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In situ anchoring in carbon matrix of Bi_(2)O_(2)CO_(3) as a high-performance anode material for Li-ion batteries

Rare Metals 2024年第8期43卷 3634-3646页

作者： Pu-Qiang He Jun guo Hui Huang zhong-Cheng guo Faculty of Metallurgy and Energy Engineering Kunming University of Science and TechnologyKunming 650093China Research Center of Metallurgical Electrode Materials Engineering Technology Kunming 650106China Kunming Hendera Science and Technology Co. Ltd.Kunming 650106China

Bismuth-based anode materials have been regarded as promising Li-ion batteries due to their high theoretical ***,their low conductivity and associated volume expansion inhabited their *** this work,Bi_(2)O_(2)CO_(3)@C composites were successfully synthesized by in situ anchoring of flower-like Bi_(2)O_(2)CO_(3) nanosheets on a carbon-based substrate via *** unique composited structure of Bi_2O_(2)-CO_(3)@C leads to a stable specific capacity of 547 mAh·g^(-1)after 100 cycles at a current density of 0.1 A·g^(-1).Notably,it demonstrates excellent rate capability with a specific capacity of 210 mAh·g^(-1)at 5 A·g^(-1).After 550 cycles at a current density of 0.5 A·g^(-1),a high reversible capacity of nearly 400 mAh·g^(-1)was ***,in situ X-ray diffraction measurements clearly demonstrate the conversion between Bi and Li_(3)Bi during alloying/dealloying,confirming the good electrochemical reversibility of the materials for Li *** reaction kinetics of Bi_(2)O_(2)CO_(3)@C were further investigated using galvanostatic intermittent titration ***,Bi_2O_(2)-CO_(3)@C exhibited excellent long-term stability,maintaining its high reversible capacity for over 200 cycles at a current density of 0.5 A·g^(-1)in a full cell configuration using Li_(1.20)Mn_(0.54)Ni_(0.13)Co_(0.13)O_(2) as the cathode *** result further underscores its promising potential for lithium-ion *** work may provide inspiration for the design of alloy-type negative electrode materials for high-performance rechargeable batteries.

关键词： Bi_(2)O_(2)CO_(3) Composite materials Anode materials Full batteries

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C-X-C chemokine receptor type 5+CD8+T cells as immune regulators in hepatitis Be antigen-positive chronic hepatitis B under interferonalpha treatment

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World Journal of Gastroenterology 2025年第3期31卷 73-83页

作者： Zhen-Yu Xu zhong-Shang Dai guo-zhong Gong Min Zhang Department of Infectious Diseases Second Xiangya HospitalCentral South UniversityChangsha 410011Hunan ProvinceChina Institute of Hepatology and Department of Infectious Diseases The Second Xiangya HospitalCentral South UniversityChangsha 410011Hunan ProvinceChina

BACKGROUND C-X-C chemokine receptor type 5(CXCR5)+CD8+T cells represent a unique immune subset with dual roles,functioning as cytotoxic cells in persistent viral infections while promoting B cell *** their importance,the specific role of CXCR5+CD8+T cells in chronic hepatitis B(CHB),particularly during interferon-alpha(IFN-α)treatment,is not fully *** study aims to elucidate the relationship between CXCR5+CD8+T cells and sustained serologic response(SR)in patients undergoing 48 weeks of pegylated IFN-α(peg-IFN-α)treatment for *** To elucidate the relationship between CXCR5+CD8+T cells and sustained SR in patients undergoing 48 weeks of peg-IFN-αtreatment for *** This study enrolled 60 patients with hepatitis Be antigen(HBeAg)-positive CHB undergoing 48 weeks of peg-IFN-α*** were assessed for eligibility based on criteria such as persistent HBsAg-positive status for at least six months,HBeAb-negative,hepatitis B virus DNA levels exceeding 2×104 copies/mL,and alanine aminotransferase(ALT)levels between 2 and 10 times the upper limit of *** samples were collected at baseline and at weeks 12,24,48,and a 24-week treatment-free follow-up(week 72)to measure serum interleukin(IL)-21 concentration via ELISA and to analyze CXCR5 and programmed death-ligand 1(PD-L1)expression on CD8+T cells by flow cytometry,CXCR5 is a chemokine receptor that directs immune cells to specific tissues,while PD-L1 is a protein that regulates immune responses by inhibiting T cell *** Patients with CHB exhibited significantly lower levels of circulating CXCR5+CD8+T cells compared to healthy controls(P<0.01).Notably,CXCR5+CD8+T cells were prominently expressed in patients who achieved sustained SR compared to non-SR(NSR).A significant correlation was observed between CXCR5 and PD-L1 expression(r=-0.189,P=0.002).However,there was no significant correlation between serum IL-21 levels and CXCR5+CD8+lymphocytes(r=-0.03,P=0.62

