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CMAS-phobic and infiltration-inhibiting protective layer material for thermal barrier coatings

Journal of Advanced Ceramics 2024年第8期13卷 1254-1267页

作者： Shjun Meng Lei guo Hongbo guo Yuanpeng Wang Hongli Liu School of Materials Science and Engineering Tianjin UniversityTianjin 300072China Tianjin Key Laboratory of Advanced Joining Technology Key Lab of Advanced Ceramics and Machining Technology of Ministry of EducationTianjin300072China School of Materials Science and Engineering Beihang UniversityBeijing 100191China College of Aeronautical Engineering Civil Aviation University of ChinaTianjin 300300China

Calcium-magnesium-alumina-silicate(CMAS)corrosion has attracted special attention in the thermal barrier coating(TBC)*** high temperatures,when CMAS melts,it adheres to the coating surface and penetrates the interior,severely destroying the *** this study,a promising CMAS-phobic and infiltration-inhibiting material,GdPO4,on which molten CMAs is difficult to wet and penetrate,was *** desirable attributes are explained by analyzing the material characteristics of GdPO_(4) and its interfacial reaction with ***4 is demonstrated to have low surface energy,making it difficult for molten CMAS to wet and adhere to the *** in contact with molten CMAS,a double-layer structured reaction layer consisting of an acicular upper sublayer and a compact lower sublayer is formed on the GdPO4 surface,which can effectively impede molten CMAS spreading and ***-principles calculation results revealed that the reaction layer has low surface energy and low adhesion to CMAS,which are favorable for molten CMAS ***,the formation of the reaction layer increases the viscosity of the molten CMAS,which can increase melt wetting and ***,GdPO4,which exhibits excellent CMAS-phobicity and infiltration-inhibiting ability,is a promising protective layer material for TBCs against CMAS adhesion and attack.

关键词： thermal barrier coatings(TBCs) calcium-magnesium-alumina-silicate(CMAS)-phobicity GdPO_(4) interface reaction layer first-principles calculation

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一种微波介质材料介电常数的测量方法

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电子元件与材料 2022年第3期41卷 238-242,290页

作者：朱明亮李勃郭云胜内蒙古科技大学理学院内蒙古包头014010 清华大学材料学院新型陶瓷与精细工艺国家重点实验室北京100084

介电常数和损耗是微波介质材料的重要参数。目前介电常数的测量方法比较多,但存在测试仪器昂贵、测量方法严格、样品制备苛刻等问题。在当今电磁商业软件十分强大的时代背景下,利用数值仿真详细研究了矩形波导中介质圆柱的谐振模态随自... 详细信息

介电常数和损耗是微波介质材料的重要参数。目前介电常数的测量方法比较多,但存在测试仪器昂贵、测量方法严格、样品制备苛刻等问题。在当今电磁商业软件十分强大的时代背景下,利用数值仿真详细研究了矩形波导中介质圆柱的谐振模态随自身介电常数和几何大小的变化规律,进而提出一种在矩形波导中直接放入待测样品,通过寻找样品的特征谐振峰得到介电常数的测量方法。研究结果表明,对于介电常数为2.5~100的介质材料,都可通过制备成直径为10 mm的圆柱样品放在BJ100波导中准确地测出其介电常数和损耗的大小。为证明方法的优越性,以氧化铝、滑石和其他陶瓷样品为例进行了实测,得到与第三方测试一致的结果。本文提出的方法简单、高效、便捷,能够对介质材料的广泛应用起到极大推动作用。

关键词：介电常数损耗透射系数波导电磁谐振

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A unified stochastic damage model for concrete based on multi-scale energy dissipation analysis

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Science China(Technological Sciences) 2024年第3期67卷 863-877页

作者： guo ChengGong LI Jie College of Civil Engineering Tongji UniversityShanghai 200092China State Key Laboratory of Disaster Reduction in Civil Engineering Shanghai 200092China

