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Influences of shale microstructure on mechanical properties and bedding fractures distribution

Petroleum Science 2024年第3期21卷 1944-1954页

作者： Ming-Zhe Gu Mao Sheng Shi-Zhong Cheng Fan-hao gong Gen-Sheng Li State Key Laboratory of Petroleum Resources and Engineering China University of Petroleum-BeijingBeijing2249China College of Petroleum Engineering China University of Petroleum-BeijingBeijing102249China Shenyang Center of China Geological Survey ShenyangLiaoning110034China

The difference in microstructure leads to the diversity of shale mechanical properties and bedding fractures distribution *** this paper,the microstructure and mechanical properties of Longmaxi marine shale and Qingshankou continental shale were studied by X-ray diffractometer(XRD),field emission scanning electron microscope(FE-SEM)with mineral analysis system,and ***,the typical bedding layers area was properly stratified using Focused Ion Beam(FIB),and the effects of microstructure and mechanical properties on the distribution patterns of bedding fractures were *** results show that the Longmaxi marine shale sample contains more clay mineral grains,while the Qingshankou continental shale sample contains more hard brittle mineral grains such as *** Longmaxi marine shale sample,hard brittle minerals with grain sizes larger than 20μm is18.24%and those with grain sizes smaller than 20μm is 16.22%.For Qingshankou continental shale sample,hard brittle minerals with grain sizes larger than 20μm is 40.7%and those with grain sizes smaller than 20μm is 11.82%.In comparison to the Qingshankou continental shale sample,the Longmaxi marine shale sample has a lower modulus,hardness,and *** shales are formed by alternating coarse-grained and fine-grained layers during *** average single-layer thickness of Longmaxi marine shale sample is greater than Qingshankou continental shale *** two types of shale have similar bedding fractures distribution patterns and fractures tend to occur in the transition zone from coarse-grained to fine-grained *** orientation of the fracture is usually parallel to the bedding plane and detour occurs in the presence of hard brittle *** fracture distribution density of the Longmaxi marine shale sample is lower than that of the Qingshankou continental shale sample due to the strong heterogeneity of the Qingshankou continental *** current resea

关键词： Shale Nanoindentation Microstructure Mechanical property Fracture

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Stable hydrogen-bonded organic frameworks and their photo-and electro-responses

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Nano Research 2024年第8期17卷 7675-7699页

作者： Ying Hou Xin-Song Huang Sheng-hao gong Chen Liu Yangyang Liu Tian-Fu Liu State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of MatterChinese Academy of SciencesFuzhou 350002China University of Chinese Academy of Sciences Beijing 100049China Department of Chemistry and Biochemistry California State UniversityLos AngelesCalifornia 90032USA College of Chemistry and Materials Science Fujian Normal UniversityFuzhou 350007China

Hydrogen-bonded organic frameworks(HOFs)are a recent class of porous materials that have garnered considerable research interest owing to their distinctive *** can be constructed through judicious selection of H-bonding motifs,which are further enforced by other weak intermolecular interactions such asπ–πstacking,van der Waals forces,and framework *** advantage of these interactions,we can expand the functional field of HOFs by introducing active ***,researchers have made substantial advancements in using HOFs for chemical sensing,catalysis,proton conduction,biological applications,and *** low bonding energy of H-bonds allows for precise control over the concentration of ligands in solvents,forming diverse HOF *** varied structures offer significant advantages for producing HOFs with photo-responsive and electro-responsive ***,the presence of H-bonds in HOFs results in their inherent lower stability compared to metal-organic frameworks(MOFs)and covalent-organic frameworks(COFs)formed via coordination and covalent bonds,*** a result,the pursuit of stable and innovative HOF materials with novel functional sites remains an ongoing *** review provides an overview of recent research progress in the development of new strategies for stable HOF synthesis and applications of HOFs with stimuli-responsive *** first classified all synthetic methods reported to date and discussed the stable HOFs synthesized,as well as their unique properties and *** addition,we summarized the applications of HOFs utilizing their synergistic responses to external stimuli,including photo,electrical,pressure,and chemical *** systematically reviewed stable HOF synthesis and applications,which may lead to a deeper understanding of the structure–activity relationship for these materials and guide future HOF design.

