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Journal of Energy Chemistry 2025年第1期100卷 26-38页

作者： Xiaodong yang Haochen Shen Xiaoming Xiao Zhichao Li Qi Zhou Wei yang Bin Jiang Yongli Sun Luhong Zhang Zhenhua Yan School of Chemical Engineering and Technology Tianjin University Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education) Nankai University

This study presents a novel method to fabricate metal-decorated,sulfur-doped layered double hydroxides （M/SLDH） through spontaneous redox and sulfurization *** developed Ag/SLDH and Pt/SLDH catalysts with abundant heterogeneous interfaces and hierarchical nanostructures demonstrated outstanding oxygen evolution reaction （OER） and hydrogen evolution reaction （HER） performance,achieving low overpotentials of 212 and 35 mV at 10 mA cm-2in 1 M KOH,*** both anode and cathode in water splitting,they required only 1.47 V to reach 10 mA cm-2and exhibited high structural robustness,maintaining stability at 1000 mA cm-2for 300 ***-situ Raman analysis revealed that the synergistic effects of metal nanoparticles and S doping significantly promote the transformation into the S-Co1-xFexOOH layer,which serves as the active phase for water ***,ultraviolet photoelectron spectroscopy （UPS） and density functional theory （DFT） analyses indicated that incorporating metal nanoparticles and S doping increase electron density near the Fermi level and reduce reaction energy barriers,thus enhancing intrinsic OER and HER *** study provides a scalable strategy for synthesizing high-performance electrocatalysts for water splitting,with promising potential for broader applications.

关键词： LDH Spontaneous reaction Metal nanoparticles Water splitting

Multi boron-doping effects in hard carbon toward enhanced sodium ion storage

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Journal of Energy Chemistry 2025年第1期100卷 730-738页

作者： Peng Zheng Wang Zhou Ying Mo Biao Zheng Miaomiao Han Qin Zhong Wenwen yang Peng Gao Lezhi yang Jilei Liu College of Materials Science and Engineering Hunan Joint International Laboratory of Advanced Materials and Technology for Clean Energy Hunan Province Key Laboratory for Advanced Carbon Materials and Applied Technology Hunan University Greater Bay Area Institute for Innovation Hunan University Changsha Research Institute of Mining & Metallurgy Co. LTD.

Hard carbon （HC） has been considered as promising anode material for sodium-ion batteries （SIBs）.The optimization of hard carbon’s microstructure and solid electrolyte interface （SEI） property are demonstrated effective in enhancing the Na+storage capability,however,a one-step regulation strategy to achieve simultaneous multi-scale structures optimization is highly ***,we have systematically investigated the effects of boron doping on hard carbon’s microstructure and interface chemistry.A variety of structure characterizations show that appropriate amount of boron doping can increase the size of closed pores via rearrangement of carbon layers with improved graphitization degree,which provides more Na+storage ***-situ Fourier transform infrared spectroscopy/electrochemical impedance spectroscopy （FTIR/EIS） and X-ray photoelectron spectroscopy （XPS） analysis demonstrate the presence of more BC3and less B–C–O structures that result in enhanced ion diffusion kinetics and the formation of inorganic rich and robust SEI,which leads to facilitated charge transfer and excellent rate *** a result,the hard carbon anode with optimized boron doping content exhibits enhanced rate and cycling *** general,this work unravels the critical role of boron doping in optimizing the pore structure,interface chemistry and diffusion kinetics of hard carbon,which enables rational design of sodium-ion battery anode with enhanced Na+storage performance.

关键词： X ray photoelectron spectroscopy

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钛合金裂纹产生原因及改进工艺

火箭推进 2019年第6期45卷 78-83页

作者：吴晓明王玉郭蓓高斌高怀胜杨欢庆西安航天发动机有限公司

针对某型号发动机壳体组件水力试验后进口段荧光线性缺陷问题,通过对缺陷进行宏观观察、金相组织检查、断口分析、材料成分分析和硬度检查,确定了缺陷类型产生原因。运用Procast铸造仿真模拟软件开展了针对性的改进工艺研究。结果表明:... 详细信息

