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Unveiling oscillatory nature for sustainable fuel production

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National Science Review 2024年第05期11卷 90-91页

作者： ning han Ye Wang Bao-Lian Su Department of Materials Engineering State Key Laboratory of Physical Chemistry of Solid Surfaces Collaborative Innovation Center of Chemistry for Energy Materials National Engineering Laboratory for Green Chemical Productions of Alcohols Ethers and Esters College of Chemistry and Chemical Engineering Xiamen University Laboratory of Inorganic Materials Chemistry(CMI) University of Namur State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of Technology

A century ago, in 1923, Franz Fischer and hans Tropsch introduced the groundbreaking Fischer–Tropsch (FT) synthesis, a heterogeneous catalytic process used to convert synthesis gas (syngas,CO+H2) into multi-carbon hydrocarbons [1]. Over the past 100 years, FT synthesis has emerged as a pivotal method for converting non-petroleum resources into exceptionally clean fuels or valuable chemicals via syngas [2–4].

关键词： CO HYDROGENATION CATALYSTS BEHAVIOR KINETICS

Tungsten pnictides for water electrolysis:advances and perspectives

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Tungsten 2024年第4期6卷 675-695页

作者： Xue Kang Xi-han Tan ning han Jian-Feng Hou Chen-Min Yao Zhi-Jie Chen Bing-Jie Ni Department of Chemistry and Chemical Engineering Lyuliang University Department of Materials Engineering State Key Laboratory of Oral & Maxillofacial Reconstruction and Regeneration Key Laboratory of Oral Biomedicine Ministry of Education Hubei Key Laboratory of Stomatology School & Hospital of Stomatology Wuhan University School of Civil and Environmental Engineering The University of New South Wales

Hydrogen fuel is recognized as a promising energy carrier for the sustainable development of global energy system and the green hydrogen production via water electrolysis attracts great *** development of cost-effective electrocatalysts for water electrolysis is important for enhancing green hydrogen production ***,tungsten pnictides(phosphides and nitrides) have emerged as promising catalysts for water electrolysis,and efficient tungsten pnictide-based catalysts with different nanostructures,compositions,and surface chemical properties have been *** this review,recent progress in the design of tungsten pnictide-based electrocatalysts for water electrolysis is comprehensively *** synthesis of tungsten pnictide-based electrocatalysts are discussed ***,current achievements in developing efficient tungsten pnictide electrocatalysts for water electrolysis are detailed,and four key catalyst design strategies(i.e.,nanostructure control,heteroatom doping,defect engineering,and heterostructure design) are *** physicochemical properties-catalytic performance relationship of tungsten pnictide-based electrocatalysts is also *** last,perspectives in this field are put forward for guiding further research on the design and application of high-performance tungsten pnictide-based electrocatalysts.

关键词： Electrocatalysts Hydrogen evolution reaction Oxygen evolution reaction Tungsten nitrides Tungsten phosphides

Amorphous electrocatalysts for urea oxidation reaction

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Progress in Natural Science:Materials International 2024年第2期34卷 362-375页

作者： Fenghui Guo Dongle Cheng Qian Chen Hao Liu Zhiliang Wu ning han Bing-Jie Ni Zhijie Chen School of Materials Science and Technology China University of Geosciences Shenzhen Academy of Metrology and Quality Inspection Centre for Technology in Water and Wastewater School of Civil and Environmental Engineering University of Technology Sydney College of Safety and Environmental Engineering Shandong University of Science and Technology Institute of Yellow River Delta Earth Surface Processes and Ecological Integrity Shandong University of Science and Technology Discipline of Chemical Engineering Western Australian School of Mines: Minerals Energy and Chemical Engineering Curtin University Department of Materials Engineering School of Civil and Environmental Engineering The University of New South Wales

Electrochemical urea oxidation reaction(UOR) is a promising alternative to oxygen evolution reaction(OER) for realizing energy-saving hydrogen production. Developing efficient electrocatalysts for UOR becomes a central challenge. Recently, amorphous materials have been extensively used as UOR catalysts because of their numerous defective sites and flexible electronic properties. In this review, recent advancements in the development of amorphous UOR electrocatalysts are analyzed. The UOR mechanism is discussed, and the design of amorphous catalysts is then analyzed. The main catalyst design strategies are illustrated, including nanostructure control,heteroatom doping, composition regulation, and heterostructure construction. Also, electrocatalysts' structureperformance correlation is interpreted. Perspectives in this field are proposed for guiding future studies on the development of high-performance amorphous catalysts towards energy sustainability.

