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Aggregation-Induced Synthesis (AIS): Asymmetric Synthesis via Chiral Aggregates

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Research 2022年第4期2022卷 731-739页

作者： hossein rouh Yao Tang Ting Xu Qingkai Yuan Sai Zhang Jia-Yin Wang Shengzhou Jin Yu Wang Junyi Pan Hannah LWood James D.McDonald Guigen Li Department of Chemistry and Biochemistry Texas Tech UniversityLubbockTexas 79409-1061USA Institute of Chemistry and BioMedical Sciences School of Chemistry and Chemical EngineeringNanjing UniversityNanjing 210093China

A new chiral aggregate-based tool for asymmetric synthesis has been developed by taking advantage of chiral aggregates of GAP(Group-Assisted Purification)reagents,N-phosphonyl *** tool was proven to be successful in the asymmetric GAP synthesis of functionalized 2,3-dihydrobenzofurans by reacting salicyl N-phosphonyl imines with dialkyl bromomalonates in various cosolvent *** chiral induction can be controlled by differentiating between two asymmetric directions simply by changing the ratios of cosolvents which are commonly adopted in AIE(aggregation-induced emission)*** formation of chiral aggregates was witnessed by a new analytical tool-aggregation-induced polarization(AIP).The present synthetic method will be broadly extended for general organic synthesis,particularly,for asymmetric synthesis and asymmetric catalysis in the future.

关键词： asymmetric chiral synthesis

Enantioselective assembly of multi-layer 3D chirality

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National Science Review 2020年第3期7卷 588-599页

作者： Guanzhao Wu Yangxue Liu Zhen Yang Tao Jiang Nandakumar Katakam hossein rouh Liulei Ma Yao Tang Sultan Ahmed Anis U.Rahman Hongen Huang Daniel Unruh Guigen Li Institute of Chemistry and Bio Medical Sciences School of Chemistry and Chemical EngineeringNanjing University Department of Chemistry and Biochemistry Texas Tech University School of Medicine and Pharmacy Ocean University of China

The first enantioselective assembly of sandwich-shaped organo molecules has been achieved by conducting dual asymmetric Suzuki-Miyaura couplings and nine other reactions. This work also presents the first fully C-C anchored multi-layer 3 D chirality with optically pure enantiomers. As confirmed by X-ray diffraction analysis that this chiral framework is featured by a unique C2-symmetry in which a nearly parallel fashion consisting of three layers: top, middle and bottom aromatic rings. Unlike the documented planar or axial chirality, the present chirality shows its top and bottom layers restrict each other from free rotation, i.e., this multi-layer 3 D chirality would not exist if either top or bottom layer is removed. Nearly all multi-layered compounds showed strong luminescence of different colors under UV irradiation, and several randomly selected samples displayed aggregation-induced emission(AIE) properties. This work is believed to have broad impacts on chemical, medicinal and material sciences including optoelectronic materials in future.

关键词： multi-layer 3D chirality organo sandwich chirality C2-symmetry multi-layered organic framework(M-LOF) architecture chirality aggregation-induced emission(AIE)

Triple-Columned and Multiple-Layered 3D Polymers:Design,Synthesis,Aggregation-Induced Emission(AIE),and Computational Study

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Research 2021年第1期2021卷 112-124页

作者： Guanzhao Wu Yangxue Liu Zhen Yang Liulei Ma Yao Tang Xianliang Zhao hossein rouh Qixuan Zheng Peng Zhou Jia-Yin Wang Farhan Siddique Sai Zhang Shengzhou Jin Daniel Unruh Adelia JAAquino Hans Lischka Kristin M.Hutchins Guigen Li Department of Chemistry and Biochemistry Texas Tech UniversityLubbockTexas 79409-1061USA Institute of Chemistry and Biomedical Sciences School of Chemistry and Chemical EngineeringNanjing UniversityNanjing 210093China School of Pharmaceutical Sciences and Technology Tianjin UniversityTianjin 300072China Department of Mechanical Engineering Texas Tech UniversityLubbockTX 79409USA

Conjugated polymers and oligomers have great potentials in various fields,especially in materials and biological sciences because of their intriguing electronic and optoelectronic *** recent years,the through-space conjugation system has emerged as a new assembled pattern of multidimensional ***,a novel series of structurally condensed multicolumn/multilayer 3D polymers and oligomers have been designed and synthesized through one-pot Suzuki polycondensation(SPC).The intramolecularly stacked arrangement of polymers can be supported by either X-ray structural analysis or computational *** all cases,polymers were obtained with modest to good yields,as determined by GPC and 1 ***-TOF analysis has proven the speculation of the step-growth process of this *** computational study of ab initio and DFT calculations based on trimer and pentamer models gives details of the structures and the electronic *** results of optical and AIE research confirmed by calculation indicates that the present work would facilitate the research and applications in materials.

