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A novel chemosensor-bipyridyl end capped hyperbranched conjugated polymer

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Chinese Chemical Letters 2011年第6期22卷 725-728页

作者： Xin Meng Qing Guo He Hui Min Cao jian gong cheng State Key Laboratory of Transducer Technology Shanghai Institute of Microsystem and Information Technology Chinese Academy of Sciences Shanghai 200050 China Graduate School of the Chinese Academy of Sciences Beijing 100039 China

A novel hyperbranched conjugated chemosensor with bipyridyl groups as periphery groups（BPY-HPV） was ***-HPV was highly sensitive to metal ions（Cu^（2＋）,Ni^（2＋）） for the strong coordination interaction（K_（sv） at the order of 10~7 mol^（-1） L） monitored by fluorescence ***,by hydrogen bonds and charge transfer interaction,BPY-HPV shows strong interaction with 1,1,2,2-tetrachloroethane whatever in CH_2Cl_2（K_（sv）～10~6 mol^（-1） L） or film.

关键词： Hyperbranched conjugated polymer Hydrogen bonding Fluorescence Tetrachloroethane

Synthesis and properties of a luminescent organic material with triphenylamine and pentiptycene units

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Chinese Chemical Letters 2007年第7期18卷 820-822页

作者： Qing Guo He Xi Peng Guo jian gong cheng Feng Lian Bai Shanghai Institute of Microsystem and Information Technology Chinese Academy of Sciences Shanghai 200050 China Institute of Chemistry Chinese Academy of Sciences Beijing 100080 China

A donor-bridge-donor compound for blue light-emitting with triphenylamine as donor and pentiptycene derivative units as bridge was synthesized via Sonogashira reaction. The chemical structure was confirmed by NMR and MALDI-TOF MS. It emits blue light peaked at 442 nm with a FWHM of 59 nm in CH2Cl2. Fluorescent quantum efficiency in THF is 82% relative to 9,10-diphenylanthracene. A slight hypsochromic shift was found in its drop-cast film. Cyclic voltammetry revealed that it has high HOMO level corresponding to hole transporting character.

关键词： Triphenamine Pentiptycene Sonogashira reaction Blue light Hole transport

Recent advances in fluorescence sensor for the detection of peroxide explosives

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Chinese Chemical Letters 2016年第8期27卷 1429-1436,1471页

作者： Yu Zhang Yan-Yan Fu De-Feng Zhu Jia-Qiang Xu Qing-Guo He jian-gong cheng State Key Lab of Transducer Technology Shanghai Institute of Microsystem and Information TechnologyChinese Academy of Sciences Department of Chemistry College of SciencesShanghai University

The detection of peroxide explosives（PEs） has attracted considerable attention all over the world in global security owing to their simple preparation,poor chemical stability and easy *** recent years,great efforts have been devoted to developing organic fluorescence sensors for detecting the PEs because of their fast response,high sensitivity and high *** this short review,we firstly discuss the sensing mechanisms for fluorescence based the PEs ***,we reviewed recent progress of PE probes in the nearly 5 years and the design strategies of the material structures to enhance the sensitivity or selectivity,such as conjugated polymers and assembled nanoparticles.

关键词： Fluorescence Sensor Peroxide explosives Vapor Redox reaction

Organic semiconductors-coated polyacrylonitrile(PAN) electrospun nanofibrous mats for highly sensitive chemosensors via evanescent-wave guiding effect

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Chinese Chemical Letters 2013年第7期24卷 643-646页

作者： Kang-Yi Hua Chang-Min Deng Chao He Li-Qi Shi De-Feng Zhu Qing-Guo He jian-gong cheng State key of Transducer Technology Shanghai Institute of Microsystem and Information TechnologyChinese Academy of Science Graduate School of Chinese Academy of Sciences

