检索结果-南通市图书馆

Photodegradation of xylene isomers:Kinetics,mechanism,secondary pollutant formation potential and health risk evaluation

引用

journal of Environmental Sciences 2024年第2期136卷 658-669页

作者： Xiaoyan Chen Weikun zhu Sufen feng jiangyao Chen Guangdong Key Laboratory of Environmental Catalysis and Health Risk Control Guangdong Technology Research Center for Photocatalytic Technology Integration and Equipment EngineeringInstitute of Environmental Health and Pollution ControlGuangdong University of TechnologyGuangzhou 510006China Guangzhou Key Laboratory of Environmental Catalysis and Pollution Control Guangdong-Hong Kong-Macao Joint Laboratory for Contaminants Exposure and HealthSchool of Environmental Science and EngineeringGuangdong University of TechnologyGuangzhou 510006China

Photodegradation technology has been widely applied in the purification of industrial aromatic ***,whether this technology efficiently removes the pollutants to prevent secondary pollution and health risk is still ***,the photodegradation processes of three xylenes were compared under designed reaction atmospheres and light *** lamp showed poor photodegradation ability toward xylenes,no matter in n_(2) or n_(2)+O_(2)system,while much higher photodegradation performance of xylenes were obtained under ultraviolet(UV)and vacuum ultraviolet(VUV)irradiation,especially in n_(2)+O_(2)+VUV system,where 97.9%of m-xylene,99.0%of o-xylene or 87.5%of p-xylene with the initial concentration of 860 mg/m^(3) was removed within 240 *** xylenes underwent three processes of photo-isomerization,photodecomposition and photo-oxidation to produce intermediates of aromatics,alkanes and *** them,the photo-isomerization products showed the highest concentration percentage(e.g.,≥50%in o-xylene system),confirming that photo-isomerization reaction was the dominated photodegradation process of ***,these isomerized products not only contributed about 97%and91%to the formation potential of O3(OFP)and secondary organic aerosols(SOAFP),but also displayed obvious non-carcinogenic risk,although one of photodecomposition product—benzene showed the highest occupational exposure ***,the secondary pollution and health risks of photodegradation products of xylenes were non-ignorable,although the OFP,SOAFP and health risks of the generated products reduced at least 4.5 times in comparison with that of the degraded *** findings are helpful for the appropriate application of this technology in the purification of industrial organic waste gas.

关键词： Isomer aromatics Photodegradation Ozone formation Secondary organic aerosols Health risk

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

A dual-function selection system enables positive selection of multigene CRISPR mutants and negative selection of Cas9-free progeny in Arabidopsis

引用

aBIOTECH 2024年第2期5卷 140-150页

作者： feng-zhu Wang Ying Bao Zhenxiang Li Xiangyu Xiong jian-feng Li State Key Laboratory of Biocontrol Guangdong Provincial Key Laboratory of Plant ResourcesSchool of Life SciencesSun Yat-sen UniversityGuangzhou 510275China

The CRISPR/Cas9 technology revolutionizes targeted gene knockout in diverse organisms including ***,screening edited alleles,particularly those with multiplex editing,from herbicide-or antibiotic-resistant transgenic plants and segregating out the Cas9 transgene represent two laborious *** solutions to facilitate these processes rely on different selection ***,by taking advantage of the opposite functions of a D-amino acid oxidase(DAO)in detoxifying D-serine and in metabolizing non-toxic D-valine to a cytotoxic product,we develop a DAO-based selection system that simultaneously enables the enrichment of multigene edited alleles and elimination of Cas9-containing progeny in Arabidopsis *** five DAOs tested in Escherichia coli,the one encoded by Trigonopsis variabilis(TvDAO)could confer slightly stronger D-serine resistance than other *** expression of TvDAO in Arabidopsis allowed a clear distinction between transgenic and nontransgenic plants in both D-serine-conditioned positive selection and D-valine-conditioned negative *** a proof of concept,we combined CRISPR-induced single-strand annealing repair of a dead TvDAO with D-serine-based positive selection to help identify transgenic plants with multiplex editing,where D-serine-resistant plants exhibited considerably higher co-editing frequencies at three endogenous target genes than those selected by ***,D-valine-based negative selection successfully removed Cas9 and TvDAO transgenes from the survival offspring carrying inherited ***,this work provides a novel strategy to ease CRISPR mutant identification and Cas9 transgene elimination using a single selection marker,which promises more efficient and simplified multiplex CRISPR editing in plants.

