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From waste to wealth:Coal tar residue derived carbon materials as low-cost anodes for potassium-ion batteries

International Journal of Minerals,Metallurgy and Materials 2025年第2期32卷 464-475页

作者： Zhonghua Lu jun Shen Xin Zhang Lingcong Chao Liang Chen Ding Zhang Tao Wei Shoudong Xu College of Chemical Engineering and Technology Taiyuan University of TechnologyTaiyuan 030024China College of Chemistry Taiyuan University of TechnologyTaiyuan 030024China School of Chemical Engineering and Pharmacy Wuhan Institute of TechnologyWuhan 430205China School of Energy and Power Jiangsu University of Science and TechnologyZhenjiang 212003China

Carbon materials are widely recognized as highly promising electrode materials for various energy storage system *** tar residues(CTR),as a type of carbon-rich solid waste with high value-added utilization,are crucially important for the development of a more sustainable *** this study,we employed a straightforward direct carbonization method within the temperature range of 700-1000℃to convert the worthless solid waste CTR into economically valuable carbon materials as anodes for potassium-ion batteries(PIBs).The effect of carbonization temperature on the microstructure and the potassium ions storage properties of CTR-derived carbons(CTRCs)were systematically explored by structural and morphological characterization,alongside electrochemical performances *** on the co-regulation between the turbine layers,crystal structure,pore structure,functional groups,and electrical conductivity of CTR-derived carbon carbonized at 900℃(CTRC-900h),the electrode material with high reversible capacity of 265.6m Ah·g^(-1)at 50 m A·g^(-1),a desirable cycling stability with 93.8%capacity retention even after 100 cycles,and the remarkable rate performance for PIBs were ***,cyclic voltammetry(CV)at different scan rates and galvanostatic intermittent titration technique(GITT)have been employed to explore the potassium ions storage mechanism and electrochemical kinetics of *** indicate that the electrode behavior is predominantly governed by surface-induced capacitive processes,particularly under high current densities,with the potassium storage mechanism characterized by an“adsorption-weak intercalation”*** work highlights the potential of CTR-based carbon as a promising electrode material category suitable for high-performance PIBs electrodes,while also provides valuable insights into the new avenues for the high value-added utilization of CTR.

关键词： coal tar residue carbon materials anode potassium-ion batteries high value-added

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Reliability of flip-chip bonded RFID die using anisotropic conductive paste hybrid material

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Transactions of Nonferrous Metals Society of China 2011年第A01期21卷 175-181页

作者： jun-Sik LEE jun-Ki kim Mok-Soon kim Namhyun KANG Jong-hyun LEE Advanced Joining Technology Team/Microjoining Center Korea Institute of Industrial Technology(KITECH) Yeonsu-gu Incheon 406-840 Korea School of Materials Science & Engineering Inha University Department of Materials Science & Engineering Pusan National University Department of Materials Science & Engineering Seoul National University of Technology

A reliability of flip-chip bonded die as a function of anisotropic conductive paste (ACP) hybrid materials, bonding conditions, and antenna pattern materials was investigated during the assembly of radio frequency identification(RFID) inlay. The optimization condition for flip-chip bonding was determined from the behavior of bonding strength. Under the optimized condition, the shear strength for the antenna printed with paste-type Ag ink was larger than that for Cu antenna. Furthermore, an identification distance was varied from the antenna materials. Comparing with the Ag antenna pattern, the as-bonded die on Cu antenna showed a larger distance of identification. however, the long-term reliability of inlay using the Cu antenna was decreased significantly as a function of aging time at room temperature because of the bended shape of Cu antenna formed during the flip-chip bonding process.

关键词： RFID inlay ACP flip-chip, bonding process reliability

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Tribological properties of multilayer tetrahedral amorphous carbon coatings deposited by filtered cathodic vacuum arc deposition

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Friction 2021年第5期9卷 1292-1302页

作者： Young-jun JANG Jae-Il kim WooYoung LEE Jongkuk kim Department of Extreme Environmental Coatings Surface Technology DivisionKorea Institute of Materials Science(KIMS)Gyeongnam-do 51508Republic of Korea Department of Mechanical Science and Engineering Graduate School of EngineeringNagoya UniversityNagoya 464-8603Japan

