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Characterization and source apportionment of volatile organic compounds in hong Kong:A 5-year study for three different archetypical sites

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Journal of Environmental Sciences 2025年第5期151卷 424-440页

作者： Yuchen Mai Vincent Cheung Peter K.K.Louie Kenneth Leung Jimmy C.h.Fung Alexis K.h.Lau Donald R.B.lake Dasa gu Division of Environment and Sustainability The Hong Kong University of Science and TechnologyHong Kong 999077China Environmental Protection Department Hong Kong 999077China Environment and Ecology Bureau Hong Kong 999077China Department of Chemistry University of CaliforniaIrvine 92617USA

Initial success has been achieved in hong Kong in controlling primary air pollutants,but ambient ozone levels kept increasing during the past three *** organic compounds(VOCs)are important for mitigating ozone pollution as its major *** study analyzed VOC characteristics of roadside,suburban,and rural sites in hong Kong to investigate their compositions,concentrations,and source *** showthat the TVOC concentrations were 23.05±13.24,12.68±15.36,and 5.16±5.48 ppbv for roadside,suburban,and rural sites between May 2015 to June 2019,*** using Positive Matrix Factorization(PMF)model,six sources were identified at the roadside site over five years:Liquefied petroleum gas(LPG)usage(33%–46%),gasoline evaporation(8%–31%),aged air mass(11%–28%),gasoline exhaust(5%–16%),diesel exhaust(2%–16%)and fuel filling(75–9%).Similarly,six sources were distinguished at the suburban site,including LPG usage(30%–33%),solvent usage(20%–26%),diesel exhaust(14%–26%),gasoline evaporation(8%–16%),aged air mass(4%–11%),and biogenic emissions(2%–5%).At the rural site,four sources were identified,including aged airmass(33%–51%),solvent usage(25%–30%),vehicular emissions(11%–28%),and biogenic emissions(6%–12%).The analysis further revealed that fuel filling and LPG usage were the primary contributors to OFP and Oh reactivity at the roadside site,while solvent usage and biogenic emissions accounted for almost half of OFP and Oh reactivity at the suburban and rural sites,*** findings highlight the importance of identifying and characterizing VOC sources at different sites to help policymakers develop targeted measures for pollution mitigation in specific areas.

关键词： Volatile organic compounds Positive matrix factorization Source apportionment Ozone formation

Catalytic detoxification of mitoxantrone by graphitic carbon nitride(g-C_(3)N_(4))supported Fe/Pd bimetallic nanoparticles

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Journal of Environmental Sciences 2025年第2期148卷 614-624页

作者： Qianyu Xu haoyang Fu Jiyuan gu Liyu Lei Lan Ling State Key Laboratory for Pollution Control and Resource Reuse College of Environmental Science and EngineeringTongji UniversityShanghai 200092China

The overuse of antibiotics and antitumor drugs has resulted in more and more extensive pollution of water bodies with organic drugs,causing detrimental ecological effects,which have attracted attention towards effective and sustainable methods for antibiotics and antitumor drug ***,the hybrid nanomaterial(g-C_(3)N_(4)@Fe/Pd)was synthesized and used to remove a kind of both an antibiotic and antitumor drug named mitoxantrone(MTX)with 92.0%removal efficiency,and the MTX removal capacity is 450 mg/*** exposing to the hybrid material the MTX aqueous solution changed color from dark blue to lighter progressively,and LC-UV results of residual solutions showthat a newpeak at 3.0min(MTX:13.2min)after removal by g-C_(3)N_(4)@Fe/Pd appears,with the simultaneous detection of intermediate products indicating that g-C_(3)N_(4)@Fe/Pd indeed degrades *** mass spectrometric analysis suggests that the nuclear mass ratio decreased from 445.2(M+1h)to 126.0(M+1h),169.1(M+1h),239.2(M+1h),267.3(M+1h),285.2(M+1h),371.4(M+1h)and 415.2(M+1h),and the maximum proportion(5.63%)substance of all degradation products(126.0(M+1h))is 40-100 times less toxic than MTX.A mechanism for the removal and degradation of mitoxantrone was ***,actual water experiments confirmed that the maximum removal capacity of MTX by g-C_(3)N_(4)@Fe/Pd is up to 492.4 mg/g(0.02 g/L,10 ppm).

