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Investigation of spatiotemporal distribution and formation mechanisms of ozone pollution in eastern Chinese cities applying convolutional neural network

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journal of Environmental Sciences 2025年第2期148卷 126-138页

作者： Qiaoli wang Dongping Sheng Chengzhi wu Xiaojie Ou Shengdong Yao jingkai Zhao Feili li wei li jianmeng Chen 无 College of Environment Zhejiang University of TechnologyHangzhou 310032China Key Laboratory of Biomass Chemical Engineering of the Ministry of Education Institute of Industrial Ecology and EnvironmentCollege of Chemical and Biological EngineeringZhejiang University(Zijingang Campus)Hangzhou 310027China Trinity Consultants Inc.(China office)Hangzhou 310012China Zhejiang University of Science&Technology Hangzhou 310023China

Severe ground-level ozone(O_(3))pollution over major Chinese cities has become one of the most challenging problems,which have deleterious effects on human health and the sustainability of *** study explored the spatiotemporal distribution characteristics of ground-level O_(3) and its precursors based on conventional pollutant and meteorological monitoring data in Zhejiang Province from 2016 to ***,a high-performance convolutional neural network(CNN)model was established by expanding the moment and the concentration variations to general ***,the response mechanism of O_(3) to the variation with crucial influencing factors is explored by controlling variables and interpolating target *** results indicated that the annual average MDA8-90th concentrations in Zhejiang Province are higher in the northern and lower in the *** the wind direction(wD)ranges from east to southwest and the wind speed(wS)ranges between 2 and 3 m/sec,higher O_(3) concentration prone to *** different temperatures(T),the O_(3) concentration showed a trend of first increasing and subsequently decreasing with increasing NO_(2) concentration,peaks at the NO_(2) concentration around 0.02mg/m^(3).The sensitivity of NO_(2) to O_(3) formation is not easily affected by temperature,barometric pressure and dew point ***,there is a minimum IRNO_(2) at each temperature when the NO_(2) concentration is 0.03 mg/m^(3),and this minimum IRNO_(2) decreases with increasing *** study explores the response mechanism of O_(3) with the change of driving variables,which can provide a scientific foundation and methodological support for the targeted management of O_(3) pollution.

关键词： Ozone Spatiotemporal distribution Convolutional neural network Ozone formation rules Incremental reactivity

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Fracture behavior of sandstone with partial filling flaw under mixed-mode loading: Three-point bending tests and discrete element method

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journal of Rock Mechanics and Geotechnical Engineering 2025年第1期17卷 291-308页

作者： Dongdong Ma Yu wu Xiao Ma Xunjian Hu wenbao Dong Decheng li lingyu li State Key Laboratory for Geomechanics and Deep Underground Engineering China University of Mining and TechnologyXuzhou221116China State Key Laboratory of Structural Health and Safety of Bridges Wuhan430034China Research Center of Coastal and Urban Geotechnical Engineering Zhejiang UniversityHangzhou310058China State Key Laboratory of Geomechanics and Geotechnical Engineering Institute of Rock and Soil MechanicsChinese Academy of SciencesWuhan430071China

The fracture behavior of natural fracture in the geological reservoir subjected to filling property,affects the crack initiation and propagation under stress *** filling flaws were intermediate between open fractures and filled fractures,the fracture response may be worth *** this work,the effect of the filling property of sandstone with partial filling flaws on the fracture behavior was systematically investigated based on three-point bending tests and the numerical approach of discrete element method(DEM).In the laboratory,semi-circular three-point bending tests were carried out with partial filling flaws of various filling *** on this,numerical simulations were used to further investigate the effect of the filling ratio and the inclination of the partial filling flaw on the mechanical and fracture responses,and the effect of the partial filling flaw under mixed-mode loading on the fracture mechanism was elucidated coupled with acoustic emission(AE)*** obtained results showed that the increase in filling strength and filling ratio of partial filling flaw led to an increase in peak strength,with a decreasing trend in peak strength with the inclination of partial filling *** terms of crack propagation pattern,the increasing filling strength of the partial filling flaw induced the transformation of the fracture mechanism toward deflection,with a tortuosity path,while the filling ratio and inclination of partial filling flaw led to fracture mechanism change from deflection to penetration and attraction,accompanied with a larger AE event source in ***,the b-value based on the Gutenberg-Richter equation fluctuated between 5 and 4 at low filling ratio and inclination and remained around 5 at high filling ratio and inclination of partial filling *** results may provide an application prospective for reservoir stimulation using the natural fracture system.