关键词： stable hydrogen-bonded organic frameworks(HOFs) photo-response electro-response photoelectric synergistic response

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Early peripheral perfusion index predicts 28-day outcome in patients with septic shock

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World Journal of Emergency Medicine 2024年第5期15卷 372-378页

作者： Cheng Chi hao gong Kai Yang Peng Peng Xiaoxia Zhang Department of Emergency Peking University People's HospitalBeijing 100044China Department of Emergency Intensive Care Unit the First Affi liated Hospital of Xinjiang Medical UniversityUrumqi 830000China

BACKGROUND:To investigate the prognostic value of the peripheral perfusion index(PPI)in patients with septic ***:This prospective cohort study,conducted at the emergency intensive care unit of Peking University People's Hospital,recruited 200 patients with septic shock between January 2023 and August *** patients were divided into survival(n=84)and death(n=116)groups based on 28-day *** evaluations included laboratory tests and clinical scores,with lactate and PPI values assessed upon admission to the emergency room and at 6 h and 12 h after *** factors associated with mortality were analyzed using univariate and multivariate Cox regression *** operator characteristic(ROC)curve was used to assess predictive *** rates were compared,and Kaplan-Meier survival plots were ***:Compared to the survival group,patients in the death group were older and had more severe liver damage and coagulation dysfunction,necessitating higher norepinephrine doses and increased fl uid *** lactate levels and lower PPI levels at 0 h,6 h,and 12 h were observed in the death *** Cox regression identifi ed prolonged prothrombin time(PT),decreased 6-h PPI and 12-h PPI as independent risk factors for *** area under the curves for 6-h PPI and 12-h PPI were 0.802(95%CI 0.742-0.863,P<0.001)and 0.945(95%CI 0.915-0.974,P<0.001),respectively,which were superior to Glasgow Coma Scale(GCS),Sequential Organ Failure Assessment(SOFA)scores(0.864 and 0.928).Cumulative mortality in the low PPI groups at 6 h and 12 h was signifi cantly higher than in the high PPI groups(6-h PPI:77.52%vs.22.54%;12-h PPI:92.04%vs.13.79%,P<0.001).CONCLUSION:PPI may have value in predicting 28-day mortality in patients with septic shock.

关键词： Peripheral perfusion index Septic shock Prognosis Predictive value

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New material of Coniopteris simplex from the Middle Jurassic of the Ordos Basin,Inner Mongolia,China and implications on its spatio-temporal distribution and paleogeography

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Journal of Palaeogeography 2024年第2期13卷 199-211页

作者： Yun-Feng Li Chang-Lu Zhang Fei Liang Xiao Tan Fan-hao gong Chun-Lin Sun Tao Li Yu-Ling Na Research Center of Paleontology and Stratigraphy Jilin UniversityChangchun 130026Jilin ProvinceChina College of Earth Sciences Jilin UniversityChangchun 130061Jilin ProvinceChina College of Paleontology Shenyang Normal UniversityShenyang 110034Liaoning ProvinceChina Key Lab of Evolution of Past Life in NE Asia Ministry of Natural ResourcesShenyang Normal UniversityShenyang 110034Liaoning ProvinceChina Shenyang Center of Geological Survey China Geological SurveyShenyang 110034Liaoning ProvinceChina

Coniopteris simplex is a common component in many Jurassic ***,due to morphological variations in sterile fronds and incomplete preservation of reproductive organs,its classification has been controversial for a long ***,we present new material collected from the Middle Jurassic Yan’an Formation in the Ordos Basin,Inner *** new material reveals important morphological characters,including hemi-dimorphic fronds,two forms of sterile pinnae,short-stalked sori and sporangia on fertile fronds,annulus of sporangium composed of about 30 cells,in situ rounded triangular spores with protruded suture,and the lips of trilete laesura encircled by one or two rows of small *** on these observations,we emended the diagnosis of this common *** spatio-temporal distribution of Coniopteris simplex shows that the iconic species was restricted to the paleolatitudes ranging from 19.5°N to 48.9°N in the Northern Hemisphere during the Early—Late Jurassic,mainly distributed in the tropical to paratropical zones,and the paleolongitude ranging from 9.6°E to 129.3°E,which may be limited by the opening of the Viking Corridor and the splitting of the Central Atlantic Ocean.

关键词： Coniopteris simplex Yan'an Formation Middle Jurassic Inner Mongolia Paleogeography

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Highly coupled off-resonance lattice design in diffraction-limited light sources

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Nuclear Science and Techniques 2024年第9期35卷 92-102页

作者： Yi-hao gong·Shun-Qiang Tian ·Xin-Zhong Liu·Shou-Zhi Xuan·Li-Yuan Tan ·Ling-Long Mao Shanghai Advanced Research Institute Chinese Academy of Sciences Shanghai 201204 ShanghaiChina Shanghai Institute of Applied Physics Chinese Academy of Sciences Shanghai 201800 ShanghaiChina University of Chinese Academy of Sciences 100049 BeijingChina

The round-beam operation presents many benefits for scientific experiments regarding synchrotron radiation and the weak-ening influences of intra-beam scattering in diffraction-limited synchrotron light sources.A round-beam generation method based on the global setting of skew quadrupoles and the application of a non-dominated sorting genetic algorithm was pro-posed in this *** schemes,including large-emittance coupling introduced via betatron coupling and vertical disper-sion,were explored in a candidate lattice for an upgrade-proposal of the Shanghai synchrotron radiation *** variations with lattice imperfections and their influence on the beam dynamics of beam optic distortions were *** results demonstrated that a precise coupling control ranging from 10 to 100%was achieved under low optical distortion,whereas full-coupling generation and its robustness were achieved by our proposed method by adjusting the skew quadrupole components located in the dispersion-free *** Touschek lifetime increased by a factor of 2–2.5.

