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Isolated Cu-Sn diatomic sites for enhanced electroreduction of CO_(2)to CO

Nano Research 2023年第7期16卷 8729-8736页

作者： Wei liu Haoqiang li Pengfei Ou Jing Mao lili Han Jun Song Jun luo huolin l.xin State Key laboratory of Structural Chemistry Fujian Institute of Research on the Structure of MatterChinese Academy of SciencesFuzhou 350002China Department of Physics and Astronomy University of CaliforniaIrvineCA 92697USA Tsinghua Shenzhen International Graduate School Tsinghua UniversityShenzhen 518055China School of Materials Science and Engineering Tianjin Key Lab of Photoelectric Materials&DevicesTianjin University of TechnologyTianjin 300384China Department of Mining and Materials Engineering McGill UniversityMontreal H3A 0C5Canada Teaching and Analytical Instrumentation Center School of Materials Science and EngineeringTianjin UniversityTianjin 300072China

Electrochemical CO_(2)reduction reaction(CO_(2)RR)to high-value product,CO,not only provides a key feedstock for the wellestablished Fischer-Tropsch process but also mitigates the greenhouse ***,it suffers from sluggish reaction kinetics,competitive hydrogen evolution reaction,and low ***,we report non-precious Cu-Sn diatomic sites anchored on nitrogen-doped porous carbon(CuSn/NPC)as an efficient catalyst for CO_(2)RR to *** catalyst exhibits outstanding selectivity with CO Faradaic efficiency(FE)up to 99.1%,much higher than those of individual Cu(66.2%)and Sn(51.3%)single-atom ***,high stability is confirmed by consecutive 24 h electrolysis with high selectivity from CO_(2)to *** calculations reveal an obvious activation of CO_(2)with weakened C-O bonds and distorted CO_(2)configuration upon chemisorption on the CuSn/NPC *** is also suggested CuSn/NPC is more selective for the CO_(2)RR with dominant CO production during the electrolysis,rather than the competing hydrogen evolution reaction.

关键词： CO_(2)reduction reaction Cu-Sn active site CO product dual-atom electrocatalyst density functional theory(DFT)calculation

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Highly active N-doped carbon encapsulated Pd-Fe intermetallic nanoparticles for the oxygen reduction reaction

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Nano Research 2020年第9期13卷 2365-2370页

作者： Yezhou Hu Yun lu Xueru Zhao Tao Shen Tonghui Zhao Mingxing Gong Ke Chen Chenglong lai Jian Zhang huolin l.xin Deli Wang Key laboratory of Material Chemistry for Energy Conversion and Storage(Huazhong University of Science and Technology) Ministry of EducationHubei Key Laboratory of Material Chemistry and Service FailureSchool of Chemistry and Chemical EngineeringHuazhong University of Science and TechnologyWuhan 430074China Institute of New-Energy Materials Key Laboratory of Advanced Ceramics and Machining Technology of Ministry of EducationSchool of Materials Science and EngineeringTianjin UniversityTianjin 300072China Department of Physics and Astronomy University of CaliforniaIrvineIrvineCA 92697USA

Developing highly efficient non-R catalysts for fuel cells and metal-air batteries is highly desirable but still challenging due to the sluggish oxygen reduction reaction(ORR).Herein,a facile and efficient strategy is demonstrated to prepare N-doped carbon encapsulated ordered Pd-Fe intermetallic(O-Pd-Fe@NC/C)nanoparticles via a one-step thermal annealing *** obtained O-Pd-Fe@NC/C nanoparticles show enhanced ORR activity,durability and anti-poisoning capacity in both acid and alkaline *** O-Pd-Fe@NC/C serving as cathode catalyst for Zn-air battery,it exhibits higher voltage platform and superior cycling performance with respect to the Zn-air battery based on the mixture of Pt/C and Ir/C *** enhanced electrocatalytic performance can be ascribed to the formation of face-centered tetragonal(fct)Pd-Fe nanoparticles,the protective action of the N-doped carbon layer and the interface confinement effect between *** in situ formed N-doped carbon shell not only restrains the Pd-Fe ordered intermetallics from aggregating effectively during the thermal annealing process,but also provides a strong anchoring effect to avoid the detachment of Pd-Fe nanoparticles from the carbon support during the potential *** facile carbon encapsulation strategy may also be extended to the preparation of a wide variety of N-doped carbon encapsulated intermetallic compounds for fuel cell application.

