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Prussian Blue Analogue‑Templated Nanocomposites for Alkali‑Ion Batteries:Progress and Perspective

Nano-Micro Letters 2025年第1期17卷 216-261页

作者： jian‑En zhou Yilin Li Xiaoming Lin Jiaye Ye Key Laboratory of Theoretical Chemistry of Environment Ministry of EducationSchool of ChemistrySouth China Normal UniversityGuangzhou 510006People’s Republic of China School of Chemistry and Physics Faculty of ScienceQueensland University of Technology2 George StreetBrisbaneQLD 4000Australia Centre for Materials Science Queensland University of Technology2 George StreetBrisbaneQLD 4000Australia

Lithium-ion batteries(LIBs)have dominated the portable electronic and electrochemical energy markets since their commercialisation,whose high cost and lithium scarcity have prompted the development of other alkali-ion batteries(AIBs)including sodium-ion batteries(SIBs)and potassium-ion batteries(PIBs).Owing to larger ion sizes of Na^(+)and K^(+)compared with Li^(+),nanocomposites with excellent crystallinity orientation and well-developed porosity show unprecedented potential for advanced lithium/sodium/potassium *** enticing open rigid framework structures,Prussian blue analogues(PBAs)remain promising self-sacrificial templates for the preparation of various nanocomposites,whose appeal originates from the well-retained porous structures and exceptional electrochemical activities after thermal *** review focuses on the recent progress of PBA-derived nanocomposites from their fabrication,lithium/sodium/potassium storage mechanism,and applications in AIBs(LIBs,SIBs,and PIBs).To distinguish various PBA derivatives,the working mechanism and applications of PBA-templated metal oxides,metal chalcogenides,metal phosphides,and other nanocomposites are systematically evaluated,facilitating the establishment of a structure–activity correlation for these *** on the fruitful achievements of PBA-derived nanocomposites,perspectives for their future development are envisioned,aiming to narrow down the gap between laboratory study and industrial reality.

关键词： Prussian blue analogues Self-sacrificial template Lithium-ion batteries Sodium-ion batteries Potassium-ion batteries

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Pharmacological targeting cGAS/STING/NF-κB axis by tryptanthrin induces microglia polarization toward M2 phenotype and promotes functional recovery in a mouse model of spinal cord injury

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Neural Regeneration Research 2025年第11期20卷 3287-3301页

作者： Ziwei Fan Mengxian Jia jian zhou zhoule Zhu Yumin Wu Xiaowu Lin Yiming Qian Jiashu Lian Xin Hua jianhong Dong Zheyu Fang Yuqing Liu Sibing Chen Xiumin Xue Juanqing Yue Minyu Zhu Ying Wang Zhihui Huang Honglin Teng Department of Orthopedics(Spine Surgery) the First Affiliated Hospital of Wenzhou Medical UniversityWenzhouZhejiang ProvinceChina School of Pharmacy Hangzhou Normal UniversityHangzhouZhejiang ProvinceChina Department of Neurology The First Affiliated Hospital of Wenzhou Medical UniversityWenzhouZhejiang ProvinceChina Department of Pathology Affiliated Hangzhou First People’s HospitalSchool of MedicineWestlake UniversityHangzhouZhejiang ProvinceChina Department of Clinical Research Center Affiliated Hangzhou First People’s HospitalSchool of MedicineWestlake UniversityHangzhouZhejiang ProvinceChina

