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Defect Engineering in Earth-Abundant Cu_(2)ZnSnSe_(4) Absorber Using Efficient Alkali Doping for Flexible and Tandem Solar Cell Applications

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Energy & Environmental Materials 2024年第2期7卷 249-256页

作者： Muhammad Rehan Ara cho Inyoung jeong Kihwan Kim Asmat Ullah jun-Sik cho joo Hyung Park Yunae jo Sung jun Hong Seung Kyu Ahn Sejin Ahn jae Ho Yun jihye Gwak Donghyeop Shin Photovoltaics Research Department Korea Institute of Energy Research(KIER)152-Gajeong-roYuseong-guDaejeon 34129Korea Department of Renewable Energy Engineering University of Science and Technology(UST)217-Gajeong-roYuseong-guDaejeon 34113Korea Korea Institute of Energy Technology(KENTECH) 50772 Ujeong-roNaju Jeonnam 58217Korea

To demonstrate flexible and tandem device applications,a low-temperature Cu_(2)ZnSnSe_(4)(CZTSe)deposition process,combined with efficient alkali doping,was ***,high-quality CZTSe films were grown at 480℃by a single co-evaporation,which is applicable to polyimide(PI)*** of the alkali-free substrate,Na and K alkali doping were systematically studied and optimized to precisely control the alkali distribution in *** bulk defect density was significantly reduced by suppression of deep acceptor states after the(NaF+KF)*** the low-temperature deposition with(NaF+KF)PDTs,the CZTSe device on glass yields the best efficiency of 8.1%with an improved Voc deficit of 646 *** developed deposition technologies have been applied to *** the first time,we report the highest efficiency of 6.92%for flexible CZTSe solar cells on ***,CZTSe devices were utilized as bottom cells to fabricate four-terminal CZTSe/perovskite tandem cells because of a low bandgap of CZTSe(~1.0 eV)so that the tandem cell yielded an efficiency of 20%.The obtained results show that CZTSe solar cells prepared by a low-temperature process with in-situ alkali doping can be utilized for flexible thin-film solar cells as well as tandem device applications.

关键词： alkali doping Earth-abundant Cu_(2)ZnSnSe_(4) flexible solar cells four-terminal tandem cells low-temperature process

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Bidirectional rotating direct-current triboelectric nanogenerator with self-adaptive mechanical switching for harvesting reciprocating motion

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International journal of Extreme Manufacturing 2024年第4期6卷 324-335页

作者： Donghan Lee joonmin Chae Sumin cho jong Woo Kim Awais Ahmad Mohammad Rezaul Karim Moonwoo La Sung jea Park Dongwhi choi Department of Mechanical Engineering(Integrated Engineering Program) Kyung Hee University1732 Deogyeong-daeroYonginGyeonggi 17104Republic of Korea Department of Chemistry University of LahoreLahorePakistan Department of Mechanical Engineering College of EngineeringKing Saud UniversityRiyadh 11421Saudi Arabia School of Mechanical Engineering Korea University of Technology and Education1600 Chungjeol-roCheonanChungnam 31253Republic of Korea

Amid the growing interest in triboelectric nanogenerators(TENGs)as novel energy-harvesting devices,several studies have focused on direct current(DC)TENGs to generate a stable DC output for operating electronic ***,owing to the working mechanisms of conventional DC TENGs,generating a stable DC output from reciprocating motion remains a ***,we propose a bidirectional rotating DC TENG(BiR-TENG),which can generate DC outputs,regardless of the direction of rotation,from reciprocating *** distinct design of the BiR-TENG enables the mechanical rectification of the alternating current output into a rotational-direction-dependent DC ***,it allows the conversion of the rotational-direction-dependent DC output into a unidirectional DC output by adapting the configurations depending on the rotational *** to these tailored design strategies and subsequent optimizations,the BiR-TENG could generate an effective unidirectional DC *** of the BiR-TENG for the reciprocating motions of swinging doors and waves were demonstrated by harnessing this *** study demonstrates the potential of the BiR-TENG design strategy as an effective and versatile solution for energy harvesting from reciprocating motions,highlighting the suitability of DC outputs as an energy source for electronic devices.

