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Metal-organic frameworks with dinuclear metal centers for synergistically boosting CO2 photoreduction

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Science China Chemistry 2025年第01期 201-208页

作者： hui-Feng Wang wen-Jie Shi Yu-Xin Yang Bao-Xia Dong Tong-Bu Lu Di-Chang Zhong School of Chemistry and Chemical Engineering Yangzhou University Institute for New Energy Materials and Low Carbon Technologies School of Materials Science and Engineering Tianjin University of Technology

Dinuclear metal synergistic catalysis （DMSC） has been proved powerful in boosting CO2reduction,while this has not been achieved in heterogeneous catalysts with long-range order *** this study,we,by introduction of metal catalytic centers into an indium-based metal-organic framework （MOF）,obtained a series of isostructural In-MOFs,including three MOFs with mononuclear metal catalytic center （M-In）,three MOFs with dinuclear homometallic catalytic centers （MM-In）,and three MOFs with dinuclear heterometallic catalytic centers (MM’-In,M/M’=Co（II）,Ni（II）,Zn（II）).It was found that all these MOFs can serve as catalysts for photochemical CO2reduction to *** with M-In,the catalytic activities of MM-In were obviously enhanced,and that of MM’-In was further significantly *** example,the CO yield of Co Zn-In reaches a record value of 12,700μmol g-1h-1,which is 4.0,8.1,9.4,and 18.6-fold higher than that of Co Co-In,Zn Zn-In,Co-In,and Zn-In,***,the catalytic activities of Co Ni-In and Ni Zn-In also show different fold increase than those of corresponding dinuclear homometallic and mononuclear metallic *** results of control experiments and theoretical calculation reveal that the higher catalytic activities of MM-In over M-In can be ascribed to the DMSC effect,and the higher catalytic activity of MM’-In over MM-In can be ascribed to the strengthened DMSC *** work reveals the relationship between DMSC effect and bimetal centers in CO2reduction,which provides new insights into the DMSC and paves a new way to design highly active catalysts for photochemical CO2reduction.

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Efficient large-area flexible organic photovoltaic modules on transparent thin silver electrodes

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Science China Chemistry 2025年

作者： Cong Xie Zedong Xiong Xinlu Liu wen Wang Yang Liu Xueshi Jiang Xin Lu Lulu Sun Yinhua Zhou Wuhan National Laboratory for Optoelectronics Huazhong University of Science and Technology Kunming Institute of Physics

Large-area flexible organic photovoltaic（OPV） modules are challenging to achieve high power conversion efficiency（PCE）.Electrical shunts or shortages generally occur in large-area OPV modules due to the ultrathin（100–200 nm） and soft active layers. Improving the surface smoothness of bottom transparent electrode will be able to suppress the shunts and shortages. In this work, we report a method to fabricate smooth and flexible transparent electrodes based on thin silver film, and further to fabricate efficient large-area flexible OPV modules. The fabricated thin silver transparent electrodes simultaneously have high conductivity, high optical transmittance, good mechanical flexibility and low surface roughness. humidity exposure（h.e.）treatment on MoO3effectively facilitates the continuous growth of the thin transparent silver electrode. 6 nm silver film on MoO3（h.e.） on plastic substrate shows a transmittance up to 89%, a sheet resistance of 15 Ω/sq, and a low surface roughness with a rootmean-square value of 0.276 nm. Furthermore, 52-cm2flexible organic solar modules（15 subcells） showed a certified PCE of12.66%. Furthermore, a 1350 cm2flexible component assembled by 25 pieces of 52–55 cm2modules showed certified PCE of12.10% with an open-circuit voltage of 62.85 V.

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A versatile synthetic strategy towards rare earth based metal-organic frameworks

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Science China Chemistry 2025年

作者： Quan Shi Yun-hao Xu Ming-hui Chen Peng Zhao wen-Bo Deng Ji Xiong Kai Guo Ya-Qing Feng Bao Zhang School of Chemical Engineering and Technology Tianjin University Tianjin Collaborative Innovation Center of Chemical Science and Engineering Guangdong Laboratory Chemistry & Fine Chemical Industry Jieyang Center

Rare earth metal-organic frameworks (RE-MOFs) have drawn wide attention owing to diverse network structures and various application ***,due to the unpredictable formation of the nodes,it is still challenging to design novel RE-MOFs.A novel versatile strategy was developed employing a RE-acetate complex (RE2(Ch3COO)6·4h2O) as a precursor to construct RE-MOFs.2D RE-MOFs (RE-DBP) and 3D RE-MOFs (RE-TCPP) could be obtained by using dicarboxylic porphyrin ligands h2DBP and tetracarboxylic porphyrin ligands h2TCPP,*** RE-MOFs were further synthesized to verify the universality of the *** crystalline RE-MOFs could also be prepared at room temperature via the developed strategy,which could significantly promote large-scale preparation and practical application of *** proof of the concept,the performance of porphyrin-based RE-MOFs was investigated in the photocatalytic cycloaddition of CO2with *** the RE-DBP(Co) MOFs,Tb-DBP(Co) exhibited the best photocatalytic performance,which was also greater than that of the corresponding 3D MOF Tb-TCPP(Co) due to the optimal 2D structure and thus the accelerated photogenerated charge separation and transfer *** work not only provides a novel versatile strategy to design and develop RE-MOFs,but also proposes a promising approach for the potential bulk production of RE-MOFs at room temperature.

