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Bioinspired urchin-like murray carbon nanostructure with protection shell for advanced lithium-sulfur batteries

Journal of Energy Chemistry 2023年第10期85卷 1-10,I0002页

作者： Ya-Wen Tian Yong Yu Liang Wu Min Yan Wen-Da Dong Chen-Yang Wang hemdan s.h.mohamed Zhao Deng Li-hua Chen Tawfique hasan Yu Li Bao-Lian su state Key Laboratory of Advanced Technology for Materials synthesis and Processing Wuhan University of TechnologyWuhan 430070HubeiChina school of Automotive Engineering Xiangyang PolytechnicXiangyang 441050HubeiChina hubei Key Laboratory of Plasma Chemistry and Advanced Materials Hubei Engineering Technology Research Center of Optoelectronic and New Energy MaterialsSchool of Materials Science and EngineeringWuhan Institute of TechnologyWuhan 430205HubeiChina Physics Department Faculty of ScienceFayoum UniversityEl Gomhoria Street63514 FayoumEgypt Cambridge Graphene Centre University of CambridgeCambridge CB30FAUnited Kingdom Laboratory of Inorganic Materials Chemistry(CMI) University of Namur61 rue de BruxellesB-5000 NamurBelgium

Commercial application of lithium-sulfur(Li-s) batteries is hindered by the insulating nature of sulfur and the dissolution of polysulfides. here, a bioinspired 3D urchin-like N-doped Murray's carbon nanostructure(N-MCN) with interconnected micro-meso-macroporous structure and a polydopamine protection shell has been designed as an effective sulfur host for high-performance Li-s batteries. The advanced 3D hierarchically porous framework with the characteristics of the generalized Murray's law largely improves electrolyte diffusion, facilitates electrons/ions transfer and provides strong chemisorption for active species, leading to the synergistic structural and chemical confinement of polysulfides. As a result,the obtained P@s/N-MCN electrode with high areal sulfur loading demonstrates high capacity at high current densities after long cycles. This work reveals that following the generalized Murray's law is feasible to design high-performance sulfur cathode materials for potentially practical Li-s battery applications.

关键词： Li-s batteries Murray’s law hierarchically porous framework N-doped carbon structural-chemical confinement

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Phase-junction Ag/TiO_(2)nanocomposite as photocathode for h_(2)generation

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Journal of Materials science & Technology 2021年第24期83卷 179-187页

作者： hemdan s.h.mohamed mohamed Rabia Xian-Gang Zhou Xu-sen Qin Gomaa Khabiri mohamed shaban hussein A.Younus s.Taha Zhi-Yi hu Jing Liu Yu Li Bao-Lian su state Key Laboratory of Advanced Technology for Materials synthesis and Processing Wuhan University of TechnologyWuhan430070China Physics Department Faculty of ScienceFayoum UniversityFayoum63514Egypt Nanophotonics and Applications Lab Physics DepartmentFaculty of ScienceBeni-Suef UniversityBeni-Suef62514Egypt Chemistry Department Faculty of ScienceFayoum UniversityFayoum63514Egypt Nanostructure Research Centre(NRC) Wuhan University of TechnologyWuhan430070China Laboratory of Inorganic Materials Chemistry(CMI) University of Namur61 rue de Bruxelles5000NamurBelgium