关键词： Degradation LC-QTOF-MS Nanoparticles Mitoxantrone Aqueous solution

Enhanced dynamics of Al3+/h+ ions in aqueous aluminum ion batteries:Construction of metastable structures in vanadium pentoxide upon oxygen vacancies

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Journal of Energy Chemistry 2025年第2期101卷 562-569页

作者： zhibao Wang hanqing gu Tianci Wu Wenming zhang zhanyu Li hebei Key Laboratory of Optic-Electronic Information and Materials National & Local Joint Engineering Laboratory of New Energy Photoelectric Devices College of Physics Science and Technology Hebei University

In recent years,aqueous aluminum ion batteries have been widely studied owing to their abundant energy storage and high theo retical *** in-depth study of vanadium oxide materials is necessary to address the precipitation of insoluble products covered cathode surface and the slow reaction ***,a method using a simple one-step hydrothermal preparation and oxalic acid to regulate oxygen vacancies has been reported.A high starting capacity(400 mAh g-1) can be achieved by Ov-V2O5,and it is capable of undergoing 200 cycles at 0.4 A g-1,with a termination discharge capacity of103 mAh *** analysis demonstrated that metastable structures（AlxV2O5and hxV2O5） were constructed through the insertion of Al3+/h+during discharging,which existed in the lattice intercalation with *** incorporation of oxygen vacancies lowers the reaction energy barrier while improving the ion transport *** addition,the metastable structure allows the electrostatic interaction between Al3+and the main backbone to establish protection and optimize the transport *** parallel,this work exploits ex-situ characterization and DFT to obtain a profound insight into the instrumental effect of oxygen vacancies in the construction of metastable structures during in-situ electrochemical activation,with a view to better understanding the mechanism of the synergistic participation of Al3+and h+in the *** work not only reports a method for cathode materials to modulate oxygen vacancies,but also lays the foundation for a deeper understanding of the metastable structure of vanadium oxides.

关键词： Electrochemical activation Metastable structure Oxygen vacancies Vanadium pentoxide

Design of a cationic accelerator enabling ultrafast ion diffusion kinetics in aqueous zinc-ion batteries

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Journal of Energy Chemistry 2025年第1期100卷 377-384页

作者： Yawei Xiao Qianqian gu haoyu Li Mengyao Li Yude Wang National Center for International Research on Photoelectric and Energy Materials School of Materials and EnergyYunnan UniversityKunming 6500504YunnanChina Key Laboratory of Ministry of Education for Advanced Materials in Tropical Island Resources School of Chemistry and Chemical EngineeringHainan UniversityHaikou 570228HainanChina College of Chemical Engineering Fuzhou UniversityFuzhou 350108FujianChina Yunnan Key Laboratory of Carbon Neutrality and Green Low-carbon Technologies Yunnan UniversityKunming 6500504YunnanChina

Aqueous zincion batteries are highly favored for grid-level energy storage owing to their low cost and high safety,but their practical application is limited by slow ion *** address this,a strategy has been developed to create a cation-accelerating electric field on the surface of the cathode to achieve ultrafast zn^(2+)diffusion *** employing electrodeposition to coat MoS_(2)on the surface of BaV_(6)O_(16)·3h_(2)O nanowires,the directional builtin electric field generated at the heterointerface acts as a cation accelerator,continuously accelerating zn^(2+)diffusion into the active *** optimized zn^(2+)diffusion coefficient in CC@BaV-V_(6)O_(16)·3h_(2)@MoS_(2)(7.5×10^(8)cm^(2)s^(-1)) surpasses that of most reported V-based ***,MoS_(2)serving as a cathodic armor extends the cycling life of the zn-CC@BaV_(6)O_(16)·3h_(2)@MoS_(2)full batteries to over 10000 *** work provides valuable insights into optimizing ion diffusion kinetics for high-performance energy storage devices.