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基于隐性句逗号识别的汉语长句机器翻译

外语学刊 2025年第1期 39-46页

作者：冯文贺李熳佳张文娟广东外语外贸大学外国语言学及应用语言学研究中心语言工程与计算实验室广州510420 广州理工学院计算机科学与工程学院广州510420

长句翻译一直是机器翻译的难题。本文根据汉语中相当数量的逗号和句号可相互转化的特点,提出“隐性句号”和“隐性逗号”概念,并实现其自动识别,以将汉语长句变为短句用于汉英机器翻译。为此,首先通过人工与半监督学习结合方法构建一个... 详细信息

长句翻译一直是机器翻译的难题。本文根据汉语中相当数量的逗号和句号可相互转化的特点,提出“隐性句号”和“隐性逗号”概念,并实现其自动识别,以将汉语长句变为短句用于汉英机器翻译。为此,首先通过人工与半监督学习结合方法构建一个隐性句逗数据集,实现基于预训练模型的隐性句逗识别方法,其中性能最好的hierarchical BERT作为后续应用模型。进而,实现基于隐性句逗识别的汉英机器翻译方法。在新闻和文学公开翻译测试语料上基于预训练机器翻译模型的实验表明,对于汉语长句的英译,本文方法相比基准翻译的BLEU值整体有所提高,而且在相对稳健机器翻译模型上,呈现为句子越长本文方法效果越明显。

关键词：机器翻译长句翻译隐性句逗号汉语长句逗号识别句内标点

Simple Metrics for Representing East Asian Winter Monsoon Variability:Urals Blocking and Western Pacific Teleconnection Patterns

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Advances in Atmospheric Sciences 2016年第6期33卷 695-705页

作者： hoffman h.N.ChEUNG wen ZhOU Guy Carpenter Asia-Pacific Climate Impact Centre School of Energy and EnvironmentCity University of Hong KongHong Kong SAR City University of hong Kong Shenzhen Research Institute Shenzhen 518057

Instead of conventional East Asian winter monsoon indices （EAWMIs）, we simply use two large-scale teleconnection patterns to represent long-term variations in the EAWM. First, the Urals blocking pattern index （UBI） is closely related to cold air advection from the high latitudes towards western Siberia, such that it shows an implicit linkage with the Siberian high intensity and the surface air temperature （SAT） variations north of 40°N in the EAWM region. Second, the well-known western Pacific teleconnection index （WPI） is connected with the meridional displacement of the East Asian jet stream and the East Asian trough. This is strongly related to the SAT variations in the coastal area south of 40°N in the EAWM region. The temperature variation in the EAWM region is also represented by the two dominant temperature modes, which are called the northern temperature mode （NTM） and the southern temperature mode （STM）. Compared to 19 existing EAWMIs and other well-known teleconnection patterns, the UBI shows the strongest correlation with the NTM, while the WPI shows an equally strong correlation with the STM as four EAWMIs. The UBI-NTM and WPI-STM relationships are robust when the correlation analysis is repeated by （1） the 31-year running correlation and （2） the 8-year high-pass and low-pass filter. hence, these results are useful for analyzing the large-scale teleconnections of the EAWM and for evaluating this issue in climate models. Int particular, more studies should focus on the teleconnection patterns over extratropical Eurasia.

关键词： East Asian winter monsoon Urals blocking high western Pacific teleconnection pattern teleconnection

Cascaded Sliding-mode Observer and Its Applications in Output Feedback Control Part I:Observer Design and Stability Analysis

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CSEE Journal of Power and Energy Systems 2021年第2期7卷 295-306页

作者： Tianhao wen Yang Liu Q.h.Wu Luonan Qiu School of Electric Power Engineering South China University of TechnologyGuangzhou 510640China

This paper proposes a cascaded sliding-mode observer for systems with high relative degree and studies its applications in output feedback controller *** part I,the working principle and parameter design of the proposed observer are discussed in *** is proved that,within a sufficiently short period of time,the states of the proposed observer will reach the intersection of all the sliding *** sliding surfaces,the observation error of the proposed observer will converge to sufficiently small *** with traditional high-gain observers,the proposed observer has smaller gain *** addition,the peaking-phenomenon occurred in the proposed observer is less ***,the proposed observer has a convergence rate of observation error as fast as that of traditional high-gain *** studies are carried out on a fifth-order system to verify the properties of the proposed observer.