Developing anatase/rutile phase-junction in Ti O_(2)to construct Z-scheme system is quite effective to improve its photoelectrochemical *** this work,the anatase/rutile phase-junction Ag/Ti O_(2)nanocomposites are developed as photocathodes for hydrogen *** optimized Ag/Ti O_(2)nanocomposite achieves a high current density of 1.28 m A cm-2,an incident photon-to-current conversion efficiency(IPCE)of 10.8%,an applied bias photon-to-current efficiency(ABPE)of 0.32 at 390 nm and a charge carriers’lifetime up to 2000 *** enhancement on photoelectrochemical activity can be attributed to:(ⅰ)the generated Z-scheme system in the anatase/rutile phase-junction Ag/Ti O_(2)photocathode enhances the separation,diffusion and transformation of electron/hole pairs inside the structure,(ⅱ)Ag nanodots modification in the anatase/rutile phases leading to the tuned band gap with enhanced light absorption and(ⅲ)the formed schottky barrier after Ag nanodots surface modification provides enough electron traps to avoid the recombination of photogenerated electrons and *** results here suggest that developing phase-junction nanocomposite as photocathode will provide a new vision for their enhanced photoelectrochemical generation of hydrogen.

关键词： Ag/TiO_(2)nanocomposites Anatase/rutile phase-junction Z-scheme Photocathode h2 generation

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Assessment of plant diversity of endemic species of the saharo-Arabian region in Egypt

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Journal of Arid Land 2024年第7期16卷 1000-1021,I0002-I0044页

作者： Asmaa s ABO hATAB Yassin M AL-sODANY Kamal h shALTOUT soliman A hAROUN mohamed M EL-KhALAFY Botany and Microbiology Department Faculty of ScienceKafrelsheikh UniversityKafrelsheikh 33511Egypt Botany Department Faculty of ScienceTanta UniversityTanta 31527Egypt

savanna, semi-deserts, and hot deserts characterize the saharo-Arabian region, which includes Morocco, Mauretania, Algeria, Tunisia, Libya, Egypt, Palestine, Kuwait, saudi Arabia, Qatar, Bahrain, the United Arab Emirates, Oman, Yemen, southern Jordan, syria, Iraq, Iran, Afghanistan, Pakistan, and northern India. Its neighboring regions, the sudano-Zambezian region belonging to the Paleotropical Kingdom and the Mediterranean and Irano-Turanian regions included in the holarctic Kingdom, share a large portion of their flora with the saharo-Arabian region. Despite the widespread acknowledgment of the region's global importance for plant diversity, an up to date list of the saharo-Arabian endemics is still unavailable. The available data are frequently insufficient or out of date at both the whole global and the national scales. Therefore, the present study aims at screening and verifying the saharo-Arabian endemic plants and determining the phytogeographical distribution of these taxa in the Egyptian flora. hence, a preliminary list of 429 saharo-Arabian endemic plants in Egypt was compiled from the available literature. Indeed, by excluding the species that were recorded in any countries or regions outside the saharo-Arabian region based on different literature, database reviews, and websites, the present study has reduced this number to 126 taxa belonging to 87 genera and 37 families. Regarding the national geographic distribution, south sinai is the richest region with 83 endemic species compared with other eight phytogeographic regions in Egypt, followed by the Isthmic Desert(the middle of sinai Peninsula, 53 taxa). sahara regional subzone(ss1) distributes all the 126 endemic species, Arabian regional subzone(ss2) owns 79 taxa, and Nubo-sindian subzone(ss3) distributes only 14 endemics. seven groups were recognized at the fourth level of classification as a result of the application of the two-way indicator species analysis(TWINsPAN) to the saharo-Arabian endemic sp

关键词： endemism phytogeographical regions saharo-Arabian floristic region Egyptian flora plant diversity two-way indicator species analysis(TWINsPAN)

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A Distributionally Robust Optimization scheduling Model for Regional Integrated Energy systems Considering hot Dry Rock Co-Generation

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Computer Modeling in Engineering & sciences 2024年第8期140卷 1387-1404页

