检索结果-南通市图书馆

Gas Diffusion Layers:Experimental and Modeling Approach for Morphological and Transport Properties

Accounts of Materials Research 2022年第4期3卷 416-425页

作者： Pongsarun Satjaritanun Sirivatch Shimpalee iryna v.zenyuk Department of Chemical and Biomolecular Engineering and National Fuel Cell Research Center University of California IrvineIrvineCalifornia 92697United States Department of Chemical Engineering University of South CarolinaColumbiaSouth Carolina 29208United States

CONSPECTUS:Electrochemical technologies are key to decarbonizing the energy *** of the energy sector is underway with battery technologies dominating the lightduty electric vehicles *** is more challenging to decarbonize historically difficult to decarbonize sectors,such as heavy-duty transportation,planes,ships,and the chemical manufacturing industry(ammonia,cement,steel).Green hydrogen produced via electrolysis will be used as a fuel and a feedstock in some of these *** the heart of the hydrogen economy are polymer electrolyte fuel cells(PEFCs),devices that convert hydrogen into *** diffusion layers(GDLs)have an integral role in PEFCs,as they are porous carbon layers that transport reactants and products and also remove heat and conduct *** improve the PEFCs’performance and reduce degradation of materials,an understanding of coupled morphological properties and transport phenomena in the GDLs is *** this Account,we emphasize the integration of experimental and modeling approaches to achieve complete understanding of materials and transport properties of the *** approach builds in complexity from simpler ex situ experiments to in situ and last to 3-D integrated modeling *** morphology is complex,as its fabrication includes several stochastic steps(immersion of GDL in various baths to achieve the desired surface wettability)and only 3-D techniques,such as X-ray computed tomography can capture morphology ***,pore-size distribution,tortuosity,and formation factor are the most important morphological properties of the *** PEFC applications,water is generated in the catalyst layers and is transported through the ***,GDL wettability directly impacts water permeability through the *** in situ water injection experiments,we directly observe which pores water fill at what liquid *** result provides information about the GDL’s affinity to intake wat

关键词： Diffusion battery simpler

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Detecting lithium plating dynamics in a solid-state battery with operando X-ray computed tomography using machine learning

引用

npj Computational Materials 2023年第1期9卷 1402-1410页

作者： Ying Huang David Perlmutter Andrea Fei-Huei Su Jerome Quenum Pavel Shevchenko Dilworth Y.Parkinson iryna v.zenyuk Daniela Ushizima Department of Materials Science&Engineering University of California IrvineIrvineCaliforniaUSA National Fuel Cell Research Center University of California IrvineIrvineCaliforniaUSA Applied Math and Computational Research Division Lawrence Berkeley National LaboratoryBerkeleyCaliforniaUSA Department of Chemical&Biomolecular Engineering University of California IrvineIrvineCaliforniaUSA Department of Electrical Engineering and Computer Sciences College of EngineeringUniversity of California BerkeleyBerkeleyCaliforniaUSA Advanced Photon Source Argonne National Laboratory9700 South Cass AvenueLemontIllinoisUSA Advanced Light Source Lawrence Berkeley National LaboratoryBerkeleyCaliforniaUSA Berkeley Institute for Data Science University of California BerkeleyBerkeleyCaliforniaUSA

Operando X-ray micro-computed tomography(µCT)provides an opportunity to observe the evolution of Li structures inside pouch *** is an essential step to quantitatively analyzingµCT datasets but is challenging to achieve on operando Li-metal battery datasets due to the low X-ray attenuation of the Li metal and the sheer size of the ***,we report a computational approach,batteryNET,to train an Iterative Residual U-Net-based network to detect Li *** resulting semantic segmentation shows singular Li-related component changes,addressing diverse morphologies in the *** addition,visualizations of the dead Li are provided,including calculations about the volume and effective thickness of electrodes,deposited Li,and redeposited *** also report discoveries about the spatial relationships between these *** approach focuses on a method for analyzing battery performance,which brings insight that significantly benefits future Li-metal battery design and a semantic segmentation transferrable to other datasets.

