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Dynamic Mechanical Relaxation in Bulk Metallic Glasses:A Review

journal of Materials Science & Technology 2014年第6期30卷 523-545页

作者： j.c.qiao j.M.Pelletier Université de Lyon CNRS France INSA-Lyon MATEIS UMR5510 F-69621 Villeurbanne France

Metallic glasses have aroused considerable interest in the past decades because they exhibit fascinating properties. First, this article briefly outlines the mechanical, thermal properties and application of the metallic glasses. In addition, we focus on the dynamic mechanical relaxation behaviors, i.e. main （α） and secondary （β） relaxations, in metallic glasses. The mechanical relaxation behaviors are connected to the mechanical properties and physical properties in glassy materials. The main relaxation in glassy materials is related to the glass transition phenomenon and viscous flow. On the other hand, the β relaxation is linked to many fundamental issues in metallic glasses. In these materials relaxation processes are directly related to the plastic deformation mechanism. The mechanical relaxations, particularly, the β relaxation provides an excellent opportunity to design metallic glasses with desired physical and mechanical properties. We demonstrate the universal characteristics of main relaxation in metallic glasses. The phenomenological models and the physical theories are introduced to describe the main relaxation in metallic glasses. In parallel, we show the dependence of the α. and β relaxations on the thermal treatments in metallic glasses. Finally, we analyze the correlation between the atomic mobility and the thermo-mechanical treatments in metallic glasses. On the one hand, the atomic mobility in metallic glasses is reduced by physical aging or crystallization. On the other hand, the atomic mobility in metallic glass is enhanced by deformation （i.e. compression and cold rolling）. Importantly, to analyze the atomic mobility in amorphous materials, a physical theory is introduced. This model invokes the concept of quasi-point defects, which correspond to the density fluctuations in the glassy materials.

关键词： Metallic glasses Mechanical properties Main relaxation Secondary relaxation Physical analysis

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Training β relaxation to rejuvenate metallic glasses

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journal of Materials Science & Technology 2023年第27期158卷 53-62页

作者： L.T.Zhang Yun-jiang Wang Y.Yang j.c.qiao School of Mechanics Civil Engineering and ArchitectureNorthwestern Polytechnical UniversityXi’an 710072China State Key Laboratory of Nonlinear Mechanics Institute of MechanicsChinese Academy of SciencesBeijing 100190China School of Engineering Science University of Chinese Academy of SciencesBeijing 100049China Department of Mechanical Engineering College of EngineeringCity University of Hong KongTat Chee AvenueKowloon TongKowloonHong Kong SARChina Department of Materials Science and Engineering College of EngineeringCity University of Hong KongTat Chee AvenueKowloon TongKowloonHong Kong SARChina Innovation center NPU-ChongqingChongqing 401135China

In the current work,we demonstrated that the rejuvenation of metallic glasses can be achieved through training theβrelaxation *** the increase in the training frequency,a transition from structural relaxation to rejuvenation can be *** rejuvenation treatment is unexpected due to it occurs at a relatively small cyclic strain of 0.2%.Rejuvenation is beneficial to increase the relaxation enthalpy and promotes the decoupling of theβrelaxation process andαrelaxation process.A cluster ofβrelaxation time curves are formulated to describe any energetic state between ultrastable and ultimately rejuvenated metallic *** addition,rejuvenation expands the distribution ofβrelaxation process,anelastic and viscoplastic components during the deformation process.

关键词： Metallic glass βrelaxation Rejuvenation Structural heterogeneity

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comprehensive insights into the thermal and mechanical effects of metallic glasses via creep

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journal of Materials Science & Technology 2022年第4期99卷 39-47页

作者： Z.R.Xu j.c.qiao j.Wang E.Pineda D.crespo School of Mechanics Civil Engineering and ArchitectureNorthwestern PolytechnicalUniversityXi’an 710072China State Key Laboratory of Solidification Processing Northwestern PolytechnicalUniversityXi’an 710072China Department of Physics Barcelona Research Center in Multiscale Science and TechnologyInstitute of Energy TechnologiesUniversitat Politècnica de CatalunyaBarcelona 08019Spain

Evolution of deformation and relaxation behaviors of a prototypical cu_(46)Zr_(46)A_(l8)metallic glass was explored by extensive creep tests under both physical aging and cyclic *** insights into the microstructure-induced dynamic heterogeneity which accommodates creep deformation were successively revealed via experimental measurements and spectral *** annihilation of local defects within metallic glass with increasing annealing time and cyclic numbers was observed through the reduction of amplitude in both activation energy spectra and relaxation-time spectra,which were also accompanied by an ascending value of β_(KWW).It is further found that the corresponding deformation units within the metallic glass do not disappear permanently,but are recoverable over the course of cyclic *** apparent suppressed relaxation process can be gradually alleviated with increasing resuming time between two consecutive cycles,behaving differently from physical aging,which indicates a notable discrepancy between thermal treatment and mechanical treatment.

