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Selection of Negative Charged Acidic Polar Additives to Regulate Electric Double Layer for Stable Zinc Ion Battery

Nano-Micro Letters 2024年第12期16卷 342-356页

作者： Xing Fan Lina chen Yongjing Wang Xieyu Xu Xingxing Jiao Peng Zhou Yangyang Liu Zhongxiao Song Jiang Zhou State Key Laboratory for Mechanical Behavior of Materials Xi’an Jiaotong UniversityXi’an 710049People’s Republic of China School of Materials Science and Engineering Harbin Institute of Technology(Shenzhen)Shenzhen 518055People’s Republic of China Research Institute of Frontier Science Southwest Jiaotong UniversityChengdu 610031People’s Republic of China Hunan Provincial Key Defense Laboratory of High Temperature Wear-Resisting Materials and Preparation Technology Hunan University of Science and TechnologyXiangtan 411201People’s Republic of China School of Instrument Science and Technology Xi’an Jiaotong UniversityXi’an 710049People’s Republic of China School of Materials Science and Engineering Hunan Provincial Key Laboratory of Electronic Packaging and Advanced Functional MaterialsCentral South UniversityChangsha 410083People’s Republic of China

Zinc-ion batteries are promising for large-scale electrochemical energy storage systems,which still suffer from interfacial issues,e.g.,hydrogen evolution side reaction(HER),self-corrosion,and uncontrollable dendritic Zn *** the regulation of electric double layer(EDL)has been verified for interfacial issues,the principle to select the additive as the regulator is still ***,several typical amino acids with different characteristics were examined to reveal the interfacial behaviors in regulated EDL on the Zn *** charged acidic polarity(NCAP)has been unveiled as the guideline for selecting additive to reconstruct EDL with an inner zincophilic H_(2)O-poor layer and to replace H_(2)O molecules of hydrated Zn^(2+)with NCAP *** the synergistic effects of EDL regulation,the uncontrollable interface is significantly stabilized from the suppressed HER and anti-self-corrosion with uniform ***,by adding NCAP glutamate,a high average Coulombic efficiency of 99.83%of Zn metal is achieved in Zn|Cu asymmetrical cell for over 2000 cycles,and NH4V4O10|Zn full cell exhibits a high-capacity retention of 82.1%after 3000 cycles at 2 A g^(-1).Recapitulating,the NCAP principle posted here can quicken the design of trailblazing electrolyte additives for aqueous Zn-based electrochemical energy storage systems.

关键词： Aqueous Zn-ion batteries Zn metal anode Negative charged acidic polar additives Electric double-layer regulation

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Achieving Negatively Charged Pt Single Atoms on Amorphous Ni(OH)_(2)Nanosheets with Promoted Hydrogen Absorption in Hydrogen Evolution

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Nano-Micro Letters 2024年第10期16卷 213-224页

作者： Yue Liu Gui Liu Xiangyu chen Chuang Xue Mingke Sun Yifei Liu Jianxin Kang Xiujuan Sun Lin Guo School of Chemistry Beijing Advanced Innovation Center for Biomedical EngineeringKey Laboratory of Bio-inspired Smart Interfacial Science and TechnologyBeihang UniversityBeijing 100191People's Republic of China School of Chemistry Key Laboratory of Environmentally Friendly Chemistry and Applications of Ministry of EducationXiangtan UniversityXiangtan 411105HunanPeople'Republic of China