关键词： battery lithium state

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Electrochemical top-down synthesis of C-supported Pt nanoparticles with controllable shape and size:Mechanistic insights and application

引用

Nano Research 2021年第8期14卷 2762-2769页

作者： Batyr Garlyyev Sebastian Watzele Johannes Fichtner Jan Michalicka Alexander Schokel Anatoliy Senyshyn Andrea Perego Dingjie Pan Hany A.El-Sayed Jan M.Macak Plamen Atanassov iryna v.zenyuk Aliaksandr S.Bandarenka Physics of Energy Conversion and Storage Technical University of MunichJames Franck Strafle 185748 Garching Germany Central European Institute of Technology Brno University of TechnologyPurkynova 12361200 BrnoCzech Republic Deutsches Elektronen Synchrotron(DESY) Notkestr.8522607HamburgGermany Heinz Maier-Leibnitz-Zentrum(MLZ) Technische Universitat MiinchenLichtenbergstr.185748 Garching Germany Department of Chemical Engineering National Fuel Cell Research Center University of CaliforniaIrvine92697-2580 CaliforniaUSA Department of Material Science and Engineering University of CaliforniaIrvine92697-2580 CaliforniaUSA Chair of Technical Electrochemistry Technical University of MunichLichtenbergstrafie 485748 Garching Germany

In this work,we demonstrate the power of a simple top-down electrochemical erosion approach to obtain Pt nanoparticle with controlled shapes and sizes(in the range from-2 to-10 nm).Carbon supported nanoparticles with narrow size distributions have been synthesized by applying an alternating voltage to macroscopic bulk platinum structures,such as disks or *** using any surfactants,the size and shape of the particles can be changed by adjusting simple parameters such as the applied potential,frequency and electrolyte *** instance,application of a sinusoidal AC voltage with lower frequencies results in cubic nanoparticles;whereas higher frequencies lead to predominantly spherical *** the other hand,the amplitude of the,sinusoidal signal was found to affect the particle size;the lower the amplitude of the applied AC signal,the smaller the resulting particle ***/C catalysts prepared by this approach showed 0.76 A/mg mass activity towards the oxygen reduction reaction which is-2 times higher than the state-of-the-art commercial Pt/C catalyst(0.42 A/mg)from *** addition to this,we discussed the mechanistic insights about the nanoparticle formation pathways.

关键词： electrochemical synthesis platinum nanoparticles oxygen reduction reaction

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Investigation of Microstructure and Phase Composition of Chromic Oxide, AZS/Cr and High-alumina Refractories after Exposure of Basalt and Aluminaboronsilicate Glasses Melts

引用

China's Refractories 2024年第1期33卷 1-6页

作者： valeriy v.MARTYNENKO iryna G.SHULYK Yuliya Ye.MISHNYOvA Tetyana G.TYSHYNA The Ukrainian Research Institute of Refractories named after A.S.Berezhnoy Kharkiv 61024Ukraine

The microstructure and phase composition of high-alumina,chromic oxide,and AZS/Cr refractories containing 30%and 60%(by mass)Cr_(2)O_(3) after exposure to aluminaboronsilicate glasses and basalt melts depending on the type of melts and temperature have been *** mechanisms of refractory corrosion by the used melts and the factors contributing to the inhibition of corrosion development have been investigated by the method of petrographic *** the basis of obtained results,the use of high-alumina,chromic oxide,and AZS/Cr refractories in the sections of glass furnace linings,experiencing the intensive impact of aluminaboronsilicate glasses and basalt melts,has been confirmed and scientifically substantiated.