关键词： CRISPR Genome editing D-amino acid oxidase Cas9-free Selection marker

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Permeable carbon fiber based thermoelectric film with exceptional EMI shielding performance and sensor capabilities

引用

journal of Advanced Ceramics 2024年第8期13卷 1119-1131页

作者： j.njie zhu Chuan Sun Wanlin feng Mengran Chen Peng-An Zong Chunlei Wan College of Materials Science and Engineering Nanjing Tech UniversityNanjing 211800China nationai Innovation Institute of Defense Technology Academy of Military Sciences of the People's Liberation Army of ChinaBeijing 100089China Institute of nuclear Physics and Chemistry Innovation Research Team for Advanced CeramicsChina Academy of Engineering PhysicsMianyang 621900China State Key Laboratory of new Ceramics and Fine Processing School of Materials Science and EngineeringTsinghua UniversityBeijing 100084China

Thermoelectric(TE)technologies offer a promising approach for directly converting skin heat into electricity for wearable *** p-type Sb2Tes and n-type BizTes as top-performing materials at room temperature,their rigid inorganic structure,with ultralow moisture permeability,poses challenges in warm and humid conditions,fostering bacterial growth and potential skin *** address this issue,we developed a cross-linked core-shell structure by electrodepositing Sb_(2)Te_(3)(Bi_(2)Te_(3))onto carbon fiber(CF).This architecture significantly improved the electrical conductivity and the Seebeck coefficient,resulting in a remarkable 300-fold increase in the power factor compared to that of pure *** CF/Sb_(2)Te_(3) and CF/Bi2Te films demonstrated optimal power factors of 450 and 121μW·m^(-1)·K^(-2),***,the fabricated films exhibited outstanding moisture permeability,over 3000 g·m^(-2)·d^(-1),exceptional electromagnetic interference shielding efficiency approaching 93 dB,and versatility as sensors for language assistance and respiratory *** attributes underline their broad applicability,emphasizing their suitability for human health protection in diverse scenarios.

关键词： thermoelectric(TE) carbon fiber(CF) Bi_(2)Te_(3) electrodeposition moisture permeability electromagnetic interference shielding

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Enhanced electrochemical oxidation of perfluorooctanoic acid on Ti/SnO_(2)-Sb electrode by surface morphology regulation

引用

Chinese Chemical Letters 2024年第3期35卷 140-143页

作者： Kaiqiang Hou Genwang zhu Yujie feng Yanming Liu Xie Quan Key Laboratory of Industrial Ecology and Environmental Engineering(Ministry of Education China)School of Environmental Science and TechnologyDalian University of TechnologyDalian 116024China State Key Laboratory of Urban Water Resource and Environment School of EnvironmentHarbin Institute of TechnologyHarbin 150090China

Electrochemical oxidation is an effective method to degrade persistent organic ***,due to the limited catalytic activity of traditional thin film electrodes,the anodic oxidation process is slow and usually requires high energy ***,Ti/SnO_(2)-Sb electrode with regulated surface structure was reported to enhance the performance for electrochemical oxidation of persistent organic *** electrode deposited with SnO_(2)-Sb nanoneedles(Ti/n-SnO_(2)-Sb)showed higher oxidation *** kinetic constant for perfluorooctanoic acid(PFOA)oxidation was 2.0 h^(-1)and the total organic carbon removal rate was 81.7%(4 h)at a relatively low current density of 6 mA/cm^*** with Ti/SnO_(2)-Sb thin film and nanoparticles,Ti/n-SnO_(2)-Sb significantly improved the electrochemical active area and·OH yield,and simultaneously reduced the electron transfer resistance,which enabled it to oxidize PFOA more rapidly even at a lower *** work provides a new strategy for promoting the electrochemical oxidation performance.

