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Bimetal MOF-derived NiFe-P nanocomposites coupled with Cu_(3)P nanoparticles to construct tandem electron transfer channels for photocatalytic hydrogen evolution

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Journal of Environmental Sciences 2024年第3期137卷 333-346页

作者： Haiyan Zhang shitao Yang Peng Zhu Senpei Tang Ming Li College of Chemistry and Chemical Engineering Jishou UniversityJishou 416000China School of Account Hunan University of Technology and BusinessChangsha 410205China

Finely modulated light-induced charge separation and transfer is a central challenge to achieve efficient *** progress has been made in this field,most of the previous research works focused on the separation or migration of photogenerated carriers but did not build a bridge between the *** to realize the strong driving and precise migration of carriers has become the focus of our *** report an ingeniously designed ternary *** NiFe-MOF as the“parent material”,the FeP_(4)/Ni_(x)P_(y)heterojunction is derived in situ while maintaining the frame structure through gas-solid reaction,and finally the Z-type electron transfer is *** Cu_(3)P anchoring spindle matrix,an electron transport tunnel is opened up in Cu_(3)P/FeP_(4)/Ni_(x)P_(y)ternary heterojunction under the action of p-n heterojunction built-in electric field driving and accurate energy band *** strong driving force of the built-in electric field provides an inexhaustible power for the transmission of electrons,and the fine series of electron transmission channels realizes the precise transmission of *** above fine design makes the perfect fit between the built-in electric field and the electron transfer channel,which not only effectively improves the embarrassing situation of insufficient electron driving force of hydrogen evolution reaction in the previous research,but also makes up for the weakening of semi-conductor reduction ability caused by the construction of traditional p-n *** research work provides a new idea for the construction of multiple heterostructures and the design of fine interface engineering in the future.

关键词： Cu_(3)P/FeP_(4)/Ni_(x)P Built-in electric field Electron transfer channels Photocatalysis

Electrochemical CO_(2)reduction to C_(2+)products over Cu/Zn intermetallic catalysts synthesized by electrodeposition

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Frontiers in Energy 2024年第1期18卷 80-88页

作者： Ting DENG Shuaiqiang JIA shitao HAN Jianxin ZHAI Jiapeng JIAO Xiao CheN Cheng XUE Xueqing XING Wei XIA Haihong WU Mingyuan he Buxing HAN School of Chemistry and Molecular Engineering East China Normal UniversityShanghai 200062China Institute of Eco-Chongming Shanghai 202162China Institute of High Energy Physics Chinese Academy of SciencesBeijing 100049China Institute of Chemistry Chinese Academy of SciencesBeijing 100190China

Electrocatalytic CO_(2)reduction(ECR)offers an attractive approach to realizing carbon neutrality and producing valuable chemicals and fuels using CO_(2)as the ***,the lack of cost-effective electrocatalysts with better performances has seriously hindered its ***,a one-step co-electrodeposition method was used to introduce Zn,a metal with weak^(*)CO binding energy,into Cu to form Cu/Zn intermetallic catalysts(Cu/Zn IMCs).It was shown that,using an H-cell,the high Faradaic efficiency of C_(2+)hydrocarbons/alcohols()could be achieved in ECR by adjusting the surface metal components and the applied *** suitable conditions,FEC_(2+)and current density could be as high as 75%and 40 mA/cm^(2),*** with the Cu catalyst,the Cu/Zn IMCs have a lower interfacial charge transfer resistance and a larger electrochemically active surface area(ECSA),which accelerate the ***,the^(*)CO formed on Zn sites can move to Cu sites due to its weak binding with*CO,and thus enhance the C–C coupling on the Cu surface to form C_(2+)products.

关键词： carbon dioxide electroreduction electrochemistry co-electrodeposition intermetallic catalysts value-added chemicals

Transient Damping of Virtual Synchronous Generator for Enhancing Synchronization Stability during Voltage Dips

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CES Transactions on Electrical Machines and Systems 2024年第2期8卷 143-151页

作者： shitao Sun Yu Lei Guowen Hao Yi Lu Jindong Liu Zhaoxin Song Jie Zhang North China Electric Power Research Institute Co. Ltd.Beijing 100045China State Grid Xinyuan Co. Ltd.Beijing 100761China hebei Fengning Pumped Storage Energy Co.Ltd. Chengde 068350China

Virtual synchronous generators(VSGs)are widely introduced to the renewable power generation,the variablespeed pumped storage units,and so on,as a promising gridforming *** is noted that VSGs can provide virtual inertia for frequency support,but the larger inertia would worsen the synchronization stability,referring to keeping synchronization with the grid during voltage ***,this paper presents a transient damping method of VSGs for enhancing the synchronization stability during voltage *** is revealed that the loss of synchronization(LOS)of VSGs always accompanies with the positive frequency deviation and the damping is the key factor to remove LOS when the equilibrium point *** order to enhance synchronization stability during voltage dips,the transient damping is proposed,which is generated by the frequency deviation in active power ***,the proposed method can realize seamless switching between normal state and grid ***,detailed control design for transient damping gain is given to ensure the synchronization stability under different inertia requirements during voltage ***,the experimental results are presented to validate the analysis and the effectiveness of the improved transient damping method.