关键词： high-alumina refractories chromic oxide refractories AZS/Cr refractories microstructure phase composition aluminaboronsilicate glasses melts basalt melt

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

On the Possibilities of using Some Modern Three-dimensional Modeling Means in Forensic Examination

引用

Journal of Forensic Science and Medicine 2022年第1期8卷 17-23页

作者： Dmitry S Afonin iryna v Hora valerii A Kolesnyk Inna I Popovych iryna v Kuchynska Department of Administrative Activity of Police Odesa State University of Internal AffairsOdesa Scientific Center National Academy of the Security Service of Ukraine Department of Criminal Law and Procedure Uzhhorod National UniversityUzhhorod Center for Forensic and Special Examinations The Ukrainian Scientific and Research Institute of Special Equipment and Forensic Expertise of the Security Service of UlaaineKyivUkraine

Background:The paper examines the state and prospects of using 3D modeling in solving identification,classification,diagnostic and situational tasks of forensic *** and Objectives:The aim of this study is to analyze the world expert practice of using scientific and technical means of three-dimensional modeling in solving problems of forensic examination,using the example of our country,the leading countries of Europe,as well as the United *** and Methods:The empirical basis of the study is the results of the systematization of scientific and technical means for 3D modeling in solving identification,classification,diagnostic and situational problems of forensic examinations used in the expert practice of Ukraine,the United Kingdom,France,Germany,and the ***:The systematization of modem scientific and technical means for 3D modeling,used in solving identification,classification,diagnostic and situational tasks of forensic examination,has been carried *** analyzed and identified 3D modeling software that most fully meets the requirements of effective forensic expert *** features of the use of effective 3D modeling mean for solving identification,classification,diagnostic and situational tasks of forensic examination,namely the software systems"ToolScan"and"TrasoScan",and the SketchUp program have been ***:The introduction of the SketchUp 8 software into forensic expert activities will increase the effectiveness of the modeling method in forensic examinations,which,in turn,will have an impact on the effectiveness of expert conclusions,increase their evidentiary value and,as a result,contribute to the entire process of a criminal investigation.

关键词： Classification tasks diagnostic tasks forensic practice identification tasks photogrammetric modeling simulation modeling three-dimensional model

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

The Effect of Ultra Low Concentrations of Some Biologically Active Substances on the Aerobic Respiration

引用

CellBio 2016年第1期5卷 1-13页

作者： Sergii v. Girin iryna v. Savinova iryna v. Antonenko Natalia v. Naumenko Cascade-Medical Reference Laboratory UBI Glevakha Ukraine

For today it is known, that primary and secondary disorders of the aerobic respiration, which are based on mitochondrial deficiency, lead to a wide spectrum of clinical manifestations and diseases. Therefore, the question about effective correction of various types of energy exchange disorders remains topical. Thus, the aim of our work was the study effect of the complex of biologically active substances (BAS) in ultra low concentrations on the activity of key enzymes of aerobic energy metabolism succinate dehydrogenase (EC 1.***.99.1) (SQR) and mitochondrial glycerol-3-phosphate dehydrogenase (EC 1.***.99.5) (GPD2). The human lymphocytes assays were tested in vitro (22 donors). In negative control lymphocytes, cell culture normal saline solution was added. Normal saline solution with NaN3 was added in positive control lymphocytes cell culture. Experimental cell culture contained NaN3 and BAS. Our investigations had been revealed increase SQR activity in the experimental cell culture as compared with positive control culture throughout the time of experiment (measurements were carried out at 4, 24, 48, 72 h of incubation). The SQR activity of experimental cell culture and negative control lymphocytes cell culture was equal up to 24 h of experiment. It showed neutralization of NaN3 inhibitory effect (during 24 h) due to BAS influence. Activity of base glycerophosphate shunt ferment GPD2 of experimental lymphocyte cell culture was not different from GPD2 index in the negative control, but was lower than GPD2 activity in the positive control. It also indicated neutralization NaN3 inhibitory effect due to BAS influence. So we had found that extremely low concentrations of selected BAS with their complex impact on human lymphocytes in vitro could effectively neutralize the inhibitory effect of NaN3 on processes of aerobic energy metabolism link.