关键词： Diffraction-limited storage ring(DLSR) Shanghai synchrotron radiation facility upgrade(SSRF-U) Round beam Off-resonance coupling

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玄武岩纤维/树脂基复合混凝土的力学性能和抗冻性能研究

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功能材料 2024年第2期55卷 2148-2154页

作者：龚皓中南大学土木工程学院长沙410000

以环氧树脂E51为基体材料,丙酮为稀释剂,通过添加玄武岩纤维,制备出了玄武岩纤维/树脂基复合混凝土,探究了玄武岩纤维掺杂量对复合混凝土的力学性能和抗冻性能的影响。结果表明,掺入适量玄武岩纤维后,复合混凝土宏观裂纹数量减少,玄武... 详细信息

以环氧树脂E51为基体材料,丙酮为稀释剂,通过添加玄武岩纤维,制备出了玄武岩纤维/树脂基复合混凝土,探究了玄武岩纤维掺杂量对复合混凝土的力学性能和抗冻性能的影响。结果表明,掺入适量玄武岩纤维后,复合混凝土宏观裂纹数量减少,玄武岩纤维在混凝土中横纵交错分布,与凝胶和骨料结合紧密,混凝土的力学性能得到了显著提高。随着玄武岩纤维掺杂量的增多,复合混凝土的抗压强度、抗折强度和相对动弹性模量均先升高后轻微降低,质量损失率先减小后增大。当玄武岩纤维掺杂量为0.60%(体积分数)时,复合混凝土的抗压强度和抗折强度均达到最大值,分别为41.63和8.90 MPa,在冻融循环100次时,相对动弹性模量最大为59.54%,质量损失率最低为1.02%,其力学性能和抗冻性能最佳。通过对质量损失率和相对动弹性模量进行曲线拟合分析可知,相对动弹性模量对于冻融循环的敏感程度更高,更适合用于评估混凝土的使用寿命,测试出玄武岩纤维的掺杂量为0.60%(质量分数)的混凝土的预估寿命可达9.84年,较未掺杂的试样提高了51.38%。综合可知,玄武岩纤维的最佳掺杂量为0.60%(体积分数)。

关键词：玄武岩纤维环氧树脂混凝土力学性能抗冻性能使用寿命

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Highly coupled off-resonance lattice design in diffraction-limited light sources

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Nuclear Science and Techniques 2024年第09期 224-234页

作者： Yi-hao gong Shun-Qiang Tian Xin-Zhong Liu Shou-Zhi Xuan Li-Yuan Tan Ling-Long Mao Shanghai Advanced Research Institute Chinese Academy of Sciences Shanghai Shanghai Institute of Applied Physics Chinese Academy of Sciences Shanghai University of Chinese Academy of Sciences

The round-beam operation presents many benefits for scientific experiments regarding synchrotron radiation and the weakening influences of intra-beam scattering in diffraction-limited synchrotron light sources. A round-beam generation method based on the global setting of skew quadrupoles and the application of a non-dominated sorting genetic algorithm was proposed in this study. Two schemes, including large-emittance coupling introduced via betatron coupling and vertical dispersion, were explored in a candidate lattice for an upgrade-proposal of the Shanghai synchrotron radiation facility. Emittance variations with lattice imperfections and their influence on the beam dynamics of beam optic distortions were *** results demonstrated that a precise coupling control ranging from 10 to 100% was achieved under low optical distortion,whereas full-coupling generation and its robustness were achieved by our proposed method by adjusting the skew quadrupole components located in the dispersion-free sections. The Touschek lifetime increased by a factor of 2–2.5.

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基于多尺度时空图神经网络的污染物浓度预测

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控制与决策 2024年第4期39卷 1396-1402页

作者：廖海斌袁理龚颢巍武汉纺织大学电子与电气工程学院武汉430200

基于深度学习的细粒度污染物浓度预测是一种新兴且具有前景的方法,如何充分利用气象、空间和时间等3大信息是其关键.为了协同融合3大信息,提出一种基于多尺度时空图神经网络的污染物浓度预测模型.该模型利用空气质量模型动态构建多尺度... 详细信息

基于深度学习的细粒度污染物浓度预测是一种新兴且具有前景的方法,如何充分利用气象、空间和时间等3大信息是其关键.为了协同融合3大信息,提出一种基于多尺度时空图神经网络的污染物浓度预测模型.该模型利用空气质量模型动态构建多尺度的时空图神经网络,学习污染物之间的动态时空关系.具体为:利用图神经网络学习污染物之间的多尺度空间关系,采用空气质量模型HYSPLIT构建图的结点和边属性,通过基于注意力机制的GRU(gate recurrent unit)学习污染物浓度之间的时序关系.该模型不仅充分考虑了气象、空间和时间3大影响因素,还将3个因素联动起来统一到一个框架内协同学习.该方法与传统的机理模型方法相比具有灵活部署、易于实施的特点.实际项目数据集和公开数据集上的实验表明:与现有先进的基于图神经网络的方法相比,该方法预测的污染物浓度平均绝对误差降低了0.6左右,对称平均绝对百分比误差降低0.005左右.