关键词： Metallic glasses creep Physical aging cyclic loading Relaxation-time spectrum

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Isochronal and isothermal crystallization in Zr_(55)cu_(30)Ni_5Al_(10) bulk metallic glass

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Transactions of Nonferrous Metals Society of china 2012年第3期22卷 577-584页

作者： j.c.qiao j.M.PELLETIER Université de Lyon MATEISUMR CNRS5510Bat.B.PascalINSA-LyonF-69621 Villeurbanne cedexFrance

Non-isothermal crystallization transformation kinetics and isothermal crystallization kinetics in super-cooled liquid region（SLR） in Zr55cu30Ni5Al10 bulk metallic glasses were studied by differential scanning calorimetry（DSc） and X-ray diffraction（XRD）.In isochronal mode,the average values of activation energy in Zr55cu30Ni5Al10 bulk metallic glass determined by different models（Kissinger method,Flynn-Wall-Ozawa method and Augis-Bennett method） are in good agreement with each *** addition,the isothermal transformation kinetics in Zr55cu30Ni5Al10 bulk metallic glasses was described by the johnson-Mehl-Avrami（jMA） *** Zr55cu30Ni5Al10 bulk metallic glass,the Avrami exponent n ranges from 2.2 to 2.9,indicating that crystallization mechanism in the bulk metallic glass was mainly diffusion-controlled;crystal growth is controlled by long range ordering diffusion in three-dimensional growth during isothermal crystallization *** average value of activation energy in Zr55cu30Ni5Al10 bulk metallic glass is 469 kj/mol in isothermal transformation process.

关键词： Zr55cu30Ni5Al10 metallic glass thermal analysis crystallization kinetics Avrami exponent

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Influence of high configuration entropy on damping behaviors of Ti-Zr-Hf-Ni-co-cu high entropy alloys

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journal of Materials Science & Technology 2023年第22期153卷 242-253页

作者： W.Q.Wu L.Zhang K.K.Song j.M.Pelletier H.F.Zhang j.c.qiao School of Mechanics Civil Engineering and ArchitectureNorthwestern Polytechnical UniversityXi’an 710072China Shi-changxu Innovation center for Advanced Materials Institute of Metal ResearchChinese Academy of SciencesShenyang 110016China School of Mechanical and Electrical Engineering Shandong UniversityWeihai 264209China Universitéde Lyon MATEISUMR CNRS5510Bat.B.PascalINSA-LyonVilleurbanne Cedex F-69621France chongqing Science and Technology Innovation center of NPU Chongqing 401135China

TiNi-based shape memory alloys(SMAs)have been used as damping materials to eliminate noise and mechanical ***,their application is limited by low working temperatures and damping *** this work,two novel Ti-Zr-Hf-Ni-co-cu high entropy shape memory alloys(HESMAs)with different transformation temperatures and damping properties were *** results show that Ti_(25)Zr_(8)Hf_(17)Ni_(30)co_(5)cu_(15) has superior damping performance arising from martensitic transformation,shape memory effect(thermal cycle at constant load)as well as *** to traditional TiNi-based SMAs,the as-cast HESMAs exhibit a much higher ultrahigh yield strength(∼2 GPa)and storage modulus(∼50 GPa).The high configuration entropy of the HESMAs with high uneven internal stress and severe lattice distortion is revealed as the underlying mechanisms governing distinctive damping *** effects of high configuration entropy and microheterogeneity on the martensitic transforma-tion behavior and damping performance of HESMAs are clarified in this work,which provides a basis for designing alloys with superior damping properties.

