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ThE PREPARATION AND ChARACTERISTICS STUDY OF TiN_xO_y SPECTRAL SELECTIVE ABSORBING FILM BY MAGNETRON SPUTTERING

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Acta Metallurgica Sinica(English Letters) 2005年第3期18卷 385-388页

作者： D.Chen h.Shen B.W.wang h.Q.wang MaterialandScienceEngineeringInstitute SouthChinaUniversityofTechnologyGuangzhou510641China EnergyEngineeringInstitute ZhongshanUniversityGuangzhou510275China／／GuangzhouInstituteofEnergyConversionTheChineseAcademyofSciencesGuangzhou510640China GuangzhouInstituteofEnergyConversion TheChineseAcademyofSciencesGuangzhou510640China SchoolofMechanismandAutomobile ShenyangInstituteofAeronauticalEngineeringShenyang110034China

Spectral selective absorbent film is a crucial factor for the solar heating devi ce. There are many kinds of spectral selective absorbing film made by different ways. TiNxOy thin film with excellent spectral selecting absobent property were successfully prepared by DC magnetron sputtering with Ar as working gas, N2 and O2 as reactive gas, 99.9% titanium as the target and is copper slice as the subs trate. In this article, the optical characteristics and microstructure of TiNxO y thin film were studied. Inputing O2 can decrease the reflection of the visible lights, and double layer film can get good absorption for solar energy.

关键词： spectrum selecting absorbent film TiNxOy magnetron sputtering

Flux focusing with a superconducting nanoneedle for scanning SQUID susceptometry

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Microsystems & Nanoengineering 2023年第3期9卷 411-417页

作者： B.K.Xiang S.Y.wang Y.F.wang J.J.Zhu h.T.Xu Y.h.wang State Key Laboratory of Surface Physics and Department of Physics FudanUniversity200433 ShanghaiChina Shanghai Research Center for Quantum Sciences 201315 ShanghaiChina

A nanofabricated superconducting quantum interference device(nano-SQUID)is a direct and sensitive flux probe used for magnetic imaging of quantum materials and mesoscopic *** to the functionalities of superconductive integrated circuits,nano-SQUIDs fabricated on chips are particularly versatile,but their spatial resolution has been limited by their planar ***,we use femtosecond laser 3-dimensional(3D)lithography to print a needle onto a nano-SQUID susceptometer to overcome the limits of the planar *** nanoneedle coated with a superconducting shell focused the flux from both the field coil and the *** performed scanning imaging with such a needle-on-SQUID(NoS)device on superconducting test patterns with topographic *** NoS showed improved spatial resolution in both magnetometry and susceptometry relative to the planarized *** work serves as a proof-of-principle for integration and inductive coupling between superconducting 3D nanostructures and on-chip Josephson nanodevices.

关键词： lithography SQUID needle

鹿角多肽调控SLC7A11/GPX4轴抑制地塞米松诱导的成骨细胞铁死亡

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中国组织工程研究 2025年第14期29卷 2875-2881页

作者：邵学坤王成王仪王平邱卓雅王欣如孙铁锋山东中医药大学山东省济南市250355 山东省中医药研究院山东省济南市250014 齐鲁理工学院山东省济南市273100

背景:激素性股骨头坏死与成骨细胞铁死亡密切相关,鹿角多肽可以通过抑制成骨细胞铁死亡,促进成骨细胞的存活与功能的建立,具有治疗激素性股骨头坏死的潜力,但其对成骨细胞铁死亡的调控机制尚未明确。目的:探究鹿角多肽抑制地塞米松诱导... 详细信息