关键词： Internal electric field Cationic accelerator lon diffusion kinetics Cathode modification strategy Aqueous zinc ion battery

Dynamic modeling of a three-dimensional braided composite thin plate considering braiding directions

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Applied Mathematics and Mechanics(English Edition) 2025年第1期46卷 123-138页

作者： Chentong GAO huiyu SUN Jianping gu W.M.hUANG College of Aerospace Engineering Nanjing University of Aeronautics and Astronautics School of Mechanical and Aerospace Engineering Nanyang Technological University Jiangsu Key Laboratory of Advanced Structural Materials and Application Technology School of Materials Science and EngineeringNanjing Institute of Technology

Currently, there are a limited number of dynamic models available for braided composite plates with large overall motions, despite the incorporation of three-dimensional(3D) braided composites into rotating blade components. In this paper, a dynamic model of 3D 4-directional braided composite thin plates considering braiding directions is established. Based on Kirchhoff's plate assumptions, the displacement variables of the plate are expressed. By incorporating the braiding directions into the constitutive equation of the braided composites, the dynamic model of the plate considering braiding directions is obtained. The effects of the speeds, braiding directions, and braided angles on the responses of the plate with fixed-axis rotation and translational motion, respectively, are investigated. This paper presents a dynamic theory for calculating the deformation of 3D braided composite structures undergoing both translational and rotational motions. It also provides a simulation method for investigating the dynamic behavior of non-isotropic material plates in various applications.

关键词： braiding direction composite thin plate dynamic model large overall motion O313.7 three-dimensional (3D) braided composite

New breakthrough: Building non-markovian environments for single-qubit systems at any time interval

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Science China(Physics,Mechanics & Astronomy) 2025年第3期Mechanics & Astronomy) .卷 193页

作者： h.z.Shen Center for Quantum Sciences and School of Physics Northeast Normal University

The proposal of quantum simulation provides a highly effective approach for experimental research on open quantum systems. To date, numerous quantum simulation studies pertaining to open quantum systems have been put forward,including Fanchini et al.’s simulation of a dephasing noise channel utilizing an optical system [1], and Xiong et al.’s realization of a quantum simulation for a non-rotating-wave approximation noise channel, also leveraging an optical system [2].

关键词： quantum system breakthrough

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Fluorinated poly(p-triphenylene isatin)anion exchange membranes based on hydrophilic hydroxyl side chain modulation for fuel cells

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Journal of Energy Chemistry 2025年第1期100卷 702-709页

作者： Yiman gu Yanchao zhang zhanyu Li Yijia Lei Baozeng Sun Xiaoyu Yu zhe Wang College of Chemistry and Life Science Changchun University of TechnologyChangchun 130012JilinChina College of Chemical Engineering Changchun University of TechnologyChangchun 130012JilinChina School of Materials Science and Engineering Changchun University of TechnologyChangchun 130012JilinChina Key Laboratory of Advanced Functional Polymer Membrane Materials of Jilin Province Changchun 130012JilinChina

The development of alkaline fuel cells is moving forward at an accelerated pace,and the application of ether-free bonded polymers to anion exchange membranes(AEMs)has been widely ***,the question of the“trade-off”between AEM ionic conductivity and dimensional stability remains *** strategy of inducing microphase separation to improve the performance of AEM has attracted much attention recently,but the design of optimal molecular structures is still being ***,this work introduced different ratios of 3-bromo-1,1,1-trifluoroacetone(x=40,50,and 60)into the main chain of poly(p-terphenylene isatin).Because fluorinated groups have excellent hydrophobicity,hydrophilic hydroxyl-containing side chains are introduced to jointly adjust the formation of phase separation *** results show that PTI-PTF_(50)-NOh AEM with the appropriate fluorinated group ratio has the best ionic conductivity and alkali stability under the combined effect of *** has an ionic conductivity of 133.83 mS cm^(-1)at 80°*** addition,the Oh-conductivity remains at 89%of the initial value at 80°C and 3 M KOh for 1056 h of *** cell polarization curve based on PTI-PTF_(50)-NOh shows a power density of 734.76 mW cm^(-2)at a current density of 1807.7 mA cm^(-2).