关键词：污染物浓度预测时空数据深度学习机理模型图神经网络

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基于CT扫描技术的煤试件力学特性及裂隙扩展规律研究

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采矿与安全工程学报 2024年第3期41卷 611-622页

作者：弓昊李地元李铮胡皓宇中南大学资源与安全工程学院湖南长沙410083 中国矿业大学(北京)能源与矿业学院北京100083

我国中东部矿区相继进入深部开采阶段,随着构造应力的增大与开采扰动效应的增强,工作面煤体内部裂隙发育程度逐渐升高,导致煤壁失稳现象频发。为研究煤体在高地应力环境下的力学特性及裂纹扩展规律,基于CT扫描技术实现煤试件内部各组分... 详细信息

我国中东部矿区相继进入深部开采阶段,随着构造应力的增大与开采扰动效应的增强,工作面煤体内部裂隙发育程度逐渐升高,导致煤壁失稳现象频发。为研究煤体在高地应力环境下的力学特性及裂纹扩展规律,基于CT扫描技术实现煤试件内部各组分的精准识别,建立煤试件三维重构模型和精细化数值模型,并结合单轴压缩试验研究煤试件内部各组分空间分布特征对试件变形参数、峰值强度和裂隙扩展路径的影响。结果表明:原生裂隙倾角越大,试件初始模量值Ei降低,试件容易发生纵向劈裂破坏;原生裂隙倾角越小,试件峰值强度σ_(c)降低,试件容易发生拉剪混合破坏;高密度杂质体积占比越大,煤试件弹性模量值E_(t)增大,试件所呈现的脆性特征越强;原生裂隙体积占比越大,试件应变硬化特征明显,且试件压缩破坏后的裂隙体积占比与复杂程度也明显增大。煤试件裂隙的扩展路径主要沿着原生裂隙横向扩张和纵向延伸,由于裂隙的快速扩展,常常伴随着分叉裂隙的产生,且原生裂隙的倾向分布越复杂,产生分叉裂隙的数目就越多;当原生裂隙未经过高密度杂质时,裂隙扩展路径往往会绕过其位置扩展;当原生裂隙经过高密度杂质时,裂隙的扩展路径会贯通其位置扩展。数值模拟结果与室内试验结果吻合程度较高,数值模型微裂隙的扩展模式与CT扫描所得的裂隙扩展路径一致,验证了精细化数值模型的可靠性。

关键词： CT扫描三维重构力学特性裂隙扩展精细化数值模型

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基于材料和试验方法的沥青混合料抗车辙研究进展

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市政技术 2024年第6期42卷 270-284页

作者：宫浩济宁市鸿翔公路勘察设计研究院有限公司山东济宁272000

车辙病害作为沥青路面常见的病害之一,在国内外备受关注,基于不同研究方向各研究机构围绕沥青混合料车辙开展了大量的相关研究。基于材料和试验方法 2个方面综述了沥青混合料抗车辙的研究进展。用于摊铺沥青路面的沥青混合料主要由沥青... 详细信息

车辙病害作为沥青路面常见的病害之一,在国内外备受关注,基于不同研究方向各研究机构围绕沥青混合料车辙开展了大量的相关研究。基于材料和试验方法 2个方面综述了沥青混合料抗车辙的研究进展。用于摊铺沥青路面的沥青混合料主要由沥青和集料组成,因此对不同改性沥青进行了汇总,并分析了不同改性沥青对沥青混合料抗车辙性能的影响;基于级配、形态和运动状态等因素对沥青混合料中的集料进行了研究,总结了不同集料对沥青混合料抗车辙变形性能的影响。目前,试验方法多集中于室内试验方法与数值模拟试验方法,基于室内试验总结了车辙试验和间接拉伸试验等多种方法,可用于评价沥青混合料抗车辙性能;基于数值模拟试验分别介绍了有限元和离散元2种方法,并总结了2种方法的特点。此外,综述了预估方法、AI算法等其他测试沥青混合料抗车辙的方法,为沥青路面抗车辙性能的相关研究提供了理论和技术参考。

关键词：路面工程沥青混合料抗车辙性能材料试验方法

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