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Polarizable Additive with Intermediate Chelation Strength for Stable Aqueous Zinc‑Ion Batteries

Nano-Micro Letters 2024年第5期16卷 41-55页

作者： Yuting Xia Rongao Tong Jingxi Zhang Mingjie Xu Gang Shao hailong wang Yanhao Dong Chang‑An wang State Key Lab of New Ceramics and Fine Processing School of Materials Science and EngineeringTsinghua UniversityBeijing 100084People’s Republic of China School of Materials Science and Engineering Zhengzhou UniversityZhengzhou 450001HenanPeople’s Republic of China

Aqueous zinc-ion batteries are promising due to inherent safety,low cost,low toxicity,and high volumetric capacity.However,issues of dendrites and side reactions between zinc metal anode and the electrolyte need to be solved for extended storage and cycle life.Here,we proposed that an electrolyte additive with an intermediate chelation strength of zinc ion—strong enough to exclude water molecules from the zinc metal-electrolyte interface and not too strong to cause a significant energy barrier for zinc ion dissociation—can benefit the electrochemical stability by suppressing hydrogen evolution reaction,overpotential growth,and den-drite formation.Penta-sodium diethylene-triaminepentaacetic acid salt was selected for such a purpose.It has a suitable chelating ability in aqueous solutions to adjust solvation sheath and can be readily polarized under electrical loading conditions to further improve the passivation.Zn||Zn symmetric cells can be stably operated over 3500 h at 1 mA cm^(-2).Zn||NH4V4O10 full cells with the additive show great cycling stability with 84.6%capacity retention after 500 cycles at 1 A g^(-1).Since the additive not only reduces H2 evolution and corrosion but also modifies Zn2+diffusion and deposition,highlyreversible Zn electrodes can be achieved as verified by the experimental results.Our work offers a practical approach to the logical design of reliable electrolytes for high-performance aqueous batteries.

关键词： Aqueous zinc-ion batteries Electrolyte additives DTPA-Na Chelation strength

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Porous high-entropy rare-earth phosphate(REPO_(4),RE=La,Sm,Eu,Ce,Pr and Gd)ceramics with excellent thermal insulation performance via pore structure tailoring

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International Journal of Minerals,Metallurgy and Materials 2024年第7期31卷 1651-1658页

作者： Peixiong Zhang Enhui wang Jingjing Liu Tao Yang hailong wang Xinmei Hou Institute for Carbon Neutrality University of Science and Technology BeijingBeijing 100083China Liaoning Academy of Materials Shenyang 110000China Technical Support Center for Prevention and Control of Disastrous Accidents in Metal Smelting University of Science and Technology BeijingBeijing 100083China School of Materials Science Engineering Zhengzhou UniversityZhengzhou 450001China

Thermal insulation materials play an increasingly important role in protecting mechanical parts functioning at high temperatures.In this study,a new porous high-entropy(La_(1/6)Ce_(1/6)Pr_(1/6)Sm_(1/6)Eu_(1/6)Gd_(1/6))PO_(4)(HE(6RE_(1/6))PO_(4))ceramics was prepared by combining the high-entropy method with the pore-forming agent method and the effect of different starch contents(0–60vol%)on this ceramic properties was systematically investigated.The results show that the porous HE(6RE_(1/6))PO_(4)ceramics with 60vol%starch exhibit the lowest thermal conductivity of 0.061 W·m^(-1)·K^(-1)at room temperature and good pore structure stability with a linear shrinkage of approximately1.67%.Moreover,the effect of large regular spherical pores(>10μm)on its thermal insulation performance was discussed,and an optimal thermal conductivity prediction model was screened.The superior properties of the prepared porous HE(6RE_(1/6))PO_(4)ceramics allow them to be promising insulation materials in the future.

关键词： porous high-entropy(La_(1/6)Ce_(1/6)Pr_(1/6)Sm_(1/6)Eu_(1/6)Gd_(1/6))PO_(4) ceramics high-entropy strategy pore-forming agent method thermal insulation material thermal conductivity

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Realization of Low in-Band Harmonic for Compact 6–18-GHz T/R Module Under TX-Mode Operation

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Chinese Journal of Electronics 2024年第2期33卷 380-384页

作者： Jinming LAI Zhiyou LI Chaojie wang hailong wang Xiaohua MA School of Microelectronics Xidian University CETC 29th Research Institute