关键词： Anion exchange membranes Poly(p-terphenylene isatin) hydrophilic-hydrophobic phase separation Fluorinated group

Interpretable Machine Learning-Based Spring Algal Bloom Forecast Model for the Coastal Waters of zhejiang

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Journal of Ocean University of China 2025年第1期24卷 1-12页

作者： hUANG guoqiang BAO Min zhANG zhao gu Dongming LIANG Liansong TAO Bangyi State Key Laboratory of Satellite Ocean Environment Dynamics Second Institute of OceanographyMinistry of Natural ResourceHangzhou 310012China Wenzhou Marine Center Ministry of Natural ResourcesWenzhou 325000China Observation and Research Station of Yangtze River Delta Marine Ecosystems Ministry of Natural ResourcesZhoushan 316000China Key Laboratory of Marine Ecological Monitoring and Restoration Technologies Ministry of Natural ResourceShanghai 201206China

The 2016–2022 monitoring data from three ecological buoys in the Wenzhou coastal region of zhejiang Province and the dataset European Centre for Medium-Range Weather Forecasts were examined to clarify the elaborate relationship between variations in ecological parameters during spring algal bloom incidents and the associated changes in temperature and wind fields in this study.A long short-term memory recurrent neural network was employed,and a predictive model for spring algal bloom in this region was *** model integrated various inputs,including temperature,wind speed,and other pertinent variables,and chlorophyll concentration served as the primary output *** model training used chlorophyll concentration data,which were supplemented by reanalysis and forecast temperature and wind field *** model demonstrated proficiency in forecasting next-day chlorophyll concentrations and assessing the likelihood of spring algal bloom occurrences using a defined chlorophyll concentration *** historical validation from 2016 to 2019 corroborated the model's accuracy with an 81.71%probability of correct prediction,which was further proven by its precise prediction of two spring algal bloom incidents in late April 2023 and early May *** interpretable machine learning-based model for spring algal bloom prediction,displaying effective forecasting with limited data,was established through the detailed analysis of the spring algal bloom mechanism and the careful selection of input *** insights gained from this study offer valuable contributions to the development of early warning systems for spring algal bloom in the Wenzhou coastal area of zhejiang Province.

关键词： spring algal bloom forecast LSTM interpretable

The advanced development of innovative photocatalytic coupling strategies for hydrogen production

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Chinese Chemical Letters 2025年第1期36卷 80-91页

作者： Yuehai zhi Chen gu huachao Ji Kang Chen Wenqi Gao Jianmei Chen Dafeng Yan College of Electronic and Optical Engineering&College of Flexible Electronics(Future Technology) Nanjing 210023China hubei Key Laboratory for Precision Synthesis of Small Molecule Pharmaceuticals&Ministry of Education Key Laboratory for the Synthesis and Application of Organic Functional Molecules&College of Chemistry and Chemical Engineering Hubei UniversityWuhan 430062China

Photocatalytic technology harnesses solar energy to facilitate chemical transformations,presenting significant potential in energy generation and environmental ***,the conventional O_(2)evolution process is hindered by high reaction barriers and inefficiencies,which limit its widespread ***,exploring novel photocatalytic coupling strategies to replace water oxidation has become a key route to enhance the efficiency of h_(2)*** this review,organic pollutants removal and the valorization of organics as substitutes for water oxidation coupling strategies for photocatalytic h_(2)production are comprehensively *** strategies not only circumvent the high reaction barriers associated with O_(2)evolution to enhance the h_(2)production but also aid in the removing of organic pollutants or synthesis of value-added *** also present future research directions and underscore the significance of advanced catalyst design,in-depth analysis of reaction mechanisms,and systematic optimization strategies in realizing an efficient and sustainable photocatalytic *** guidance is anticipated to provide theoretical and practical new insights for the future development of photocatalytic coupling reactions,fostering further explorations in the realm of renewable energy and environmental governance.

关键词： Photocatalysis Pollutants removal Valorization of organics Catalyst design