关键词： palladium carbon encapsulation strategy ordered intermetallic nanoparticles oxygen reduction reaction(ORR) Zn-air battery

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Ultrafast Preparation of Nonequilibrium FeNi Spinels by Magnetic Induction Heating for Unprecedented Oxygen Evolution Electrocatalysis

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Research 2022年第4期2022卷 165-177页

作者： Bingzhang lu Qiming liu Chunyang Wang Zaheer Masood David J.Morris Forrest Nichols Rene Mercado Peng Zhang Qingfeng Ge huolin l.xin Shaowei Chen Department of Chemistry and Biochemistry University of California1156 High StretSanta CruzCalifornia 95064USA Department of Physics and Astronomy University of CaliforniaIrvineCalifornia 92697USA Department of Chemistry and Biochemistry Southern Ilinois UniversityCarbondaleIlinois 62901USA Department of Chemistry Dalhousie University6274 Coburg RoadHalifaxNSCanada B3H 4R2

Carbon-supported nanocomposites are attracting particular attention as high-performance,low-cost electrocatalysts for electrochemical water *** are mostly prepared by pyrolysis and hydrothermal procedures that are time-consuming(from hours to days)and typically difficult to produce a nonequilibrium ***,for the first time ever,we exploit magnetic induction heating-quenching for ultrafast production of carbon-FeNi spinel oxide nanocomposites(within seconds),which exhibit an unprecedentedly high performance towards oxygen evolution reaction(OER),with an ultralow overpotential of only+260 mV to reach the high current density of 100 mA cm^(-2).Experimental and theoretical studies show that the rapid heating and quenching process(ca.10^(3)K s^(-1))impedes the Ni and Fe phase segregation and produces a Cl-rich surface,both contributing to the remarkable catalytic *** from this study highlight the unique advantage of ultrafast heating/quenching in the structural engineering of functional nanocomposites to achieve high electrocatalytic performance towards important electrochemical reactions.

关键词： quenching Oxygen attracting

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Rational design of three-dimensional nitrogen and phosphorus co-doped graphene nanoribbons/CNTs composite for the oxygen reduction

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Chinese Chemical letters 2016年第4期27卷 597-601页

作者： Jie Wang Ze-xing Wu li-li Han Yuan-Yang liu Jun-Po Guo huolin l.xin De-li Wang Key laboratory of Material Chemistry for Energy Conversion and Storage (Huazhong University of Science and Technology) Ministry of Education Hubei Key Laboratory of Material Chemistry and Service Failure School of Chemistry and Chemical Engineering Huazhong University of Science and Technology Center for Functional Nanomaterials Brookhaven National Laboratory School of Materials Science and Engineering Tianjin University

In the present work, we report nitrogen and phosphorus co-doped 3-D structured carbon nanotube intercalated graphene nanoribbon composite. The graphene nanoribbons are prepared via partial exfoliation of multi-walled carbon nanotubes. In the graphene nanoribbons/CNTs composite, carbon nanotubes play a role of skeleton and support the exfoliated graphene nanoribbons to form the stereo structure. After high temperature heat-treatment with ammonium dihydrogen phosphate, the unique structure reserves both the properties of carbon nanotube and graphene, exhibiting excellent catalytic performance for the ORR with excellent onset and half-wave potential, which is similar to commercial Pt/C electrocatalysts.