Wideband high power amplifier(PA) with poor harmonic suppression will degrade the performance of the active electronically scanned array(AESA) due to its harmonic products falling into the operating bandwidth of a wideband T/R module. In view of this, a compact reconfigurable harmonic suppress circuit(HSC) is proposed to achieve low in-band harmonic for compact T/R module with multiple octaves under TX-mode operation. The HSC consists of eight microstrip resonant stubs with high impedance and multiple p-i-n switches. By controlling the p-i-n switches, the HSC can work in three states. When six of the used p-i-n switches are “ON” state, the corresponding microstrip resonant stubs are loaded onto the 50 Ω transmission line, which performs a bandstop filter(BSF). For verification, the HSC with bandwidth of 12–15 GHz/15–18 GHz is designed to apply to a 6–18 GHz T/R module. As a result, the second harmonic of 6–9 GHz transmitting signal can be suppressed below 32 d Bc when compared to the PA's fundamental output. While the p-i-n switches are “OFF” state, the HSC is almost the same as a 50 Ω transmission line, which will have a little effect on the 9–18 GHz transmitting signal. The measurement results approximately agree with the calculated results and simulated results, which demonstrate the validity of the proposed HSC.

关键词： GaN power amplifier (PA) Harmonic suppression Low in-band harmonic p-i-n switch Wideband T/R module

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Ternary layered boride MoAlB:A novel thermo-regulation microwave absorbing ceramic material

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Journal of Advanced Ceramics 2024年第5期13卷 699-710页

作者： Zhangjue wang Fan Zhang Nannan wang Wei Li Yongqiang Chen hailong wang Rui Zhang Yanqiu Zhu Bingbing Fan School of Material Science and Engineering Zhengzhou UniversityZhengzhou 450001China Henan Academy of Sciences Zhengzhou 450046China State Key Laboratory of Featured Metal Materials and Life Cycle Safety for Composite Structures MOE Key Laboratory of New Processing Technology for Nonferrous Metals MaterialsSchool of ResourcesEnvironment and MaterialsGuangxi UniversityNanning 530004China Department of Materials and Earth Sciences Technical University of DarmstadtDarmstadt 64287Germany School of Material Science and Engineering Luoyang Institute of Science and TechnologyLuoyang 471023China Department of Engineering Faculty of EnvironmentScience and EconomyUniversity of ExeterExeter EX44QFUK

In the context of the fifth-generation(5G)smart era,the demand for electromagnetic wave(EMW)-absorbing materials has become increasingly prominent,so it is necessary to explore promising candidate materials.This work focuses on the exploration of the material absorbing properties of a MoAlB MAB(MAB represents a promising group of alternatives,where M stands for a transition metal,A typically denotes Al,and B is boron)phase system.First,the first-principles calculations were performed to reveal the unique crystal and layered structure of the MoAlB ceramics and to predict their potential for use as an EMW absorption material.Subsequently,a series of MoAlB ceramics were synthesized at temperatures ranging from 800 to 1300°C,and the influence of temperature on the phase compositions and microstructures of the obtained MoAlB ceramics was characterized and analyzed.Finally,the practical EMW absorption performance of the prepared MoAlB ceramics was evaluated via a combination of experiments and radar cross-sectional calculations.The MoAlB sample synthesized at 900°C exhibits superior EMW absorption performance,achieving an impressive minimum reflection loss(RL)of−50.33 dB.The unique layered structure and good electrical conductivity of the MoAlB samples are the main reasons for their enhanced wave absorption performance,which provides interfacial polarization and multiple dielectric loss mechanisms.Therefore,this study not only contributes to the understanding of the preparation of MoAlB materials but also provides potential guidance for their utilization in the realm of electromagnetic wave absorption.

关键词： MoAlB electronic band structure electromagnetic wave(EMW)absorption layered ternary boride density of states

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PVDF/6H-SiC composite fiber films with enhanced piezoelectric performance by interfacial engineering for diversified applications

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Journal of Materials Science & Technology 2024年第3期170卷 238-245页

作者： Linlin Zhou Tao Yang Chunyu Guo Kang wang Enhui wang Laipan Zhu hailong wang Sheng Cao Kuo-Chih Chou Xinmei Hou Institute for Carbon Neutrality University of Science and Technology BeijingBeijing 100083China Beijing Institute of Nanoenergy and Nanosystems Chinese Academy of SciencesBeijing 101400China School of Materials Science Engineering Zhengzhou UniversityZhengzhou 450001China State Key Laboratory of Featured Metal Materials and Life-cycle Safety for Composite Structures Guangxi UniversityNanning 530004China