The M1/M2 phenotypic shift of microglia after spinal cord injury plays an important role in the regulation of neuroinflammation during the secondary injury phase of spinal cord *** of shifting microglia polarization from M1(neurotoxic and proinflammatory type)to M2(neuroprotective and anti-inflammatory type)after spinal cord injury appears to be *** possesses an anti-inflammatory biological ***,its roles and the underlying molecular mechanisms in spinal cord injury remain *** this study,we found that tryptanthrin inhibited microglia-derived inflammation by promoting polarization to the M2 phenotype in *** promoted M2 polarization through inactivating the cGAS/STING/NF-κB ***,we found that targeting the cGAS/STING/NF-κB pathway with tryptanthrin shifted microglia from the M1 to M2 phenotype after spinal cord injury,inhibited neuronal loss,and promoted tissue repair and functional recovery in a mouse model of spinal cord ***,using a conditional co-culture system,we found that microglia treated with tryptanthrin suppressed endoplasmic reticulum stress-related neuronal *** together,these results suggest that by targeting the cGAS/STING/NF-κB axis,tryptanthrin attenuates microglia-derived neuroinflammation and promotes functional recovery after spinal cord injury through shifting microglia polarization to the M2 phenotype.

关键词： cGAS/STING functional recovery microglia neuroinflammation neuroprotection nuclear factor-κB polarization spinal cord injury tryptanthrin

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Emergent Geometry of KP Hierarchy

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Acta Mathematica Sinica,English Series 2024年第1期40卷 3-25页

作者： jian zhou Department of Mathematical Sciences Tsinghua UniversityBeijng 100084P.R.China

We explain how to construct a quantum deformation of a spectral curve associated to a tau-function of the KP *** construction is applied to Witten-Kontsevich tau-function to give a natural explanation of some earlier ... 详细信息

关键词： KP hierarchy tau-functions spectral curves

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Tailoring geometric phases of two-dimensional functional materials under light:a brief review

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International Journal of Smart and Nano Materials 2020年第3期11卷 191-206页

作者： jian zhou Center for Advancing Materials Performance from the Nanoscale State Key Laboratory for Mechanical Behavior of MaterialsXi’an Jiaotong UniversityXi’anChina

Information storage relies on the fast and reversible memory devices,which can read and write data easily with low energy *** addition,in order to pursue high data storage density and miniatur-izing device size,low-dimensional materials with large area to volume ratio would be *** to date,there are already a lot of explorations of two-dimensional functional material based devices with interesting phase *** to Ginzburg-Landau theory,phase transition occurs when order parameter changes,under external stimuli such as temperature,electric field,or external *** than these,novel phase transition mechan-isms under low-frequency light irradiation has been recently *** light frequency is below the corresponding energy bandgap of the semiconductors,which intuitively has very small scattering cross ***,according to thermodynamic theory,there could have light-matter *** struc-ture can be changed and manipulated under light *** ion displacements are strong enough,phase transition could *** optically driven phase transition approach requires no direct contacts with the sample,so that this procedure is easily *** this mini-review,we briefly summarize the basic theory,computational predictions and some very recent experiments on low-frequency light induced phase transition in various systems.

关键词： Phase transition optomechanics ferroelectric materials 2D materials

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Novel rockburst prediction criterion with enhanced explainability employing CatBoost and nature-inspired metaheuristic technique

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Underground Space 2024年第6期19卷 101-118页

作者： Yingui Qiu jian zhou School of Resources and Safety Engineering Central South UniversityChangsha 410083China

Rockburst is a major challenge to hard rock engineering at great *** and timely assessment of rockburst risk can avoid unnecessary casualties and property *** the existence of various methods for rockburst assessment,there remains an urgent need for a comprehensive and reliable criterion that is easy to both apply and *** a new rockburst criterion based on simple parameters can potentially fill this *** its advantages,this criterion can facilitate a more effective and efficient prediction of rockburst potential,thereby contributing significantly to enhancing safety *** this paper,combined with the internal and external factors of rockburst,four control variables(i.e.,integrity index,stress index,brittleness index,and elastic energy index)were selected to be incorporated into a comprehensive rockburstability index(RBSI).Based on 116 sets of rockburst cases,the rockburst potential was accurately quantified and predicted using the categorical boosting(CatBoost)model and the nature-inspired metaheuristic African vultures optimization algorithm(AVOA).In its performance validation,the criterion achieved the highest accuracy of 90.48%,verifying the reliability and effectiveness of the proposed RBSI ***,an interpretive method was applied to analyze the variable influence on the criterion,facilitating the explanation of predictions and the analysis of the formula’s robustness under different *** general,compared with existing criterion methods involving relevant indicators,the newly proposed RBSI criterion enhances the accuracy of rockburst potential prediction,and it can effectively and swiftly evaluate the preliminary risk of ***,a graphical user interface was developed to provide a clear visualization of the assessment of rockburst potential.