关键词： Virtual synchronous generator(VSG) Transient damping Synchronization stability Voltage dips

Polymer-on-HOF: a new strategy for fabricating “armour-plated” HOFs to sequester radioactive anions

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Science China Chemistry 2024年第9期67卷 2958-2967页

作者： Hai-Ruo Li shitao Wu Xuezhuo Jing Zhengyi Di Kun Liu Lu Wang Cheng-Peng Li Zhong Liu Miao Du College of Chemistry Tianjin Key Laboratory of Structure and Performance for Functional Molecules Tianjin Normal University Shanghai Key Laboratory of High-Resolution Electron Microscopy School of Physical Science and Technology Shanghai Tech University Key Laboratory of Comprehensive and Highly Efficient Utilization of Salt Lake Resources Qinghai Provincial Key Laboratory of Resources and Chemistry of Salt Lakes Qinghai Institute of Salt Lakes Chinese Academy of Sciences College of Material and Chemical Engineering Institute of New Energy Science and Technology School of Future Hydrogen Energy Technology Zhengzhou University of Light Industry

The development of hydrogen-bonded organic frameworks（HOFs） faces significant constraints, primarily attributed to their fragile architectures and limited functionalization capabilities. To overcome these limitations, this work presents a new polymeron-HOF strategy by covalently tethering armor-like polymers onto the surface of HOFs. The application of this approach not only bolsters the stability of HOFs, but also facilitates the customization of their functional expansion in radionuclide sequestration. The optimized HOF-polymer materials display extraordinary ability in radionuclide sequestration, achieving uptake of I–(0.699 g g–1), IO3–(0.285 g g–1) and ReO4–(1.616 g g–1, setting a world record), fast adsorption kinetics（～100% removal within 45 s）, and exceptional regeneration capability（>30 cycles） under continuous flow conditions. These outstanding performances benefit from the internal porous channels and surface imidazolium polymer coatings of HOFs, as proved by density functional theory calculation and molecular dynamics simulations. This work paves the way for the rational design of HOF-based hybrid materials tailored to versatile applications.

关键词： hydrogen-bonded organic frameworks (HOFs) post-synthetic modification radionuclide sequestration

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混凝土内部受压力学性能试验与本构分析

振动．测试与诊断 2024年第1期44卷 135-141,202页

作者：何浩祥王峥程时涛高伟北京工业大学工程抗震与结构诊治北京市重点实验室北京100124

为了精准测量受压混凝土内部应力-应变关系,通过在丙烯酸树脂杆上布置电阻式应变片,测量得到混凝土试块内部应变,研发大量程微型土压力盒实现混凝土内部应力测量。将相关测试装置预埋在混凝土试块内部,完成混凝土试块单轴压缩试验,获得... 详细信息

为了精准测量受压混凝土内部应力-应变关系,通过在丙烯酸树脂杆上布置电阻式应变片,测量得到混凝土试块内部应变,研发大量程微型土压力盒实现混凝土内部应力测量。将相关测试装置预埋在混凝土试块内部,完成混凝土试块单轴压缩试验,获得精准的混凝土内部应力-应变关系数据。结果表明,混凝土内部本构模型相对于传统本构模型具有良好的延性,且峰值强度远高于传统本构模型。结合国内外几种具有代表性的混凝土本构方程对试验进行了有限元模拟,针对应力-应变曲线、峰值强度及峰值应变进行了对比分析。分析结果表明:实测的混凝土内部应力-应变曲线合理准确,相关测量方法具有良好的精度和可行性;基于我国规范模型的有限元模拟结果与试验结果吻合最好,可进一步推广使用。

关键词：混凝土内部应力-应变曲线本构模型传感器峰值强度峰值应变

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预算的法律保留:理论证成与规范分析

政治与法律 2024年第4期 76-90页

作者：王世涛大连海事大学法学院辽宁大连116026

预算的法律保留是指预算立法权的法律保留,其并非传统的“侵害保留”,也不是宪法意义上的法律保留以及“绝对保留”。我国《立法法》第11条关于“专属立法权”条款实质上确立了法律保留的原则,因而其中包括预算在内的“财政基本制度”... 详细信息

预算的法律保留是指预算立法权的法律保留,其并非传统的“侵害保留”,也不是宪法意义上的法律保留以及“绝对保留”。我国《立法法》第11条关于“专属立法权”条款实质上确立了法律保留的原则,因而其中包括预算在内的“财政基本制度”属于法律保留的范围。全国人大及其常委会的“专属立法权”事项并不排斥全国人大及其常委会对这些事项的授权立法。当然,“专属立法权”属于立法权的保留,我国《宪法》规定的有关预算条款却是国家机关的事项权。因此,《宪法》有关预算条款不能成为预算立法权法律保留的宪法依据。《预算法》第98条关于“国务院根据本法制定实施条例”的规定不符合《立法法》规定的授权明确性要件,从根本上解决预算法律保留及其授权立法的明确性问题还要诉诸宪法,并在《立法法》授权明确性规范基准上,由《预算法》在授权立法条款中予以具体规定。