关键词： Partial filling flaw Mixed-mode loading Semi-circular three-point bending Acoustic emission(AE) b-value

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Organic solvent nanofiltration membranes for separation in non-polar solvent system

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Green Energy & Environment 2025年第2期10卷 244-267页

作者： Shuyun Gu Siyao li Zhi Xu State Key Laboratory of Chemical Engineering School of Chemical EngineeringEast China University of Science and Technology130 Meilong RoadShanghai200237China

Membrane technology holds significant potential for augmenting or partially substituting conventional separation techniques,such as heatdriven distillation,thereby reducing energy *** solvent nanofiltration represents an advanced membrane separation technology capable of discerning molecules within a molecular weight range of approximately 100-1000 Da in organic solvents,offering low energy requirements and minimal carbon *** separation in non-polar solvent system,such as toluene,n-hexane,and n-heptane,has gained paramount importance due to their extensive use in the pharmaceutical,biochemical,and petrochemical *** this review,we presented recent advancements in membrane materials,membrane fabrication techniques and their promising applications for separation in nonpolar solvent system,encompassing hydrocarbon separation,bioactive molecule purification and organic solvent ***,this review highlighted the challenges and opportunities associated with membrane scale-up strategies and the direct translation of this promising technology into industrial applications.

关键词： Organic solvent nanofiltration Membranes Membrane separation Non-polar solvent system Petrochemical and pharmaceutical application

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Galileo multi-day precise orbit determination using L-band and SLR data

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Geodesy and Geodynamics 2025年第1期16卷 99-110页

作者： Tianhe Xu Honglei Yang Song li Zhenlong Fang wenfeng Nie Min li Baoguo Yu Shandong Key Laboratory of Optical Astronomy and Solar-Terrestrial Environment Institute of Space Sciences Shandong University Navigation Laboratory of the 54th Research Institute of China Electronics Technology Group Corporation

The continuously available satellites of European Galileo currently reach more than 25. To explore the rationality and reliability of the L-band and satellite laser ranging(SLR) data processing strategies, we design the Galileo L-band, the SLR-only, and the combined L-band/SLR dynamic precise orbit determination(POD) strategies by using the normal equations(NEQs) stacking, and investigate their continuity and stability by employing the Galileo L-band data and SLR observations for the time span of the whole year of 2023, based on the Bei Dou/GNSS analysis center platform of Shandong University by using the modified Bernese GNSS Software Version 5.4. The orbital consistency of the L-band 1-day solution is the best with the Three-dimensional Root-Mean-Square(3D-RMS) values of 3.6 cm compared with the Center for Orbit Determination in Europe Multi-GNSS Experiment(COM) orbits, the corresponding values is 1.4 cm, 2.5 cm, and 2.3 cm in Radial, the Tangential, and the Normal(RTN) direction, respectively. while the SLR-only 9-day arc length is optimal with the RTN values of 5.3 cm, 30 cm, and 38.2 cm,as well as the 3D-RMS values of 48.9 cm. Encouragingly, the difference of the orbital accuracy between the combined L-band/SLR multi-day solution and the COM orbits is reduced by 0.5 cm and 0.9 cm, 0.6 cm and 1.2 cm in T-, and N-direction for the 3-and 5-day solution respectively. The corresponding values improve 0.7 cm and 0.9 cm, 1.4 cm and 1.8 cm for the 3-and 5-day orbital overlaps difference between the combined L-band/SLR and the L-band solution. Take the E09 satellite as a case study, the SLR-only orbital accuracy is regularly optimized as the multi-day arc lengthens and with the sites ***, the SLR residuals of its three types of orbits further demonstrate the positive contribution of SLR to the combination of the GNSS and SLR techniques.

