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Conversion of N-doped biochar from carotenoid-extracted Tetraselmis suecica and its application to produce supercapacitors

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Journal of Environmental Sciences 2025年第5期151卷 410-423页

作者： Se Hun Lee Kang Hyun Lee Sang-hwa Lee Soo Kweon Lee Ok Sung Jeon young Pyo Jeon Dongpyo Hong young Joon Yoo Sang Yoon Park Hah young Yoo Advanced Institute of Convergence Technology(AICT) Seoul National UniversitySuwon 16229Republic of Korea Department of Biotechnology Sangmyung University20 Hongjimun 2-GilJongno-GuSeoul 03016Republic of Korea Department of Bio-Convergence Engineering Dongyang Mirae University445-8Gyeongin-roGuro-guSeoul 08221Republic of Korea Fermentation team Lotte R&D Center210 Magokjungang-RoGangseo-GuSeoul 07594Republic of Korea School of Electronic Engineering Kyonggi UniversityGyeonggi-do 16227Republic of Korea

microalgae are one of the promising feedstocks for biorefinery,contributing significantly to net-zero emissions through carbon capture and ***,the disposal of microalgal byproducts from the manufacturing process causes additional environmental pollution,thus,a new application strategy is *** this study,the Tetraselmis suecica byproduct from the carotenoid extraction process was carbonized and converted into *** converted biochar was proved to be nitrogen-doped biochar(NDB),up to 4.69%,with a specific surface area of 206.59m^(2)/g andwas used as an electrode for a *** NDB electrode(NDB-E)in half-cell showed a maximum specific capacitance of 191 F/*** a full-cell test,the NDB-E exhibited a high energy density of 7.396 Wh/kg and a high-power density of 18,100 W/kg,and maintained specific capacity of 95.5%after charge and discharge of 10,000 *** conclusion,our study demonstrated that the carotenoid-extracted microalgal byproducts are a useful resource for the supercapacitor *** approach is the first to convert *** into active materials for supercapacitors.

关键词： microalgae Tetraselmis suecica Carbonization N-doped biochar Supercapacitor

Enhancing micro-scale SiOx anode durability:Electro-mechanical strengthening of binder networks via anchoring carbon nanotubes with carboxymethyl cellulose

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Journal of Energy Chemistry 2025年第2期101卷 23-33页

作者： Chaeyeon Ha Jin Kyo Koo Jun myoung Sheem young-Jun Kim SKKU Advanced Institute of Nano Technology (SAINT) Sungkyunkwan University Department of Nano Science and Technology Sungkyunkwan University Advanced Center for Convergence Energy Storage System Sungkyunkwan University SKKU Institute of Energy Science and Technology (SIEST) Sungkyunkwan University

With the increasing prevalence of lithium-ion batteries（LIBs） applications,the demand for high-capacity next-generation materials has also *** currently considered a promising anode material due to its exceptionally high capacity for ***,the significant volumetric changes of SiOxduring cycling and its initial Coulombic efficiency（ICE） complicate its use,whether alone or in combination with graphite *** this study,a three-dimensional conductive binder network with high electronic conductivity and robust elasticity for graphite/SiOxblended anodes was proposed by chemically anchoring carbon nanotubes and carboxymethyl cellulose binders using tannic acid as a chemical *** addition,a dehydrogenation-based prelithiation strategy employing lithium hydride was utilized to enhance the ICE of *** combination of these two strategies increased the CE of SiOxfrom 74% to87% and effectively mitigated its volume expansion in the graphite/SiOxblended electrode,resulting in an efficient electron-conductive binder *** led to a remarkable capacity retention of 94% after30 cycles,even under challenging conditions,with a high capacity of 550 mA h g-1and a current density of 4 mA ***,to validate the feasibility of utilizing prelithiated SiOxanode materials and the conductive binder network in LIBs,a full cell incorporating these materials and a single-crystalline Ni-rich cathode was *** cell demonstrated a～27.3% increase in discharge capacity of the first cycle(～185.7 mA h g-1) and exhibited a cycling stability of 300 ***,this study reports a simple,feasible,and insightful method for designing high-performance LIB electrodes.