关键词：预算法律保留授权立法授权明确性原则

钢管混凝土柱-钢连梁耗能墙设计方法及抗震性能试验

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建筑结构学报 2024年第4期45卷 24-37页

作者：兰炳稷何浩祥陈易飞吴山程时涛北京工业大学工程抗震与结构诊治北京市重点试验室北京100124

针对多高层钢框架结构中的钢筋混凝土抗侧力墙体在地震作用下损伤集中、材料利用率低、延性及耗能效果均不理想的问题,提出一种钢管混凝土柱-钢连梁耗能墙,并优选出强柱弱梁型墙体与强梁弱柱型墙体两种墙体构造形式,推导了两类墙体的构... 详细信息

针对多高层钢框架结构中的钢筋混凝土抗侧力墙体在地震作用下损伤集中、材料利用率低、延性及耗能效果均不理想的问题,提出一种钢管混凝土柱-钢连梁耗能墙,并优选出强柱弱梁型墙体与强梁弱柱型墙体两种墙体构造形式,推导了两类墙体的构造条件与关键性能参数理论计算方法,通过试验与有限元模拟相结合的方式对比了两类墙体的抗震性能,同时对提出的设计和性能参数计算理论开展验证。研究结果表明:强柱弱梁型墙体可以实现分布式均匀耗能,其等效黏滞阻尼比系数峰值大于0.3,位移延性系数大于8,其抗震性能显著优于强梁弱柱型墙体的;所提出的墙体设计原则及关键性能参数计算方法具备良好的有效性和准确性。

关键词：耗能墙耗能机制拟静力试验设计方法有限元模拟

面向电磁水声换能器的高静低动型悬架动力学研究

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振动与冲击 2024年第7期43卷 300-307,316页

作者：孙士涛么宇辉张希李鸿光上海交通大学机械系统与振动国家重点实验室上海200240

针对目前线性悬架无法兼顾电磁水声换能器降低谐振频率与承载较大静水压力的难题,设计引入了高静低动型悬架装置,并分析其对换能器声辐射性能的影响。建立了系统动力学模型和动态特性微分方程组,仿真分析了引入非线性刚度前后换能器系... 详细信息

针对目前线性悬架无法兼顾电磁水声换能器降低谐振频率与承载较大静水压力的难题,设计引入了高静低动型悬架装置,并分析其对换能器声辐射性能的影响。建立了系统动力学模型和动态特性微分方程组,仿真分析了引入非线性刚度前后换能器系统声源级及谐振频率的变化。研究了输入电压对不同系统谐振频率的影响,探究了不同高静低动系统之间的差异。通过锤击试验测得引入高静低动刚度前后悬架的固有频率和加速度导纳。研究结果表明:相较于原线性悬架,高静低动型悬架在承受相同负载时具备更低的固有频率,低频段内具有更高的加速度。在电磁换能器中引入具有高静低动刚度特性的悬架装置可以获得比原系统更低的谐振频率,使低频区域内的声源级得到提升。

关键词：换能器谐振频率高静低动仿真分析

A dynamically stable self-healable wire based on mechanical±electrical coupling

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National Science Review 2024年第3期 250-258页

作者： Shuo Wang Zhaofeng Ouyang shitao Geng Yan Wang Xiaoju Zhao Bin Yuan Xiao Zhang Qiuchen Xu Chengqiang Tang Shanshan Tang Han Miao Huisheng Peng Hao Sun Frontiers Science Center for Transformative Molecules School of Chemistry and Chemical EngineeringZhangjiang Institute for Advanced Studyand Key Laboratory of Green and High-End Utilization of Salt Lake Resources(Chinese Academy of Sciences)Shanghai Jiao Tong University State Key Laboratory of Molecular Engineering of Polymers Department of Macromolecular Science Institute of Fiber Materials and Devices and Laboratory of Advanced MaterialsFudan University School of Materials Science and Engineering East China University of Science and Technology

The rise in wearable electronics has witnessed the advancement of self-healable wires, which are capable of recovering mechanical and electrical properties upon structural damage. However, their highly fluctuating electrical resistances in the range of hundreds to thousands of ohms under dynamic conditions such as bending, pressing, stretching and tremoring may seriously degrade the precision and continuity of the resulting electronic devices, thus severely hindering their wearable applications. here, we report a new family of self-healable wires with high strengths and stable electrical conductivities under dynamic conditions, inspired by mechanical–electrical coupling of the myelinated axon in nature. Our self-healable wire based on mechanical–electrical coupling between the structural and conductive components has significantly improved the electrical stability under dynamic scenarios, enabling precise monitoring of human health status and daily activities, even in the case of limb tremors from simulated Parkinson's *** mechanical–electrical coupling strategy opens a new avenue for the development of dynamically stable electrodes and devices toward real-world wearable applications.

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