关键词： properties transition materials

Multilayer 3D Chirality and Its Synthetic Assembly

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Research 2019年第1期2019卷 822-832页

作者： Guanzhao Wu Yangxue Liu Zhen Yang Nandakumar Katakam hossein rouh Sultan Ahmed Daniel Unruh Kazimierz Surowiec Guigen Li Institute of Chemistry and BioMedical Sciences School of Chemistry and Chemical EngineeringNanjing UniversityNanjing 210093China Department of Chemistry and Biochemistry Texas Tech UniversityLubbockTX 79409-1061USA

3D chirality of sandwich type of organic molecules has been *** key element of this chirality is characterized by three layers of structures that are arranged nearly in parallel fashion with one on top and one down from the center *** enantiomers of these molecules have been fully characterized by spectroscopies with their enantiomeric purity measured by chiral *** absolute confguration was unambiguously assigned by X-ray difraction *** is the frst multilayer 3D chirality reported and is anticipated to lead to a new research area of asymmetric synthesis and catalysis and to have a broad impact on chemical,medicinal,and material sciences in future.

关键词： purity absolute sandwich

An SDN-Based Algorithm for Caching,Routing,and Load Balancing in ICN

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China Communications 2024年第5期21卷 64-76页

作者： MohammadBagher Tavasoli hossein Saidi Ali Ghiasian Department of Electrical and Computer Engineering Isfahan University of TechnologyIsfahanIran Department of Technology and Engineering Shahrekord UniversityShahrekordIran

One of the challenges of Informationcentric Networking(ICN)is finding the optimal location for caching content and processing users’*** this paper,we address this challenge by leveraging Software-defined Networking(SDN)for efficient ICN *** achieve this,we formulate the problem as a mixed-integer nonlinear programming(MINLP)model,incorporating caching,routing,and load balancing *** explore two distinct scenarios to tackle the ***,we solve the problem in an offline mode using the GAMS environment,assuming a stable network state to demonstrate the superior performance of the cacheenabled network compared to non-cache ***,we investigate the problem in an online mode where the network state dynamically changes over *** the computational complexity associated with MINLP,we propose the software-defined caching,routing,and load balancing(SDCRL)algorithm as an efficient and scalable *** evaluation demonstrates that the SDCRL algorithm significantly reduces computational time while maintaining results that closely resemble those achieved by GAMS.

关键词： in-network caching information-centric network power efficiency routing software-defined networking

Special Issue:International Conference on Sustainable Energy Sources,Technologies and Systems 2023(ICSESTS-2023)

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Clean Energy 2024年第3期8卷 136-137页

作者： Ravinder Kumar Mohammad hossein Ahmadi School of Mechanical Engineering Lovely Professional UniversityPhagwra-144411PunjabIndia Faculty of Mechanical Engineering Shahrood University of TechnologyShahroodIran

The Division of Research and Development at Lovely Professional University,Punjab organized the International Conference on Sustainable Energy Sources,Technologies and Systems 2023(ICSESTS-2023),which took place on 3-... 详细信息

关键词： solar energy storage wind energy geothermal hydropower biofuels batteries

Powering the future: A comprehensive review on calcium-ion batteries

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Journal of Energy Chemistry 2024年第3期90卷 77-97,I0004页

作者： Ameneh Taghavi-Kahagh hossein Roghani-Mamaqani Mehdi Salami-Kalajahi Faculty of Polymer Engineering Sahand University of TechnologyP.0.Box 51335-1996Tabriz Iran Institute of Polymeric Materials Sahand University of TechnologyP.0.Box 51335-1996Tabriz Iran