作者： hao Qi mohamed sharaf Andres Annuk Adrian Ilinca mohamed A.mohamed College of Electrical and New Energy China Three Gorges UniversityYichang443002China Department of Industrial Engineering College of EngineeringKing Saud UniversityRiyadh11421Saudi Arabia Institute of Forestry and Engineering Estonian University of Life SciencesTartu51006Estonia Department of Mechanical Engineering école de Technologie SupérieureMontréalQC H3C 1K3Canada Electrical Engineering Department Faculty of EngineeringMinia UniversityMinia61519Egypt

hot dry rock(hDR)is rich in reserve,widely distributed,green,low-carbon,and has broad development potential and *** this paper,a distributionally robust optimization(DRO)scheduling model for a regionally integrated energy system(RIEs)considering hDR co-generation is ***,the hDR-enhanced geothermal system(hDR-EGs)is introduced into the ***-EGs realizes the thermoelectric decoupling of combined heat and power(ChP)through coordinated operation with the regional power grid and the regional heat grid,which enhances the system wind power(WP)feed-in ***,peak-hour loads are shifted using price demand response guidance in the context of time-of-day ***,the optimization objective is established to minimize the total cost in the RIEs scheduling cycle and construct a DRO scheduling model for RIEs with *** simulating a real small-scale RIEs,the results show that hDR-EGs can effectively promote WP consumption and reduce the operating cost of the system.

关键词： Energy harvesting integrated energy systems optimum scheduling time-of-use pricing demand response geothermal energy

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A new technique for fault diagnosis in transformer insulating oil based on infrared spectroscopy measurements

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high Voltage 2024年第2期9卷 319-335页

作者： mohamed M.F.Darwish mohamed h.A.hassan Nagat M.K.Abdel-Gawad Matti Lehtonen Diaa-Eldin A.Mansour Department of Electrical Engineering Faculty of Engineering at ShoubraBenha UniversityCairoEgypt Department of Electrical Engineering and Automation School of Electrical EngineeringAalto UniversityEspooFinland Department of Electrical Power Engineering Egypt-Japan University of Science and Technology(E-JUST)New Borg El-Arab CityEgypt Department of Electrical Power and Machines Engineering Faculty of EngineeringTanta UniversityTantaEgypt

Condition monitoring of the insulating system within power transformers has a massive importance according to the electrical *** gas analysis(DGA)is frequently used for this ***,DGA lacks the necessary level of accuracy to identify all equipment faults,particularly in their initial stages of ***,it does not have the capability for real-time monitoring and relies on manual sampling and laboratory testing,causing potential delays in fault ***,the interpretation of DGA data necessitates specialised expertise,which may pose difficulties for smaller entities that have limited access to ***,the contribution of this research is to use infrared spectroscopy measurements as a new effective technique substituting the DGA method for fault diagnosis in insulating *** inception faults that were considered in this study were the electrical fault(discharges of high energy)and the thermal fault(300°Chat,two test cells were crafted especially for serving the simulation processes inside the laboratory for both types of inception ***,six samples of pure paraffinic mineral oil were taken to be degraded in the *** that,all of them besides another sample that were not subjected to any kind of faults were taken to be examined by Fourier transform infrared(FTIR)spectroscopy to obtain an overview of the oil's behaviour in each fault *** that,the FTIR analysis was initially verified utilising the DGA ***,for further affirmation,the dielectric dissipation factor(DDF)for all samples was *** the final analysis,the verification tests provide experimental evidence about the outperformance of this new optical technique in detecting the transformer's inception faults in addition to proving its potential for being a superior alternative to the well-known traditional diagnostic techniques.

关键词： fault diagnosis spectroscopy

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二硫化锡纳米颗粒嵌入二维多孔碳纳米片中间层用于快充锂硫电池

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science China Materials 2021年第11期64卷 2697-2709页

作者：周娜董文达张云静王迪吴亮王浪胡执一刘婧 hemdan shmohamed 李昱陈丽华苏宝连 state Key Laboratory of Advanced Technology for Materials synthesis and Processing Wuhan University of TechnologyWuhan 430070China Nanostructure Research Center(NRC) Wuhan University of TechnologyWuhan 430070China Physics Department Faculty of ScienceFayoum UniversityEl Gomhoria Street63514 FayoumEgypt Laboratory of Inorganic Materials Chemistry(CMI) University of Namur61 rue de BruxellesB-5000 NamurBelgium

