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Indolocarbazole-Based Small Molecule Cathode-Active Material Exhibiting Double Redox for High-Voltage Li-Organic Batteries

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Energy & Environmental Materials 2024年第5期7卷 86-94页

作者： Hyunji Park Hyojin Kye Jong-Sung Lee Young-Chang Joo Dong Joo Min Bong-Gi Kim Soo Young Park ji Eon kwon Laboratory for Supramolecular Optoelectronic Materials(LSOM) Department of Materials Science and EngineeringResearch Institute of Advanced Materials(RIAM)Seoul National University1 Gwanak-roGwanak-guSeoul 08826Korea Functional Composite Materials Research Center Jeonbuk Institute of Advanced Composite MaterialsKorea Institute of Science and Technology(KIST)92 Chudong-roBongdong-eupWanju-gunJeonbuk 55324Korea Department of Organic and Nano System Engineering Konkuk University120 Neungdong-roGwangjin-guSeoul 05029Korea Department of Materials Science and Engineering Seoul National University1 Gwanak-roGwanak-guSeoul 08826Korea Department of JBNU-KIST Industry Academia Convergence Research Jeonbuk National University567 Baekje-daeroDeokjin-guJeonjuJeonbuk 54896Korea

Most organic electrode materials(OEMs)for rechargeable batteries employ n-type redox centers,whose redox potentials are intrinsically limited<3.0 V versus Li^(+)/***,p-type materials possessing high redox potentials experience low specific capacities because they are capable of only a single redox reaction within the stable electrochemical window of typical ***,we report 5,11-diethyl-5,11-dihydroindolo[3,2-b]carbazole(DEICZ)as a novel p-type OEM,exhibiting stable plateaus at high discharge potentials of 3.44 and 4.09 V versus Li^(+)/***,the second redox potential of DEICZ is within the stable electrochemical *** mechanism of the double redox reaction is investigated using both theoretical calculations and experimental measurements,including density functional theory calculations,ex situ electron spin resonance,and X-ray photoelectron ***,hybridization with single-walled carbon nanotubes(SWCNT)improves the cycle stability and rate performance of DEICZ owing to theπ-πinteractions between the SWCNT and co-planar molecular structure of DEICZ,preventing the dissolution of active materials into the *** DEICZ/SWCNT composite electrode maintains 70.4%of its initial specific capacity at 1-C rate and also exhibits high-rate capability,even performing well at 100-C ***,we demonstrate its potential for flexible batteries after applying 1000 bending stresses to the composite electrode.

关键词： composite electrodes flexible batteries indolocarbazoles organic rechargeable batteries p-type

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Experimental Investigation on Noise Suppression in Supersonic Jets from Convergent-Divergent Nozzles with Baffles

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Journal of Thermal Science 2003年第3期12卷 260-263,269页

作者： Yoshiaki Miyazato Yong-Hun Kweon Toshiyuki Aoki Mitsuharu Masuda kwon-hee Lee Heuy-Dong Kim Toshiaki Setoguchi Kazuyasu Matsuo Graduate School of Engineering Sciences Kyushu University 6-1 Kasuga-kouen Kasuga Fukuoka816-8580 JapanSchool of Mechanical Engineering Andong National University 388 Songchun-dong AndongKyungbuk 760-749 KoreaGraduate School of Engineering Sciences Kyushu University 6-1 Kasuga-kouen Kasuga Fukuoka816-8580 JapanGraduate School of Engineering Sciences Kyushu University 6-1 Kasuga-kouen Kasuga Fukuoka816-8580 JapanDepartment of Mechanical Engineering Saga University 1 Honjo-machi Saga Saga 840-8502 JapanSchool of Mechanical Engineering Andong National University 388 Songchun-dong AndongKyungbuk 760-749 KoreaDepartment of Mechanical Engineering Saga University 1 Honjo-machi Saga Saga 840-8502 JapanFaculty of Environmental Engineering The University of Kitakyushu 1-1 Hibikino Wakamatsu-kuKitakyushu Fukuoka 808-0135 Japan

The acoustic properties of supersonic jet noise from a convergent-divergent nozzle with a baffle have been studied experimentally over the range of nozzle pressure ratios from 2.0 to 8.0. Acoustic measurements were conducted in a carefully designed anechoic room providing a free-field environment. A new approach for screech noise suppression by a cross-wire is proposed. Schlieren photographs were taken to visualize the shock wave patterns in the supersonic jet with and without the cross-wire. The effects of the baffle and the cross-wire on acoustic properties are discussed. It is shown that the baffle has little effect on the screech frequency for the underexpanded supersonic jet without the cross-wire. Also, the cross-wire introduced in supersonic jets is found to lead to a significant reduction in overall sound pressure level.