关键词： Electrochemical oxidation nanoneedle SnO_(2)-Sb Perfluoroalkyl compounds Electrochemical degradation Persistent organic pollutants

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Crystallization of RE_(2)(OH)_(2)CO_(3)SO_(4)·nH_(2)O as a new family of layered hydroxides(RE=Gd-Lu lanthanides and Y),derivation of RE_(2)O_(2)SO_(4),photoluminescence and optical thermometry

引用

journal of Rare Earths 2024年第8期42卷 1496-1506,I0003页

作者： Fan Li Zhenqi Song Zhiyuan Pan Sihan feng Qi zhu ji-Guang Li Key Laboratory for Anisotropy and Texture of Materials(Ministry of Education) School of Materials Science and EngineeringNortheastern UniversityShenyang110819China Research Center for Functional Materials National Institute for Materials ScienceTSsukuboaIbaraki3050044Japan

Layered rare-earth hydroxides(LREHs) draw wide research interest because of their peculiar crystal structure,rich interlayer chemistry and abundant functionality of the RE element,but are limited to the two categories of RE_(2)(OH)_(5)A·nH_(2)O(A:typical of Cl^(-)or nO_(3)^(-)) and RE_(2)(OH)_(4)SO_(4)·nH_(2)*** the other hand,rare-earth oxysulfates(RE_(2)O_(2)SO_(4)) have attracted attention due to their properties of large-capacity oxygen storage,low-temperature magnetism and luminescence,but their preparation procedure mostly involves toxic SO_(x) gases and/or complicated *** this work,RE_(2)(OH)_(2)CO_(3)SO_(4)·nH_(2)O as a new family of LREHs(RE=Gd-Lu lanthanides and Y) were produced via hydrothermal reaction,from which phase-pure RE_(2)O_(2)SO_(4) was derived via subsequent annealing at 800℃ in air without the involvement of SO_(x),The compounds were thoroughly characterized to reveal the intrinsic influence of lanthanide contraction(RE^(3+) radius) on crystal structure,thermal behavior(dehydroxylation/decarbonation/desulfurization),vibrational property and crystallite *** analyzing the photoluminescence of Eu^(3+) and Sm^(3+)in the Gd_(2)O_(2)SO_(4) typical host it is found that the 617 nm(Eu^(3+),λ_(ex)=275 nm) and 608 nm(Sm^(3+),λ_(ex)=407 nm) main emissions can retain as high as ^(7)9.6% and 85.5%of their room-temperature intensities at 423 K,with activation energies of ~0.19 and 0.21 eV for thermal quenching,*** also indicates that both the phosphors have the potential for optical temperature sensing via the fluorescence intensity ratio(FIR) technology,whose maximum relative sensitivity reaches -2.70%/K for Eu^(3+)and 1.73%/K for Sm^(3+) at 298 K.

关键词： Layered hydroxide RE_(2)O_(2)SO_(4) Luminescence Optical temperature sensing Rare earths

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Pd/n-doped carbon dots@dendritic mesoporous silica nanospheres:A highly efficient catalyst for the hydrogenation of 4-nitrophenol

引用

nano Research 2024年第9期17卷 7967-7974页

作者： Weiruo Liu Yanbin zhu jiwei Wang Haisong feng Yunpu Zhai Wei Li Dongyuan Zhao College of Chemistry Zhengzhou University100 Kexue AvenueZhengzhou 450001China Department of Chemistry Laboratory of Advanced MaterialsShanghai Key Laboratory of Molecular Catalysis and Innovative Materialsand State Key Laboratory of Molecular Engineering of PolymersFudan UniversityShanghai 200433China State Key Laboratory of Chemical Resource Engineering Beijing Advanced Innovation Center for Soft Matter Science and EngineeringBeijing University of Chemical TechnologyBeijing 100029China