本文报道了将小尺寸二硫化锡(sns_(2))纳米颗粒嵌入到二维多孔碳纳米片(PCN)中间层,形成多功能纳米复合材料(PCN-sns_(2))作为硫正极载体,从而降低穿梭效应,实现锂硫电池快充.一方面,复合材料中石墨化碳纳米片可整体性提高电极的导电性... 详细信息

本文报道了将小尺寸二硫化锡(sns_(2))纳米颗粒嵌入到二维多孔碳纳米片(PCN)中间层,形成多功能纳米复合材料(PCN-sns_(2))作为硫正极载体,从而降低穿梭效应,实现锂硫电池快充.一方面,复合材料中石墨化碳纳米片可整体性提高电极的导电性.另一方面,复合材料丰富的孔道既促进离子转移和电解质的渗透,又缓解充放电过程中的体积变化,从而确保电极材料的完整性.特别地,PCN的物理限域和小尺寸sns_(2)纳米颗粒的强化学吸附协同作用可有效降低多硫化物的穿梭效应.因此,PCN-sns_(2)-s电极具有良好的电化学性能,即使在2 C的高电流密度下,150圈循环后仍可维持650 mA h g^(-1)的放电容量.本研究工作为小尺寸sns_(2)纳米结构更利于捕获多硫化物以减弱锂硫电池的穿梭效应提供了理论基础.

关键词：纳米复合材料纳米颗粒锂硫电池二硫化锡纳米结构多硫化物穿梭效应中间层

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Ballistic design and testing of a composite armour reinforced by CNTs suitable for armoured vehicles

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Defence Technology（防务技术） 2024年第2期32卷 173-195页

作者： Evangelos Ch.Tsirogiannis Evangelos Daskalakis mohamed h.hassan Abdalla M.Omar Paulo Bartolo EODh sA Research and Development DepartmentLakkoma Chalkidikis63080Greece school of Mechanical Aerospace and Civil EngineeringUniversity of ManchesterManchesterM139PLUK singapore Centre for 3D Printing School of Mechanical and Aerospace EngineeringNanyang Technological University639798Singapore

This paper is investigating the use of composite armour reinforced by nanomaterials, for the protection of light armoured(LAV) and medium armoured military vehicles(MAV), and the interaction between the composite materials and high-performance ballistic projectiles. Four armour materials, consisted of front hybrid fibre reinforced polymer cover layer, ceramic strike-face, fibre reinforced polymer intermediate layer and the metal matrix composite reinforced backplate, were manufactured and assembled by adhesive technology. The proposed laminated protection system is suitable for armoured ground vehicles;however, it could be used as armour on ground, air and naval platforms. The design of the protection system, including material selection and thickness, was elaborated depending on the performance requirements of Level 4 + sTANAG 4569 military standard(projectile 14.5 mm × 114 mm API B32) and especially on a design philosophy which is analysed with the specifications. The backplate of this new composite is a hybrid material of Metal Matrix Composite(MMC) reinforced with carbon nanotubes(CNTs), manufactured with the use of powder metallurgy technique. The composite backplate material was morphologically, mechanically and chemically analysed. Results show that all plates are presenting high mechanical properties and ballistic characteristics, compared to commonly used armour plates. Real military ballistic tests according to AEP-sTANAG 4569 were carried out for the total composite armour systems. After the ballistic tests, AA2024-CNT3 showed the best protection results, compared with the other plates(AA2024-CNT1 and AA2024-CNT2), with the projectile being unable to fully penetrate the composite plate.