关键词：超音速流动噪声控制实验研究收敛-扩散喷管流体力学超音速喷射

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Development of an analytical method for multi-residue quantification of 18 anthelmintics in various animal-based food products using liquid chromatography-tandem mass spectrometry

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Journal of Pharmaceutical Analysis 2021年第1期11卷 68-76页

作者： Kyung-hee Yoo Da-hee Park A.M.Abd El-Aty Seong-Kwan Kim Hae-Ni Jung Da-Hye Jeong hee-Jung Cho Ahmet Hacimuftuoglu Jae-Han Shim ji Hoon Jeong Ho-Chul Shin Department of Veterinary Pharmacology and Toxicology College of Veterinary MedicineKonkuk UniversitySeoul143-701Republic of Korea State Key Laboratory of Biobased Material and Green Papermaking College of Food Science and EngineeringQilu University of TechnologyShandong Academy of ScienceJinan250353China Department of Pharmacology Faculty of Veterinary MedicineCairo University12211GizaEgypt Department of Medical Pharmacology Medical FacultyAtaturk UniversityErzurum25240Turkey Department of Veterinary Physiology College of Veterinary MedicineKonkuk UniversitySeoul143-701Republic of Korea Natural Products Chemistry Laboratory College of Agriculture and Life SciencesChonnam National UniversityGwangju500-757Republic of Korea Department of Pharmacology College of MedicineChung-Ang UniversitySeoul156-756Republic of Korea

In this study,we developed a simple screening procedure for the determination of 18 anthelmintics(including benzimidazoles,macrocyclic lactones,salicylanilides,substituted phenols,tetrahydropyrimidines,and imidazothiazoles)in five animal-derived food matrices(chicken muscle,pork,beef,milk,and egg)using liquid chromatography-tandem mass *** were extracted using acetonitrile/1% acetic acid(milk and egg)and acetonitrile/1% acetic acid with 0.5 mL of distilled water(chicken muscle,pork,and beef),and purified using saturated n-hexane/acetonitrile.A reversed-phase analytical column and a mobile phase consisting of(A)10 mM ammonium formate in distilled water and(B)methanol were used to achieve optimal chromatographic ***-matched standard calibration curves(R^(2)≥0.9752)were obtained for concentration equivalent to ×1/2,×1,×2,×3,×4,and×5 fold the maximum residue limit(MRL)stipulated by the Korean Ministry of Food and Drug *** of 61.2e118.4%,with relative standard deviations(RSDs)of ≤19.9%(intraday and interday),were obtained for each sample at three spiking concentrations(×1/2,×1,and ×2 the MRL values).Limits of detection,limits of quantification,and matrix effects were 0.02e5.5 mg/kg,0.06e10 mg/kg,and -98.8 to 13.9%(at 20 μg/kg),*** five samples of each food matrix(chicken muscle,pork,beef,milk,and egg)purchased from large retailers in Seoul that were tested,none of the target analytes were *** has therefore been shown that this protocol is adaptable,accurate,and precise for the quantification of anthelmintic residues in foods of animal origin.

关键词： Anthelmintics Tandem mass spectrometry Animal-based food products Residue analysis Method validation

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Simultaneous robot-assisted approach in a super-elderly patient with urothelial carcinoma and synchronous contralateral renal cell carcinoma:A case report

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World Journal of Clinical Cases 2022年第20期10卷 7153-7162页

作者： ji Kang Yun Si Hyun Kim Woong Bin Kim hee Kyung Kim Sang Wook Lee Department of Urology Soonchunhyang University Bucheon HospitalSoonchunhyang University College of MedicineBucheon 14584South Korea Department of Urology Soonchunhyang University Cheonan HospitalSoonchunhyang University College of MedicineCheonan 31151South Korea Department of Pathology Soonchunhyang University Bucheon HospitalSoonchunhyang University College of MedicineBucheon 14584South Korea

BACKGROUND It is rare for urothelial and renal cell carcinomas to coexist in the same patient,and even rarer for them to be detected *** of this rarity,a standard treatment has not been established and studies about overall survival are ***,physicians must modify treatments according to the individual’s situation and the stage of each *** recent years,with advances in the instruments and techniques,minimal invasive robotic surgeries have become available for advanced-stage or high-risk *** SUMMARY An 85-year-old woman with a medical history of hypertension and hyperlipidemia visited our *** had visited her local hospital complaining of intermittent,painless,gross hematuria that had started 3 mo *** computed tomography,a right renal mass and left proximal ureteral mass with hydronephrosis were found *** decided to perform robot-assisted surgery on both sides during one *** renal function and kidney loading,right partial nephrectomy was performed first,followed by left nephroureterectomy with bladder cuff *** the 6-mo follow-up,no specific symptoms were reported and dialysis was not *** were no unusual findings in the imaging study,and regular follow-up and imaging studies are *** This case report assessed the feasibility of simultaneous minimal invasive robotic surgery as an alternative to conventional open or laparoscopic surgery.