关键词： Galileo POD SLR L-band NEQs stacking

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The study of antibacterial activity of cationic poly(β-amino ester)regulating by amphiphilic balance

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Chinese Chemical Letters 2025年第2期36卷 332-336页

作者： Chong liu ling li jiahui Gao Yanwei li Nazhen Zhang jing Zang Cong liu Zhaopei Guo Yanhui li Huayu Tian School of Materials Science and Engineering Changchun University of Science and Technology School of Materials Science and Engineering Xiamen University of Technology Key Laboratory of Polymer Ecomaterials Changchun Institute of Applied Chemistry Chinese Academy of Sciences College of Chemistry and Chemical Engineering Xiamen University

It is well known that cationic polymers have excellent antimicrobial capacity accompanied with high biotoxicity, to reduce biotoxicity needs to decrease the number of cationic groups on polymers, which will influence antimicrobial activity. It is necessary to design a cationic polymer mimic natural antimicrobial peptide with excellent antibacterial activity and low toxicity to solve the above dilemma. Here,we designed and prepared a series of cationic poly(β-amino ester)s(PBAEs) with different cationic contents, and introducing hydrophobic alkyl chain to adjust the balance between antimicrobial activity and biotoxicity to obtain an ideal antimicrobial polymer. The optimum one of synthesized PBAE(hydrophilic cationic monomer:hydrophobic monomer = 5:5) was screened by testing cytotoxicity and minimum inhibitory concentration(MIC), which can effectively kill S. aureus and E. coli with PBAE concentration of15 μg/m L by a spread plate bacteriostatic method and dead and alive staining test. The way of PBAE killing bacterial was destroying the membrane like natural antimicrobial peptide observed by scanning electron microscopy(SEM). In addition, PBAE did not exhibit hemolysis and cytotoxicity. In particular, from the result of animal tests, the PBAE was able to promote healing of infected wounds from removing mature S. aureus and E. coli on the surface of infected wound. As a result, our work offers a viable approach for designing antimicrobial materials, highlighting the significant potential of PBAE polymers in the field of biomedical materials.

关键词： Amphiphilic balance Antimicrobial Cationic polymers Michael addition polymerization Poly(β-amino ester)s

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Advantages of the Multimodel Ensemble Approach for Subseasonal Precipitation Prediction in China and the Driving Factor of the MjO

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Advances in Atmospheric Sciences 2025年第3期42卷 551-563页

作者： li GUO jie wU Qingquan li Xiaolong jIA China Meteorological Administration Key Laboratory for Climate Prediction Studies National Climate CentreBeijing 100081China Collaborative Innovation Centre On Forecast and Evaluation of Meteorological Disasters Nanjing University of Information Science and TechnologyNanjing 210066China

Based on the hindcasts from five subseasonal-to-seasonal(S2S)models participating in the S2S Prediction Project,this study evaluates the performance of the multimodel ensemble(MME)approach in predicting the subseasonal precipitation anomalies during summer in China and reveals the contributions of possible driving *** results suggest that while single-model ensembles(SMEs)exhibit constrained predictive skills within a limited forecast lead time of three pentads,the MME illustrates an enhanced predictive skill at a lead time of up to four pentads,and even six pentads,in southern *** on both deterministic and probabilistic verification metrics,the MME consistently outperforms SMEs,with a more evident advantage observed in probabilistic *** superior performance of the MME is primarily attributable to the increase in ensemble size,and the enhanced model diversity is also a contributing *** reliability of probabilistic skill is largely improved due to the increase in ensemble members,while the resolution term does not exhibit consistent ***,the Madden–julian Oscillation(MjO)is revealed as the primary driving factor for the successful prediction of summer precipitation in China using the *** improvement by the MME is not solely attributable to the enhancement in the inherent predictive capacity of the MjO itself,but derives from its capability in capturing the more realistic relationship between the MjO and subseasonal precipitation anomalies in *** study establishes a scientific foundation for acknowledging the advantageous predictive capability of the MME approach in subseasonal predictions of summer precipitation in China,and sheds light on further improving S2S predictions.

