications of Ministry of Natural Resources Chengdu University of TechnologyChengdu610059SichuanChina

The northeastern Sichuan area in the northern Yangtze margin has unique Ediacaran geological records,especially the Doushantuo Formation(DST),and become a hot research area in recent ***,the Cryogenian-Ediacaran(C-E)boundary has not been precisely identified,which restricts the in-depth study of geological information during this crucial transitional period and is unfavorable for a systematic and complete understanding of the Yangtze Block and even the global paleogeographic *** study conducted stratigraphy,sedimentology,and chronostratigraphy to establish the stratigraphic framework and sedimentary evolution of the C-E transition strata in northeastern *** results showed that the Ediacaran sediments,without the cap dolomite,unconformably overlaid the Cryogenian sediments in the studied *** Member II of the DST,characterized by 50-160 m of red-green sandstone(approximately equivalent to the original Chengkou“Guanyinya Formation”),directly overlaid the Cryogenian sediments and displayed a 623±2.3 Ma maximum depositional age from the detrital zircon U-Pb *** stratigraphic correlations indicate that the C-E transition strata in northeastern Sichuan had a consistent lithological association and sedimentary sequence characteristics but differed from the Three ***,the upper Nantuo massive glacial diamictites transition to the icebergs rafted lonestone-bearing mudstones at the top,then change upward to DST barrier coast *** proposed DST of the northeastern Sichuan Basin was divided into three lithostratigraphic members without the regional Member I cap dolomite:(i)Member II purple-red,gray-green sandstone strata,(ii)MemberⅢblack mudstone strata,and(iii)Member IV P-Mn bearing *** the C-E transition,the study area experienced(i)the global deglaciation stage in the terminal Marinoan glaciation and(ii)the filling-leveling up stage with clastic rocks in the early ***,the early Ediacaran

关键词： Marinoan glaciation Doushantuo formation Cap dolomite Deglacial and coastal deposits Detrital zircon U-Pb dating

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“后理论”的行动纲领、基本诉求与价值取向

山东社会科学 2024年第5期 47-56页

作者：杨建刚张林轩山东大学文艺美学研究中心

“后理论”的核心问题是对“大写的理论”的反思与重构,它标志着理论研究步入了需要重新探索自身的功能效用、生长模式、价值诉求以及未来走向的新阶段。“后理论”的行动纲领是从神谕式的“大写的理论”转向“小理论”,以此明确理论应... 详细信息

“后理论”的核心问题是对“大写的理论”的反思与重构,它标志着理论研究步入了需要重新探索自身的功能效用、生长模式、价值诉求以及未来走向的新阶段。“后理论”的行动纲领是从神谕式的“大写的理论”转向“小理论”,以此明确理论应具备的实践导向和价值关怀。“后理论”的基本诉求是回归文学,推动理论与文学之间的互动与共生,使理论能够从丰富的文学经验中获取养分。“后理论”的价值取向是反对传统的人文主义和人类中心主义的思维范式,积极参与后人类主体性的建构。同时,“后理论”倡导将理论置于纷繁复杂的现实世界之中,并承担起帮助人们在不稳定状况中继续向好而生的重要使命。

关键词：后理论大写的理论小理论后人类

Veno-arterial extracorporeal membrane oxygenation as a bridge in patients with advanced heart failure:Initial experience in China

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Chinese Medical Journal 2024年第10期137卷 1228-1230页

作者： Jing Wang jian Wang Sizhe Gao gang Liu Qian Wang Shujie Yan Boyi Zhou Yuan Yuan Guodong Gao Bingyang Ji Department of Cardiopulmonary Bypass Fuwai hospitalNational Center for Cardiovascular DiseaseChinese Academy of Medical Sciences&Peking Union Medical CollegeBeijing 100037China

To the Editor:Veno-arterial extracorporeal membrane oxygenation(VA-ECMO)has been used as a bridge in patients with advanced heart failure(AdHF)while waiting for heart transplantation(HTx).Many studies reported by developed countries have confirmed the advantages of VA-ECMO in terms of bridge to left ventricular assist device(LVAD)or HTx,with stabilizing the condition and improving the possibility of further treatment of patients.[1-3]Recent data from the Extracorporeal Life Support Organization(ELSO)[4]indicated that ECMO used as a bridge has increased by 20.5%over a ***,to date,there are few studies on the bridge experience of VA-ECMO in the mainland of China.