关键词： Sliding-mode observer stability output feedback control

基于微流控芯片评估富血小板血浆促进子宫内膜细胞的增殖

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中国组织工程研究 2025年第10期29卷 2091-2096页

作者：闻哲嘉吕芳苏州大学附属第二医院生殖中心江苏省苏州市215004

背景:富血小板血浆可促进薄型子宫内膜细胞的增殖,但存在剂量难以控制、取样困难等问题。微流控芯片具有高通量、低消耗、操作简便等优点,为模拟子宫内膜细胞在体微环境提供了新途径。目的:利用三通道微流控芯片构建富血小板血浆促进子... 详细信息

背景:富血小板血浆可促进薄型子宫内膜细胞的增殖,但存在剂量难以控制、取样困难等问题。微流控芯片具有高通量、低消耗、操作简便等优点,为模拟子宫内膜细胞在体微环境提供了新途径。目的:利用三通道微流控芯片构建富血小板血浆促进子宫内膜细胞增殖的研究模型。方法:从1名女性外周静脉血中提取富血小板血浆。采用含不同浓度[0%(对照),0.5%,1%,2%]富血小板血浆的无血清细胞培养基培养人子宫内膜间质细胞,采用划痕实验检测细胞迁移,CCK-8法检测细胞增殖。利用聚二甲基硅氧烷胶制备微流控芯片,该微流控芯片设计有3个通道,中间通道为细胞外基质水凝胶通道,左右两侧分别为人子宫内膜间质细胞及富血小板血浆通道,3个通道之间保存有可以相互沟通以及实现物质交换的面积,实验组两侧通道分别加入人子宫内膜间质细胞(绿色荧光蛋白GFP标记)和含0.5%富血小板血浆的无血清培养基,对照组两侧通道分别加入人子宫内膜间质细胞(绿色荧光蛋白GFP标记)和无血清细胞培养基,共培养48 h后,采用Ki67免疫荧光染色观察细胞增殖与迁移。结果与结论:(1)细胞划痕实验和CCK-8检测结果显示,与对照组相比,0.5%,1%,2%浓度的富血小板血浆可促进人子宫内膜间质细胞的迁移与增殖(P <0.05),并且0.5%浓度富血小板血浆的促进细胞迁移与增殖作用强于其他2个浓度(P <0.05);(2)Ki67免疫荧光染色结果显示,与对照组相比,实验组人子宫内膜间质细胞的增殖和迁移能力更强;(3)实验证实通过三通道微流控芯片可以模拟子宫内膜细胞的微环境,同时利用该系统验证了富血小板血浆可显著促进子宫内膜间质细胞的增殖与迁移。

关键词：微流控芯片富血小板血浆子宫内膜间质细胞子宫内膜增殖迁移细胞外基质薄型子宫内膜子宫内膜相关疾病

Magnetic Properties of Ni Nanoparticles and Ni(C) Nanocapsules

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Journal of Materials Science & Technology 2002年第2期18卷 99-100页

作者： Z.J.Li G.h.wen 等 ShenyangNationalLaboratoryforMaterialsScienceandInternationalCentreforMaterialsPhysics InstituteofMetalResearchChineseAcademyofSciencesShenyang110016China DepartmentofPhysics H

Structure and magnetic properties of Ni nanoparticles and Ni(C) nanocapsules were studied. The carbon atoms hardly affect the lattice of Ni to form Ni-C solid solution or nickel carbides. The large thermal irreversibility in zero-field-cooled and zero-field magnetization curves indicates magnetic blocking with a wide energy barrier. Saturation magnetization, remanent magnetization and coercivity of Ni(C) nanocapsules decrease with increasing temperature.

关键词： Nanoparticles Nanocapsules Magnetic properties

MEShFREE METhOD BASED ON POINT COLLOCATION FOR METAL FORMING SIMULATION

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Acta Metallurgica Sinica(English Letters) 2006年第2期19卷 79-84页

作者： h.Y. wen X.h. Dong X.Y. Ruan Department of Plasticity Forming Engineering Shanghai Jiaotong University Shanghai 200030 China

A meshfree method based on reproducing kernel approximation and point collocation is presented for analysis of metal ring compression. The point collocation method is a true meshfree method without the employment of a background mesh. It is shown that, in a point collocation approach, the remesh problem because of the mesh distortion in FEM （finite element method） and the low efficiency in Galerkin-based meshfree method are avoided. The corrected kernel functions are introduced to the stabilization of free-surface boundary conditions. The solution of symmetric ring compression problem is compared with a conventional finite element solution, and reasonable results have been obtained.

关键词： meshfree method RKPM (reproducing kernel particle method) point collocation metal forming frictional contact