关键词： Passive armour protection Protective armour Ballistic performance hybrid composites Vehicle protection

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Dysprosium oxide,alumina,and graphene oxide reinforced polycaprolactone thin films:Thermal stability,morphology,and cell viability

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Journal of Rare Earths 2024年第7期42卷 1337-1343,I0005页

作者： mohamed Tharwat Elabbasy mohamed R.Atteya Mai A.samak Mousa Abdelrahman Tahani AlMahmoud M.A.El-Morsy A.A.Menazea M.F.h.Abd El-Kader Department of Public health College of Public Health and Health InformaticsUniversity of Ha'ilHa'il2440Saudi Arabia Food Control Department Faculty of Veterinary MedicineZagazig UniversityZagazig44519Egypt Department of Physical Therapy College of Applied Medical SciencesUniversity of Ha'ilHa'ilSaudi Arabia Department of histology and Cell Biology Faculty of MedicineZagazig UniversityZagazig44519Egypt College of Nursing University of Ha'ilHa'ilSaudi Arabia College of science and humanities in Al-Kharj Physics DepartmentPlasma Technology and Material Science UnitPrince Sattam Bin Abdulaziz UniversityAl-kharj11942Saudi Arabia Physics Department Faculty of ScienceUniversity of DamiettaNew Damietta34517Egypt spectroscopy Department Physics Research InstituteNational Research CentreDokki12622GizaEgypt Biophysics Department Faculty of ScienceCairo UniversityGizaEgypt

Developing a biomaterial for wound healing applications is still a ***,dysprosium oxide(Dy_(2)O_(3)),aluminum oxide(Al_(2)O_(3)),and graphene oxide(GO)were embedded in cast films based on polycaprolactone(PCL)to be examined for wound dressing *** techniques were used to characterize the fabricated films including X-ray diffraction(XRD),Fourier transform infrared spectroscopy(FTIR),Raman,and scanning electron microscopy(sEM),besides their biological *** thermogravimetric analysis(TGA)exhibits high thermal stability as the scaffold weight decreases slightly to 98.6%after raising the temperature from room temperature to 280℃.The cell viability was investigated and it is shown that the viable cells grow up to approximately 93%at 75μg/***,the cell attachment shows excellent behavior as the cells attach on most of the surface of the modified PCL which shows high biocompatibility.

关键词： Wound healing Polycaprolactone Dy_(2)O_(3) Al_(2)O_(3) Biocompatible Rare earths

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Evaluating mechanism of banana pseudo-stem retting using seawater:A cost-effective surface pre-treatment approach

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Journal of Bioresources and Bioproducts 2024年第3期9卷 322-335页

作者： Prince hotor Ahmed h.hassanin Osbert Akatwijuka mohamed A.h.Gepreel Mitsuo Yamamoto Yukie saito Ahmed Abdel-Mawgood Egypt-Japan University of science and Technology Biotechnology ProgramAlexandria GovernorateNew Borg Al Arab 21934Egypt Alexandria University Department of Textile EngineeringAlexandria GovernorateBab Sharqi 5424041Egypt Egypt-Japan University of science and Technology Material Science and EngineeringAlexandria GovernorateNew Borg Al Arab 21934Egypt Graduate school of Agricultural and Life sciences The University of TokyoBunkyo-KuTokyo 113-8657Japan

Retting has been employed to extract natural fibers from agricultural wastes as a biological and cost-effective approach for *** its global abundance,banana pseudo-stem is a promising agro-waste for lignocellulosic fiber *** this study,fibers were extracted from the pseudo-stems after being pre-treated under four conditions using seawater at room temperature for up to 35 d Bacterial isolation from the fresh seawater sample and screening for ligninolytic ability were *** load as well as laccase and manganese peroxidase enzyme activity profile assay during the retting duration were *** transform infrared(FT-IR)and X-day diffraction(XRD)analyses were also examined for both pre-treated and untreated extracted *** results shows that six out of the eight bacterial isolates had the ability to degrade *** treatments(Raw stem+Raw seawater)and(Autoclaved stem+Raw seawater)recorded the highest viable bacterial load of 9.24×102 and 4.46×102 CFU,respectively,on the 14th day of the retting ***,the highest laccase and manganese peroxidase enzymes activity was recorded for(Raw stem+Raw seawater)and(Autoclaved stem+Raw seawater)treatments in the second to the third *** FT-IR spectra of the pre-treated fibers revealed relative reductions in peaks attributed to polysaccharides and other amorphous substances for all retting *** XRD diffractogram revealed that the crystallinity index(CI)of pre-treated fibers increased in all seawater retting treatment ***,the CI for fibers pre-treated under enzymatic conditions were enhanced even after five *** analysis for selected bacterial isolates showed homology to sequences of Bacillus velezensis,shewanella sp.L8–5,and Citrobacter amalonaticus and Bacillus subtilis j8 *** these findings,it was suggested that physical,biological,and chemical actions were collectively involved in the seawater retting process of banana ps