关键词： Rockburst criterion CatBoost Metaheuristic optimization Model interpretation Graphical user interface

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Procreating Tiles of Double Commutative-Step Digraphs

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Acta Mathematicae Applicatae Sinica 2008年第2期24卷 185-194页

作者： jian-qin zhou Telecommunication School Hangzhou Dianzi University Hangzhou 310018 China Department of Computer Science Anhui University of Technology Ma'anshan 243002 China

Double commutative-step digraph generalizes the double-loop digraph. A double commutative-step digraph can be represented by an L-shaped tile, which periodically tessellates the plane. Given an initial tile L（l, h, x, y）, Aguil5 et al. define a discrete iteration L（p） = L（l ＋ 2p, h ＋ 2p, x ＋ p, y ＋ p）, p = 0, 1, 2,..., over L-shapes （equivalently over double commutative-step digraphs）, and obtain an orbit generated by L（l, h, x,y）, which is said to be a procreating k-tight tile if L（p）（p = 0, 1, 2, ~ ~ ~ ） are all k-tight tiles. They classify the set of L-shaped tiles by its behavior under the above-mentioned discrete dynamics and obtain some procreating tiles of double commutative-step digraphs. In this work, with an approach proposed by Li and Xu et al., we define some new discrete iteration over L-shapes and classify the set of tiles by the procreating condition. We also propose some approaches to find infinite families of realizable k-tight tiles starting from any realizable k-tight L-shaped tile L（l, h, x, y）, 0 ≤ y - x ≤ 2k ＋ 2. As an example, we present an infinite family of 3-tight optimal double-loop networks to illustrate our approaches.

关键词： Double-loop digraph double commutative-step digraph L-shaped tile procreate infinite family

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Viscoelastic microfluidics: progress and challenges

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Microsystems & Nanoengineering 2020年第1期6卷 63-86页

作者： jian zhou Ian Papautsky Department of Bioengineering University of Illinois at ChicagoChicagoIL 60607USA

The manipulation of cells and particles suspended in viscoelastic fluids in microchannels has drawn increasing attention,in part due to the ability for single-stream three-dimensional focusing in simple channel *** in the understanding of non-Newtonian effects on particle dynamics has led to expanding exploration of focusing and sorting particles and cells using viscoelastic *** factors,such as the driving forces arising from fluid elasticity and inertia,the effect of fluid rheology,the physical properties of particles and cells,and channel geometry,actively interact and compete together to govern the intricate migration behavior of particles and cells in ***,we review the viscoelastic fluid physics and the hydrodynamic forces in such flows and identify three pairs of competing forces/effects that collectively govern viscoelastic *** discuss migration dynamics,focusing positions,numerical simulations,and recent progress in viscoelastic microfluidic applications as well as the remaining ***,we hope that an improved understanding of viscoelastic flows in microfluidics can lead to increased sophistication of microfluidic platforms in clinical diagnostics and biomedical research.

关键词： Viscoelastic flow Elastic and inertial force Microfluidics Numerical modeling Particle separation and cell sorting 3D focusing

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Thermal analysis of walls in a new-type billet caster tundish with a vacuum shell

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Journal of Iron and Steel Research International 2017年第5期24卷 501-507页

作者： jian-bo Xie jian-an zhou Lan-hua zhou Bao Wang Hua Zhang State Key Laboratory of Refractories & Metallurgy Wuhan University of Science & Technology Wuhan 430081 Hubei China Key Laboratory of Ferrous Metallurgy and Resources Utilization Ministry of Education Wuhan University of Science & Technology Wuhan 430081 Hubei China School of Resources and Environmental Engineering Panzhihua University Panzhihua 617000 Sichuan China