Single-atom(SA)catalysts with nearly 100%atom utilization have been widely employed in electrolysis for decades,due to the outperforming catalytic activity and ***,most of the reported SA catalysts are fixed through the strong bonding between the dispersed single metallic atoms with nonmetallic atoms of the substrates,which greatly limits the controllable regulation of electrocatalytic activity of SA *** this work,Pt-Ni bonded Pt SA catalyst with adjustable electronic states was successfully constructed through a controllable electrochemical reduction on the coordination unsaturated amorphous Ni(OH)_(2)nanosheet *** on the X-ray absorption fine structure analysis and first-principles calculations,Pt SA was bonded with Ni sites of amorphous Ni(OH)_(2),rather than conventional O sites,resulting in negatively charged Pt^(δ-).In situ Raman spectroscopy revealed that the changed configuration and electronic states greatly enhanced absorbability for activated hydrogen atoms,which were the essential intermediate for alkaline hydrogen evolution *** hydrogen spillover process was revealed from amorphous Ni(OH)_(2)that effectively cleave the H-O-H bond of H_(2)O and produce H atom to the Pt SA sites,leading to a low overpotential of 48 mV in alkaline electrolyte at-1000 mA cm^(-2)mg^(-1)_(Pt),evidently better than commercial Pt/C *** work provided new strategy for the control-lable modulation of the local structure of SA catalysts and the systematic regulation of the electronic states.

关键词： Hydrogen evolution reaction Amorphous Pt single atoms Hydrogen spillover

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Risk assessment of oil and gas investment environment in countries along the Belt and Road Initiative

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Petroleum Science 2024年第2期21卷 1429-1443页

作者： Bao-Jun Tang Chang-Jing Ji Yu-Xian Zheng Kang-Ning Liu Yi-Fei Ma Jun-Yu chen Center for Energy and Environmental Policy Research Beijing Institute of TechnologyBeijing100081China School of Management and Economics Beijing Institute of TechnologyBeijing100081China Collaborative Innovation Center of Electric Vehicles in Beijing BeijingChina Sustainable Development Research Institute for Economy and Society of Beijing BeijingChina Institute of Carbon Neutrality ShanghaiTech UniversityShanghai201210China

With the implementation of the Belt and Road Initiative, China is deepening its cooperation in oil and gas resources with countries along the Initiative. In order to better mitigate risks and enhance the safety of investments, it is of significant importance to research the oil and gas investment environment in these countries for China's overseas investment macro-layout. This paper proposes an indicator system including 27 indicators from 6 dimensions. On this basis, game theory models combined with global entropy method and analytic hierarchy process are applied to determine the combined weights, and the TOPSIS-GRA model is utilized to assess the risks of oil and gas investment in 76 countries along the Initiative from 2014 to 2021. Finally, the GM(1,1) model is employed to predict risk values for 2022-2025. In conclusion, oil and gas resources and political factors have the greatest impact on investment environment risk, and 12 countries with greater investment potential are selected through cluster analysis in conjunction with the predicted results. The research findings may provide scientific decisionmaking recommendations for the Chinese government and oil enterprises to strengthen oil and gas investment cooperation with countries along the Belt and Road Initiative.

关键词： Belt and Road Initiative Oil and Gas Investment Risk assessment

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Extrusion-base d 3D-printe d“rolle d-up”composite scaffolds with hierarchical pore structure for bone growth and repair

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Journal of Materials Science & Technology 2024年第4期171卷 222-234页

作者： Yufan Li Li chen Yijing Stehle Mingyue Lin chenxin Wang Rui Zhang Min huang Yubao Li Qin Zou Research Center for Nano Biomaterials Analytical&Testing CenterSichuan UniversityChengdu 610064China Analytical&Testing Center Sichuan UniversityChengdu 610064China Department of mechanical engineering Union College807 Union St.SchenectadyNY 12308USA Sichuan Institute of Atomic Energy Chengdu 610101China

Three-dimensional(3D)bioprinting,specifically direct ink writing(DIW)capable of printing biologically active substances such as growth factors or drugs under low-temperature conditions,is an emerging di-rection in bone tissue ***,limited by the bio-ink mobility and the poor resolution of this printing technology,the lateral pores of current crisscross-stacked scaffolds printed through DIW tend to clog and are inimical to bone ***,it is critical to develop DIW printed biologi-cal scaffold structure with high mechanical strength,porosity,and biocompatibility ***,patterned polylactic acid(PLA)/polycaprolactone(PCL)/nano-hydroxyapatite(n-HA)based scaffold was printed through DIW technological and rolled-up for properties characterization,cytocompatibility test,and bone repair *** result not only shows that the hexagonal patterned scaffolds are me-chanically strong with porosity,but also demonstrated that the hierarchical pore structure formed during rolled-up has the potential to address the clogging problem and stimulates bone growth and repair.