Due to concerns regarding the future availability,cost,and safety of lithium in Li-ion batteries(LIBs),researchers are exploring alternative chemistries such as Na-ion,Li-S,Li-air,and multivalent ion *** ion technologies,which utilize divalent or trivalent ions,like Mg^(2+),Ca^(2+),and Al^(3+),show promise in achieving greater energy densities than LIBs due to their ability to deposit uniformly on anodes and intercalate into *** magnesium-ion batteries(MIBs) have been the primary area of research for multivalent ion batteries,the cost-effectiveness and abundance of calcium have sparked a growing interest in calcium-ion batteries(CIBs) in recent *** to LIBs,CIBs have the potential to provide longer cycle life,enhanced safety,and increased energy ***,the development of CIBs comes with several challenges,such as finding suitable electrode and electrolyte materials that ensure the stability and safety of the *** primary hurdle in CIBs lies in the plating/stripping *** is a significant hindrance preventing the occurrence of plating/stripping in CIBs,which lies in the formation of a passive layer resulting from the decomposition of the *** objective of this article is to examine the advancements made in ***,it aims to comprehensively assess the mechanisms and materials employed in various battery components,as well as the obstacles encountered in *** includes recent advancements in electrode materials,electrolytes,cell configurations,and the challenges and opportunities for enhancing the performance and commercial viability of CIBs.

关键词： Ca-ion batteries Cathode Anode Electrolyte

Characteristics of turbulent flow in 3-D pools in the presence of submerged rigid vegetation in channel bed

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Journal of Hydrodynamics 2024年第1期36卷 158-169页

作者： Kourosh Nosrati hossein Afzalimehr Jueyi Sui Hamid Reza Reisifar Natural Disasters Prevention Research Center Faculty of Civil EngineeringIran University of Science and TechnologyTehranIran School of Engineering University of Northern British ColumbiaPrince GeorgeCanada

In this study,the interaction between 3-D bedforms and submerged rigid vegetation has been *** laboratory experiments were conducted to study the distribution of flow velocity,Reynolds shear stress,turbulent kinetic energy,and skewness coefficients for a constant density of *** showed that the velocity profile in the pool section deviates from those in the upstream section of the *** has been found that the dip parameter varied between 0.6H and 0.9H depending on various factors including bed roughness,vegetation distribution,and pool entrance/exit ***,scattered vegetation in the pool and differences in slopes created non-uniform flow ***,in the wake region behind each vegetated element,flow velocity reduced significantly,and small-scale eddies are formed,causing increased *** decreasing the entrance slope and bed roughness,relatively uniform flow and weaker turbulence was resulted,but the random distribution of vegetated elements counteracted this balance and intensified *** the decrease in the pool entrance slope,the contribution of sweep event decreased and the contribution of ejection event increased.

关键词： Submerged rigid vegetation 3-D pool Reynolds shear stress skewness coefficients

Seamless morphing trailing edge flaps for UAS-S45 using high-fidelity aerodynamic optimization

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Chinese Journal of Aeronautics 2024年第2期37卷 12-29页

作者： Mir hossein NEGAHBAN Musavir BASHIR Victor TRAISNEL Ruxandra Mihaela BOTEZ LARCASE Laboratory of Applied Research in Active Controls Avionics and AeroservoelasticityEcole de Technologie SuperieureUniversite du QuebecMontreal H3C1K3Canada

The seamless trailing edge morphing flap is investigated using a high-fidelity steady-state aerodynamic shape optimization to determine its optimum configuration for different flight conditions,including climb,cruise,and gliding descent.A comparative study is also conducted between a wing equipped with morphing flap and a wing with conventional hinged *** optimization is performed by specifying a certain objective function and the flight performance goal for each flight *** the climb rate,extending the flight range and endurance in cruise,and decreasing the descend rate,are the flight performance goals covered in this *** optimum configurations were found for the morphing wing by determining the optimum morphing flap deflection for each flight condition,based on its objective function,each of which performed better than that of the baseline *** was shown that by using optimum configuration for the morphing wing in climb condition,the required power could be reduced by up to 3.8%and climb rate increases by 6.13%.The comparative study also revealed that the morphing wing enhances aerodynamic efficiency by up to 17.8%and extends the laminar ***,the optimum configuration for the gliding descent brought about a 43%reduction in the descent rate.

关键词： Seamless morphing trailing edge flap Aerodynamic optimization Gradient-based optimiza-tion Climb flight condition Gliding descent Flight range Endurance