关键词： Energy Metabolism Ultralow Concentrations Succinate Dehydrogenase Glycerol-3-Phosphate Dehydrogenase

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Methods for the Efficient Energy Management in a Smart Mini Greenhouse

引用

Computers, Materials & Continua 2022年第2期70卷 3169-3187页

作者： vasyl Teslyuk Ivan Tsmots Michal Gregus ml. Taras Teslyuk iryna Kazymyra Department of Automated Control Systems Lviv Polytechnic National UniversityLviv79013Ukraine Faculty of Management Comenius University in BratislavaBratislava2582005Slovakia Department of Information Systems and Networks Lviv Polytechnic National UniversityLviv79013Ukraine

To solve the problem of energy efficiency of modern enterprise it is necessary to reduce energy *** of the possible ways is proposed in this research.A multi-level hierarchical system for energy efficiency management of the enterprise is designed,it is based on the modular principle providing rapid *** novelty of the work is the development of new and improvement of the existing methods and models,in particular:1)models for dynamic analysis of IT tools for data acquisition and processing(DAAP)in multilevel energy management systems,which are based on Petri nets;2)method of synthesis of DAAP tools in energy efficiency management information systems(EEMIS)of the enterprise which provides a reduction in hardware and time costs from 10%to 40%;3)method of conflict-free data exchange determining the minimum memory speed for the synthesis of realtime exchanges,it reduces the cost and energy consumption;4)method of calculating the signal of postsynaptic excitation of neural elements decreases the processing time of technological data two or more *** proposed methods,models and tools have been tested while implementing the EEMIS of the intelligent mini-greenhouse,as a result,energy efficiency has increased by 12%-25%(depending on season and peculiarities of growing plants).

关键词： Energy efficiency management information system(EEMIS) data acquisition and processing(DAAP) industry 4.0 Petri nets smart mini greenhouse

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Prospects of Technological Improvement of Nuclear and Environmental Safety of World Energy

引用

Open Journal of Ecology 2023年第8期13卷 536-548页

作者： iryna Korduba Zhanna Patlashenko Olena Zhukova Department of Environmental Protection and Labor Protection Technologies Kyiv National University of Construction and Architecture Kyiv Ukraine Department of Education Methodology for Sustainable Development of the State Environmental Academy of Postgraduate Education and Management Kyiv Ukraine

Today, the most urgent problem of the existing and future nuclear power industry is to ensure the nuclear and environmental safety of the operation of nuclear power reactor units (NPPs) and nuclear power plants (NPPs). It is solved thanks to the application of deeply echeloned protection and an anti-accident complex of methods and means for effective control of the operation of active reactor zones (AZR). However, the danger of existing NPPs in the world from time to time manifests itself in the form of severe post-project accidents and catastrophes with the release into the environment of a significant amount of radioactive materials dangerous for all living things. The results of the analysis show that the unconditional fulfillment of the main requirements of nuclear environmental safety and biocompatibility is possible only in the so-called wave nuclear reactor of the G-v generation, which, unlike reactors of the previous generations III, II+ and Iv, does not require supercritical loading of the core with nuclear fuel. In the active zone of this reactor, nuclear-physical processes governed by physical law are implemented, which exclude the operator’s participation in regulating the reactivity of the reactor’s active zone, which makes it the reactor with the highest level of nuclear and environmental safety today, which is based on the principles of so-called internal safety, free from the human factor. The possibility of burning nuclear fuel based on U238 and Th232 in it expands the reserves of energetic nuclear fuel almost to inexhaustibility. The technology of nuclear reactors of the G5 generation through the secondary use of spent irradiated nuclear fuel (SNF) for the production of energy and energy raw materials with simultaneous burning of it to an environmentally safe state is able to quickly reduce the available stocks and further production of dangerous SNF, guarantee the nuclear and environmental safety of NPPs with reactors G5 and to technologically mak