关键词： multimodel ensemble subseasonal predictions summer precipitation S2S model MjO

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Barrierless reactions of C2 Criegee intermediates with H_(2)SO_(4)and their implication to oligomers and new particle formation

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journal of Environmental Sciences 2025年第3期149卷 574-584页

作者： Yang Cheng Chao Ding Tianlei Zhang Rui wang Ruxue Mu Zeyao li Rongrong li juan Shi Chongqin Zhu Institute of Theoretical and Computational Chemistry Shaanxi Key Laboratory of CatalysisSchool of Chemical&Environment ScienceShaanxi University of TechnologyHanzhongShaanxi 723001China College of Chemistry Key Laboratory of Theoretical&Computational Photochemistry of Ministry of EducationBeijing Normal UniversityBeijing 100190China

The formation of oligomeric hydrogen peroxide triggered by Criegee intermediate maybe contributes significantly to the formation and growth of secondary organic aerosol(SOA).However,to date,the reactivity of C2 Criegee intermediates(CH_(3)CHOO)in areas contaminated with acidic gas remains poorly ***,high-level quantum chemical calculations and Born-Oppenheimer molecular dynamics(BOMD)simulations are used to explore the reaction of CH_(3)CHOO and H_(2)SO_(4)both in the gas phase and at the airwater *** the gas phase,the addition reaction of CH_(3)CHOO with H_(2)SO_(4)to generate CH_(3)HC(OOH)OSO_(3)H(HPES)is near-barrierless,regardless of the presence of water *** simulations showthat the reaction at the air-water interface is even faster than that in the gas *** calculations reveal that the HPES has a tendency to aggregate with sulfuric acids,ammonias,and water molecules to form stable clusters,meanwhile the oligomerization reaction of CH_(3)CHOO with HPES in the gas phase is both thermochemically and kinetically ***,it is noted that the interfacial HPES−ion can attract H_(2)SO_(4),NH_(3),(COOH)_(2)and HNO_(3)for particle formation from the gas phase to the water ***,the results of this work not only elucidate the high atmospheric reactivity of C2 Criegee intermediates in polluted regions,but also deepen our understanding of the formation process of atmospheric SOA induced by Criegee intermediates.

关键词： Criegee intermediates H_(2)SO_(4) Atmospheric behavior Air-water interface Chemical processes

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Iron scrap derived nano zero-valent iron/biochar activated persulfate for p-arsanilic acid decontamination with coexisting microplastics

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journal of Environmental Sciences 2025年第5期151卷 733-746页

作者： Zihan Shu Hailan Yang Shujing Ye Hong li Zhiming Yang Chuang li Xiaofei Tan Shaobo liu Hou wang College of Environmental Science and Engineering Hunan University and Key Laboratory of Environmental Biology and Pollution Control(Hunan University)Ministry of EducationChangsha 410082China Shenzhen Research Institute of Hunan University Shenzhen 518055China School of Resources Environment and MaterialsGuangxi UniversityNanning 530004China College of Resources and Environment University of Chinese Academy of SciencesBeijing 101408China School of Architecture and Art Central South UniversityChangsha 410083China School of Metallurgy and Environment Central South UniversityChangsha 410083China

P-arsanilic acid(AA)has received widespread attention because of its conversion to more toxic inorganic arsenic compounds(arsenate and arsenite)in the natural *** removal process and mechanisms with co-existence of microplastics remain *** this study,biochar loaded with nano zero-valent iron(nZVI)particles(ISBC)was prepared by using iron scrap obtained from a steel works and wood chips collected from a wood processing *** advanced oxidation system of sodium persulfate(PDS)activated by ISBC was applied for AA degradation and inorganic arsenic control in aqueous *** than 99%of the AA was completely degraded by the ISBC/PDS system,and the As(III)on AA was almost completely oxidized to As(V)and finally removed by ***_(3)−inhibited the removal of AA by the ISBC/PDS system,while Cl^(−)had a dual effect that showing inhibition at low concentrations yet promotion at high *** effect of microplastics on the degradation of AA by the ISBC/PDS system was further investigated due to the potential for combined microplastic and organic arsenic contamination in rural/remote *** were found to have little effect on AA degradation in the ISBC/PDS system,while affect the transport of inorganic arsenic generated from AA ***,this study provides new insights and methods for efficient removal of p-arsanilic acid from water with coexisting microplastics.