Piezoelectric silicon carbide(SiC)has been quite attractive due to its superior chemical and physical properties as well as wide potential applications.However,the inherent brittleness and unsatisfactory piezoelectric response of piezoelectric semiconductors remain the major obstacles to their diversified applications.Here,flexible multifunctional PVDF/6H-SiC composite fiber films are fabricated and utilized to assemble both piezoelectric nanogenerators(PENGs)and stress/temperature/light sensors.The open cir-cuit voltage(V_(oc))and the density of short circuit current(I_(sc))of the PENG based on the PVDF/5 wt%6H-SiC composite fiber films reach 28.94 V and 0.24μA cm^(-2),showing a significant improvement of 240%and 300%compared with that based on the pure PVDF films.The effect of 6H-SiC nanoparticles(NPs)on inducing interfacial polarization and stress concentration in composite fiber films is proved by first-principles calculation and finite element analysis.The stress/temperature/light sensors based on the composite fiber film also show high sensitivity to the corresponding stimuli.This study shows that the PVDF/6H-SiC composite fiber film is a promising candidate for assembling high-performance energy harvesters and diverse sensors.

关键词： 6H-SiC PVDF Multifunctional composite fiber film Energy harvester Stress/temperature/light sensor

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Improved damage tolerance and oxidation resistance of (Ti_(0.2)Zr_(0.2)Hf_(0.2)Nb_(0.2)Ta_(0.2))B_(2)–SiC by introducing chopped carbon fibers

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Journal of Advanced Ceramics 2024年第1期13卷 101-112页

作者： Feilong Huang hailong wang Cheng Fang Mingliang Li Gang Shao Jinpeng Zhu Yanchun Zhou School of Materials Science and Engineering Zhengzhou UniversityZhengzhou 450001China

High-entropy diborides(HEBs)are considered as promising high-temperature structure materials owing to their high melting point and excellent thermal stability.However,the intrinsic brittleness is the main obstacle that seriously limits their practical applications.To overcome with this obstacle,carbon fibers(Cf)with outstanding mechanical properties are used in the present work as a first attempt to improve the damage tolerance of HEBs.The as-prepared C_(f)/(Ti_(0.2)Zr_(0.2)Hf_(0.2)Nb_(0.2)Ta_(0.2))B_(2)–SiC composite(C_(f)/HEB–SiC)shows high relative density(97.9%)and good mechanical properties with flexural strength of 411±3 MPa and fracture toughness of 6.15±0.11 MPa·m^(1/2).More importantly,the damage tolerance parameter(Dt)has increased from 0.10 m^(1/2) for HEB–SiC to 0.29 m^(1/2) for C_(f)/HEB–SiC.Through microstructural analysis and Vickers indentation of the composite,the toughening mechanisms are disclosed.The carbon fibers coated with carbon coatings demonstrate unique capacity for prolonging the crack propagation path,which promotes the reliability of the composite effectively.Moreover,the C_(f)/(Ti_(0.2)Zr_(0.2)Hf_(0.2)Nb_(0.2)Ta_(0.2))B_(2)–SiC composite also exhibits good static oxidation resistance in the temperature range of 1100–1500℃in air due to the formation of the protective oxide layer constituting of multicomponent oxides(Zr)HfTiO4 and(Zr)Hf_(6)Ta_(2)O_(17) embedded in a continuous SiO_(2) glass.These results are promising,and this primary work can be used as a reference to the synthesis of C_(f)/HEBs for thermal protection materials under hightemperature serving conditions.

关键词： high-entropy ceramics carbon fibers(Cf) toughening mechanisms oxidation resistance

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Microstructure,elastic/mechanical and thermal properties of CrTaO_(4):A new thermal barrier material?

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Journal of Advanced Ceramics 2024年第3期13卷 373-387页

作者： Shuang Zhang Xiaohui wang Chao Zhang Huimin Xiang Yingwei Li Cheng Fang Mingliang Li hailong wang Yanchun Zhou School of Materials Science and Engineering Zhengzhou UniversityZhengzhou 450001China Shenyang National Laboratory for Materials Science Institute of Metal ResearchChinese Academy of SciencesShenyang 110016China School of Civil Engineering Wuhan UniversityWuhan 430072China