To reduce thermal loss from molten steel in a tundish during continuous casting production, a new tundish fabricated by welding radiation-proof steel plates onto the steel plates of the exterior walls of a billet caster tundish was proposed. This new tundish was used to investigate the effect of pressures inside the vacuum chamber on the uniformity of the temperature of molten steel and the thermal conditions of the vacuum layer. The results show that the conversion radiation coefficient is not sensitive to pressure and its value at high temperatures is merely 1.5 times greater than that at low temperatures. Pressure is the key factor af- fecting additional factor of conversion convection. This factor is more than 100 times greater at 10-5 Pa than at 10-2 Pa, and the temperature at inner points at 10-2 Pa is, on average, 4 K higher than that at 10-5 Pa. Meanwhile, the local temperature difference of the inlet at 10-2 Pa is 1 K higher than that at 10-5 Pa. Thus, the proposed vacuum billet caster tundish can achieve low superheat teeming of steel because of the ther- mal preservation capability of the vacuum, which helps to reduce the tapping temperature and improve the uniformity of the temperature of steel.

关键词： Tundish Vacuum chamber Pressure Thermal preservation Superheat

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Three-dimensional numerical simulation and earth pressure analysis on double-row piles with consideration of spatial effects

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Journal of Zhejiang University-Science A(Applied Physics & Engineering) 2011年第10期12卷 758-770页

作者： Zi-han WANG jian zhou Department of Geotechnical Engineering Tongji University Shanghai 200092 China

As a new kind of technology in retaining structures, the characteristics of double-row piles are significantly affected by spatial effects. In this paper, double-row piles as a retaining structure are simulated numerically in three-dimension by finite element software PLAXIS 3D FOUNDATION. The behavior differences of piles in different positions around the foundation pit are analyzed. By changing the parameters, including the length-width ratio, the excavation depth, the distance between rows and the diameter of piles, the variations of the lateral deformation, the bending moment and the earth pressure around the piles are determined. The reasonable values of parameters and some suggestions with consideration of earth pressure are proposed for the design of double-row piles as a retaining structure. The results show that the lateral deformation and bending moment are the largest in the middle of long side of the foundation pit, which is identified as the most unfavorable position. It is indicated that the earth pressure between rows above pit bottom is close to active earth pressure, while the earth pressure between rows under pit bottom is close to static earth pressure. It is suggested that 1/2-2/3 of pile length, 0.6-1.2 m, 3d-6d, and 2d-2.5d be chosen as embedded depth of piles, diameter of piles, distance between rows, and distance between piles, respectively, where d is the pile diameter.

关键词： Double-row piles Retaining structure Spatial effect Finite element Earth pressure

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Coupled 3D discrete-continuum numerical modeling of pile penetration in sand

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Journal of Zhejiang University-Science A(Applied Physics & Engineering) 2012年第1期13卷 44-55页

作者： jian zhou Qi-wei jian Jiao ZHANG jian-jun GUO Department of Geotechnical Engineering Tongji University Shanghai 200092 China School of Civil Engineering and Transportation Shanghai Technical College of Urban Management Shanghai 200432 China Sichuan Provincial Chuanjian Investigation and Design Institute Chengdu 610017 China

A coupled discrete-continuum simulation incorporating a 3D aspect and non-circular particles was performed to analyze soil-pile interactions during pile penetration in sand.A self-developed non-circular particle numerical simulation program was used which considered sand near the pile as interacted particles using a discrete element method;the sand away from the pile was simulated as a continuous medium exhibiting linear elastic *** domain analyzed was divided into two *** forces at the interface between the two zones were obtained from a discrete zone and applied to the continuum boundaries as nodal forces,while the interface velocities were obtained from the continuum zone and applied to the discrete *** show that the coupled discrete-continuum simulation can give a microscopic description of the pile penetration process without losing the discrete nature of the zone concerned,and may significantly improve computational efficiency.

关键词： Coupled numerical modeling Discrete-continuum Micro and macro 3D simulation Non-circular particles Pilepenetration mechanism

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