关键词： direct-current triboelectric nanogenerator mechanical rectification self-adaptive mechanical design harvesting reciprocation motion

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Optimal transcorneal electrical stimulation parameters for preserving photoreceptors in a mouse model of retinitis pigmentosa

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Neural Regeneration Research 2024年第11期19卷 2543-2552页

作者： Sam Enayati Karen Chang Anton Lennikov Menglu Yang Cherin Lee Ajay Ashok Farris Elzaridi Christina Yen Kasim Gunes jia Xie Kin-Sang cho Tor Paaske Utheim Dong Feng Chen Schepens Eye Research Institute of Massachusetts Eye and Ear Department of OphthalmologyHarvard Medical SchoolBostonMAUSA Institute of clinical medicine Faculty of MedicineUniversity of OsloOsloNorway Department of Medical Biochemistry Oslo University HospitalUniversity of OsloOsloNorway Department of Ophthalmology Drammen HospitalVestre Viken Hospital TrustDrammenNorway Department of Histology and Embryology School of MedicineMarmara UniversityIstanbulTurkiye

Retinitis pigmentosa is a hereditary retinal disease that affects rod and cone photoreceptors,leading to progressive photoreceptor *** research supports the beneficial effect of electrical stimulation on photoreceptor *** study aims to identify the most effective electrical stimulation parameters and functional advantages of transcorneal electrical stimulation(tcES)in mice affected by inherited retinal ***,the study seeked to analyze the electric field that reaches the retina in both eyes in mice and post-mortem *** this study,we recorded waveforms and voltages directed to the retina during transcorneal electrical stimulation in C57BL/6j mice using an intraocular needle probe with rectangular,sine,and ramp *** investigate the functional effects of electrical stimulation on photoreceptors,we used human retinal explant cultures and rhodopsin knockout(Rho^(-/-))mice,demonstrating progressive photoreceptor degeneration with *** retinal explants isolated from the donors’eyes were then subjected to electrical stimulation and cultured for 48 hours to simulate the neurodegenerative environment in *** density was evaluated by rhodopsin *** vivo Rho^(-/-)mice were subjected to two 5-day series of daily transcorneal electrical stimulation using rectangular and ramp *** function and visual perception of mice were evaluated by electroretinography and optomotor response(OMR),*** was used to assess the morphological and biochemical changes of the photoreceptor and bipolar cells in mouse *** recordings indicated effective delivery of rectangular,sine,and ramp waveforms to the retina by transcorneal electrical stimulation,of which the ramp waveform required the lowest *** of the total conductive resistance of the post-mortem human compared to the mouse eyes indicated higher cornea-to-retina resistance in human *** tem

关键词： bipolar cells electrical stimulation neuroprotection photoreceptor degeneration retina retinal explants retinitis pigmentosa transcorneal electrical stimulation waveform

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Vertical plane depth-resolved surface potential and carrier separation characteristics in flexible CZTSSe solar cells with over 12% efficiency

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Carbon Energy 2024年第3期6卷 36-52页

作者： Dae-Ho Son Ha Kyung Park Dae-Hwan Kim jin-Kyu Kang Shi-joon Sung Dae-Kue Hwang jaebaek Lee Dong-Hwan jeon Yunae cho William jo Taeseon Lee junHo Kim Sang-Hoon Nam Kee-jeong Yang Division of Energy Technology DGISTDaeguRepublic of Korea Research Center for Thin Film Solar Cells DGISTDaeguRepublic of Korea Department of Physics Ewha Womans UniversitySeoulRepublic of Korea Department of Physics Incheon National UniversityIncheonRepublic of Korea Department of Mechanical Engineering Massachusetts Institute of TechnologyCambridgeMassachusettsUSA

Cu2ZnSn(S,Se)4(CZTSSe)solar cells have resource distribution and economic *** main cause of their low efficiency is carrier loss resulting from recombination of photo-generated electron and *** overcome this,it is important to understand their electron-hole behavior *** determine the carrier separation characteristics,we measured the surface potential and the local current in terms of the absorber *** elemental variation in the intragrains(IGs)and at the grain boundaries(GBs)caused a band edge shift and bandgap(Eg)*** the absorber surface and subsurface,an upward Ec and Ev band bending structure was observed at the GBs,and the carrier separation was *** the absorber center,both upward Ec and Ev and downward Ec-upward Ev band bending structures were observed at the GBs,and the carrier separation was *** improve the carrier separation and suppress carrier recombination,an upward Ec and Ev band bending structure at the GBs is desirable.