关键词： C-X-C chemokine receptor type 5 Programmed death-ligand 1 Interleukin-21 Pegylated interferon-alpha Chronic hepatitis B

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Survey of recent progress in semantic image segmentation with CNNs

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Science China(Information Sciences) 2018年第5期61卷 107-124页

作者： Qichuan GENG zhong zhou Xiaochun CAO State Key Laboratory of Virtual Reality Technology and Systems School of Computer Science and Engineering Beihang University State Key Laboratory of Information Security Institute of Information EngineeringChinese Academy of Sciences

In recent years, convolutional neural networks(CNNs) are leading the way in many computer vision tasks, such as image classification, object detection, and face recognition. In order to produce more refined semantic image segmentation, we survey the powerful CNNs and novel elaborate layers, structures and strategies, especially including those that have achieved the state-of-the-art results on the Pascal VOC 2012 semantic segmentation challenge. Moreover, we discuss their different working stages and various mechanisms to utilize the structural and contextual information in the image and feature spaces. Finally, combining some popular underlying referential methods in homologous problems, we propose several possible directions and approaches to incorporate existing effective methods as components to enhance CNNs for the segmentation of specific semantic objects.

关键词： semantic image segmentation CNN Pascal VOC 2012 challenge multi-granularity features construction of contextual relationships

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Systematics of a-preformation factors in closed-shell regions

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Nuclear Science and Techniques 2016年第6期27卷 54-60页

作者： Da-Ming Deng zhong-zhou Ren Key Laboratory of Modern Acoustics and Department ofPhysics Nanjing UniversityNanjing 210093China Center of Theoretical Nuclear Physics National Laboratoryof Heavy-Ion AcceleratorLanzhou 730000China State Key Laboratory of Theoretical Physics Institute ofTheoretical PhysicsChinese Academy of ScienceBeijing 100190China

The a-preformation factors of medium and heavy-mass nuclei are calculated by using the cluster-formation *** obtained preformation factors of even–even,odd-A,and odd–odd nuclei consist in both magnitude and trend with the general features predicted by standard *** variation of a clustering affected by the evolution of nuclear structure is observed from different behaviors of preformation *** typically analyze the variation of preformation factors in the closed-shell N =126 and Z =82 regions,and discuss in detail the structural effects on a-cluster *** work shows the strong correlation between a-preformation factors and the shell structure,which would be a useful reference for microscopic cluster-model calculations of a-decay half-lives.

关键词：分类外壳封闭结构演变形成模型行为观察中重核计算

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Improved Reliability Analysis Method Based on the Failure Assessment Diagram

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Chinese Journal of Mechanical Engineering 2012年第4期25卷 832-837页

作者： zhou Yu ZHANG Zheng zhong Qunpeng School of Material Science and Engineering Beihang University Beijing 100191 China