关键词： Robot surgical procedure Renal cell carcinoma Transitional cell carcinoma Minimally invasive surgical procedures Case report

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Restoration of an Inner-City Stream and Its Impact on Air Temperature and Humidity Based on Long-Term Monitoring Data

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Advances in Atmospheric Sciences 2009年第2期26卷 283-292页

作者： Kyu Rang KIM Tae Heon kwon Yeon-hee KIM Hae-Jung KOO Byoung-Cheol CHOI Chee-Young CHOI Applied Meteorology Research Laboratory National Institute of Meteorological Research Korea Meteorological Administration Applied Meteorology Research Laboratory National Institute of Meteorological ResearchKorea Meteorological Administration

Spatiotemporal changes in air temperature and humidity associated with the restoration of an innercity stream in Seoul, Korea, are investigated based on long-term monitoring data. The Cheonggye stream, covered under a concrete structure for 46 years, was restored in 2005 and runs 5.8 km eastward through a central region of Seoul. Long-term monitoring of the air temperature and relative humidity was made along the stream throughout the restoration and across the stream after the restoration. The area along the stream had a higher air temperature than the entire metropolitan area. The temperature anomaly between the monitoring area and the surrounding metropolitan area was 0.13℃ lower on average at the center of the stream after the restoration. The stream＇s effect on the air temperature was also evident in the temperature distribution along a street traversing the stream. The relative and specific humidities were increased due to the restoration. The restored stream modified the nearby urban climate in the opposite direction compared to urbanization. The results could be used as a model case in mitigating urban climate by a stream in future urban planning practices.

关键词： urban heat island stream restoration land-use vegetation Cheonggye stream

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Short-term interval combined chemoembolization and radiofrequency ablation for hepatocellular carcinoma

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World Journal of Gastroenterology 2014年第35期20卷 12588-12594页

作者： Won Hyeok Choe Young Jun Kim hee Sun Park Sang Woo Park Jeong Han Kim So Young kwon Department of Internal Medicine Konkuk University School of Medicine Department of Radiology Konkuk University School of Medicine

AIM: To investigate hepatic function after combined transcatheter arterial chemoembolization (TACE) and radiofrequency ablation (RFA) with a short-term interval (0-2 d).

关键词： Child-Pugh score Liver cirrhosis Hepatocellular carcinoma Transcatheter arterial chemoembolization Radiofrequency ablation

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Comparison of two Nd:YAG laser posterior capsulotomy: cruciate pattern vs circular pattern with vitreous strand cutting

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International Journal of Ophthalmology(English edition) 2018年第2期11卷 235-239页

作者： jin-Soo Kim Jung Yeol Choi ji-Won kwon Won Ryang Wee Young Keun Han Department of Ophthalmology Seoul National University College of Medicine Department of Ophthalmology Seoul Metropolitan Government-Seoul National University Boramae Medical Center Department of Ophthalmology Seonam University College of Medicine Myongji Hospital

AIM： To investigate the effects and safety of neodymium： yttrium-aluminium-garnet（Nd：YAG） laser posterior capsulotomy with vitreous strand cuttingMETHODS： A total of 40 eyes of 37 patients with symptomatic posterior capsular opacity（PCO） were included in this prospective randomized study and were randomly subjected to either cruciate pattern or round pattern Nd：YAG posterior capsulotomy with vitreous strand cutting（modified round pattern）. The best corrected visual acuity（BCVA）, intraocular pressure（IOP）, refractive error, endothelial cell count（ECC）, anterior segment parameters, including anterior chamber depth（ACD） and anterior chamber angle（ACA） were measured before and 1 mo after the laser posterior capsulotomy. RESULTS： In both groups, the BCVA improved significantly（P〈0.001 for the modified round pattern group, P=0.001 for the cruciate pattern group）; the IOP and ECC did not significantly change. The ACD significantly decreased（P〈0.001 for both） and the ACA significantly increased（P=0.001 for the modified round pattern group and P=0.034 for the cruciate group）. The extent of changes in these parameters was not significantly different between the ***： Modified round pattern Nd：YAG laser posterior capsulotomy is an effective and safe method for the treatment of PCO. This method significantly changes the ACD and ACA, but the change in refraction is not significant. Modified round pattern Nd：YAG laser posterior capsulotomy can be considered a good alternative procedure in patients with symptomatic PCO.