We report the first use of organic semiconductors （OSCs）-coated PAN nanofibrous mats as highly responsive fluorescence quenching-based chemosensors for 2,4,6-trinitrotoluene （TNT） and H2O2 detection in vapor phase. Conjugated polymers, poly（triphenylaminealt-biphenylene vinylene）（TPA- PBPV）, and small organic molecules, l-horonic-ester pyrene and 1,6-bisboron-ester pyrene, were coated onto the nanofibers fabricated by electrospinning. By introducing the nanofibers structure, a 9-fold fluorescence intensity enhancement and a 14-fold sensitivity enhancement were achieved, which could be attributed to its high area-to-volume ratio, excellent gas permeability, and more importantly, the evanescent-wave effect occurred once the diameters of the fibers were small enough. Since the organic semiconductors coated onto the nanofibrous mats could be replaced by other functional materials, the nanofibers-enhanced detection strategies could be extended to more general domains including chemical and environmental detection.

关键词： Electrospinning Nanofiber Evanescent wave Sensor Vapor

A pure blue light emitting binaphthyl derivative:Synthesis and properties

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Chinese Chemical Letters 2008年第4期19卷 431-434页

作者： Qing Guo He Zeng Ze Chu Gang Tie Lei An Jun Qin Hong Zhen Lin Feng Lian Bai jian gong cheng Yong Qiu Shanghai Institute of Microsystem and Information Technology Chinese Academy of SciencesShanghai 200050China Key Laboratory of Organic Solids Centre for Molecular ScienceInstitute of ChemistryChinese Academy of SciencesBeijing 100080China Department of Chemistry Tsinghua UniversityBeijing 100084China

A binaphthyl derivative with pyrene on 3 and 3＇ positions was synthesized and characterized via Suzuki coupling reaction. Emission maximum in solution was located at 390 nm with a quantum efficiency of 68% by taking 9,10-diphenyl anthracene as reference,while it is shifted to 450 nm with FWHM of 104 nm resulting from aggregation state in solid *** transition temperature（Tg）and decomposition temperature were measured to be 184 and 447℃,respectively,by DSC and *** its photoluminescence spectrum,electroluminescent spectrum peaked at about 460 nm and shows a FWHM of 69 nm corresponding to a pure blue *** turn-on voltage,luminance and efficiency maximum were 5 V,2953 cd/m^2 and 1.37cd/A with CIE color coordinate of（0.16,0.15）,in the device structure of ITO/NPB（40nm）/PY-BN-PY（15nm）/BPhen（40nm）/Mg：Ag.

关键词： Binaphthyl Pyrene Suzuki reaction Photoluminescence Electroluminescence

Portable fluorogenic probe for monitoring of volatile amine vapour and food spoilage

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Chinese Chemical Letters 2024年第3期35卷 257-261页

作者： jian-Hao Zhao Wen-Xing Xu Bin Li Wei Xu Wu-Kun Zhang Ming-Shuai Yuan Hui-Zi Li Qing-Guo He Xiang Ma jian-gong cheng Yan-Yan Fu State Key Lab of Transducer Technology Shanghai Institute of Microsystem and Information TechnologyChinese Academy of SciencesShanghai 200050China Center of Materials Science and Optoelectronics Engineering University of the Chinese Academy of SciencesBeijing 100039China School of Physical Science and Technology ShanghaiTech UniversityShanghai 201210China Key Laboratory for Advanced Materials and Feringa Nobel Prize Scientist Joint Research Center Frontiers Science Center for Materiobiology and Dynamic Chemistry School of Chemistry and Molecular EngineeringEast China University of Science and TechnologyShanghai 200237China

There are urgent needs of volatile amine gas sensors with high-performance in food quality control,disease monitoring and environmental ***-film fluorescent probe is suitable for amine vapour sensing due to its high sensitivity,high selectivity,and no polluting ***,a novel fluorescent probe based on indacenodithiophene structure withπconjugated system was designed and *** experimental results show that the films prepared by this material exhibit rapid and distinct fluorescence quenching after being exposed to saturated vapours of primary amine,secondary amine and tertiary amine represented by n-propylamine,diethylamine and trimethylamine,*** quenching of fluorescence is 84%,87%and 96%,respectively,within 10 *** detection mechanism of probe for primary amine is based on specific chemical reaction,while the detection mechanism for secondary amine and tertiary amine is intramolecular charge *** experiments show that the detection limit of the fluorescent probe for trimethylamine,an important marker of food spoilage,could reach 4.610 ***-site detection based on spoilage of small yellow croaker suggests the material possesses the potential for food freshness *** simple fluorogenic probe is an original approach to simplify real-time visual monitoring of volatile amine vapour.