With the uncertainties related to operating conditions,in-service non-destructive testing（NDT） measurements and material properties considered in the structural integrity assessment,probabilistic analysis based on the failure assessment diagram（FAD） approach has recently become an important ***,the point density revealing the probabilistic distribution characteristics of the assessment points is usually *** obtain more detailed and direct knowledge from the reliability analysis,an improved probabilistic fracture mechanics（PFM） assessment method is *** integrating 2D kernel density estimation（KDE） technology into the traditional probabilistic assessment,the probabilistic density of the randomly distributed assessment points is visualized in the assessment ***,a modified interval sensitivity analysis is implemented and compared with probabilistic sensitivity *** improved reliability analysis method is applied to the assessment of a high pressure pipe containing an axial internal semi-elliptical surface *** results indicate that these two methods can give consistent sensitivities of input parameters,but the interval sensitivity analysis is computationally more ***,the point density distribution and its contour are plotted in the FAD,thereby better revealing the characteristics of PFM *** study provides a powerful tool for the reliability analysis of critical structures.

关键词： reliability analysis failure assessment diagram probabilistic fracture mechanics kernel density estimation sensitivity analysis

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Wet-spinning of Regenerated Silk Fiber from Aqueous Silk Fibroin Solutions: Influence of Calcium Ion Addition in Spinning Dope on the Performance of Regenerated Silk Fiber

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Chinese Journal of Polymer Science 2014年第1期32卷 29-34页

作者： Huan zhou Zheng-zhong Shao 陈新 State Key Laboratory of Molecular Engineering of Polymers Department of Macromolecular Science Laboratory of Advanced Materials Fudan University

Ca（II） ions are added in the spinning dope to adjust the solidification rate of regenerated silk fibroin （RSF） solution during the wet-spinning process since Ca（II） ions are proved to be favorable to maintain the stable silk fibroin network in our previous work. The results show that when Ca（II）/RSF ratios are 1/50 and 1/20, the resulted RSF fibers exhibit good performance with the breaking energy more than 70 kJ/kg. However, higher Ca（II）/RSF ratio （for example, 1/10） hinders the solidification of spinning dope and results in poor RSF fibers. These observations together with earlier papers from this laboratory confirm that to produce tough silk fibers the spinning conditions must allow sufficient time for the adjustment of silk fibroin molecular chains.

关键词： Silk fiber Natural polymer Wet-spinning Protein Calcium.

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Macrophage based drug delivery:Key challenges and strategies

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Bioactive Materials 2024年第8期38卷 55-72页

作者： Qian guo zhong-Ming Qian Laboratory of Drug Delivery School of MedicineShanghai University99 Shangda RoadShanghai200444China Institute of Translational and Precision Medicine Nantong University19 Qi Xiu RoadNantongJiangsu226019China National Clinical Research Center for Aging and Medicine of Huashan Hospital Fudan UniversityShanghai201203China

As a natural immune cell and antigen presenting cell,macrophages have been studied and engineered to treat human *** are well-suited for use as drug carriers because of their biological characteristics,such as excellent biocompatibility,long circulation,intrinsic inflammatory homing and ***,macrophages’uniquely high plasticity and easy re-education polarization facilitates their use as part of efficacious therapeutics for the treatment of inflammatory diseases or *** recent studies have demonstrated promising advances in macrophage-based drug delivery,several challenges currently hinder further improvement of therapeutic effect and clinical *** article focuses on the main challenges of utilizing macrophage-based drug delivery,from the selection of macrophage sources,drug loading,and maintenance of macrophage phenotypes,to drug migration and release at target *** addition,corresponding strategies and insights related to these challenges are ***,we also provide perspective on shortcomings on the road to clinical translation and production.

关键词： Macrophages Cell therapy Drug delivery Nano-or micro-particles Cell polarization

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Catalytic activity of Cu-SSZ-13 prepared with different methods for NH_3-SCR reaction

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Rare Metals 2019年第3期38卷 210-220页

作者： Meng-Jie Han Yun-Lei Jiao Chun-Hong zhou Yang-Long guo Yun guo Guan-zhong Lu Li Wang Wang-Cheng Zhan Key Laboratory for Advanced Materials and Research Institute of Industrial Catalysis East China University of Science and Technology