关键词： Graphene nanoribbons Carbon nanotube Doping Electrocatalyst Oxygen reduction reaction

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long-range ordering of composites for organic electronics:TIPS-pentacene single crystals with incorporated nano-fibers

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Chinese Chemical letters 2017年第11期28卷 2121-2124页

作者： Huanbin li Guobiao Xue Jiake Wu Wenqiang Zhang Zhuoting Huang Zengqi Xie huolin l.xin Gang Wu Hongzheng Chen Hanying li State Key laboratory of Silicon Materials MOE Key Laboratory of Macromolecular Synthesis and Functionalization Department of Polymer Science and Engineering Zhejiang University Institute of Polymer Optoelectronic Materials and Devices State Key Laboratory of Luminescent Materials and Devices South China University of Technology Center for Functional Nanomaterials Brookhaven National Laboratory

Multi-component active materials are widely used for organic electronic devices, with every component contributing complementary and synergistic optoelectronic functions. Mixing these components generally leads to lowered crystallinity and weakened charge transport. Therefore, preparing the active materials without substantially disrupting the crystalline lattice is highly desired. Here, we show that crystallization of TIPS-pentacene from solutions in the presence of fluorescent nanofibers of a perylene bisimide derivative （PBI） leads to formation of composites with nanoflber guest incorporated in the crystal host. In spite of the binary composite structure, the TIPS-pentacene maintains the single- crystalline nature. As a result, the incorporation of the PB1 guest introduces additional fluorescence function but does not significantly reduce the charge transport property of the TIPS-pentacene host, exhibiting field-effect mobility as high as 3.34 cm^2 V^-1 s^-1 even though 26.4% of the channel area is taken over by the guest. As such, this work provides a facile approach toward high-performance multifunctional organic electronic materials.

关键词： Organic Electronics Single Crystals Composites High Mobility Field-Effect Transistors

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Non-existence of Shimura curves of Mumford type generically in the non-hyperelliptic locus

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Science China Mathematics 2025年

作者： xin lü Shengli Tan Kang Zuo School of Mathematical Sciences Key Laboratory of Mathematics and Engineering Applications(Ministry of Education) Shanghai Key Laboratory of Pure Mathematics and Mathematical PracticeEast China Normal University School of Mathematics and Statistics Wuhan University Institut für Mathematik Universit?t Mainz

We show that there does not exist any Shimura curve with a strictly maximal Higgs field generically in the Torelli locus of non-hyperelliptic curves of genus g≥4. In particular, Shimura curves of Mumford type are not...

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Research status and prospects of the fractal analysis of metal material surfaces and interfaces

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International Journal of Minerals,Metallurgy and Materials 2025年第1期32卷 20-38页

作者： Qinjin Dai Xuefeng liu xin Ma Shaojie Tian Qinghe Cui Beijing Advanced Innovation Center for Materials Genome Engineering University of Science and Technology BeijingBeijing 100083China Beijing laboratory of Metallic Materials and Processing for Modern Transportation University of Science and Technology BeijingBeijing 100083China laboratory for Advanced Materials Processing of Ministry of Education University of Science and Technology BeijingBeijing 100083China School of Mechanical and Electrical Engineering Xinjiang Institute of EngineeringUrumqi 830023China

As a mathematical analysis method,fractal analysis can be used to quantitatively describe irregular shapes with self-similar or self-affine *** analysis has been used to characterize the shapes of metal materials at various scales and *** methods make it difficult to quantitatively describe the relationship between the regular characteristics and properties of metal material surfaces and ***,fractal analysis can be used to quantitatively describe the shape characteristics of metal materials and to establish the quantitative relationships between the shape characteristics and various properties of metal *** the perspective of two-dimensional planes and three-dimensional curved surfaces,this paper reviews the current research status of the fractal analysis of metal precipitate interfaces,metal grain boundary interfaces,metal-deposited film surfaces,metal fracture surfaces,metal machined surfaces,and metal wear *** relationship between the fractal dimensions and properties of metal material surfaces and interfaces is *** from three perspectives of fractal analysis,namely,research scope,image acquisition methods,and calculation methods,this paper identifies the direction of research on fractal analysis of metal material surfaces and interfaces that need to be *** is believed that revealing the deep influence mechanism between the fractal dimensions and properties of metal material surfaces and interfaces will be the key research direction of the fractal analysis of metal materials in the future.