Highly dispersed Pd/n-doped carbon dots(Pd/nCDs)were successfully immobilized in the mesoporous channels of amino-functionalized dendritic mesoporous silica nanospheres(nMS).The synthesized Pd/nCDs@nMS catalyst exhibits outstanding performance in the catalytic reduction of 4-nitrophenol(4-nP),achieving a turnover frequency of 1461.8 mol·molPd^(-1)·h^(-1),with the conversion rate remaining above 80%after 11 *** and density functional theory calculations reveal that the nCDs significantly affect the electronic structure of Pd nanoparticles,leading to changes in the energy barriers for the adsorption of 4-nP at the Pd sites and the conversion of 4-nP reaction intermediates,which is a key factor contributing to the catalytic *** study offers a new strategy for synthesizing carbon-dot-modified metal-based catalysts.

关键词： palladium nanoparticles nitrogen-doped carbon dots dendritic mesoporous silica catalytic hydrogenation 4-nitrophenol reduction

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Mechanism of local solidification time variations with melt rate during vacuum arc remelting process of 8Cr4Mo4V high-strength steel

引用

journal of Iron and Steel Research International 2024年第2期31卷 377-388页

作者： Tao Pan Hong-chun zhu Zhou-hua jiang Hua-bing Li Rui Zhang Hao feng School of Metallurgy Northeastern UniversityShenyang110819LiaoningChina State Key Laboratory of Rolling and Automation Northeastern UniversityShenyang110819LiaoningChina

A 2D axisymmetric numerical model was established to investigate the variations of molten pool with different melt rates during the vacuum arc remelting of 8Cr4Mo4V high-strength steel,and the ingot growth was simulated by dynamic mesh *** results show that as the ingot grows,the molten pool profile changes from shallow and flat to V-shaped,and both the molten pool depth and the mushy width ***,the variation of both the molten pool shape and the mushy width melt rate is clarified by the thermal equilibrium *** melt rate increases,both the molten pool depth and the mushy width *** is caused by the increment in sensible heat stored in the ingot due to the limitation of the cooling capacity of the *** nonlinear increment in sensible heat leads to a nonlinear increase in the mushy *** addition,as melt rate increases,the local solidification time(LST)of ingot decreases obviously at first and then *** melt rate is controlled in a suitable range,LST is the lowest and the secondary dendrite arm spacing of the ingot is the smallest,which can effectively improve the compactness degree of 8Cr4Mo4V high-strength steel.

关键词： 8Cr4Mo4V high-strength steel Vacuum arc remelting process Melt rate Molten pool Local solidification time

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Multifunctional Film Assembled from n‑Doped Carbon nanofiber with Co–n_(4)–O Single Atoms for Highly Efficient Electromagnetic Energy Attenuation

引用

nano-Micro Letters 2024年第11期16卷 359-376页

作者： jia Xu Bei Li Zheng Ma Xiao Zhang Chunling zhu feng Yan Piaoping Yang Yuj.n Chen College of Materials Science and Chemical Engineering Harbin Engineering UniversityHarbin 150001People’s Republic of China Key Laboratory of In‑Fiber Integrated Optics College of Physics and Optoelectronic EngineeringHarbin Engineering UniversityHarbin 150001People’s Republic of China

Single-atom materials have demonstrated attractive physicochemical ***,understanding the relationships between the coordination environment of single atoms and their properties at the atomic level remains a considerable ***,a facile waterassisted carbonization approach is developed to fabricate well-defined asymmetrically coordinated Co–n_(4)–O sites on biomass-derived carbon nanofiber(Co–n_(4)–O/nCF)for electromagnetic wave(EMW)*** such nanofiber,one atomically dispersed Co site is coordinated with four n atoms in the graphene basal plane and one oxygen atom in the axial ***-depth experimental and theoretical studies reveal that the axial Co–O coordination breaks the charge distribution symmetry in the planar porphyrin-like Co–n_(4) structure,leading to significantly enhanced dielectric polarization loss relevant to the planar Co–n_(4) ***,the film based on Co–n_(4)–O/nCF exhibits light weight,flexibility,excellent mechanical properties,great thermal insulating feature,and excellent EMW absorption with a reflection loss of−45.82 dB along with an effective absorption bandwidth of 4.8 *** findings of this work offer insight into the relationships between the single-atom coordination environment and the dielectric performance,and the proposed strategy can be extended toward the engineering of asymmetrically coordinated single atoms for various applications.