关键词： carrier separation CZTSSe flexible solar cell local current surface potential

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Surface-functionalized hole-selective monolayer for high efficiency single-junction wide-bandgap and monolithic tandem perovskite solar cells

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journal of Energy Chemistry 2024年第1期88卷 317-326,I0008页

作者： Devthade Vidyasagar Yeonghun Yun jae Yu cho Hyemin Lee Kyung Won Kim Yong Tae Kim Sung Woong Yang jina jung Won Chang choi Seonu Kim Rajendra Kumar Gunasekaran Seok Beom Kang Kwang Heo Dong Hoe Kim jaeyeong Heo Sangwook Lee School of Materials Science and Engineering Kyungpook National UniversityDaegu 41566Republic of Korea Department of Materials Science and Engineering and Optoelectronics Convergence Research CenterChonnam National UniversityGwangju 61186Republic of Korea Department of Materials Science and Engineering Korea UniversitySeoul 02841Republic of Korea Department of Nanotechnology and Advanced Materials Engineering Sejong UniversitySeoul 05006Republic of Korea

Carbazole moiety-based 2PACz([2-(9H-carbazol-9-yl)ethyl]phosphonic acid)self-assembled monolayers(SAMs)are excellent hole-selective contact(HSC)materials with abilities to excel the charge-transferdynamics of perovskite solar cells(PSCs).Herein,we report a facile but powerful method to functionalize the surface of 2PACz-SAM,by which reproducible,highly stable,high-efficiency wide-bandgap PSCs can be *** 2PACz surface treatment with various donor number solvents improves assembly of 2PACz-SAM and leave residual surface-bound solvent molecules on 2PACz-SAM,which increases perovskite grain size,retards halide segregation,and accelerates hole *** surface functionalization achieves a high power conversion efficiency(PCE)of 17.62%for a single-junction wide-bandgap(~1.77 e V)*** also demonstrate a monolithic all-perovskite tandem solar cell using surfaceengineered HSC,showing high PCE of 24.66%with large open-circuit voltage of 2.008 V and high fillfactor of 81.45%.Our results suggest this simple approach can further improve the tandem device,when coupled with a high-performance narrow-bandgap sub-cell.

关键词： Perovskite solar cells 2PACz Monolithic tandem solar cells Wide bandgap

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应用剪切波离散成像斜率值预测移植肾急性排异反应

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国际医学放射学杂志 2024年第5期 620-621页

作者： T.M.Kim H.Ahn j.Y.cho A.Han S.I .Min j.Ha 郑永利

目的评价剪切波离散成像斜率值预测移植肾功能不全的价值。方法回顾性分析2022年11月—2023年2月期间行肾移植的128例受试者资料[中位年龄，55(43～62)

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Arsenic removal from water and soils using pristine and modified biochars

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Biochar 2022年第1期4卷 255-280页

作者： Wei Zhang Yoora cho Meththika Vithanage Sabry M.Shaheen jörg Rinklebe Daniel S.Alessi Chia-Hung Hou Yohey Hashimoto Piumi Amasha Withana Yong Sik ok Korea Biochar Research Center APRU Sustainable Waste Management and Division of Environmental Science and Ecological EngineeringKorea UniversitySeoul 02841South Korea School of Environmental Science and Engineering Guangzhou UniversityGuangzhou 510006China Ecosphere Resilience Research Center Faculty of Applied SciencesUniversity of Sri JayewardenepuraNugegoda 10250Sri Lanka Sustainability Cluster University of Petroleum and Energy StudiesUttarkhandDehradunIndia The Institute of Agriculture The University of Western AustraliaCrawleyAustralia School of Architecture and Civil Engineering Institute of Foundation EngineeringWater-and Waste-ManagementLaboratory of Soil-and Groundwater-ManagementUniversity of WuppertalPauluskirchstraße742285 WuppertalGermany Department of Earth and Atmospheric Sciences University of AlbertaEdmontonAB T6G 2E3Canada Graduate Institute of Environmental Engineering National Taiwan UniversityTaipei 10617TaiwanChina Department of Bioapplications and Systems Engineering Tokyo University of Agriculture and TechnologyTokyoJapan Department of Arid Land Agriculture Faculty of MeteorologyEnvironmentand Arid Land AgricultureKing Abdulaziz University21589 JeddahSaudi Arabia Department of Soil and Water Sciences Faculty of AgricultureUniversity of Kafrelsheikh33516 Kafr El-SheikhEgypt