针对某型号发动机壳体组件水力试验后进口段荧光线性缺陷问题,通过对缺陷进行宏观观察、金相组织检查、断口分析、材料成分分析和硬度检查,确定了缺陷类型产生原因。运用Procast铸造仿真模拟软件开展了针对性的改进工艺研究。结果表明:进口段荧光线性缺陷为裂纹,呈典型的准解理断裂特征。表层脆而硬的富氧层是导致壳体开裂的诱因,其形成与补焊有关。基于仿真模拟的改进工艺成功将缺陷转移至冒口,减少铸件内部缺陷数量,降低补焊量;使用氩气保护箱改善气体保护效果,提高补焊质量。改进措施实施后,铸件、零件以及组件的荧光检查均一次合格,并且顺利通过地面试车考核,解决荧光线性缺陷问题,消除了薄弱环节,提高了发动机的可靠性。

关键词：钛合金裂纹控制仿真模拟铸造工艺优化气体保护

Microstructural evolution during the progressive transformation-induced plasticity effect in a Fe-0.1C-5Mnmedium manganese steel

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International Journal of Minerals,Metallurgy and Materials 2025年第2期32卷 369-379页

作者： Mei Zhang Wenhao Li yangfei Chen yang Jiang Xiaofei Guo Han Dong School of Materials Science and Engineering Shanghai UniversityShanghai 200444China State Key Laboratory of Advanced Special Steel Shanghai UniversityShanghai 200444China

The microstructural evolution of a cold-rolled and intercritical annealed medium-Mn steel(Fe-0.10C-5Mn)was investigated during uniaxial tensile ***-situ observations under scanning electron microscopy,transmission electron microscopy,and X-ray diffraction analysis were conducted to characterize the progressive transformation-induced plasticity process and associated fracture initiation *** findings were discussed with the local strain measurements via digital image *** results indicated that Lüders band formation in the steel was limited to 1.5%strain,which was mainly due to the early-stage martensitic phase transformation of a very small amount of the less stable large-sized retained austenite(RA),which led to localized stress concentrations and strain hardening and further retardation of *** small-sized RA exhibited high stability and progressively transformed into martensite and contributed to a stably extended Portevin-Le Chatelier *** volume fraction of RA gradually decreased from 26.8%to 8.2%prior to *** the late deformation stage,fracture initiation primarily occurred at the austenite/martensite and ferrite/martensite interfaces and the ferrite phase.

关键词： medium-Mn steel retained austenite progressive transformation-induced plasticity effect local strain fracture initiation

Ammonia pyrolysis oxidation excited by nanosecond pulsed discharge:Global/fluid models hybrid solution

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Journal of Energy Chemistry 2025年第1期100卷 385-396页

作者： Mingming Zhang Hanyu Wu Qi Chen Jiaxin yang Bonan Liu School of Mechanical Electronic and Control Engineering Beijing Jiaotong University China University of Petroleum

The kinetic characteristics of plasma-assisted oxidative pyrolysis of ammonia are studied by using the global/fluid models hybrid solution ***,the stable products of plasma-assisted oxidative pyrolysis of ammonia are *** results show that the consumption of NH3/O2and the production of N2/H2change linearly with the increase of voltage,which indicates the decoupling of nonequilibrium molecular excitation and oxidative pyrolysis of ammonia at low ***,the detailed reaction kinetics mechanism of ammonia oxidative pyrolysis stimulated by a nanosecond pulse voltage at low pressure and room temperature is *** on the reaction path analysis,the simplified mechanism is *** detailed and simplified mechanism simulation results are compared with experimental data to verify the accuracy of the simplified ***,based on the simplified mechanism,the fluid model of ammonia oxidative pyrolysis stimulated by the nanosecond pulse plasma is established to study the pre-sheath/sheath behavior and the resultant consumption and formation of key *** results show that the generation,development,and propagation of the pre-sheath have a great influence on the formation and consumption of *** consumption of NH3by the cathode pre-sheath is greater than that by the anode pre-sheath,but the opposite is true for OH and O（1S）.However,within the sheath,almost all reactions do not ***,by changing the parameters of nanosecond pulse power supply voltage,it is found that the electron number density,electron current density,and applied peak voltages are not the direct reasons for the structural changes of the sheath and ***,the discharge interval has little effect on the sheath structure and gas mixture *** research results of this paper not only help to understand the kinetic promotion of non-equilibrium excitation in the process of oxidative pyrolysis but also help to explore th

关键词： Nanosecond pulsed discharge Ammonia Oxidative pyrolysis Fluid model Global model

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选择性激光烧结翘曲变形抑制工艺

火箭推进 2019年第3期45卷 75-80页

作者：吴晓明周亚雄杨欢庆王玉王琳西安航天发动机有限公司

针对选择性激光烧结(selective laser sintering,SLS)翘曲变形问题,阐述了翘曲变形产生机理,得出主要原因为温度场分布不均匀和烧结层强度不足,确定了预热温度控制和添加工艺支撑两种翘曲变形抑制措施。以悬臂试样为研究对象,设计正交实... 详细信息