关键词： Lithium-ion batteries SiO x anode Blended anode Carbon nanotubes Carboxymethyl cellulose Conductive binder network

High mobility group box 1 in the central nervous system:regeneration hidden beneath inflammation

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Neural Regeneration Research 2025年第1期20卷 107-115页

作者： Hanki Kim Bum Jun Kim Seungyon Koh Hyo Jin Cho Xuelian Jin Byung Gon Kim Jun young Choi Department of Brain Science Ajou University School of MedicineSuwonSouth Korea Department of Biomedical Sciences Ajou University Graduate School of MedicineSuwonSouth Korea Department of Neurology Ajou University School of MedicineSuwonSouth Korea Department of Geriatrics The Affiliated Suqian First People’s Hospital of Nanjing Medical UniversitySuqianJiangsu ProvinceChina

High-mobility group box 1 was first discovered in the calf thymus as a DNA-binding nuclear protein and has been widely studied in diverse fields,including neurology and ***-mobility group box 1 in the extracellular space functions as a pro-inflammatory damage-associated molecular pattern,which has been proven to play an important role in a wide variety of central nervous system disorders such as ischemic stroke,Alzheimer’s disease,frontotemporal dementia,Parkinson’s disease,multiple sclerosis,epilepsy,and traumatic brain *** drugs that inhibit high-mobility group box 1 as a damage-associated molecular pattern,such as glycyrrhizin,ethyl pyruvate,and neutralizing anti-high-mobility group box 1 antibodies,are commonly used to target high-mobility group box 1 activity in central nervous system *** it is commonly known for its detrimental inflammatory effect,high-mobility group box 1 has also been shown to have beneficial pro-regenerative roles in central nervous system *** this narrative review,we provide a brief summary of the history of high-mobility group box 1 research and its characterization as a damage-associated molecular pattern,its downstream receptors,and intracellular signaling pathways,how high-mobility group box 1 exerts the repair-favoring roles in general and in the central nervous system,and clues on how to differentiate the pro-regenerative from the pro-inflammatory *** targeting high-mobility group box 1 in the central nervous system may benefit from differentiating between the two functions rather than overall suppression of high-mobility group box 1.

关键词： central nervous system damage-associated molecular pattern ethyl pyruvate glycyrhizzin high mobility group box 1 inflammation neural stem cells neurodevelopment oligodendrocyte progenitor cells redox status regeneration

Gradient‑Layered mXene/Hollow Lignin Nanospheres Architecture Design for Flexible and Stretchable Supercapacitors

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Nano-micro Letters 2025年第2期17卷 447-462页

作者： Haonan Zhang Cheng Hao Tongtong Fu Dian Yu jane Howe Kaiwen Chen Ning Yan Hao Ren Huamin Zhai Jiangsu Provincial Key Lab of Sustainable Pulp and Paper Technology and Biomass materials NanJing Forestry UniversityNanjing 210037People’s Republic of China Department of Chemical Engineering and Applied Chemistry University of Toronto200 College StreetTorontoON M5S 3E5Canada Department of materials Science and Engineering University of Toronto184 College StreetTorontoON M5S 3E4Canada College of materials Science and Engineering Nanjing Forestry UniversityNanjing 210037People’s Republic of China

With the rapid development of flexible wearable electronics,the demand for stretchable energy storage devices has *** this work,a novel gradient-layered architecture was design based on single-pore hollow lignin nanospheres(HLNPs)-intercalated two-dimensional transition metal carbide(Ti_(3)C_(2)T_(x) mXene)for fabricating highly stretchable and durable *** depositing and inserting HLNPs in the mXene layers with a bottom-up decreasing gradient,a multilayered porous mXene structure with smooth ion channels was constructed by reducing the overstacking of mXene ***,the micro-chamber architecture of thin-walled lignin nanospheres effectively extended the contact area between lignin and mXene to improve ion and electron accessibility,thus better utilizing the pseudocapacitive property of *** these strategies effectively enhanced the capacitive performance of the *** addition,HLNPs,which acted as a protective phase for mXene layer,enhanced mechanical properties of the wrinkled stretchable electrodes by releasing stress through slip and deformation during the stretch-release cycling and greatly improved the structural integrity and capacitive stability of the *** electrodes and symmetric flexible all-solid-state supercapacitors capable of enduring 600%uniaxial tensile strain were developed with high specific capacitances of 1273 mF cm^(−2)(241 F g^(−1))and 514 mF cm^(−2)(95 F g^(−1)),***,their capacitances were well preserved after 1000 times of 600%stretch-release *** study showcased new possibilities of incorporating biobased lignin nanospheres in energy storage devices to fabricate stretchable devices leveraging synergies among various two-dimensional nanomaterials.