A series of Cu-SSZ-13 catalysts with the same Cu loading were prepared by different methods of incipient wetness impregnation [Cu-SSZ-13(IWI)], ion exchange[Cu-SSZ-13(IE)] and hydro-thermal synthesis [Cu-SSZ-13(HTS)]. Their activity for selective catalytic reduction of nitrogen oxides(NO_x) with NH3 was determined. The results show that the Cu-SSZ-13(HTS) catalyst exhibits a better ammonia selective catalytic reduction(NH3-SCR)activity compared with the other two catalysts, over which more than 90% NO conversion is obtained at 215-600℃under the space velocity of 180,000 h^(-1). The characterization results reveal that the Cu-SSZ-13(HTS) catalyst possesses more amount of stable Cu^(2+) in the six-membered ring and high ability for NH3 and NO adsorption, leading to its high NH3-SCR activity, although this catalyst has low surface area. On the other hand, the activity of Cu-SSZ-13(IE) catalyst is almost the same as that of Cu-SSZ-13(IWI) catalyst at the temperature lower than 400 ℃, but the activity of the former is much higher than that of the latter at > 400 ℃ due to the high activity of Cu-SSZ-13(IWI) catalyst for NH3 oxidation.

关键词： SSZ-13 zeolite Selective catalytic reduction Nitrogen oxides Preparation method Cu2+

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Study on the gamma rays and neutrons energy response optimization of a scintillating fiber detector for EAST with Geant4

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Nuclear Science and Techniques 2023年第9期34卷 40-49页

作者： Wei-Kun Chen Li-Qun Hu guo-Qiang zhong Rui-Jie zhou Bing Hong Qiang Li Li Yang Institute of Plasma Physics Hefei Institutes of Physical ScienceChinese Academy of SciencesHefei 230031China University of Science and Technology of China Hefei 230026China Institute of Energy Hefei Comprehensive National Science Center(Anhui Energy Laboratory)Hefei 230031China

A new scintillating fiber detector inside magnetic shielding tube was designed and assembled for use in the next round of fusion experiments in the experimental advanced superconducting tokamak to provide D–T neutron yield with time *** this study,Geant4 simulations were used to obtain the pulse height spectra for ideal signals produced when detecting neutrons and gamma rays of multiple *** of the main sources of interference was found to be low-energy neutrons below 10–5 MeV,which can generate numerous secondary particles in the detector components,such as the magnetic shielding tube,leading to high-amplitude output *** address this issue,a compact thermal neutron shield containing a 1-mm Cd layer outside the magnetic shielding tube and a 5-mm inner Pb layer was specifically *** effects on the measurement of fast neutrons and the shielding effect on gamma rays were *** can suppress the height of the signals caused by thermal neutrons to a level below the height corresponding to neutrons above 4 MeV because the yield of the latter is used for detector *** addition,the detector has relatively flat sensitivity curves in the fast neutron region,with the intrinsic detection efficiencies(IDEs)of approximately 40%.For gamma rays with energies that are not too high(<8 MeV),the IDEs of the detector are only approximately 20%,whereas for gamma rays below 1 MeV,the response curve cuts off earlier in the low-energy region,which is beneficial for avoiding counting saturation and signal accumulation.

关键词： Sci-Fi detector D–T fusion neutron Thermal neutron shield Energy response Geant4

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Sensor data compression based on MapReduce

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The Journal of China Universities of Posts and Telecommunications 2014年第1期21卷 60-66页

作者： YU Yu guo zhong-wen Department of Computer Science and Engineer Ocean University of China

A compression algorithm is proposed in this paper for reducing the size of sensor data. By using a dictionary-based lossless compression algorithm, sensor data can be compressed efficiently and interpreted without decompressing. The correlation between redundancy of sensor data and compression ratio is explored. Further, a parallel compression algorithm based on MapReduce [1] is proposed. Meanwhile, data partitioner which plays an important role in performance of MapReduce application is discussed along with performance evaluation criteria proposed in this paper. Experiments demonstrate that random sampler is suitable for highly redundant sensor data and the proposed compression algorithms can compress those highly redundant sensor data efficiently.

关键词： data compression sensor data MapReduce surveillance application measurement system

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