针对选择性激光烧结(selective laser sintering,SLS)翘曲变形问题,阐述了翘曲变形产生机理,得出主要原因为温度场分布不均匀和烧结层强度不足,确定了预热温度控制和添加工艺支撑两种翘曲变形抑制措施。以悬臂试样为研究对象,设计正交实验,建立了悬臂结构的预热温度与翘曲变形率的二次多元回归模型,确定了合理预热温度工艺参数,结合产品结构特点,基于Magics软件开展了某型液体火箭发动机叶轮工艺支撑设计。结果表明:悬臂试样翘曲变形由6.13%降低至0.5%,产品翘曲变形率由10.31%降低至1.80%,较改进前降低了82.5%,解决了烧结翘曲变形问题。

关键词：选择性激光烧结翘曲变形预热温度工艺支撑

Fine description of unconventional clastic oil reservoirs

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Petroleum Research 2024年第2期9卷 289-303页

作者： huanqing Chen Research Institute of Petroleum Exploration&Development PetroChinaChina

The latest researches reveal that studies on unconventional clastic oil reservoirs in China generally lag far behind those in other countries in respect of content and *** study presents the definition and classification of unconventional oil reservoirs and analyzes the problems in the fine description of unconventional oil *** key content of the fine description of unconventional oil reservoirs is summarized from four aspects:fine fracture characterization based on fine structure interpretation,reservoir architecture characterization based on sedimentary facies,characteristics of nanoscale microscopic pore structure of reservoir,and evaluation of source rock and“sweet spot zone”.Finally,this study suggests that development of fine description of unconventional clastic oil reservoirs in the future should focus on rock brittleness analysis and fracture modeling,geophysical characterization of unconventional clastic oil reservoirs,fluid description of tight reservoirs,and physical/numerical simulation experiments of unconventional oil reservoirs.

关键词： Unconventional clastic reservoir Fine reservoir description Oil sand Tight oilShale oil Fracture characterization Nanoscale microscopic pore structure Sweet spot

麝香保心丸与阿托伐他汀钙对颈动脉粥样硬化的治疗效果

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中国实用医刊 2017年第19期44卷 99-101页

作者：符少萍洪俊陈焕清杨雪梅陈玉成中山大学孙逸仙纪念医院预防保健科广东广州510120 中山大学孙逸仙纪念医院药剂科广东广州510120

目的探讨麝香保心丸与阿托伐他汀钙对颈动脉粥样硬化的疗效及其作用机制。方法选取颈动脉粥样硬化斑块患者120例，随机分为两组，每组60例。两组患者均予以常规治疗，每晚睡前口服阿托伐他汀钙20 mg；治疗组加服麝香保心丸2粒/次，3次/... 详细信息

目的探讨麝香保心丸与阿托伐他汀钙对颈动脉粥样硬化的疗效及其作用机制。方法选取颈动脉粥样硬化斑块患者120例，随机分为两组，每组60例。两组患者均予以常规治疗，每晚睡前口服阿托伐他汀钙20 mg；治疗组加服麝香保心丸2粒/次，3次/d，疗程6个月。每例患者均于治疗前、治疗后6个月检测颈动脉内膜-中层厚度（IMT）、颈动脉不稳定斑块数、空腹静脉血检测内皮素（ET）、一氧化氮（NO）和血脂水平。结果治疗后6个月，两组颈动脉IMT、不稳定斑块数、低密度脂蛋白胆固醇、总胆固醇水平较治疗前下降（P〈0.05），且治疗组低于对照组（P〈0.05）。治疗后，治疗组NO较治疗前升高（P〈0.05），ET较治疗前降低（P〈0.05）；NO较对照组治疗后升高（P〈0.05），ET较对照组治疗后降低（P〈0.05）。结论麝香保心丸可通过调节ET/NO失衡和血脂水平等机制，抑制内膜中层增生，减少不稳定斑块数目，与他汀类联用可协同延缓动脉硬化。

关键词：麝香保心丸颈动脉粥样硬化内膜-中层厚度阿托伐他汀钙

Nanoparticles for the treatment of spinal cord injury

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Neural Regeneration Research 2025年第6期20卷 1665-1680页