关键词： patients arterial ventricular

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嵌入式轨道系统振动传递研究

城市轨道交通研究 2024年第7期27卷 197-203页

作者：杨刚何远鹏韩健罗信伟张智鑫何况西南交通大学轨道交通运载系统全国重点实验室成都610031 成都市新筑交通科技有限公司成都611430 广州振宁交通科技有限公司成都611430 广州地铁设计研究院股份有限公司广州510010

[目的]嵌入式轨道的阻尼较大,有较好的减振降噪性能,因此有必要对嵌入式轨道的减振降噪机理进行研究。[方法]以广州地铁14号线为例,对嵌入式轨道系统与普通扣件式轨道系统进行了静态与动态的振动测试;基于现场测试的轨道结构频响函数及... 详细信息

[目的]嵌入式轨道的阻尼较大,有较好的减振降噪性能,因此有必要对嵌入式轨道的减振降噪机理进行研究。[方法]以广州地铁14号线为例,对嵌入式轨道系统与普通扣件式轨道系统进行了静态与动态的振动测试;基于现场测试的轨道结构频响函数及纵向衰减率,分析嵌入式轨道系统的减振特性。[结果及结论]嵌入式轨道系统在垂向减振中存在着明显的工作频段;嵌入式轨道在绝大多数频段中的振动加速度幅值均小于普通扣件式轨道的振动加速度幅值;当振动频率为550~1200 Hz时,嵌入式轨道的高分子阻尼材料与弹性垫板的减振体系在该频段具有良好的吸振能力;嵌入式轨道与调频式钢轨阻尼器一样存在固定的调整频段,其调整频带范围在振动频率为400 Hz附近;相比于离散支承的轨道结构形式,连续支承的轨道结构形式在振动频率大于750 Hz频段的钢轨振动衰减率更优。

关键词：地铁嵌入式轨道系统振动传递

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输电铁塔装配式基础抗剪键连接的剪切性能

浙江大学学报（工学版） 2024年第6期58卷 1153-1160页

作者：吕庆胡嘉飞麻坚华献宏徐刚浙江大学建筑工程学院浙江杭州310058 金华电力设计院有限公司浙江金华321000 国网浙江省电力有限公司金华供电公司浙江金华321000

预制构件连接方法及其界面剪切性能影响整个输电铁塔装配式基础的受力和变形.针对螺栓连接易松动、变形大之类的问题,提出采用高强灌浆料灌注成形的十字形抗剪键作为输电铁塔装配式基础连接方案.采用室内剪切试验和数值模拟,研究该抗剪... 详细信息

预制构件连接方法及其界面剪切性能影响整个输电铁塔装配式基础的受力和变形.针对螺栓连接易松动、变形大之类的问题,提出采用高强灌浆料灌注成形的十字形抗剪键作为输电铁塔装配式基础连接方案.采用室内剪切试验和数值模拟,研究该抗剪键连接的剪切性能,并与常用的螺栓连接进行对比分析.结果表明:十字形抗剪键剪切破坏模式为剪断型脆性破坏,破坏形态表现为以抗剪键为中心向外略有扩展成菱形.和螺栓连接相比,抗剪键连接的剪切强度略低,但剪切刚度显著提高.浇筑过程中灌浆料外溢对界面抗剪强度有提高作用.抗剪键的抗剪性能与灌浆料强度正相关,但提高灌浆料强度对抗剪性能提升并不明显.抗剪键深度对抗剪性能有影响,但在抗剪键深度超过20 mm后,抗剪键的抗剪性能不再提高.根据剪切试验和数值模拟结果,建议十字形抗剪键设计为长200 mm、宽20 mm、深20 mm.

关键词：输电铁塔装配式基础十字形抗剪键剪切性能剪切试验