背景:激素性股骨头坏死与成骨细胞铁死亡密切相关,鹿角多肽可以通过抑制成骨细胞铁死亡,促进成骨细胞的存活与功能的建立,具有治疗激素性股骨头坏死的潜力,但其对成骨细胞铁死亡的调控机制尚未明确。目的:探究鹿角多肽抑制地塞米松诱导成骨细胞铁死亡的作用机制。方法:①采用不同浓度梯度的鹿角多肽与地塞米松干预MC3T3-E114细胞,CCK-8法检测细胞活性,确定鹿角多肽与地塞米松的作用浓度;②采用不同质量浓度梯度鹿角多肽干预被地塞米松(800μmol/L)处理后的MC3T3-E114细胞,分为空白对照组、地塞米松组、地塞米松+鹿角多肽组,采用CCK-8法计算不同质量浓度鹿角多肽对地塞米松(800μmol/L)干预MC3T3-E114细胞增殖的影响;③借助试剂盒检测空白对照组、地塞米松组、地塞米松+鹿角多肽组中超氧化物歧化酶活性及谷胱甘肽、丙二醛、脂质过氧化物、细胞铁、活性氧含量的变化,并应用Western blot检测谷胱甘肽过氧化物酶4、溶质载体家族7成员11蛋白的表达,验证鹿角多肽抑制铁死亡的通路。结果与结论:①CCK-8法检测细胞活性,结果确定后续实验选择以鹿角多肽(10 mg/mL)和地塞米松(800μmol/L)干预MC3T3-E114细胞处理24 h;②地塞米松干预后,丙二醛、脂质过氧化物、细胞铁、活性氧含量均升高(P<0.01),谷胱甘肽含量、超氧化物歧化酶活性均降低(P<0.01),谷胱甘肽过氧化物酶4、溶质载体家族7成员11蛋白表达降低(P<0.05-0.01);鹿角多肽干预后,上述各指标变化明显被逆转(P<0.05-0.01);③结果表明,鹿角多肽可能通过调控溶质载体家族7成员11/谷胱甘肽过氧化物酶4轴抑制成骨细胞铁死亡,发挥对激素性股骨头坏死的治疗作用。

关键词：鹿角多肽地塞米松激素性股骨头坏死抑制成骨细胞铁死亡

Staged dendrite suppression for high safe and stable lithium-sulfur batteries

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Journal of Energy Chemistry 2025年第1期100卷 674-683页

作者： Jun Jiang Zhenjie Lu Yanwen Ding Shujun Liu Zhijie Qi Tian Tang Yunfan Zhang Zhiyuan Ma Jingwen Sun Liang Xue Wenyao Zhang Pan Xiong Xin wang Junwu Zhu Yongsheng Fu Key Laboratory for Soft Chemistry and Functional Materials of Ministry of Education Nanjing University of Science and Technology Jiangsu Pylon Battery Co.Ltd

The unavoidable dendrite growth and shuttle effect have long been stranglehold challenges limiting the safety and practicality of lithium-sulfur ***,we propose a dual-action strategy to address the lithium dendrite issue in stages by constructing a multifunctional surface-negatively-charged nanodiamond layer with high ductility and robust puncture resistance on polypropylene （PP） *** uniformly loaded compact negative layer can not only significantly enhance electron transmission efficiency and promote uniform lithium deposition,but also reduce the formation of dendrite during early deposition *** importantly,under the strong puncture stress encountered during the deterioration of lithium dendrite growth under limiting current,the high ductility and robust puncture resistance（145.88 MPa） of as-obtained nanodiamond layer can effectively prevent short circuits caused by unavoidable lithium *** Li||Li symmetrical cells assembled with nanodiamond layer modified PP demonstrated a stable cycle of over 1000 h at 2 mA cm-2with a polarization voltage of only 29.3 ***,the negative charged layer serves as a physical barrier blocking lithium polysulfide ions,effectively mitigating capacity *** improved cells achieved a capacity decay of only 0.042%per cycle after 700 cycles at 3 C,demonstrating effective suppression of dendrite growth and capacity attenuation,showing promising prospect.