CrTaO_(4)(or Cr_(0.5)Ta_(0.5)O_(2))has been unexpectedly found to play a decisive role in improving the oxidation resistance of Cr and Ta-containing refractory high-entropy alloys(RHEAs).This rarely encountered complex oxide can effectively prevent the outward diffusion of metal cations from the RHEAs.Moreover,the oxidation kinetics of CrTaO_(4)-forming RHEAs is comparable to that of the well-known oxidation resistant Cr_(2)O_(3)-and Al_(2)O_(3)-forming Ni-based superalloys.However,CrTaO_(4)has been ignored and its mechanical and thermal properties have yet to be studied.To fill this research gap and explore the untapped potential for its applications,here we report for the first time the microstructure,mechanical and thermal properties of CrTaO_(4)prepared by hot-press sintering of solid-state reaction synthesized powders.Using the HAADF and ABF-STEM techniques,rutile crystal structure was confirmed and short range ordering was directly observed.In addition,segregation of Ta and Cr was identified.Intriguingly,CrTaO_(4)exhibits elastic/mechanical properties similar to those of yttria stabilized zirconia(YSZ)with Young’s modulus,shear modulus,and bulk modulus of 268,107,and 181 GPa,respectively,and Vickers hardness,flexural strength,and fracture toughness of 12.2±0.44 GPa,142±14 MPa,and 1.87±0.074 MPa·m^(1/2).The analogous elastic/mechanical properties of CrTaO_(4)to those of YSZ has spurred inquiries to lucrative leverage it as a new thermal barrier material.The measured melting point of CrTaO_(4)is 2103±20 K.The anisotropic thermal expansion coefficients areα_(a)=(5.68±0.10)×10^(-6)K^(-1),α_(c)=(7.81±0.11)×10^(-6)K^(-1),with an average thermal expansion coefficient of(6.39±0.11)×10^(-6)K^(-1).The room temperature thermal conductivity of CrTaO_(4)is 1.31 W·m^(-1)·K^(-1)and declines to 0.66 W·m^(-1)·K^(-1)at 1473 K,which are lower than most of the currently well-known thermal barrier materials.From the perspective of matched thermal expansion coefficient,CrTaO_(4)pertains to an eligible thermal barrier material fo

关键词： microstructure synthesis thermal conductivity thermal expansion coefficient melting point CrTaO_(4) mechanical and thermal properties

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Structural evolution and high-temperature sensing performance of polymer-derived SiAlBCN ceramics

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Journal of Advanced Ceramics 2024年第4期13卷 478-485页

作者： Chao Ma Kun Liu Pengfei Shao Daoyang Han Kang wang Mengmeng Yang Rui Zhao hailong wang Rui Zhang Gang Shao School of Materials Science and Engineering Zhengzhou UniversityZhengzhou 450001China Zhongyuan Critical Metal Laboratory Zhengzhou UniversityZhengzhou 450001China State Key Laboratory of Structural Analysis Optimization and CAE Software for Industrial EquipmentZhengzhou UniversityZhengzhou 450002China

In situ temperature monitoring has become extremely imperative in high-temperature harsh environments and polymer-derived ceramics(PDCs)as sensing materials have attracted great attention.However,the stability and oxidation/corrosion resistance of PDCs cannot be simultaneously achieved at the moment,limiting their practical application.Herein,polymer-derived SiAlBCN ceramics were synthesized via polymer conversion method under different pyrolysis temperatures.Their microstructure evolution,high temperature sensing properties,and stability were investigated in detail.The results show that the amorphous SiAlBCN phase grows more orderly and the size of the free carbon phase enlarges with the increasing temperature.The defect concentration displays a decreasing tendency.Concurrently,the SiAlBCN ceramics as sensing materials exhibit a good temperature-resistance property from roo temperature to 1100℃.The fabricated SiAlBCN temperature sensor possesses excellent stability,repeatability,and accuracy.Moreover,SiAlBCN ceramics exhibit distinguished oxidation/corrosion resistance after 100 h treatment at 1200℃in a water/oxygen environment,which is attributed to their low corrosive rate constant(0.57 mg/(cm^(2)·h))and oxidative rate constant(3.43 mg^(2)/(cm^(4)·h)).Therefore,polymer-derived SiAlBCN ceramics as sensing materials,which possess outstanding stability and oxidation/corrosion resistance,have great potential for in-situ monitoring of extreme environmental temperatures in the future.