关键词： High entropy s hape memory alloy Internal friction Damping configuration entropy Martensitic transformation

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Mechanical Relaxation of a Ti36.2Zr30.3cu8.3Fe4Be21.2 Bulk Metallic Glass: Experiments and Theoretical Analysis

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Acta Metallurgica Sinica(English Letters) 2019年第6期32卷 726-732页

作者： j.c.qiao Y.H.chen G.j.Lyu K.K.Song j.M.Pelletier Y.Yao School of Mechanics Civil Engineering and ArchitectureNorthwestern Polytechnical UniversityXi'an 710072China School of Mechanical Electrical and Information EngineeringShandong University(Weihai)Weihai 264209China MATEIS UMR CNRS5510Bat.B.PascalINSA-LyonUniversite de Lyon69621 Villeurbanne CedexFrance

The dynamic mechanical relaxation behavior of Ti36.2Zr30.3cu8.3Fe4Be21.2 bulk metallic glass with good glass-forming ability was investigated by mechanical *** mechanical relaxation behavior was analyzed in the framework of quasi-point defects *** experimental results demonstrate that the atomic mobility of the metallic glass is closely associated with the correlation factorχ.The physical aging below the glass transition temperature T g shows a non-Debye relaxation behavior,which could be well described by stretched Kohlrausch exponential *** Kohlrausch exponentβaging reflects the dynamic heterogeneities of the metallic *** concentration of"defects"and atomic mobility decrease caused by the in situ successive heating during the mechanical spectroscopy experiments.

关键词： Metallic glasses Mechanical relaxation Physical aging Quasi-point defects

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Dynamic mechanical relaxation behavior of Zr_(35)Hf_(17.5)Ti_(5.5)Al_(12.5)co_(7.5)Ni_(12)cu_(10)high entropy bulk metallic glass

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journal of Materials Science & Technology 2021年第24期83卷 248-255页

作者： L.T.Zhang Y.j.Duan T.Wada H.Kato j.M.Pelletier D.crespo E.Pineda j.c.qiao School of Mechanics Civil Engineering and ArchitectureNorthwestern Polytechnical UniversityXi’an710072China Institute for Materials Research Tohoku UniversitySendai980-8577Japan Universitéde Lyon MATEISUMR CNRS5510Bat.B.PascalINSA-LyonF-69621Villeurbanne CedexFrance Department of Physics Barcelona Research Center in Multiscale Science and TechnologyInstitute of Energy TechnologiesUniversitat Politècnica de Catalunya08019BarcelonaSpain

Non-equiatomic high entropy bulk metallic glasses were reported recently and show unique mechanical and physical *** mechanical relaxation behavior of Zr_(35)Hf_(17.5)Ti_(5.5)Al_(12.5)co_(7.5)Ni_(12)cu_(10)high entropy bulk metallic glass was investigated by dynamic mechanical analysis(DMA)and the mechanical spectra could be well described by the quasi-point defects(QPD)*** to typical metallic glasses,the intensity of theβrelaxation of Zr_(35)Hf_(17.5)Ti_(5.5)Al_(12.5)co_(7.5)Ni_(12)cu_(10)high entropy bulk metallic glass is lower due to the sluggish *** the same time,the correlation factor is higher than that of conventional metallic glasses and this is ascribed to the high configuration *** parallel,physical aging below the glass transition temperature leads to a decrease of atomic mobility,caused by a decrease of the concentration of defects.

关键词： High entropy bulk metallic glass Mechanical relaxation Quasi-point defects Physical aging

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Analysis of the anelastic deformation of high-entropy Pd_(20)Pt_(20)cu_(20)Ni_(20)P_(20) metallic glass under stress relaxation and recovery

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journal of Materials Science & Technology 2022年第12期107卷 82-91页

作者： Y.j.Duan L.T.Zhang T.Wada H.Kato E.Pineda D.crespo j.M.Pelletier j.c.qiao School of Mechanics Civil Engineering and ArchitectureNorthwestern Polytechnical UniversityXi’an 710072China Department of Physics Institute of Energy TechnologiesUniversitat Politècnica de CatalunyaBarcelona 08019Spain Institute for Materials Research Tohoku UniversitySendai 980-8577Japan Universitéde Lyon MATEISUMR CNRS5510Bat.B.PascalINSA-LyonF-69621 Villeurbanne CedexFrance

The anelastic deformation behavior of Pd_(20)Pt_(20)cu_(20)Ni_(20)P_(20) high-entropy metallic glass was probed by monitoring the stress relaxation and recovery processes. The stress relaxation under consecutive strain steps can be described by the Kohlrausch-Williams-Watts(KWW) function. In addition, considering a hierarchy of relaxation processes related to the structural heterogeneity, a constitutive model is proposed in order to describe the whole process of stress relaxation and determine the contribution of different time scales. Moreover, a crossover from stochastic activation to percolation of flow defects with the ultimate strain can be observed during stress relaxation process. The anelastic recovery process after a strain step is studied as a function of the initial strain level and characterized by means of a direct spectrum analysis. The peaks in the recovery time-spectra revealed the evolution of flow defects in Pd_(20)Pt_(20)cu_(20)Ni_(20)P_(20) high-entropy metallic glass. The understanding of the atomic free-volume zones effect and the anelastic deformation provides important insight into how atomic structural features affect the deformation behavior of high-entropy metallic glasses, and may provide a new avenue into the improvement of their mechanical properties.