关键词： Co single atoms Asymmetric coordination structure Axial oxygen coordination Electromagnetic wave absorption Multifunctional film

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Achievable hole concentration at room temperature as a function of Mg concentration for MOCVD-grown p-Gan after sufficient annealing

引用

journal of Semiconductors 2024年第8期45卷 67-73页

作者： Siyi Huang Masao Ikeda feng Zhang Minglong Zhang jianj.n zhu Shuming Zhang jianping Liu School of nano-Tech and nano-Bionics University of Science and Technology of ChinaHefei 230026China Suzhou Institute of nano-Tech and nano-Bionics Chinese Academy of SciencesSuzhou 215123China Key Laboratory of nanodevices and Applications Chinese Academy of SciencesSuzhou 215123China

Relationship between the hole concentration at room temperature and the Mg doping concentration in p-Gan grown by MOCVD after sufficient annealing was studied in this *** annealing conditions were applied to obtain sufficient activation for p-Gan samples with different Mg doping *** concentration,resistivity and mobility were characterized by room-temperature Hall *** Mg doping concentration and the residual impurities such as H,C,O and Si were measured by secondary ion mass spectroscopy,confirming negligible compensations by the *** hole concentration,resistivity and mobility data are presented as a function of Mg concentration,and are compared with literature *** appropriate curve relating the Mg doping concentration to the hole concentration is derived using a charge neutrality equation and the ionized-acceptor-density[n-(A)^(-)](cm^(−3))dependent ionization energy of Mg acceptor was determined asE_(A)^(Mg)=184−2.66×10^(−5)×[n_(A)^(-)]1/3 meV.

关键词： p-Gan hole concentration electrical properties annealing ionization energy

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

The infection kinetics and transmission potential of two Guaico Culex viruses in Culex quinquefasciatus mosquitoes

引用

Virologica Sinica 2024年第2期39卷 228-234页

作者： Ru-Yi Chen Teng Zhao j.ng-j.ng Guo feng zhu na-na Zhang Xiao-feng Li Hai-Tao Liu Fei Wang Yong-Qiang Deng Cheng-feng Qin College of Bioscience and Bioengineering Jiangxi Agricultural UniversityNanchang330045China State Key Laboratory of Pathogen and Biosecurity Beijing Institute of Microbiology and EpidemiologyAMMSBeijing100071China School of Life Sciences Southwest Forestry UniversityKunming650224China

Guaico Culex virus(GCXV)is a newly identified segmented j.ngmenvirus from Culex *** in Central and South *** genome of GCXV is composed of four or five single-stranded positive RnA ***,the infection kinetics and transmission capability of GCXV in mosquitoes remain *** this study,we used reverse genetics to rescue two GCXVs(4S and 5S)that contained four and five RnA segments,respectively,in C6/36 *** in vitro characterization revealed that the two GCXVs exhibited comparable replication kinetics,protein expression and viral ***,GCXV RnAs were detected in the bodies,salivary glands,midguts and ovaries of Culex quinquefasciatus at 4–10 days after oral *** addition,two GCXVs can colonize *** eggs,resulting in positive rates of 15%–35%for the second gonotrophic *** conclusion,our results demonstrated that GCXVs with four or five RnA segments can be detected in *** eggs during the first and second gonotrophic cycles after oral infection.

关键词： Guaico Culex virus(GCXV) j.ngmenvirus Culex quinquefasciatus Vertical transmission

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

欢迎您,

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

请选择保存的检索档案：

请选择收藏分类：

通借通还

欢迎您,

建议与咨询 留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

请选择保存的检索档案： 新增检索档案 确定 取消

请选择收藏分类： 新增自定义分类 确定 取消

通借通还

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

请选择保存的检索档案：

请选择收藏分类：