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Weatherability and heat resistance enhanced by interaction between AG25 and Mg/AI-LDH

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Rare Metals 2024年第6期43卷 2758-2768页

作者： Pei-Yao Yang Xiang-Cui Liu Yu-Chao Wang Huan-Ran zheng Jin-Xian Wang jia-yi zheng Meng-Jie Liu Dan-Ni Deng Yu Bai ying-Bi Chen Tong Zhang Zhi-Ming Liu Yong-Peng Lei State Key Laboratory of Powder Metallurgy Powder Metallurgy Research InstituteCentral South UniversityChangsha 410083China Research Institute of Chemical Defense Beijing 102205China

Although inorganic pigments in common spectral tuning materials show good weatherability and heat resistance,the limited color choices,weak coloring power,poor dispersibility,and a possibility of toxicity limit their *** the basis of organic pigments which possess a wide range of colors,high coloring power,good transparency,and high safety,herein,the modified pigment and biomimetic coating with improved weatherability,especially ultraviolet(UV)resistance(from 2 to 6 days),was achieved by intercalating acid green 25(AG25)pigment into Mg/Al-layered double hydroxides(Mg/Al-LDH).Furthermore,the heat resistance of AG25 was also significantly ***,the spectral stability of pigments after heat treatment is superior with almost unchanged spectral profile and green reflection *** formation of strong N-H bonds and the S-M(Mg,Al)bonds between Mg/Al-LDH laminates and AG25 molecules contributes to the *** work shows potential for biomimetic leaf materials in respect of reflective spectra stability.

关键词： Layered double hydroxide Biomimetic Acid green 25 Interaction Weatherability Heat resistance

The interpretation of the CMBR

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Research in Astronomy and Astrophysics 2021年第9期21卷 180-184页

作者： yi-jia zheng National Astronomical Observatories Chinese Academy of SciencesBeijing 100101China

In the popular ACDM model,the cosmic microwave background radiation(CMBR)is thought to be the remnant of the early hot *** important precondition of this interpretation of CMBR is:after the last scattering surface formed,the high temperature ionized gases in the universe became low temperature neutral gases and so the universe has been completely transparent to the radiation which comes from the hot early ***,observations show that today most gases in the universe are still in a high temperature ionized *** universe is not completely transparent to the radiation which comes from the hot early *** to the famous Sunyaev-Zeldovich effect,if the CMBR comes from the early hot universe and follows a perfect blackbody spectrum,the free electrons in the cosmic plasma will distort the perfect blackbody spectrum of the *** this case,the observed CMBR cannot be of a perfect blackbody *** is a fatal flaw in the interpretation of CMBR using the ACDM *** order to overcome this fatal flaw,in this paper it is proposed that in the ACDM model frame,a better interpretation of CMBR is:The CMBR is a thermal equilibrium product between the high temperature ionized gases and the cosmic radiation field in the local universe space.

关键词： cosmology:theory cosmological model cosmic microwave background radiation

A Quick Calculation Method for Radiation Pattern of Submillimeter Telescope with Deformation and Displacement

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Research in Astronomy and Astrophysics 2024年第3期24卷 249-265页

作者： jia You yi-Wei Yao zheng Wang School of Automation Southeast UniversityNanjing 210096China

Radiation pattern captures the electromagnetic performance of reflector antennas,which is significantly affected by the deformation of the primary reflector due to gravity and the displacement of the secondary *** the design process of large reflector antennas,a substantial amount of time is often dedicated to iteratively adjusting structural parameters and validating electromagnetic *** improve the efficiency of the design process,we first propose an approximate calculation method of optical path difference(OPD)for the deformation of the primary reflector under gravity and the displacement of the secondary *** an OPD fitting function based on the modified Zernike polynomials is proposed to capture the phase difference of radiation over the aperture plane,based on which the radiation pattern will be obtained quickly by the aperture field integration *** experiments demonstrate the effectiveness of the proposed quick calculation method for analyzing the radiation pattern of a 10.4 m submillimeter telescope antenna at its highest operating frequency of 856 *** comparison with the numerical simulation method based on GRASP(which is an antenna electromagnetic analysis tool combining physical optics(PO)and physical theory of diffraction(PTD)),the quick calculation method reduces the time for radiation pattern analysis from more than one hour to less than two ***,the quick calculation method exhibits excellent accuracy for the figure of merit(FOM)of the radiation ***,the proposed quick calculation method can obtain the radiation pattern with high speed and *** to the time-consuming numerical simulation method(PO and PTD),it can be employed for quick analysis of the radiation pattern for the lateral displacement of the secondary reflector and the deformation of the primary reflector under gravity in the design process of a reflector antenna.