关键词： posterior capsulotomy modified round pattern vitreous strand cutting anterior segment parameter

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Dexamethasone inhibits hypoxia-induced epithelial-mesenchymal transition in colon cancer

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World Journal of Gastroenterology 2015年第34期21卷 9887-9899页

作者： Jung Ho Kim You-jin Hwang Sang Hoon Han Young Eun Lee Saerom Kim Yoon Jae Kim Jae hee Cho Kwang An kwon Ju Hyun Kim Se-hee Kim Department of Internal Medicine Gachon University Gil Medical Center Division of Biological Science Gachon University of Medicine and Science Department of Internal Medicine Jeju National University School of Medicine Gachon Medical Research Institute Gachon University Gil Medical Center

AIM:To elucidate the effects of dexamethasone on hypoxia-induced epithelial-to-mesenchymal transition(EMT) in colon ***:Human colon cancer HCT116 and HT29 cells were exposed to normoxic(21%) and hypoxic(1%) conditions. First,the effect of dexamethasone on cell viability was examined by MTT cell proliferation assay. In order to measure the expression levels of EMT markers(Snail,Slug,Twist,E-cadherin,and integrin αVβ6) and hypoxia-related genes [Hypoxia-inducible factor-1α(HIF-1α) and vascular endothelial growth factor(VEGF)] by dexamethasone,quantitative real-time polymerase chain reaction and western blot analysis were performed. Furthermore,the morphological changes of colon cancer cells and the expression pattern of E-cadherin by dexamethasone were detected through immunocytochemistry. Finally,the effects of dexamethasone on the invasiveness and migration of colon cancer cells were elucidated using matrigel invasion,migration,and wound healing migration ***:Under hypoxia,dexamethasone treatment inhibited HIF-1α protein level and its downstream gene,VEGF m RNA level in the colon cancer cell lines,HCT116 and HT29. In addition,the presence of dexamethasone down-regulated the m RNA levels of hypoxia-induced Snail,Slug,and Twist,all transcriptional factors of EMT,as well as hypoxia-induced integrin αVβ6 protein level,a well-known EMT marker for colon cancer cells. Furthermore,reduced E-cadherin in hypoxic condition was found to be recoverable by treating with dexamethasone in both colon cancer cell lines. Similarly,under hypoxic conditions,dexamethasone restored the growth pattern and morphological phenotype reminiscent of colon cancer cells grown under normoxic conditions; dexamethasone blocked the migration and invasion of both colorectal cancer cell lines in ***:Our study suggested that dexamethasone has inhibitory effects on cell migration and invasion by suppressing EMT of colon cancer cell lines in hypoxic condition.

关键词： Dexamethasone Colon cancer Hypoxia Hypoxia-inducib

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Correlation of Microstructure and Hydrogen Delayed Fracture for 1GPa Steels

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Journal of Iron and Steel Research International 2011年第S1期18卷 252-254页

作者： hee Jae Kang ji Tae Park Soon Tae Ahn Kyung Mox Cho Nam Hyun Kang Department of Materials Science and Engineering Pusan National UniversityBusan 609-735Korea Samhwa Steel 339-4 Samrak-dongSasang-guBusan 617-825Korea

Automobile industry tries to reduce the weight of automobile using high-strength ***,the high-strength steels are highly susceptible to delayed-fracture caused by hydrogen *** increasing the strength,hydrogen embrittlement is more sensitive to diffusible *** mechanism of delayed-fracture and the relationship with the microstructure and alloying elements are still *** study analyzed the effect of the size and the spheroidization rate for the carbides on hydrogen-induced delayed fracture for 1GPa TS steel.

关键词： hydrogen delayed fracture microstructure spheroidization

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Design of small-area and high-efficiency DC-DC converter for 1 T SRAM

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Journal of Central South University 2012年第2期19卷 417-423页

作者： LEE Jae-hyung 金丽妍余忆宁 JANG ji-hye KIM Kwang-il HA Pan-bong KIM Young-hee Department of Electronic Engineering Changwon National University9 Sarim-Dong

The direct current-direct current （DC-DC） converter is designed for 1 T static random access memory （SRAM） used in display driver integrated circuits （ICs）, which consists of positive word-line voltage （VpwL）, negative word-line voltage （VinyL） and half-VDD voltage （VHDo） generator. To generate a process voltage temperature （PVT）-insensitive VpWL and VNWL, a set of circuits were proposed to generate reference voltages using bandgap reference current generators for respective voltage level detectors. Also, a VOWL regulator and a VNWL charge pump were proposed for a small-area and low-power design. The proposed VpwL regulator can provide a large driving current with a small area since it regulates an input voltage （VCI） from 2.5 to 3.3 V. The VmvL charge pump can be implemented as a high-efficiency circuit with a small area and low power since it can transfer pumped charges to VNWL node entirely. The DC-DC converter for 1 T SRAM were designed with 0.11 μm mixed signal process and operated well with satisfactory measurement results.

关键词： 1 T-static random access memory direct current-direct current converter positive word-line voltage negative word-line voltage half- VDb generator

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