关键词： Hollow lignin nanospheres mXene Gradient-layered architecture Wrinkled electrodes Stretchable supercapacitors

Confined metal-acid units for boosting benzene hydroalkylation via efficient activation of key intermediate

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Nano Research 2025年第2期18卷 193-205页

作者： Jianpeng Li Kaihang Sun Jinyu Huang Yongheng Jia Shufang Zhao young Dok Kim Li Han Baojun Li Jie Feng Zhongyi Liu Zhikun Peng College of Chemistry Henan Institutes of Advanced TechnologyCollege of Ecology and EnvironmentState Key Laboratory of Coking Coal Resources Green ExploitationZhengzhou UniversityZhengzhou 450001China Department of Chemistry Sungkyunkwan UniversitySuwon 16419Republic of Korea

Precisely *** micro-nanoscale characteristics and synergistic effect of metal-acid sites to regulate the distribution of hydroconversion products are significant but *** protonated carbocation intermediates triggered by tandem reaction on metal-acid region hinder target product formation due to their high reactivity and *** m/Zeolite hydroconversion catalysts,which often excel in simple synthesis,ease of separation and ***,they usually consist of sterically unconstrained metal centers which are isolated from acid sites,only providing limited coupling-selectivity to target ***,metal nanoparticles enveloped in acidic zeolite frameworks were developed and used for investigating the process of hydroalkylation of benzene to *** show that appropriate metal encapsulation comprising adequate efficient metal-acid units successfully avoids the more thermodynamically favorable hydrogenation of cyclohexene to cyclohexane,but steers to alkylation of cyclohexene with benzene to *** resulted in the highest cyclohexylbenzene yield of 47.7%among the reported work,and surpassed the performance of all supported m/Zeolite *** and theoretical results supported that the abundant bifunctional metal-acid units enhance the activation frequency and probability of intermediate *** work might provide insights for the integration strategy of dual active site and guidance for the construction of efficient"metal-acid balance"in tandem reactions.

关键词： tandem reaction benzene hydroalkylation metal-acid balance metal encapsulation intermediate transformation

Contemporary management of locally advanced rectal cancer:Resolving issues, controversies and shifting paradigms

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Chinese Journal of Cancer Research 2018年第1期30卷 131-146页

作者： Aeris jane D.Nacion Youn young Park Nam Kyu Kim Department of Surgery Eastern Visayas Regional Medical Center Division of Colorectal Surgery Department of Surgery Yonsei University College of Medicine

Advancements in rectal cancer treatment have resulted in improvement only in locoregional control and have failed to address distant relapse, which is the predominant mode of treatment failure in rectal cancer. As the efficacy of conventional chemoradiotherapy（CRT） followed by total mesorectal excision（TmE） reaches a plateau, the need for alternative strategies in locally advanced rectal cancer（LARC） has grown in relevance. Several novel strategies have been conceptualized to address this issue, including： 1） neoadjuvant induction and consolidation chemotherapy before CRT; 2） neoadjuvant chemotherapy alone to avoid the sequelae of radiation; and 3） nonoperative management for patients who achieved pathological or clinical complete response after CRT. This article explores the issues, recent advances and paradigm shifts in the management of LARC and emphasizes the need for a personalized treatment plan for each patient based on tumor stage, location, gene expression and quality of life.

关键词： Locally advanced rectal cancer neoadjuvant treatment chemoradiotherapy

Innovative dispersion techniques of graphene nanoplatelets(GNPs)through mechanical stirring and ultrasonication:Impact on morphological,mechanical,and thermal properties of epoxy nanocomposites

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Defence Technology(防务技术) 2025年第1期43卷 13-25页

作者： Vasi Uddin Siddiqui S.m.Sapuan mohd Roshdi Hassan Advanced Engineering materials and Composites Research Centre(AEmC) Department of Mechanical and Manufacturing EngineeringUniversiti Putra MalaysiaUPM SerdangSelangor 43400Malaysia Department of mechanical and manufacturing Engineering Universiti Putra MalaysiaUPM SerdangSelangor 43400Malaysia

Graphene nanoplatelets(GNPs)have attracted tremendous interest due to their unique properties and bonding *** study focuses on the effect of GNP dispersion on the mechanical,thermal,and morphological behavior of GNP/epoxy *** study aims to understand how the dispersion of GNPs affects the properties of epoxy nanocomposite and to identify the best dispersion approach for improving mechanical performance.A solvent mixing technique that includes mechanical stirring and ultrasonication was used for producing the *** transform infrared spectroscopy was used to investigate the interaction between GNPs and the epoxy *** measurements of density and moisture content were used to confirm that GNPs were successfully incorporated into the *** findings showed that GNPs are successfully dispersed in the epoxy matrix by combining mechanical stirring and ultrasonication in a single step,producing well-dispersed nanocomposites with improved mechanical ***,the nanocomposites at a low GNP loading of 0.1 wt%,demonstrate superior mechanical strength,as shown by increased tensile properties,including improved young's modulus(1.86 GPa),strength(57.31 mPa),and elongation at break(4.98).The nanocomposite with 0.25 wt%GNP loading performs better,according to the viscoelastic analysis and flexural properties(113.18 mPa).Except for the nanocomposite with a 0.5 wt%GNP loading,which has a higher thermal breakdown temperature,the thermal characteristics do not significantly *** effective dispersion of GNPs in the epoxy matrix and low agglomeration is confirmed by the morphological *** findings help with filler selection and identifying the best dispersion approach,which improves mechanical *** effective integration of GNPs and their interaction with the epoxy matrix provides the doorway for additional investigation and the development of sophisticated *** fiel