关键词： Catalyst design Hydrogen energy Heterostructures Heteroatom doping Component regulation

Carbon dot-based artificial light-harvesting systems with sequential energy transfer and white light emission for photocatalysis

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Chinese Chemical Letters 2024年第4期35卷 409-413页

作者： Chaoqun Ma Yuebo Wang ning han Rongzhen Zhang Hui Liu Xiaofeng Sun Lingbao Xing School of Chemistry and Chemical Engineering Shandong University of TechnologyZibo 255000China Department of Materials Engineering KU LeuvenLeuven 3001Belgium

In this work, we designed and synthesized cationic carbon dots(CDs) with a size distribution of 1.6–3.7 nm, which exhibited dark blue fluorescence in the aqueous solution. Based on its excellent luminescence properties, we used it as an energy donor to construct a sequential artificial light-harvesting system(LHS) by employing the energy-matching dyes eosin Y disodium salt(EY) and sulforhodamine101(SR101), which could regulate the white light emission(Commission Internationale de l'Eclairage(CIE) coordinate:(0.30, 0.31)) with the energy transfer efficiency(ΦET) of 53.9% and 20.0%. Moreover, a single-step artificial LHS with white light emission(0.32, 0.28) can be constructed directly using CDs and dye solvent 43(SR) with ΦETand antenna effect(AE) of 48.8% and 6.5, respectively. More importantly,CDs-based artificial LHSs were firstly used in photocatalytic of α-bromoacetophenone, with a yield of90%. This work not only provides a new strategy for constructing CDs-based LHSs, but also opens up a new application for further applying the energy harvested in CDs-based LHSs to the field of the aqueous solution photocatalysis.

关键词： Carbon dots White light emission Energy transfer Antenna effect Artificial light-harvesting system Photocatalysis

Peroxidase-like active Cu-ZIF-8 with rich copper(I)-nitrogen sites for excellent antibacterial performances toward drug-resistant bacteria

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Nano Research 2024年第8期17卷 7427-7435页

作者： Xiaoze Wang Hui Wang Jingkun Zhang ning han Wenjun Ma Donghai Zhang Mingshui Yao Xianliang Wang Yunfa Chen State Key Laboratory of Mesoscience and Engineering Institute of Process EngineeringChinese Academy of SciencesBeijing 100190China University of the Chinese Academy of Sciences Beijing 100049China Laboratory of Theoretical and Computational Nanoscience CAS Key Laboratory of Nanosystem and Hierarchial FabricationCAS Center for Excellence in NanoscienceNational Center for Nanoscience and TechnologyBeijing 100190China China CDC Key Laboratory of Environment and Population Health National Institute of Environmental HealthChinese Center for Disease Control and PreventionBeijing 100021China

Bacterial pathogens pose a serious threat to human health,and there is an urgent need to develop highly effective antibacterial materials to eliminate the increasingly serious contamination of drug-resistant ***,a Cu-doped ZIF-8 particle with unsaturated copper exhibits high peroxidase-like activity.99.998%antibacterial efficiency against *** can be achieved for 30 min at a low concentration of 50μg·mL^(−1),as well as complete sterilization against ***(up to 8 log).99.999%antibacterial efficiency against Methicillin-resistant Staphylococcus aureus can be achieved,performing orders of magnitude higher than *** mechanism shows that the unsaturated Cu-Nx sites are enzyme-like active centers,which could promote the consumption of bacteria reducing substances by H_(2)O_(2),and the generated*OH further aggravates bacterial oxidative stress and membrane *** importantly,the oxidation activity of adsorbed oxygen species on Cu-ZIF-8 is enhanced by charge transfer and structural changes between the ligand and copper center like natural ***-doped ZIF-8 with peroxidase-like activity shows great potential in antibacterial application and the revealed catalytic mechanism is helpful for understanding the high antibacterial activity of nanoparticles with Cu-Nx sites.

关键词： Cu-doped ZIF-8 peroxidase-like reactive oxygen species(ROS) catalytic mechanism antibacterial activity

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基于多域特征提取的水下目标材料分类方法

东南大学学报（自然科学版） 2024年第3期54卷 781-788页

作者：韩宁王祎庭东南大学信息科学与工程学院南京211189

针对水下目标材料的分类问题,提出了一种基于多域特征提取的水下目标材料分类方法.将目标回波信号的时域自回归(AR)系数、倒谱域特征、时频联合域的谱峰及谱峰频率相结合,实现了对金属、岩石、塑料、橡胶4类水下目标材料的分类,并利用... 详细信息

针对水下目标材料的分类问题,提出了一种基于多域特征提取的水下目标材料分类方法.将目标回波信号的时域自回归(AR)系数、倒谱域特征、时频联合域的谱峰及谱峰频率相结合,实现了对金属、岩石、塑料、橡胶4类水下目标材料的分类,并利用消声水池的实测数据来验证该方法的有效性.结果表明,对于4类材料的仿真数据,所提方法的分类正确率均高于80%,且利用多域特征的效果明显优于利用单一特征.对于塑料和金属的实测数据,在信混比不小于0 dB时,所提方法的分类正确率可达80%以上.该方法对目标大小或形状等几何特征的差异具有较好的鲁棒性.