关键词： Direct ink writing(DIW) bone repair scaffold,Micro-CT Bio composites

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Research on the flow stability and noise reduction characteristics of quasi-periodic elastic support skin

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Defence Technology（防务技术） 2024年第3期33卷 222-236页

作者： Lu chen Shao-gang Liu Dan Zhao Li-qiang Dong Kai Li Shuai Tang Jin Cui Hong Guo Department of Mechanical and Electrical Engineering Harbin Engineering UniversityHarbin150001China

To enhance flow stability and reduce hydrodynamic noise caused by fluctuating pressure,a quasiperiodic elastic support skin composed of flexible walls and elastic support elements is proposed for fluid noise *** arrangement of the elastic support element is determined by the equivalent periodic distance and quasi-periodic *** this paper,a dynamic model of skin in a fluid environment is *** influence of equivalent periodic distance and quasi-periodic coefficient on flow stability is *** results suggest that arranging the elastic support elements in accordance with the quasi-periodic law can effectively enhance flow ***,the hydrodynamic noise calculation results demonstrate that the skin exhibits excellent noise reduction performance,with reductions of 10 dB in the streamwise direction,11 dB in the spanwise direction,and 10 dB in the normal *** results also demonstrate that the stability analysis method can serve as a diagnostic tool for flow fields and guide the design of noise reduction structures.

关键词： Flow stability Quasi-period Flexible wall Elastic support element Hydrodynamic noise

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Efficient recovery of tungsten from scheelite concentrates using a sulfur-phosphorus mixed acid leaching system

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Tungsten 2024年第4期6卷 821-832页

作者： Jiang-Tao Li Li-Li Gao Zhong-Wei Zhao Xu-Heng Liu Xing-Yu chen School of Metallurgy and Environment Central South University Key Laboratory of Hunan Province for Metallurgy and Material Processing of Rare Metals

In recent years,a new process for leaching scheelite concentrates with sulfur-phosphorus mixed acid has been successfully *** process suffers from the elimination of the retarding effect of calcium sulfate,the selective extraction of tungsten from the H3PW12O40-H2SO4-H3PO4mixture solution,and the removal of introduced ***,in this paper,we investigated the inhibition measures of a calcium sulfate-blocking membrane,the selective extraction of tungsten by ion exchange,and the removal of phosphorus by the magnesium ammonium salt *** results showed that the addition of calcium sulfate whisker seeds and a higher H3PO4concentration inhibited spontaneous diffuse nucleation,promoted crystal growth,and avoided the formation of a dense blocking *** 98 wt.% of the scheelite concentrate was digested by *** selective adsorption of PW12O403-was realized using D301 resin,and the extraction efficiency of tungsten exceeded 99.9%.After desorption with ammonia water,PW12O403-was depolymerized into WO42-and PO43-.99.9 wt.% of phosphorus was removed in the form of MgNH4PO4by the magnesium ammonium salt method,and the residual phosphorus concentration in the solution was lower than 10 mg·*** purification,the highest-grade ammonium paratungstate product was prepared by evaporative crystallization.

关键词： Calcium sulfate Ion exchange Scheelite concentrates Sulfur-phosphorus mixed acid Tungsten

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河西走廊东部不同气候态气温变化及其对气候评价的影响

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干旱区研究 2024年第7期41卷 1089-1098页

作者：杨晓玲周华陈静赵慧华吴雯武威国家气候观象台甘肃武威733099 中国气象局兰州干旱气象研究所甘肃省干旱气候变化与减灾重点实验室中国气象局干旱气候变化与减灾重点开放实验室甘肃兰州730020