关键词： instrumentation high angular resolution-methods data analysis-methods analytical

Effect of Pore Distribution on Melting Behavior of Paraffin in Fractal Metal Foam

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Communications in Theoretical Physics 2018年第10期70卷 501-510页

作者： jia-yi zheng Tao Wang Tao-Tao Chen Yan-Shun Yu MIIT Key Laboratory of Thermal Control of Electronic Equipment School of Energy and Power Engineering Nanjing University of Science & Technology Nanjing 210094 China Shanghai Institute of Satellite Engineering Shanghai 200240 China

An unsteady model of melting heat transfer in metal foam filled with paraffin is developed and numerically analyzed. In the model, the pore distribution of metal foam is described by Sierpinski fractal. By this fractal description,six types of metal foams with the identical porosity, different pore distributions are reconstructed. The effect of pores distribution on the heat transfer performance of the paraffin/copper foam composite is emphatically investigated. The solid-liquid distribution, the evolution of the melting front, the dynamic temperature response and the total melting time in these six fractal structures are all examined and analyzed. The results indicate that, the pores distribution has a significant impact on the melting heat transfer of the paraffin in the metal foam. When the first-level fractal pore is located near the heat source boundary, the thermal hysteresis effect of the paraffin on the solid matrix heat transfer is more significant. If the cross-sectional length of the pores along the normal direction of heat transfer is larger, the heat transfer barrier of the solid matrix is greater. It is favorable for the paraffin heat transfer when the pores specific surface area is larger.

关键词： fractal foam pores distribution melting heat transfer

A Better Candidate for Dark Matter is Cosmic Plasma

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Research in Astronomy and Astrophysics 2023年第10期23卷 277-280页

作者： yi-jia zheng National Astronomical Observatories Chinese Academy of SciencesBeijing 100101China

In the ΛCDM cosmological model, based on observations of supernovae Ia, the cosmic dark energy density is assumed to be Ω_(Λ)~ 0.70 and the gravitational mass density is assumed to be Ω_(m)~ 0.30. Based on the assumption that the observed cosmic microwave background(CMB) is a thermal relic of the early hot universe, the cosmic plasma density should be small, i.e., Ω_(b)~ 0.05(otherwise the Sunyaev-Zeldovich effect of the cosmic plasma would ruin the observed CMB's perfect blackbody spectrum). To fill the gap between Ω_(m) and Ω_(b), non-baryonic dark matter Ω_(c)~ 0.25 is introduced into the ΛCDM model. If the CMB is the result of a partial thermal equilibrium between cosmic radiation and cosmic plasma, then the observed perfect blackbody spectrum of the CMB can coexist with cosmic plasma. In this case, it is not necessary to introduce non-baryonic cold dark matter into cosmological models. A better candidate for dark matter is the cosmic plasma.

关键词： cosmology:theory (cosmology:)dark matter gravitational lensing:weak X-rays:galaxies:clusters

Effects of two silicone resin coatings on performance of FeSiAl magnetic powder cores

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Journal of Iron and Steel Research International 2024年第5期31卷 1279-1288页

作者： jia-qi Liu zheng-qu Zhu Pu Wang yi-fan Li Jing Pang jia-quan Zhang School of Metallurgical and Ecological Engineering University of Science and Technology BeijingBeijing100083China Qingdao Yunlu Advanced Materials Technology Co. Ltd.Qingdao266232ShandongChina

Two silicon resins with excellent thermal stability,JH1123 and JH7102,are used as the insulated agents and binders for the gas-atomized FeSiAl powder,and corresponding magnetic powder cores(MPCs)are *** insulation capability and application prospects of the two silicon resins are evaluated by comparing the magnetic properties of the coated powder and *** scanning electron microscopy,energy dispersive X-ray spectroscopy and Fourier transform infrared spectroscopy results show that uniform insulation layers are both formed on the powder ***1123 has stronger binding ability,and the JH1123-coated powder exhibits severe agglomeration,with d50(average particle size)approximately twice that of the JH7102-coated *** as-prepared MPCs exhibit outstanding soft magnetic ***,the permeability of FeSiAl@JH1123 is up to 74.0,which is 35.5%higher than that of FeSiAl@JH7102 because JH1123 can further improve the density of the *** for FeSiAl@JH7102,it has better direct current bias and lower core loss of 716.9 mW cm^(−3) at 20 mT and 1000 kHz due to its lower coercivity and greater anti-magnetic saturation ability.A comprehensive comparison shows that FeSiAl@JH1123 is suitable for medium and high frequency applications,while FeSiAl@JH7102 is more suitable for high frequency *** indicates that the use of JH1123 and JH7102 silicon resins for binding and insulated coating not only simplifies the preparation process of MPCs,but also enables the controlled production of MPCs for different applications.

关键词： FeSiAl Insulated coating Magnetic powder core Permeability Core loss

Undrained anisotropy and non-coaxial behavior of clayey soil under principal stress rotation

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Journal of Zhejiang University-Science A(Applied Physics & Engineering) 2014年第4期15卷 241-254页

作者： jian ZHOU jia-jia YAN zheng-yi LIU Xiao-nan GONG Research Center of Coastal and Urban Geotechnical Engineering Zhejiang University Hangzhou 310058 China

In this study, a series of undrained tests were conducted on both intact and reconstituted clay using an automatic hollow cylinder apparatus. Monotonic shearing tests with fixed principal stress directions were carried out, pure and cyclic prin- cipal stress rotation tests were also performed. The non-coaxiality, defined as the non-coincidence of the principal plastic strain increment direction and the corresponding principal stress direction, of clayey soil was studied experimentally. The effects of the intermediate principal stress, shear stress level, and inherent anisotropy were highlighted. Clear non-coaxiality was observed during pure principal stress rotation, in both intact and reconstituted clay. The influence of the intermediate principal stress pa- rameter, shear stress level, and inherent anisotropy on the non-coaxial behavior of the clayey soil was found to be insignificant when compared with the sand. The non-coaxial behavior of the clayey soil depended more on the stress paths. Under undrained conditions, the contribution of elastic strain to the direction of the total principal strain increment cannot be ignored.