关键词： polymer-derived SiAlBCN ceramics temperature sensor harsh environments oxidation and corrosion resistance

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Enhanced electromagnetic wave absorption via optical fiber-like PMMA@Ti_(3)C_(2)T_(x)@SiO_(2) composites with improved impedance matching

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Nano Research 2024年第3期17卷 1676-1686页

作者： Huanhuan Niu Xuewen Jiang Wei Li Zhiyu Min Budi Riza Putra Wulan Tri Wahyuni hailong wang Rui Zhang Bingbing Fan School of Material Science and Engineering Zhengzhou UniversityZhengzhou 450001China School of Materials Science and Engineering Tongji UniversityShanghai 201804China Department of Materials and Earth Sciences Technical University of DarmstadtDarmstadt 64287Germany School of Material Science and Engineering Luoyang Institute of Science and TechnologyLuoyang 471023China Research Center for Metallurgy National Research and Innovation Agency(BRIN)PUSPIPTEK Gd.470South TangerangBanten 15315Indonesia Analytical Chemistry Division Department of ChemistryFaculty of Mathematics and Natural SciencesIPB UniversityWest Java 16680Indonesia

Ti_(3)C_(2)T_(x) nanosheets have attracted significant attention for their potential in electromagnetic wave absorption(EWA).However,their inherent self-stacking and exorbitant electrical conductivity inevitably lead to serious impedance mismatch,restricting their EWA application.Therefore,the optimization of impedance matching becomes crucial.In this work,we developed polymethyl methacrylate(PMMA)@Ti_(3)C_(2)T_(x)@SiO_(2) composites with a sandwich-like core–shell structure by coating SiO_(2) on PMMA@Ti_(3)C_(2)T_(x).The results demonstrate that the superiority of the SiO_(2) layer in combination with PMMA@Ti_(3)C_(2)T_(x),outperforming other relative graded distribution structures and meeting the requirements of EWA equipment.The resulting PMMA@Ti_(3)C_(2)T_(x)@SiO_(2) composites achieved a minimum reflection loss of-58.08 dB with a thickness of 1.9 mm,and an effective absorption bandwidth of 2.88 GHz.Mechanism analysis revealed that the structural design of SiO_(2) layer not only optimized impedance matching,but also synergistically enhanced multiple loss mechanisms such as interfacial polarization and dipolar polarization.Therefore,this work provides valuable insights for the future preparation of high-performance electromagnetic wave absorbing Ti_(3)C_(2)T_(x)-based composites.

关键词： polymethyl methacrylate(PMMA)@Ti_(3)C_(2)T_(x)@SiO_(2)composites impedance match SiO_(2)layer optical fiber-like structure interfacial polarization and dipolar polarization

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Porous framework materials for energy&environment relevant applications:A systematic review

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Green Energy & Environment 2024年第2期9卷 217-310页

作者： Yutao Liu Liyu Chen Lifeng Yang Tianhao Lan Hui wang Chenghong Hu Xue Han Qixing Liu Jianfa Chen Zeming Feng Xili Cui Qianrong Fang hailong wang Libo Li Yingwei Li Huabin Xing Sihai Yang Dan Zhao Jinping Li College of Chemical Engineering and Technology Shanxi Key Laboratory of Gas Energy Efficient and Clean UtilizationTaiyuan University of TechnologyTaiyuan030024China School of Chemistry and Chemical Engineering South China University of TechnologyGuangzhou510640China Key Laboratory of Biomass Chemical Engineering of Ministry of Education College of Chemical and Biological EngineeringZhejiang UniversityHangzhou310027China Department of Chemistry The University of ManchesterManchesterM139PLUK Department of Chemical and Biomolecular Engineering National University of SingaporeSingapore 117585Singapore ZJU-Hangzhou Global Scientific and Technological Innovation Center Hangzhou311215China State Key Laboratory of Inorganic Synthesis and Preparative Chemistry Jilin UniversityChangchun130012China Beijing Key Laboratory for Science and Application of Functional Molecular and Crystalline Materials Department of ChemistryUniversity of Science and Technology BeijingBeijing100083China

Carbon peaking and carbon neutralization trigger a technical revolution in energy&environment related fields.Development of new technologies for green energy production and storage,industrial energy saving and efficiency reinforcement,carbon capture,and pollutant gas treatment is in highly imperious demand.The emerging porous framework materials such as metal–organic frameworks(MOFs),covalent organic frameworks(COFs)and hydrogen-bonded organic frameworks(HOFs),owing to the permanent porosity,tremendous specific surface area,designable structure and customizable functionality,have shown great potential in major energy-consuming industrial processes,including sustainable energy gas catalytic conversion,energy-efficient industrial gas separation and storage.Herein,this manuscript presents a systematic review of porous framework materials for global and comprehensive energy&environment related applications,from a macroscopic and application perspective.

关键词： Porous framework materials Catalysis Separation Gas storage Carbon neutrality

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