关键词： seawater retting Banana pseudo-stem Natural fiber Enzyme activity Colony forming unit

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Phytoconstituents Profiling of Indigenous herbal Drugs and Its in vitro Microbial,in silico Biological Examination against severe Acute Respiratory syndrome Coronavirus 2

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World Journal of Traditional Chinese Medicine 2024年第1期10卷 121-136页

作者： T.h.mohamed Ahadu shareef Mmohamed Divan Masood Irfan Navabshan Msaiyad Musthafa Department of Chemistry The New College(Autonomous)Affiliated to the University of MadrasChennaiTamil NaduIndia school of Computer Applications B.S.Abdur Rahman Crescent Institute of Science and TechnologyChennaiTamil NaduIndia Crescent school of Pharmacy B.S.Abdur Rahman Crescent Institute of Science and TechnologyChennaiTamil NaduIndia Department of Zoology The New College(Autonomous)Affiliated to the University of MadrasChennaiTamil NaduIndia

Background:habb-E-shifa,hamdard sualin,and hamdard Joshanda traditional herbal medicines may promote host resistance against infection by bacteria,viruses,and fungi which are easily accessible at inexpensive with no *** herbal medicines are used to cure sore throat,cough,fever,lung cancer,and asthma patients in developing south Asian *** traditional herbal medicines acted a crucial role in the prevention and control of coronavirus disease 2019(COVID-19).Aims and Objectives:This research article aimed at conducting phytochemistry,antimicrobial activity,COVID-19 docking and some spectroscopic(Infrared,Ultraviolet,13C-Nuclear Magnetic Resonance(13C-NMR),1h-NMR,and Mass spectra)characterizations of the polyherbal drugs were carried ***,In-vitro and In-silico analyses were performed to measure activity against *** Performance-Liquid Chromatography(hPLC),Gas Chromatography-Mass spectrometry(GC-Ms),antimicrobial,and docking studies were carried *** preliminary phytochemical assay and bioactive compounds were screened using hPLC and *** study is an attempt to assess the promising effects of selected polyherbal indigenous drugs such as habb-E-shifa,hamdard sualin,and hamdard Joshanda phytoconstituents against the severe acute respiratory syndrome coronavirus-2(sARs-Co V-2).Materials and Methods:The extract of the selected polyherbal formulations showed high-to-moderate preventive effects on the growth inhibition in the pathogenic bacterium,namely streptococcus oralis,staphylococcus aureus,Propionibacterium acnes,Pseudomonas aeruginosa,Escherichia coli,and Proteus vulgaris,and three fungal Candida albicans,Aspergillus fumigatus,and Aspergillus *** docking study evaluates the pharmacological activity of bioactive chemical compounds with sARs-Co V-2 NsP5(PDB ID:7nxh)and sARs-Co V-2 Omicron spike protein with human angiotensin-converting enzyme 2(ACE-2)(PDB ID:7wk6).Results:In this study,for the first time,we at

关键词： Antimicrobial herbal drug Omicron and coronavirus disease 2019 phytochemicals spectroscopic

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