关键词：水下目标回波特征提取材料分类

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政府合同概念的体系化重构

上海交通大学学报（哲学社会科学版） 2024年第2期32卷 63-83页

作者：韩宁浙江工商大学法学院杭州310018

现有政府合同管理规范对政府合同的内涵和外延进行了界定,但学理意义上的概念构造尚未完成,“政府合同=行政协议+缔结主体一方为行政机关的民事合同”之结论存在缺陷。通过把合同还原为通用于各部门法的中性工具,将政府合同的研究视角... 详细信息

现有政府合同管理规范对政府合同的内涵和外延进行了界定,但学理意义上的概念构造尚未完成,“政府合同=行政协议+缔结主体一方为行政机关的民事合同”之结论存在缺陷。通过把合同还原为通用于各部门法的中性工具,将政府合同的研究视角从救济前移至行政过程,政府合同的识别标准被调整为“行政机关与任何主体订立的合同均为政府合同”。以行政任务为出发点,可将政府合同区分为公务型政府合同和管理型政府合同,公务型政府合同可被进一步区分为内部公务型政府合同与外部公务型政府合同。以救济途径为落脚点,可以将政府合同区分为行政协定与非行政协定,非行政协定可被进一步区分为行政协议、民事合同、磋商性文件和劳动人事协议,其中,民事合同和行政协议属于狭义政府合同。将两条基于不同场景的体系化路径进行对接与融合,有助于形成对政府合同概念相对立体的认知,动态还原政府合同概念的全貌。

关键词：政府合同行政协议合同行政协定公务型政府合同管理型政府合同

Topological phases and edge modes of an uneven ladder

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Chinese Physics B 2024年第8期33卷 154-168页

作者：商文创韩熠宁 Shimpei Endo 高超 Department of Physics Zhejiang Normal UniversityJinhua 321004China Key Laboratory of Optical Information Detection and Display Technology of Zhejiang Zhejiang Normal UniversityJinhua 321004China Department of Engineering Science The University of Electro-CommunicationsTokyo 182-8585Japan

We investigate the topological properties of a two-chain quantum ladder with uneven legs,i.e.,the two chains differ in their periods by a factor of *** an uneven ladder presents rich band structures classified by the closure of either direct or indirect *** also provides opportunities to explore fundamental concepts concerning band topology and edge modes,including the difference of intracellular and intercellular Zak phases,and the role of the inversion symmetry(IS).We calculate the Zak phases of the two kinds and find excellent agreement with the dipole moment and extra charge *** also find that configurations with IS feature a pair of degenerate two-side edge modes emerging as the closure of the direct bandgap,while configurations without IS feature one-side edge modes emerging as not only the closure of both direct and indirect bandgaps but also within the band ***,by projecting to the two sublattices,we find that the effective Bloch Hamiltonian corresponds to that of a generalized Su–Schrieffer–Heeger model or the Rice–Mele model whose hopping amplitudes depend on the *** this way,the topological phases can be efficiently extracted through winding *** propose that uneven ladders can be realized by spin-dependent optical lattices and their rich topological characteristics can be examined by near future experiments.

关键词： ladder model symmetry-protected topological phase topological invariant bulk-boundary correspondence

Effect of inflammatory response on joint function after hip fracture in elderly patients:A clinical study

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World Journal of Orthopedics 2024年第4期15卷 337-345页

作者： Jia-Ming Wang Yu-Tao Pan Chen-Song Yang Ming-Chong Liu Sheng-Chao Ji ning han Fang Liu Gui-Xin Sun Department of Traumatic Surgery Shanghai East HospitalSchool of MedicineTongji UniversityShanghai 200092China

BACKGROUND Excellent hip joint function facilitates limb recovery and improves the quality of *** study aimed to investigate the potential risk factors affecting postoperative joint functional activity and outcomes in elderly hip fractures patients and to provide evidence for patient rehabilitation and clinical *** To explore the relationship between inflammatory factors and hip function and the interaction between inflammation and health after hip fracture in elderly *** The elderly patients who had hip fracture surgery at our hospital between January 1,2021,and December 31,2022 were chosen for this retrospective clinical *** with excellent and fair postoperative hip function had their clinical information and characteristics gathered and ***,gender,fracture site,surgical technique,laboratory indices,and other variables that could have an impact on postoperative joint function were all included in a univariate *** further identify independent risk factors affecting postoperative joint function in hip fractures,risk factors that showed statistical significance in the univariate analysis were then included in a multiple logistic regression *** addition to this,we also compared other outcome variables such as visual analogue scale and length of hospital stay between the two *** A total of 119 elderly patients with hip fractures were included in this study,of whom 37 were male and 82 were *** results of univariate logistic regression analysis after excluding the interaction of various factors showed that there was a statistically significant difference in interleukin(IL)-6,IL-8,IL-10,C-reactive protein(CRP),and complement C1q(C1q)between the fair and excellent joint function groups(P20 pg/mL[Odds ratio(OR)3.070,95%CI:1.243-7.579],IL-8>21.4 pg/mL(OR 3.827,95%CI:1.498-9.773),CRP>10 mg/L(OR 2.142,95%CI:1.

关键词： Hip function Fracture Inflammatory factors Risk factors Prevention