Tetrahedral amorphous carbon(ta‐C)has emerged as an excellent coating material for improving the reliability of application components under high normal ***,we present the results of our investigations regarding the mechanical and tribological properties of a 2‐μm‐thick multilayer ta‐C coating on high‐speed steel *** composed of alternating soft and hard layers are fabricated using filtered a cathodic vacuum arc with alternating substrate bias voltages(0 and 100 V or 0 and 150 V).The thickness ratio is discovered to be 1:3 for the sp2‐rich and sp3‐rich *** results show that the hardness and elastic modulus of the multilayer ta‐C coatings increase with the sp3 content of the hard *** hardness reached approximately 37 GPa,whereas an improved toughness and a higher adhesion strength(>29 N)are *** friction performance(μ=0.07)of the multilayer coating is similar to that of the single layer ta‐C thick coating,but the wear rate(0.13×10^(–6) mm^(3)/(N∙m))improved under a high load of 30 *** further demonstrate the importance of the multilayer structure in suppressing crack propagation and increasing the resistance to plastic deformation(h3/E2)ratio.

关键词： tetrahedral amorphous carbon(ta‐C) filtered cathodic vacuum arc deposition multilayer coatings alternating substrate bias voltage wear resistance plastic deformation resistance

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LiTFSI salt concentration effect to digest lithium polysulﬁdes for high-loading sulfur electrodes

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Journal of Energy Chemistry 2023年第3期78卷 574-581,I0015页

作者： Jin-Kwang Song Moonsoo kim Seongbae Park Young-jun kim SKKU Advanced Institute of Nano Technology(SAINT) Sungkyunkwan UniversitySuwon 16419Republic of Korea Department of Nano Engineering Sungkyunkwan UniversitySuwon 16419Republic of Korea

Sulfur utilization improvement and control of dissolved lithium polysulﬁde(LiPS;Li_(2)S x,2he development of lithium-sulfur(Li-S)batteries,especially in high-loading sulfur elec-trodes and low electrolyte/sulfur(E/S)*** sluggish reaction in the low E/S ratio induces poor LiPS solubility and unstable Li_(2)S electrodeposition,resulting in limited sulfur utilization,especially under high-loading sulfur *** this study,we report on salt concentration effects that improve sulfur utilization with a high-loading cathode(6 mgs ulfurcm^(-2)),a high sulfur content(80 wt%)and a low E/S ratio(5 m L gs ulfur^(-1)).On the basis of the rapid LiPS dissolving in a low concentration electrolyte,we estab-lished that the quantity of Li_(2)S electrodeposition from a high Li+diffusion coefﬁcient,referring to the reduction of LiPS precipitation,was signiﬁcantly enhanced by a faster *** results demonstrate the importance of kinetic factors for the rate capability and cycle life stability of Li-S battery electrolytes through high Li_(2)S deposition under high-loading sulfur electrode.

关键词： Lithium-sulfur battery Electrolyte concentration Li2S deposition high-loading sulfur electrode

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Conditional survival in patients with gallbladder cancer

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Chinese Journal of Cancer 2017年第12期36卷 744-756页

作者： Yi-jun kim Kyubo kim Department of Radiation Oncology Ewha Womans University College of Medicine1071 Anyangcheon.roYangcheon.guSeoul 07985Republic of Korea

Background: Conditional survival(CS) has been established as a clinically relevant prognostic factor for cancer survivors, and the CS in gallbladder(GB) cancer has not yet been fully evaluated. In this study, we evaluated the cancerspecific CS rate and cancer-specific survival(CSS) rate in patients with GB cancer at multiple time points and investigated prognostic factors which affect cancer-specific CS rate to provide more accurate survival ***: Between 2004 and 2013, a total of 9760 patients with GB cancer were identified from the Surveillance,Epidemiology, and End Results(SEER) data. The 3-year cancer-specific CS rate was calculated using the covariateadjusted survival function in the Cox model for each year since diagnosis, and the results were analyzed together with the adjusted CSS rates at the same time points. Cox proportional hazards regression was performed to ascertain the individual contribution of factors associated with CSS rate at diagnosis and cancer-specific CS rates at 1,3, and 5 years after ***: The adjusted 5-year CSS rate was 26.1 %. The adjusted 3-year cancer-specific CS rates at 1,2,3,4, and 5 years after diagnosis were 55.5,72.2,81.5,86.8, and 90.5%, respectively. At the time of diagnosis, age, race, histology, grade,T, N, and M categories, surgery, radiotherapy, insurance status, and marriage status were significant prognostic factors of CSS. Five years after diagnosis, however,T and M categories were significant prognostic factors for survivors(P = 0.007 and P = 0.009, respectively), whereas surgery and radiotherapy were ***: T and M categories were significant prognostic factors even 5 years after the initial diagnosis, whereas local treatments at the time of diagnosis were not, suggesting that patients with GB cancer at high risks might need further adjuvant therapy after primary treatments. The combined analysis of CSS and cancer-specific CS rates offered more accurate survival information for pa