关键词： Fluorescent probe Volatile amine Gas sensing Trimethylamine Food spoilage

The Mechanism of Heating Rate on the Secondary Recrystallization Evolution in Grain Oriented Silicon Steel

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Journal of Wuhan University of Technology(Materials Science) 2025年第1期40卷 275-282页

作者： GAO Qian LI Jun WANG Xianhui CAO Laifu gong jian LI Bo Central Iron and Steel Research Institute Group Beijing 100081China Shougang Zhixin Electromagnetic Material R&D(Beijing)Co. Ltd.Beijing 101300China Beijing Shougang Co. Ltd.Qian’an 064404China

Grain-oriented silicon steels were prepared at different heating rates during high temperature annealing,in which the evolution of magnetic properties,grain orientations and precipitates were *** illustrate the Zener factor,the diameter and number density of precipitates of interrupted testing samples were statistically *** effect of precipitate ripening on the Goss texture and magnetic property was *** indicated that the trend of Zener factor was similar under different heating rates,first increasing and then decreasing,and that the precipitate maturing was greatly inhibited as the heating rate *** recrystallization was developed at the temperature of 1010℃when a heating rate of 5℃/h was used,resulting in Goss,Brass and{110}oriented grains growing abnormally and a magnetic induction intensity of ***,increasing the heating rate to 20℃/h would inhibit the development of undesirable oriented grains and obtain a sharp Goss ***,when the heating rate was extremely fast,such as 40℃/h,poor secondary recrystallization was developed with many island grains,corresponding to a decrease in magnetic induction intensity to 1.87 *** a suitable heating rate of 20℃/h,the sharpest Goss texture and the highest magnetic induction of 1.94 T with an onset secondary recrystallization temperature of 1020℃were found among the experimental variables in this *** heating rate affected the initial temperature of secondary recrystallization by controlling the maturation of precipitates,leading to the deviation and dispersion of Goss texture,thereby reducing the magnetic properties.

关键词： high temperature annealing heating rate secondary recrystallization grain oriented silicon steel

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考虑合力作用点位置的主动土压力计算

工程力学 2016年第11期33卷 132-139页

作者：陈建功胡日成许明重庆大学土木工程学院重庆400045 重庆大学山地城镇建设与新技术教育部重点实验室重庆400045

从滑动土体整体静力平衡方程出发,推导了坡面起伏,且有不均匀超载,墙背倾斜,黏性填土等一般情况下的主动土压力泛函极值的等周模型。在此基础上,引入拉格朗日乘子,将主动土压力问题转化为确定含有两个函数自变量的泛函极值问题。依据泛... 详细信息

从滑动土体整体静力平衡方程出发,推导了坡面起伏,且有不均匀超载,墙背倾斜,黏性填土等一般情况下的主动土压力泛函极值的等周模型。在此基础上,引入拉格朗日乘子,将主动土压力问题转化为确定含有两个函数自变量的泛函极值问题。依据泛函取极值时必须满足的欧拉方程,得到了对数螺旋线的滑裂面函数和沿滑裂面分布的法向应力函数。结合边界条件和横截条件,主动土压力泛函极值问题进一步转化为以两个拉格朗日常数为未知量的函数优化问题。通过算例表明,对于一般土体,在作用点位置系数下界限处,主动土压力最小,滑裂面为平面;随着作用点位置的上移,主动土压力呈非线性增长,相应滑裂面为对数螺旋面,在作用点位置系数上界限处,主动土压力达到最大。在作用点位置系数上下界限处所对应的主动土压力构成的数值范围,包含了各种挡墙变位模式下的主动土压力。通过算例对比分析,采用库仑土压力理论进行的抗倾覆设计存在安全系数偏低的缺点,应该根据主动土压力和作用点位置的区间估计来指导设计。

关键词：刚性挡墙主动土压力变分法极限平衡滑裂面

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