关键词： Nuclear-Environmental Safety Nuclear Power Reactor Unit Nuclear Fuel Cycle Nuclear Technologies of the Fifth Generation Nuclear-Environmental Safety Wave Reactor Biocompatibility

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Functional Activity of Circulating Phagocytes as Potential Pretreatment Marker of Tumor Drug Resistance

引用

Journal of Biosciences and Medicines 2019年第7期7卷 1-15页

作者： iryna v. Prokhorova Olga v. Yurchenko Olga N. Pyaskovskaya Igor N. Todor Galina I. Solyanik Laboratory of Molecular and Cellular Mechanisms of Metastasis R.E. Kavetsky Institute of Experimental Pathology Oncology and Radiobiology of NASU Kyiv Ukraine Department of Monitoring of Tumor Process and Therapy Design R.E. Kavetsky Institute of Experimental Pathology Oncology and Radiobiology of NASU Kyiv Ukraine

The aim of this work was a study of the functional activity of neutrophils and peripheral blood monocytes in rats with the transplanted Walker carcinosarcoma as potential predictors of the sensitivity of this tumor to doxorubicin treatment. This study provides an evidence that such indices of the functional activity of circulating phagocytes of the tumor-bearing rats as the quantity and the phagocytosis intensity of monocytes, as well as the intensity of ROS production by monocytes and neutrophils, may reflect the degree of sensitivity of the tumor to doxorubicin. So it was shown that the growth of the resistant tumor caused a significant increase of the number of circulating phagocytic cells and the intensity of phagocytosis by more than 100% (p variant of the tumor. The ability of blood mono-cytes and neutrophils of rats with a resistant tumor to produce ROS was also significantly different from that in intact rats and animals with the parental carcinosarcoma variant. The predictive value of these indices is especially important in the dynamic monitoring of the development of tumor drug resistance during long-term cancer chemotherapy. Considering the standard 2 - 3 week interval between the courses of cancer therapy and the short lifetime of circulating phagocytes, an assessment of the indices of their functional activity before each subsequent course can be considered as a pretreatment assessment. Meanwhile, further studies are needed to determine the spectrum of malignant neoplasms for which the degree of tumor drug resistance correlates with the functional activity of circulating phagocytes.

关键词： Circulating Phagocytes Phagocytic Activity ROS Production Tumor Drug Resistance

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Spin-Dependent Transport in Carbon Nanotubes with Chromium Atoms

引用

Journal of Modern Physics 2014年第17期5卷 1896-1891页

作者： Stanislav P. Repetsky Oleg v. Tretyak iryna G. vyshivanaya Dmitriy K. Cheshkovskiy Department of Physics Taras Shevchenko National University of Kyiv Kyiv Ukraine Institute of High Technologies Taras Shevchenko National University of Kyiv Kyiv Ukraine

Method is developed for self-consistent calculation of the energy spectrum of free energy and electrical disordered crystals. Processes of electron scattering on the ionic core potential of different sort, fluctuations of charge, spin density and lattice vibrations are taken into account. Electronic states of the system are described using tight binding multiband model. The nature of the spin-dependent electron transport of carbon nanotubes with chromium atoms adsorbed on the surface is explained. The value of the spin polarization of electron transport is determined by the difference of the partial densities of states of electrons with opposite spin projection at the Fermi level and the difference between the relaxation times of electron states. The value of the spin polarization of the electric current increases with increasing of Cr atoms concentration and magnitude of the external magnetic field.

关键词： Spin-Dependent Transport Carbon Nanotubes with Chromium Atoms Tight Binding Model Localized Magnetic Moment Free Energy Electrical Conductivity Tensor

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

欢迎您,

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

请选择保存的检索档案：

请选择收藏分类：

通借通还

欢迎您,

建议与咨询 留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

请选择保存的检索档案： 新增检索档案 确定 取消

请选择收藏分类： 新增自定义分类 确定 取消

通借通还

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

请选择保存的检索档案：

请选择收藏分类：