关键词： Non-coaxiality Clay Principal stress rotation Anisotropy

Li-ion transport in solid-state electrolyte of Li_(1-x)Al_(1-x)Si_(2+x)O_(6):an ab initio study

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Rare Metals 2023年第7期42卷 2261-2271页

作者： Wen-Jun Li Modeste-Venin-Mendieev Nitou jia-yi zheng Zhi-Yuan Zhang Long-Fei Liu Jin-Lan Nie ying-Hua Niu Liang An Wei-Qiang Lv School of Physics University of Electronic Science and Technology of ChinaChengdu611731China Yangtze Delta Region Institute(Huzhou) University of Electronic Science and Technology of ChinaHuzhou313001China Department of Mechanical Engineering the Hong Kong Polytechnic UniversityHong Kong999077China

All-solid-state batteries are considered as nextgeneration technology for energy storage due to their high energy density and excellent s ***,only a few solid electrolytes exhibit ionic conductivities comparable to liquid *** low-cost solid electrolytes with high Liion conductivity is in high *** on the ab initio molecular dynamic simulations,the Li^(+)diffusion inβ-LiAISi_(2)O_(6),a type of cost-effective and naturally-available mineral,and its disordered systems Li_(1-x)Al_(1-x)Si_(2+x)O_(6)with-1.0≤x≤0.5 was *** calculations show that the phases of Li_(1-x)Al_(1-x)Si_(2+x)O_(6)with nonzero x all possess much lower diffusion energy barriers than pristine LiAlSi_(2)O_(6).When x is positive,increased concentration of lithium vacancies accelerates the diffusion of *** x is negative,additional Li-ions are inserted into structures and co-migration is stimulated among these *** particular,the maximal ionic conductivity at 300 K(1.92×10^(-6)S·cm^(-1))is obtained in Li_(2)Al_(2)SiO_(6)(x=-1.0),which is five orders of magnitude larger than that of pristineβ-LiAlSi_(2)O_(6).In addition,the diffusion barrier can be further reduced to 0.38 eV by replacing Si with Ge,and the ionic conductivity for Li_(2)Al_(2)GeO_(6)can reach 3.08×10~(-5)S·cm^(-1)at 300 *** work facilitates the understanding of Li+conduction mechanisms in silicatebased electrolytes and the development of cost-effective and high-performance solid-s ate electrolytes.

关键词： Ionic conductivity Diffusion barrier Solid-state electrolyte(SSE) Ab initio molecular dynamics

A multi-mechanism numerical simulation model for CO_(2)-EOR and storage in fractured shale oil reservoirs

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Petroleum Science 2024年第3期21卷 1814-1828页

作者： Yuan-zheng Wang Ren-yi Cao Zhi-Hao jia Bin-Yu Wang Ming Ma Lin-Song Cheng College of Petroleum Engineering China University of Petroleum(Beijing)Beijing102249China John&Willie Leone Department of Energy&Mineral Engineering The Pennsylvania State UniversityUniversity Park16802PA.USA

Under the policy background and advocacy of carbon capture,utilization,and storage(CCUS),CO_(2)-EOR has become a promising direction in the shale oil reservoir *** multi-scale pore structure distribution and fracture structure lead to complex multiphase flow,comprehensively considering multiple mechanisms is crucial for development and CO_(2) storage in fractured shale *** this paper,a multi-mechanism coupled model is developed by *** to the traditional Eclipse300 and MATLAB Reservoir Simulation Toolbox(MRST),this model considers the impact of pore structure on fluid phase behavior by the modified Peng—Robinson equation of state(PR-EOS),and the effect simultaneously radiate to Maxwell—Stefan(M—S)diffusion,stress sensitivity,the nano-confinement(NC)***,a modified embedded discrete fracture model(EDFM)is used to model the complex fractures,which optimizes connection types and half-transmissibility calculation approaches between non-neighboring connections(NNCs).The full implicit equation adopts the finite volume method(FVM)and Newton—Raphson iteration for discretization and *** model verification with the Eclipse300 and MRST is *** results show that the interaction between the mechanisms significantly affects the production performance and storage *** effect of molecular diffusion may be overestimated in oil-dominated(liquid-dominated)shale *** well spacing and injection gas rate are the most crucial factors affecting the production by sensitivity ***,the potential gas invasion risk is *** model provides a reliable theoretical basis for CO_(2)-EOR and sequestration in shale oil reservoirs.

关键词： CO_(2)-EOR CO_(2)storage Shale oil reservoir Complex fracture model Multiple mechanisms