河西走廊东部是气候变化的敏感区,其气候态的更替对气候评价影响较大。采用河西走廊东部5个国家气象站的1961─2022年逐月气温数据,对比分析河西走廊东部1961─1990年、1971─2000年、1981─2010年和1991─2020年4个气候态气温的差异及... 详细信息

河西走廊东部是气候变化的敏感区,其气候态的更替对气候评价影响较大。采用河西走廊东部5个国家气象站的1961─2022年逐月气温数据,对比分析河西走廊东部1961─1990年、1971─2000年、1981─2010年和1991─2020年4个气候态气温的差异及其对气候业务评价的影响。结果表明:全区域及各地4个气候态年平均气温均呈升高趋势,P2(1971—2000年气候态)~P4(1991—2020年气候态)气温升高趋势均极显著。从4个气候态气温的差值来看,全区域及各地年、季、月气温基本一致升温,除P3(1981—2010年气候态)和P4外,其他气候态表现为冬季升幅最大,夏季升幅最小,各月升温差异较大,同一季度、同一月份气温升幅存在明显空间差异。气候态平均值更替后,河西走廊东部气温距平明显偏大的特征弱化了,其等级由正距平向负距平方向调整,P1(1961—1990年气候态)~P4年平均气温评价等级高达56%~87%向偏低一级转变,冷冬年份增多17~28 a,暖冬年份减少15~23 a。本研究将为了解河西走廊东部气温的变化规律以及气候业务、决策服务和气象科学研究提供参考依据。

关键词：气候变暖温度气候态变化气候评价河西走廊东部

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Mechanical Behavior of Bamboo,and Its Biomimetic Composites and Structural Members:A Systematic Review

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Journal of Bionic Engineering 2024年第1期21卷 56-73页

作者： Shanyu Han Yuyuan He Hanzhou Ye Xueyong Ren Fuming chen Kewei Liu Sheldon Q.Shi Ge Wang Institute of Biomaterials for Bamboo and Rattan Resources International Centre for Bamboo and RattanBeijing 100102China Key Laboratory of National Forestry and Grassland Administration/Beijing for Bamboo&Rattan Science and Technology Beijing 100102China National Forestry and Grassland Engineering Technology Center for Wood Resources Recycling College of Materials Science and TechnologyBeijing Forestry UniversityBeijing 100083China International Bamboo and Rattan Organization Beijing 100102China School of Civil Engineering Tsinghua UniversityBeijing 100084China Mechanical Engineering Department University of North TexasDentonTX 762077102USA

Bamboo is a typical biological material widely growing in nature with excellent physical and mechanical *** is lightweight with high strength and *** naturally optimized bamboo structure,which has inspired global material scientists and engineers for decades,is significantly important for the bionic design of novel structural materials with ultra-light,ultra-strong,or ultra-tough and comprehensive *** literature on innovative composite materials and structural members inspired by bamboo are reviewed in this paper,and the research progress and prospects in this field are expounded in three ***,the structural characteristics of the bamboo wall layer along the thickness and height directions are described in terms of chemical composition,gradient structure,pore structure,and hollow structure with variable ***,this paper summarizes the research progress on new composite materials and structural components by applying bamboo’s structural features from the perspective of sustainability,designability,and ***,given the limitations of current research,the biomimetic scientific research on bamboo’s structural characteristics is prospected from the interpretation of bamboo structure,new bamboo-like materials,and structural design optimization perspectives,providing a reference for future research on biomimetic aspects of biomass.

关键词： Bamboo Structural characteristics-Bamboo-like material Physical and mechanical properties

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Two-color emissive AIEgens with anti-Kasha property for dual-organelle imaging and phototherapy

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Science China Chemistry 2024年第5期67卷 1740-1752页