关键词： Lithium-sulfur batteries Staged dendrite suppression Shuttle effect Surface-negatively-charged nanodiamond

Review on hydrogen Embrittlement of Press-hardened Steels for Automotive Applications

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Acta Metallurgica Sinica(English Letters) 2023年第7期36卷 1123-1143页

作者： Z.wang Q.Lu Z.h.Cao h.Chen M.X.huang J.F.wang General Motors China Science Lab Shanghai201206China Department of Mechanical Engineering The University of Hong KongPokfulam RoadHong Kong999077China Key Laboratory for Advanced Materials of Ministry of Education School of Materials Science and EngineeringTsinghua UniversityBeijing100084China

Press-hardened steel(PhS)with an ultimate tensile strength(UTS)of 1500 MPa has been widely used in automotive body-in-white in the last two decades,due to its ultra-high strength and excellent formability that is achieved by hot stamping ***,the application of PhS with UTS exceeding 1500 MPa in automotive industry could be deferred due to the increased risk of hydrogen *** reduce this kind of risk,recent research efforts have been focused on various ways to optimize the microstructure of *** present review intends to summarize these efforts,to highlight present solutions to address hydrogen embrittlement,and to shed light on directions for future *** influence of microstructure on the hydrogen embrittlement of PhS has been discussed in terms of both the steel substrate and the surface *** substrate part covers the influence of martensite,carbides,inclusions,and retained austenite,while the surface part covers decarburization and oxidation,pre-coating,and trimming.

关键词： hot stamping Press-hardened steels Coating-free hydrogen embrittlement Fracture Al-Si coating

Structures of Isodoternifolin A and B

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Chinese Chemical Letters 1996年第9期7卷 816-817页

作者： wang, ZM Feng, h Liang, XT ChINESE ACAD TRADIT ChINESE MED INST CHINESE MAT MEDBEIJING 100700PEOPLES R CHINA ChINESE ACAD MED SCI INST MAT MEDBEIJING 100050PEOPLES R CHINA

Two new diterpenoids, named isodoternifolins A(1) and B(2), together with seven known compounds were isolated from the ethanol extract of dried stems and leaves of Isodon ternifolius (D. Don) Kudo. The structures of 1 and 2 were determined as 7 beta-hydroxy-6 beta,11 alpha,15 beta-triacetoxy-7 alpha, 20-epoxy-entkaur-16-ene and 6 beta,7 beta,15 beta-trihydroxy-11 alpha-acetoxy-7 alpha,20-epoxy-entkaur-16-ene by chemical and spectral evidence respectively.

关键词： Structures of Isodoternifolin A and B

Critical Transitions of Microviscosity in Concentrated Polystyrene Solutions Revealed by Excimer Formation of Pyrenyl Probes

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Chinese Chemical Letters 1997年第6期8卷 543-546页

作者： Gao, h wang, GC he, BL NANKAI UNIV STATE KEY LAB FUNCT POLYMER MAT ADSORPT & SEPARATINST POLYMER CHEMTIANJIN 300071PEOPLES R CHINA

Excimer formation of pyrene and benzyl 4-(1-pyrenyl) butanoate was used to study the microviscosity of polystyrene/toluene solutions over the entire concentration range. Two critical concentrations (C(PS)similar to 0.32, 0.82g/ml) have been observed from the log-log plot of IB/IM vs C-PS. The results are explained in terms of the onset of cohesional interaction and the glass transition of the polymer chains, respectively.

关键词： Critical Transitions of Microviscosity in Concentrated Polystyrene Solutions Revealed by Excimer Formation of Pyrenyl Probes

Identification of resistant pharmaceuticals in ozonation using QSAR modeling and their fate in electro-peroxone process

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Frontiers of Environmental Science & Engineering 2021年第5期15卷 325-338页

作者： Majid Mustafa huijiao wang Richard h.Lindberg Jerker Fick Yujue wang Mats Tysklind Department of Chemistry UmeåUniversityUmeåS-90187Sweden School of Environment Beijing Key Laboratory for Emerging Organic Contaminants ControlState Key Joint Laboratory of Environmental Simulation and Pollution Control(Ministry of Education)Tsinghua UniversityBeijing100084China