关键词： metal material surfaces and interfaces fractal analysis fractal dimension homogeneity

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Beginning from the end:the presynaptic terminal as a pathomechanism hub in frontotemporal dementia and amyotrophic lateral sclerosis

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Neural Regeneration Research 2025年第11期20卷 3217-3218页

作者： laura Huggon Emma l.Clayton UK Dementia Research Institute at King’s College london LondonUK Department of Basic and Clinical Neuroscience Institute of Psychiatry Psychology&NeuroscienceKing’s College LondonLondonUK

Frontotemporal dementia and amyotrophic lateral sclerosis:Frontotemporal dementia(F T D)and amyo t rophic lateral sclerosis(AlS)are neurodegenerative diseases with significant overlapping *** these neurodegenerative diseases affect different neuronal populations(with FTD affecting neurons of the frontal and temporal lobes,and AlS affecting upper and lower motor neurons),these two diseases are complexly *** and AlS exist on a disease spectrum,with shared genetic causes,clinical presentations,and pathologies.

关键词： diseases amyotrophic sclerosis

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Visualizing the toughening origins of gel-grown calcite single-crystal composites

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Chinese Chemical letters 2018年第11期29卷 1666-1670页

作者： Yujing liu Kai He Wentao Yuan xinyi Jin Tao liang Yong Wang huolin l. xin Hongzheng Chen Chao Gao Hanying li MOE Key laboratory of Macromolecular Synthesis and Functionalization Department of Polymer Science and Engineering Zhejiang University Hangzhou 310027 China Center for Functional Nanomaterials Brookhaven National Laboratory Upton NY 11973 United States State Key laboratory of Silicon Materials Zhejiang University Hangzhou 310027 China Center of Electron Microscopy Department of Materials Science and Engineering Zhejiang University Hangzhou 310027 China Department of Materials Science and Engineering，Northwestern University，Evanston 60208，United States

Biogenic single crystals have been widely demonstrated to incorporate macromolecules to achieve extra damage tolerance, spurring investigations on their synthetic analogs with enhanced mechanical properties as well as the enhancement mechanism（s） behind. And the investigations rely on both rational design of the single-crystal composites and, equally importantly, nanoscale and in-situ characterization strategy. Here, composite structures are constructed inside the calcite single-crystal host by incorporating guest materials of agarose fibers, multi-walled carbon nanotubes （MWCNTs）, and graphene oxide （GO）, through crystallization in agarose gel media. Further, transmission electron microscopy-scanning probe microscopy （TEM-SPM） method, coupling compression measurements with nanoscale imaging, shows that the obtained single-crystal composites exhibit improved toughness, compared to the solution-grown pure single crystals. Particularly, the rupture time increases by 1.25 times after the gel-networks and MWCNTs are incorporated. More importantly, the in-situ observation of the crystal deformation suggests that the guest incorporation toughens the single-crystal host by the shielding effect of nanofiber on crack-bridging at nanoscale. As such, this work may have implications for understanding the damage tolerance of biominerals as well as towards the development of new mechanically reinforced single-crystal composite materials.

关键词： Biomineralization Composite single-crystal Gel-grown Calcite Carbon nanotube Graphene oxide Toughening

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Multiple sclerosis is at a checkpoint: advancing the program

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Neural Regeneration Research 2025年第3期20卷 811-812页

作者： Brandon C.Smith Jessica l.Williams Department of Neurosciences Lerner Research InstituteCleveland ClinicClevelandOHUSA Department of Biological Geologicaland Environmental SciencesCleveland State UniversityClevelandOHUSA

Multiple sclerosis(MS) is a chronic inflammatory and demyelinating disease of the central nervous system(CNS). Patients with MS experience sensory and motor function loss due to myelin and/or axon damage perpetuated b... 详细信息

关键词： Hauser sclerosis damage

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