关键词： P-arsanilic acid Biochar Arsenate and arsenite Microplastics

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Pilot-scale testing on catalytic hydrolysis of carbonyl sulfur combined with absorption-oxidation of H_(2)S for blast furnace gas purification

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journal of Environmental Sciences 2025年第5期151卷 360-372页

作者： Yuting lin Yuran li Bin wang jinglei Tian Hongqiang liu Yiren li Zhicheng Xu Qiang Cao Tingyu Zhu CAS Key Laboratory of Green Process and Engineering Institute of Process EngineeringInnovation Academy for Green ManufactureChinese Academy of SciencesBeijing 100190China University of Chinese Academy of Sciences Beijing 100190China HBIS Group Co. Ltd.Shijiazhuang 050023China Center for Excellence in Regional Atmospheric Environment Institute of Urban EnvironmentChinese Academy of SciencesXiamen 361021China

About 70%of the flue gas in the iron-steel industry has achieved multi-pollutant ultra-low emissions in China until 2023,and then the blast furnace gas purification has become the control step and *** research group has designed and constructed the world’s first blast furnace gas desulfurization pilot plant with the scale of 2000 Nm^(3)/h in October *** pilot plant is a two-step combined desulfurization device including catalytic hydrolysis of carbonyl sulfur(COS)and absorption-oxidation of H_(2)S,continuously running for 120 *** the hydrolysis system,one reason for catalyst deactivation has been verified from the sulfur *** in blast furnace gas can be hydrolyzed on the hydrolysis catalyst to produce the nitrogen deposition,which is one of the reasons for catalyst deactivation and has never been found in previous *** deposition forms of S and N elements are determined,S element forms elemental sulfur and sulfate,while N element forms-NH_(2)and NH_(4)^(+).In the absorption-oxidation system,the O_(2)loading and the residence time have been optimized to control the oxidation of HS^(−)to produce elemental sulfur instead of by-product S_(2)O_(3)^(2−).The balance and distribution of S and N elements have been calculated for thewholemulti-phase system,approximately 84.4%of the sulfur is converted to solid sulfur product,about 1.3%of the sulfur and 19.2%of N element are deposited on the hydrolysis *** pilot plant provides technical support formulti-pollutant control of blast furnace.

关键词： Blast furnace gas Carbonyl sulfur Hydrogen sulfide Hydrogen cyanide Hydrolysis and oxidation Activated carbon

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Enhancing ozone catalytic decomposition through acid treatment ofα-MnO2 for improved activity and humidity resistance

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journal of Environmental Sciences 2025年第3期149卷 35-45页

作者： Shangchao Xiong Kai Zhang Zhenghao Xu Hongjun Ou Yuanyuan Zheng Xi li Yue Peng Xubiao Luo junhua li School of life Sciences Jinggangshan UniversityJi’an 343009China Faculty of Geosciences and Environmental Engineering Southwest Jiaotong UniversityChengdu 610031China State Key joint Laboratory of Environment Simulation and Pollution Control School of EnvironmentTsinghua UniversityBeijing 100084China

Post-etching method using dilute acid solutions is an effective technology to modulate the surface compositions of metal-oxide *** theα-MnO2 catalyst treated with 0.1 mol/L nitric acid exhibits higher ozone decomposition activity at high relative humidity than the counterpart treated with acetic *** the increases in surface area and lattice dislocation,the improved activity can be due to relatively higher Mn valence on the surface and newly-formed Brønsted acid sites adjacent to oxygen *** remnant nitro species deposited on the catalyst by nitric acid treatment is ideal hydrophobic groups at ambient *** decomposition route is also proposed based on the DRIFTS and DFT calculations:ozone is facile to adsorb on the oxygen vacancy,and the protonic H of Brønsted acid sites bonds to the terminal oxygen of ozone to accelerate its cleavage to O2,reducing the reaction energy barrier of O2 desorption.

关键词： Ozone decomposition α-MnO2 Brønsted acid sites H-bonds Post-etching

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