作者： Qiwei yang Di Lu Jiuping Wu Fuming Liang Huayi Wang Junjie yang Ganggang Zhang Chen Wang Yanlian yang Ling Zhu Xinzhi Sun Department of Orthopedic Surgery The First Affiliated Hospital of Zhengzhou UniversityZhengzhouHenan ProvinceChina CAS Key Laboratory of Standardization and Measurement for Nanotechnology CAS Key Laboratory for Biomedical Effects of Nanomaterials and NanosafetyCAS Center for Excellence in NanoscienceNational Center for Nanoscience and TechnologyBeijingChina University of Chinese Academy of Sciences BeijingChina Department of Neurosurgery The First Affiliated Hospital of Chongqing Medical UniversityChongqingChina

Spinal cord injuries lead to significant loss of motor, sensory, and autonomic functions, presenting major challenges in neural regeneration. Achieving effective therapeutic concentrations at injury sites has been a slow process, partly due to the difficulty of delivering drugs effectively. Nanoparticles, with their targeted delivery capabilities, biocompatibility, and enhanced bioavailability over conventional drugs, are garnering attention for spinal cord injury treatment. This review explores the current mechanisms and shortcomings of existing treatments, highlighting the benefits and progress of nanoparticle-based approaches. We detail nanoparticle delivery methods for spinal cord injury, including local and intravenous injections, oral delivery, and biomaterial-assisted implantation, alongside strategies such as drug loading and surface modification. The discussion extends to how nanoparticles aid in reducing oxidative stress, dampening inflammation, fostering neural regeneration, and promoting angiogenesis. We summarize the use of various types of nanoparticles for treating spinal cord injuries, including metallic, polymeric, protein-based, inorganic non-metallic, and lipid nanoparticles. We also discuss the challenges faced, such as biosafety, effectiveness in humans, precise dosage control, standardization of production and characterization, immune responses, and targeted delivery in vivo. Additionally, we explore future directions, such as improving biosafety, standardizing manufacturing and characterization processes, and advancing human trials. Nanoparticles have shown considerable progress in targeted delivery and enhancing treatment efficacy for spinal cord injuries, presenting significant potential for clinical use and drug development.

关键词： antioxidants axon regeneration biocompatible materials drug carriers nanoparticles nerve regeneration neuroinflammatory diseases neuroprotection spinal cord injury stem cells

C-C motif chemokine ligand 2/C-C motif chemokine receptor 2 pathway as a therapeutic target and regulatory mechanism for spinal cord injury

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Neural Regeneration Research 2025年第8期20卷 2231-2244页

作者： Xiangzi Wang Xiaofei Niu Yingkai Wang yang Liu Cheng yang Xuyi Chen Zhongquan Qi School of Medicine Guangxi UniversityNanningGuangxi Zhuang Autonomous RegionChina Graduate School of Tianjin University of Traditional Chinese Medicine TianjinChina Characteristic Medical Center of People’s Armed Police Forces TianjinChina Fujian Maternity and Child Health Hospital FuzhouFujian ProvinceChina

Spinal cord injury involves non-reversible damage to the central nervous system that is characterized by limited regenerative capacity and secondary inflammatory *** expression of the C-C motif chemokine ligand 2/C-C motif chemokine receptor 2 axis exhibits significant differences before and after *** studies have revealed that the C-C motif chemokine ligand 2/C-C motif chemokine receptor 2 axis is closely associated with secondary inflammatory responses and the recruitment of immune cells following spinal cord injury,suggesting that this axis is a novel target and regulatory control point for *** review comprehensively examines the therapeutic strategies targeting the C-C motif chemokine ligand 2/C-C motif chemokine receptor 2 axis,along with the regenerative and repair mechanisms linking the axis to spinal cord ***,we summarize the upstream and downstream inflammatory signaling pathways associated with spinal cord injury and the C-C motif chemokine ligand 2/C-C motif chemokine receptor 2 *** review primarily elaborates on therapeutic strategies that target the C-C motif chemokine ligand 2/C-C motif chemokine receptor 2 axis and the latest progress of research on antagonistic drugs,along with the approaches used to exploit new therapeutic targets within the C-C motif chemokine ligand 2/C-C motif chemokine receptor 2 axis and the development of targeted ***,there are presently no clinical studies relating to spinal cord injury that are focusing on the C-C motif chemokine ligand 2/C-C motif chemokine receptor 2 *** review aims to provide new ideas and therapeutic strategies for the future treatment of spinal cord injury.

关键词： apoptosis C-C motif chemokine ligand 2/C-C motif chemokine receptor 2 pathway C-C motif chemokine receptor 2 antagonists chemokine ligand 2 chemokine receptor 2 inflammation macrophage microglia spinal cord injury therapeutic method