The abatements of 89 pharmaceuticals in secondary effluent by ozonation and the electro-peroxone(E-peroxone)process were *** on the results,a quantitative structure-activity relationship(QSAR)model was developed to explore relationship between chemical structure of pharmaceuticals and their oxidation rates by *** orthogonal projection to latent structure(OPLS)method was used to identify relevant chemical descriptors of the pharmaceuticals,from large number of descriptors,for model *** resulting QSAR model,based on 44 molecular descriptors related to the ozone reactivity of the pharmaceuticals,showed high goodness of fit(R^(2)=0.963)and predictive power(Q^(2)=0.84).After validation,the model was used to predict second-order rate constants of 491 pharmaceuticals of special concern(k_(O_(3)))including the 89 studied *** predicted k_(O_(3))values and experimentally determined pseudo-first order rate constants of the pharmaceuticals’abatement during ozonation(k_(OZ))and the E-peroxone process(k_(EP))were then used to assess effects of switching from ozonation to the E-peroxone process on removal of these *** results indicate that the E-peroxone process could accelerate the abatement of pharmaceuticals with relatively low ozone reactivity(k_(O_(3))han ozonation(3–10 min versus 5–20 min).The validated QSAR model predicted 66 pharmaceuticals to be highly O_(3)-*** developed QSAR model may be used to estimate the ozone reactivity of pharmaceuticals of diverse chemistry and thus predict their fate in ozone-based processes.

关键词： Ozone Electro-peroxone Wastewater Quantitative structure activity relationship Advanced oxidation processes

The complex roles of m^(6)A modifications in neural stem cell proliferation, differentiation, and self-renewal and implications for memory and neurodegenerative diseases

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Neural Regeneration Research 2025年第6期20卷 1582-1598页

作者： Yanxi Li Jing Xue Yuejia Ma Ke Ye Xue Zhao Fangliang Ge Feifei Zheng Lulu Liu Xu Gao Dayong wang Qing Xia Department of Biochemistry and Molecular Biology College of Basic Medical SciencesHarbin Medical UniversityHarbinHeilongjiang ProvinceChina College of Basic Medical Sciences Harbin Medical UniversityHarbinHeilongjiang ProvinceChina Basic Medical Institute Heilongjiang Academy of Medical SciencesHarbinHeilongjiang ProvinceChina Key Laboratory of heilongjiang Province for Genetically Modified Animals Harbin Medical UniversityHarbinHeilongjiang ProvinceChina Translational Medicine Research and Cooperation Center of Northern China Heilongjiang Academy of Medical SciencesHarbinHeilongjiang ProvinceChina Dongzhimen hospital Beijing University of Chinese MedicineBeijingChina

N6-methyladenosine(m^(6)A), the most prevalent and conserved RNA modification in eukaryotic cells, profoundly influences virtually all aspects of mRNA metabolism. mRNA plays crucial roles in neural stem cell genesis and neural regeneration, where it is highly concentrated and actively involved in these processes. Changes in m^(6)A modification levels and the expression levels of related enzymatic proteins can lead to neurological dysfunction and contribute to the development of neurological diseases. Furthermore, the proliferation and differentiation of neural stem cells, as well as nerve regeneration, are intimately linked to memory function and neurodegenerative diseases. This paper presents a comprehensive review of the roles of m^(6)A in neural stem cell proliferation, differentiation, and self-renewal, as well as its implications in memory and neurodegenerative diseases. m^(6)A has demonstrated divergent effects on the proliferation and differentiation of neural stem cells. These observed contradictions may arise from the time-specific nature of m^(6)A and its differential impact on neural stem cells across various stages of development. Similarly, the diverse effects of m^(6)A on distinct types of memory could be attributed to the involvement of specific brain regions in memory formation and recall. Inconsistencies in m^(6)A levels across different models of neurodegenerative disease, particularly Alzheimer's disease and Parkinson's disease, suggest that these disparities are linked to variations in the affected brain regions. Notably, the opposing changes in m^(6)A levels observed in Parkinson's disease models exposed to manganese compared to normal Parkinson's disease models further underscore the complexity of m^(6)A's role in neurodegenerative processes. The roles of m^(6)A in neural stem cell proliferation, differentiation, and self-renewal, and its implications in memory and neurodegenerative diseases, appear contradictory. These inconsistencies may be a

关键词： Alzheimer's disease cell self-renewal central nervous system memory microglia nerve regeneration neurodegenerative diseases neurogenesis RNA methylation