关键词： High-entropy metallic glass Stress relaxation Anelastic deformation Flow defects Free-volume zones

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co/co_(7)Fe_(3)heterostructures with controllable alloying degree on carbon spheres as bifunctional electrocatalyst forrechargeable zinc-air batteries

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International journal of Minerals,Metallurgy and Materials 2025年第2期32卷 476-487页

作者： junkang chen Yongyue Zhuang Yanxin qiao Yu Zhang Aihua Yuan Hu Zhou School of Materials Science and Engineering Jiangsu University of Science and TechnologyZhenjiang 212003China School of Environmental and chemical Engineering Jiangsu University of Science and TechnologyZhenjiang 212003China

Exploring efficient and nonprecious metal electrocatalysts of oxygen reduction reaction(ORR)and oxygen evolution reaction(OER)is crucial for developing rechargeable zinc-air batteries(ZABs).Herein,an alloying-degree control strategy was employed to fabricate nitrogen-doped carbon sphere(NcS)decorated with dual-phase co/co_(7)Fe_(3)heterojunctions(coFe@NcS).The phase composition of materials has been adjusted by controlling the alloying *** optimal coFe_(0.08)@NcS electrocatalyst displays a half-wave potential of 0.80 V for ORR and an overpotential of 283 mV at 10 mA·cm^(-2)for OER in an alkaline *** intriguing bifunctional electrocatalytic activity and durability is attributed to the hierarchically porous structure and interfacial electron coupling of highly-active co_(7)Fe_(3)alloy and metallic co *** the coFe_(0.08)@NcS material is used as air-cathode catalyst of rechargeable liquid-state zinc-air battery(ZAB),the device shows a high peak power-density(157 mW·cm^(-2))and maintains a stable voltage gap over 150 h,outperforming those of the benchmark(Pt/c+RuO_(2))-based *** particular,the as-fabricated solid-state flexible ZAB delivers a reliable compatibility under different bending *** work provides a promising strategy to develop metal/alloy-based electrocatalysts for the application in renewable energy conversion technologies.

关键词： bifunctional electrocatalysts oxygen reduction reaction oxygen evolution reaction zinc-air battery metal/alloy carbon sphere

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Plasmonic tandem heterojunctions enable high-efficiency charge transfer for broad spectrum photocatalytic hydrogen production

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journal of Energy chemistry 2025年第1期100卷 710-720页

作者： Wenxuan chen Xiu-Qing qiao Guo Hui Bojing Sun Dongfang Hou Meidi Wang Xueqian Wu Tao Wu Dong-Sheng Li college of Materials and chemical Engineering Key Laboratory of Inorganic Nonmetallic Crystalline and Energy Conversion Materials China Three Gorges University Hubei Three Gorges Laboratory college of chemistry and Materials Science and Guangdong Provincial Key Laboratory of Supramolecular Coordination Chemistry Jinan University

Rational engineering of semiconductor photocatalysts for efficient hydrogen production is of great significance but still challenging,primarily due to the limitations in charge transfer ***,a fascinating plasmonic tandem heterojunction with the hc-cdS/Mo2c@c heterostructure is aimfully prepared for effectively promoting the charge separation kinetics of the cdS photocatalyst via the synergistic strategy of phase junction,Schottky junction,and photothermal *** difference in atomic configuration between cubic-cdS （c-cdS） and hexagonal-cdS （h-cdS） leads to effective charge separation through a typical Ⅱ charge transfer mechanism,and plasmonic Schottky junction further extracts the electrons in the hc-cdS phase junction to realize gradient charge ***,the photothermal effect of Mo2c@c helps to expand the light absorption,accelerate charge transfer kinetics,and reduce the hydrogen evolution energy *** carbon layer provides a fast channel for charge transfer and protects the photocatalyst from *** a result,the optimized hc-cMc photocatalyst exhibits a significantly high photocatalytic H2production activity of 28.63 mmol/g/h and apparent quantum efficiency of 61.8%,surpassing most of the reported *** study provides a feasible strategy to enhance the charge transfer kinetics and photocatalytic activity of cdS by constructing plasmonic tandem heterogeneous junctions.

关键词： Heterojunctions LSPR Photocatalyst Phase junction Schottky junction Photothermal effect

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