关键词： Gallbladder cancer Conditional survival SEER

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Genetic-Based Keyword Matching DBSCAN in IoT for Discovering Adjacent Clusters

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Computer Modeling in Engineering & Sciences 2023年第5期135卷 1275-1294页

作者： Byoungwook kim hong-jun Jang Department of Computer Engineering Dongshin UniversityNaju58245Korea Department of Computer Science and Engineering Jeonju UniversityJeonju55069Korea

As location information of numerous Internet of Thing(IoT)devices can be recognized through IoT sensor technology,the need for technology to efficiently analyze spatial data is *** of the famous algorithms for classifying dense data into one cluster is Density-Based Spatial Clustering of Applications with Noise(DBSCAN).Existing DBSCAN research focuses on efficiently finding clusters in numeric data or categorical *** this paper,we propose the novel problem of discovering a set of adjacent clusters among the cluster results derived for each keyword in the keyword-based DBSCAN *** existing DBSCAN algorithm has a problem in that it is necessary to calculate the number of all cases in order to find adjacent clusters among clusters derived as a result of the *** solve this problem,we developed the Genetic algorithm-based Keyword Matching DBSCAN(GKM-DBSCAN)algorithm to which the genetic algorithm was applied to discover the set of adjacent clusters among the cluster results derived for each *** order to improve the performance of GKM-DBSCAN,we improved the general genetic algorithm by performing a genetic operation in *** conducted extensive experiments on both real and synthetic datasets to show the effectiveness of GKM-DBSCAN than the brute-force *** experimental results show that GKM-DBSCAN outperforms the brute-force method by up to 21 ***-DBSCAN with the index number binarization(INB)is 1.8 times faster than GKM-DBSCAN with the cluster number binarization(CNB).

关键词： Spatial clustering DBSCAN algorithm genetic algorithm textual information

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Production of Integrated Automotive Part in high Pressure Diecasting Process Using Salt Core

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Journal of Rare Earths 2004年第z2期22卷 57-60页

作者： Ki-Bae kim hyun-Kwang Seok jun-Su kim Advanced Materials Research Center Korea Institute of Science and TechnologyP.O.Box 131CheongryangSeoul130-650Korea Advanced Materials Research CenterKorea Institute of Science and TechnologyP.O.Box 131CheongryangSeoul130-650Korea Research & Development CenterTechnology Union Co.Ltd742-1Paeksok-dongChonan-siChungchongnam-do330-220Korea

A new concept of salt core, a melting temperature of which is lower than the solidus temperature of cast alloy,was introduced to produce an integrated casting part having a complicated inner shape or requiring under-cut in high pressure die casting or squeeze casting process. A salt core, named a fusible core in this paper because the salt core can be easily extracted just as holding at a temperature under a solidus temperature of a casting alloy, was developed and applied to produce a fuel control part for automotive GDI engine in high pressure diecasting machine. A different salt material of a lower melting temperature than that of A1 alloy was mixed with a different ceramic particulate to improve a thermo-physical property of fusible core. The thermo-physical property of the fusible core was measured and a weight faction of the ceramic particulate was optimized. The selected core materials were poured in metallic mold by gravity to produce a fusible core for a fuel control part for automotive GDI engine. The fuel control part, which the fusible core was included inside, was successful to fabricate in a conventional diecasting machine with no melting of fusible core during casting.

关键词： salt core high pressure diecasting casting part for automotive fusible core

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Closed-loop Control Using high Power hexapole Magnetic Tweezers for 3D Micromanipulation

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Journal of Bionic Engineering 2020年第1期17卷 113-122页

作者： Xiao Zhang Louis WRogowski Min jun kim Department of Mechanical Engineering Southern Methodist UniversityDallasTX 75275USA

This paper presents the design,modeling,integration,and application of 3D printed high power hexapole magnetic tweezers for 3D micromanipulation *** sharp-tipped magnetic poles were configured with electromagnetic coils and mounted on 3D printed magnetic yokes to form a tilted Cartesian coordinate system for actuation.A closed loop control algorithm was developed to automatically manipulate external power supplies connected to the magnetic tweezers,by using 3D positional information obtained from real-time image processing *** compared against other designs of magnetic tweezers,our system has a larger working space and can generate higher magnetic field *** allows for more diverse applications regarding small scale manipulation,including cell manipulation and cell *** and analytics explained in this paper demonstrate the closed-loop manipulation of microswimmers can provide a magnetic force as high as 800 pN while maintaining a positional error below 4μm in 3D and 1.6μm in *** the desired location as the control input,the microswimmers investigated were able to achieve arbitrary 2D and 3D *** also show that the implemented hexapole magnetic tweezers have adequate power to control microswimmers in Newtonian fluid *** system will later be optimized and deployed to control microswimmers in non-Newtonian fluid environments.