作者： Pu chen Guogang Shan Qingli Nie Yuting Yan Pengfei Zhang Zujin Zhao Hai-Tao Feng Ben Zhong Tang AIE Research Center Shaanxi Key Laboratory of PhytochemistryCollege of Chemistry and Chemical EngineeringBaoji University of Arts and SciencesBaoji 721013China Institute of Functional Material Chemistry and National&Local United Engineering Lab for Power Battery Faculty of ChemistryNortheast Normal UniversityChangchun 130024China College of Chemistry&Materials Science Northwest UniversityXi’an 710127China Guangdong Key Laboratory of Nanomedicine CAS-HK Joint Lab of BiomaterialsCAS Key Laboratory of Biomedical Imaging Science and SystemShenzhen Engineering Laboratory of Nanomedicine and NanoformulationsCAS Key Lab for Health InformaticsShenzhen Institutes of Advanced TechnologyChinese Academy of SciencesShenzhen 518055China State Key Laboratory of Luminescent Materials and Devices Key Laboratory of Luminescence from Molecular Aggregates of Guangdong ProvinceSouth China University of TechnologyGuangzhou 510640China School of Science and Engineering Shenzhen Institute of Aggregate Science and TechnologyThe Chinese University of Hong KongShenzhen(CUHK-Shenzhen)Shenzhen 518172China

Despite the rapid development of probes for targeting single organelle, the construction of robust dual-organelle targeting probes with multicolor emission was rarely reported. Herein, two dual-emissive aggregation-induced emission luminogens(AIEgens)with donor-π-acceptor structures were designed and synthesized, namely QT-1 and QF-2. both two AIEgens exhibited excitation wavelength-dependence defying the Kasha's rule, and could stain lipid droplets(LDs) and mitochondria in blue and red fluorescence, respectively. Moreover, thanks to the near-infrared emission and abundant reactive oxygen species(ROS) generation efficiency of QT-1, it was chosen as a photodynamic therapy agent to selectively kill cancer cells from normal cells. Upon light irradiation, an obvious decrease of mitochondrial membrane potential(MMP) and serious change of mitochondrial shape in cells were observed, which corresponded to the efficient inhibition of tumor growth in vivo. This work afforded a promising strategy for the construction of multicolor emission by tuning anti-Kasha behaviors and expanding their application in dualorganelle targeting-based phototheranostics.

关键词： aggregation-induced emission anti-Kasha luminescence fluorescent probe bioimaging photodynamic therapy

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Polyp-Canal Reconstruction Reveals Evolution Toward Complexity in Corals

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Research 2024年第1期2023卷 417-428页

作者： Yixin Li Xin Liao Xin Wang Yuanchao Li Hongwei Zhao Yunpeng Zhao Junyuan chen Chunpeng He Zuhong Lu State Key Laboratory of Bioelectronics School of Biological Science and Medical EngineeringSoutheast UniversityNanjing 210096China State Key Laboratory of Coastal and Offshore Engineering Dalian University of TechnologyDalian 116024China Guangxi Key Lab of Mangrove Conservation and Utilization Guangxi Mangrove Research CenterGuangxi Academy of SciencesBeihai 536000China Hainan Academy of Ocean and Fishery Sciences Haikou 571126China State Key Laboratory of Marine Resources Utilization in South China Sea Hainan UniversityHaikou 570228China Nanjing Institute of Geology and Palaeontology Chinese Academy of Sciences39 East Beijing RoadNanjing 210008China

Modern scleractinian corals are classified into robust,complex,and basal clades through comparative molecular ***,only few morphological or biological criteria can systematically determine the evolutionary trajectories of these major scleractinian coral ***,we obtained the structural information of 21 scleractinian coral species representing robust and complex clades:High-resolution micro-computed tomography was used to reconstruct the polyp-canal systems in their colonies and to visualize the dynamic polyp growth *** found that the emergence of mesh-like canals may distinguish representatives of complex and robust *** differences in polyp-canal connections suggest distinct evolutionary trajectories among coral species:The formation of the canal network promoted the development of more complex coral structures,and coral polyps within this network formed calices of very similar volume,following precise axial growth *** influence of individual polyps on the coral colony becomes less significant as coral structures become more complex,and coral species with more complicated polyp-canal systems occupied niches more *** work supplements current evolutionary studies on reef-building corals,providing insight for further studies on coral growth patterns.

关键词： Coral representing directions

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