Arsenic(As)is recognized as a persistent and toxic contaminant in the environment that is harmful to ***,a porous carbonaceous material with tunable functionality,has been used widely as an adsorbent for remediating As-contaminated water and *** types of pristine and modified biochar are available,and significant efforts have been made toward modifying the surface of biochars to increase their adsorption capacity for *** capacity is influenced by multiple factors,including biomass pyrolysis temperature,pH,the presence of dissolved organic carbon,surface charge,and the presence of phosphate,silicate,sulfate,and microbial *** As adsorption in modified biochars is attributed to several mechanisms including surface complexation/precipitation,ion exchange,oxidation,reduction,electrostatic interactions,and surface functional groups that have a relatively higher affinity for *** biochars show promise for As adsorption;however,further research is required to improve the performance of these *** example,modified biochars must be eco-friendly,cost-effective,reliable,efficient,and sustainable to ensure their widespread application for immobilizing As in contaminated water and *** relevant research to address these issues relies on a thorough understanding of biochar modifications to *** study presents an in-depth review of pristine and modified biochars,including their production,physicochemical properties,and As adsorption ***,a comprehensive evaluation of biochar applications is provided in As-contaminated environments as a guide for selecting suitable biochars for As removal in the field.

关键词： Engineered biochar Removal mechanisms Arsenic pollution Water pollution Soil pollution

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Synthesis and Characterization of Nanocapsules of α-Fe(NiCoAl) Solid-solution

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journal of Materials Science & Technology 2005年第3期21卷 297-300页

作者： DianyuGENG j.C.Kim C.j.cho chonglinCHEN XianguoZHAO ZidongZHANG ShenyangNationalLaboratoryforMaterialsScience InstituteofMetalResearchandInternationalCentretbrMaterialsPhysicsChineseAcademyofSciencesShenyang110016China KoreaInstituteofMachineryandMaterials 66Sangnam-dongChangwonKynugnam640-010SouthKorea

α-Fe(NiCoAl) solid-solution nanocapsules were prepared with pure powders of Fe, Ni, Co and Al by the plasma arc-discharging using a copper crucible. The shapes of the nanocapsules are in polyhedrons with the core/shell structure. The body centered cubic (BCC) phase is formed in the core. The size of the nanocapsules is in the range of 10-120 nm and the thickness of the shell is 4-11 nm. Saturation magnetization jS=150 Am2/kg and coercivity iHC=24.3 kA/m are achieved for the nanocapsules.

关键词： Nanocapsules a-Fe solid solution Plasma arc discharge Magnetic properties

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Damage and penetration behavior of aluminum foam at various impacts

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journal of Central South University 2014年第9期21卷 3442-3448页

作者： cho Hosun cho jaeung Division of Mechanical Engineering Graduate School Kongju National University Division of Mechanical and Automotive Engineering Kongju National University

In this work, the damage and penetration behavior of aluminum foam at various types of impact were examined through experiments. The impact energy of a striker was applied on the fixed aluminum foam having a thickness of 25 mm while increasing its impact by 2 j at each strike from 6 j to 16 j. The results show that the impact energies from 6 j to 12 j could not penetrate aluminum foam. However, the aluminum foam applied with the impact energy of 12 j incurred severe damages on its lower part. Finally, the aluminum foam applied with the impact energy of 14 j was penetrated. The striker having the impact energy of 6 j could penetrate aluminum foam around 10 mm. At this moment, aluminum foam could absorb the impact energy of around 9 j. When the impact energy of 14 j was applied on the aluminum foam, the aluminum foam was penetrated and it absorbed the impact energy of around 17.2 j. It is possible to create the safer structure against impact using the results of this work. The simulation results for the verification of the experimental results imply that the results for all the experiments in this work are reliable. It is possible to predict the structural safety of the aluminum foam for an impact if the impact behavior of aluminum foam performed in this work is utilized.

关键词： aluminum foam absorbed energy finite element analysis impact energy impact load

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COUPLED VIBRATION OF STRUCTURAL THIN-WALLED CORES

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Acta Mechanica Solida Sinica 2000年第1期13卷 81-88页

作者： Shiu cho NG j.S.Kuang Department of Civil Engineering Hong Kong University of Science and Technology

This paper presents an analysis of the coupled vibration of asymmetric core structures in tall buildings. The governing equation of free vibration and its corresponding eigenvalue problem, which is a set of equations for laterally flexural vibrations in two different directions coupled by a warping-St. Venant torsional vibration, are derived. Based on the Calerkin method, a generalized approximate method is developed for the analysis of coupled vibration and thus proposed for determining the natural frequencies and mode shapes of the structure in triply-coupled vibration. The results of the proposed method for the example structure show good agreement with those of the FEM analysis. The proposed method has been shown to provide a simple and rapid, yet accurate, means for coupled vibration analysis of core structures.

关键词： coupled vibration analysis asymmetric core structure Galerkin method natural frequency mode shape

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