关键词： magnetic tweezers micromanipulation magnetic gradient control 3D motion control microswimmers

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Staged dendrite suppression for high safe and stable lithium-sulfur batteries

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Journal of Energy Chemistry 2025年第1期100卷 674-683页

作者： jun Jiang Zhenjie Lu Yanwen Ding Sh.jun Liu Zhijie Qi Tian Tang Yunfan Zhang Zhiyuan Ma Jingwen Sun Liang Xue Wenyao Zhang Pan Xiong Xin Wang junwu Zhu Yongsheng Fu Key Laboratory for Soft Chemistry and Functional Materials of Ministry of Education Nanjing University of Science and Technology Jiangsu Pylon Battery Co.Ltd

The unavoidable dendrite growth and shuttle effect have long been stranglehold challenges limiting the safety and practicality of lithium-sulfur ***,we propose a dual-action strategy to address the lithium dendrite issue in stages by constructing a multifunctional surface-negatively-charged nanodiamond layer with high ductility and robust puncture resistance on polypropylene （PP） *** uniformly loaded compact negative layer can not only significantly enhance electron transmission efficiency and promote uniform lithium deposition,but also reduce the formation of dendrite during early deposition *** importantly,under the strong puncture stress encountered during the deterioration of lithium dendrite growth under limiting current,the high ductility and robust puncture resistance（145.88 MPa） of as-obtained nanodiamond layer can effectively prevent short circuits caused by unavoidable lithium *** Li||Li symmetrical cells assembled with nanodiamond layer modified PP demonstrated a stable cycle of over 1000 h at 2 mA cm-2with a polarization voltage of only 29.3 ***,the negative charged layer serves as a physical barrier blocking lithium polysulfide ions,effectively mitigating capacity *** improved cells achieved a capacity decay of only 0.042%per cycle after 700 cycles at 3 C,demonstrating effective suppression of dendrite growth and capacity attenuation,showing promising prospect.

关键词： Ductility

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Development and application of a multi-step porcine in vitro system to evaluate feedstuffs and feed additives for their efficacy in nutrient digestion, digesta characteristics, and intestinal immune responses

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Animal Nutrition 2024年第2期17卷 265-282页

作者： hee Yeon kim jun-Ok Moon Sung Woo kim Application Center CJ Blossom Park Department of Animal Science North Carolina State University

In vitro model provides alternatives to the use of live animals in research. In pig nutrition, there has been a tremendous increase in in vivo research over the decades. Proper utilization of in vitro models could provide a screening tool to reduce the needs of in vivo studies, research duration, cost, and the use of animals and feeds. This study aimed to develop a multi-step porcine in vitro system to simulate nutrient digestion and intestinal epithelial immune responses affected by feedstuffs and feed additives. Seven feedstuffs(corn, corn distillers dried grains with solubles [corn DDGS], barley, wheat, soybean meal, soy protein concentrates, and Corynebacterium glutamicum cell mass [CGCM]), feed enzymes(xylanase and phytase), and supplemental amino acids(arginine, methionine, and tryptophan), were used in this in vitro evaluation for their efficacy on digestibility, digesta characteristics, and intestinal health compared with the results from previously published in vivo studies. All in vitro evaluations were triplicated. Data were analyzed using Mixed procedure of SAS9.4. Evaluations included(1) nutrient digestibility of feedstuffs,(2) the effects of feed enzymes, xylanase and phytase, on digestibility of feedstuffs and specific substrates, and(3) the effects of amino acids, arginine, tryptophan, and methionine, on anti-inflammatory, anti-oxidative, and anti-heat stress statuses showing their effects(P he measured items. Differences in dry matter and crude protein digestibility among the feedstuffs as well as effects of xylanase and phytase were detected(P haride profiles and phosphorus release from phytate. Supplementation of arginine, tryptophan, and methionine modulated(P he use of this in vitro model allowed the use of 3 experimental replications providing sufficient statistical power at P his indicates in vitro models can have increased prec

关键词： Digestion Feed additive Feedstuff In vitro Intestine Pig

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