关键词： Graphene nanoplatelets Epoxy Nanocomposites mechanical properties Thermal properties mechanical stirrer Sonication

Cellulose Elementary Fibrils as Deagglomerated Binder for High-mass-Loading Lithium Battery Electrodes

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Nano-micro Letters 2025年第05期 289-304页

作者： young-Kuk Hong Jung-Hui Kim Nag-young Kim Kyeong-Seok Oh Hong-I Kim Seokhyeon Ryu Yumi Ko Ji-young Kim Kwon-Hyung Lee Sang-young Lee Department of Chemical and Biomolecular Engineering Yonsei University Advanced Analysis and Data Center Korea Institute of Science and Technology (KIST) Ulsan Advanced Energy Technology R&D Center Korea Institute of Energy Research (KIER) Department of Battery Engineering Yonsei University

Amidst the ever-growing interest in high-mass-loading Li battery electrodes,a persistent challenge has been the insufficient continuity of their ion/electron conduction ***,we propose cellulose elementary fibrils （CEFs） as a class of deagglomerated binder for high-mass-loading *** from natural wood,CEF represents the most fundamental unit of cellulose with nanoscale *** preparation of the CEFs involves the modulation of intermolecular hydrogen bonding by the treatment with a proton acceptor and a hydrotropic *** elementary deagglomeration of the cellulose fibers increases surface area and anionic charge density,thus promoting uniform dispersion with carbon conductive additives and suppressing interfacial side reactions at ***,a homogeneous redox reaction is achieved throughout the *** resulting CEF-based cathode (overlithiated layered oxide （OLO）is chosen as a benchmark electrode active material) exhibits a high areal-mass-loading (50 mg cm–2,equivalent to an areal capacity of 12.5 m Ah cm–2) and a high specific energy density (445.4 Wh kg–1) of a cell,which far exceeds those of previously reported OLO *** study highlights the viability of the deagglomerated binder in enabling sustainable high-mass-loading electrodes that are difficult to achieve with conventional synthetic polymer binders.

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Precambrian supercontinents,glaciations,atmospheric oxygenation,metazoan evolution and an impact that may have changed the second half of Earth history

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Geoscience Frontiers 2013年第3期4卷 247-261页

作者： Grant m.young Department of Earth Sciences Western University1151 Richmond Street NLondonOntarioCanada N6A 5B7

In more than 4 Ga of geological evolution, the Earth has twice gone through extreme climatic perturba- tions, when extensive glaciations occurred, together with alternating warm periods which were accom- panied by atmospheric oxygenation. The younger of these two episodes of climatic oscillation preceded the Cambrian ＂explosion＂ of metazoan life forms, but similar extreme climatic conditions existed between about 2.4 and 2.2 Ga. Over long time periods, changing solar luminosity and mantle temperatures have played important roles in regulating Earth＇s climate but both periods of climatic upheaval are associated with supercontinents. Enhanced weathering on the orogenically and thermally buoyed supercontinents would have stripped CO2 from the atmosphere, initiating a cooling trend that resulted in continental glaciation. Ice cover prevented weathering so that CO2 built up once more, causing collapse of the ice sheets and ushering in a warm climatic episode. This negative feedback loop provides a plausible explanation for multiple glaciations of the Early and Late Proterozoic, and their intimate association with sedimentary rocks formed in warm climates. Between each glacial cycle nutrients were flushed into world oceans, stimulating photosynthetic activity and causing oxygenation of the atmosphere. Accommodation for many ancient glacial deposits was provided by rifting but escape from the climatic cycle was predicated on break- up of the supercontinent, when flooded continental margins had a moderating influence on weathering. The geochemistry of Neoproterozoic cap carbonates carries a strong hydrothermal signal, suggesting that they precipitated from deep sea waters, overturned and spilled onto continental shelves at the termination of glaciations. Paleoproterozoic （Huronian） carbonates of the Espanola Formation were probably formed as a result of ponding and evaporation in a hydrothermally influenced, restricted rift setting. Why did metazoan evolution not take off a

关键词： Proterozoic supercontinents Glaciations Impacts Oxygenation metazoa