This work proposes a unified damage model for concrete within the framework of stochastic damage mechanics. Based on the micro-meso stochastic fracture model(MMSF), the nonlinear energy dissipation process of the microspring from nanoscale to microscale is investigated. In nanoscale, the rate process theory is adopted to describe the crack growth rate;therefore, the corresponding energy dissipation caused by a representative crack propagation can be obtained. The scale gap from nanoscale to microscale is bridged by a crack hierarchy model. Thus, the total energy dissipated by all cracks from the nanoscale to the microscale is gained. It is found that the fracture strain of the microspring can be derived from the above multi-scale energy dissipation analysis. When energy dissipation is regarded as some microdamage to the microspring, the constitutive law of the microspring is no longer linearly elastic, as previously assumed. By changing the expression of the damage evolution law from fracture strain to energy dissipation threshold, the new damage evolution model is derived. The proposed model can not only replicate the original static model but also extend to cases of rate dependence. By deriving the fracture strain under different strain rates, the rate sensitivity of concrete materials can be reflected. The model parameters can be conveniently obtained by identifying them with experimental data. Finally, several numerical examples are presented to verify the proposed model.

关键词： concrete damage model stochastic damage rate dependent energy dissipation

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Localizing vitamin-C through nanoconfinement enables high-rate CO_(2) electrolysis to ethylene

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Science China Materials 2024年第3期67卷 1006-1008页

作者： Zhengyi Qian Shaojun guo School of Materials Science and Engineering Peking UniversityBeijing 100871China

The electrosynthesis of value-added fuels and chemicals from carbon dioxide reduction reaction(CO_(2)RR)is a promising approach for realizing the objectives of carbon neutrality[1].Nevertheless,the current production of desirable multicarbon(C_(2+))chemicals,such as ethylene(C_(2)H_(4)),still encounters challenges related to low selectivity,low current density,and the requirement for high-purity feeding gas[2].

关键词： enable purity dioxide

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A short review of antibacterial Cu-bearing stainless steel:antibacterial mechanisms,corrosion resistance,and novel preparation techniques

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Journal of Iron and Steel Research International 2024年第1期31卷 24-45页

作者： Shuai Liu Han-jie guo School of Artificial Intelligence Beijing Technology and Business UniversityBeijing100048China Beijing Key Laboratory of Special Melting and Preparation of High-End Metal Materials University of Science and Technology BeijingBeijing100083China

Cu-bearing stainless steel is widely used in the fields of food,medical and household sanitary equipment because of its surface finish and corrosion ***,the growth of bacteria on stainless steel leads to the formation of biofilms,which causes ***,the antibacterial property of stainless steel is a worthy research *** of breakthroughs in the field of corrosion resistance and antimicrobial properties are still ***,due to the scarcity of publications on the antibacterial mechanisms and processing methods of antibacterial Cu-bearing stainless steel,we review the current state of relevant research and *** toxicity of Cu,corrosion resistance mechanism of stainless steel,and antibacterial mechanism and preparation method of antibacterial stainless steel are *** addition,alloying,surface modification and other methods are found to have limitations in balancing the toxicity and antibacterial properties of copper and the relationship between the antibacterial properties and corrosion resistance of Cu-bearing stainless steel.A new preparation method of antibacterial stainless steel associated with selective laser melting(SLM)is *** is becoming a powerful additive manufacturing technology that can be used to manufacture customized and complex *** research status of SLM applied in antibacterial stainless steel preparation is ***,the future research direction of Cu-bearing antibacterial stainless steel is discussed.

关键词： Cu-bearing stainless steel Antibacterial Processing Additive manufacturing Corrosion resistance

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Facile preparation of coal-based ultramicroporous carbon microspheres for selective CO_(2)capture

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Carbon Resources Conversion 2024年第3期7卷 97-105页

作者： Mei An Tuo guo Qingjie guo Jiangmen Laboratory of Carbon Science and Technology the Hong Kong University of Science and Technology(Guangzhou)JiangmenGuangzhou 529000China State Key Laboratory of High-efficiency Coal Utilization and Green Chemical Engineering School of Chemistry and Chemical EngineeringNingxia UniversityYinchuanNingxia 750021China Key Laboratory of Clean Chemical Engineering in Universities of Shandong College of Chemical EngineeringQingdao University of Science&TechnologyQingdao 266042China

The basic structure of aromatic compounds that are abundant in coal is the carbonaceous precursor derived from carbon ***,it remains to be a huge challenge to prepare carbon microspheres using coal due to the complex construction and composition of ***,a simple and viable way to obtain coal-based microporous carbon microspheres was developed by means of ethanol pyrolysis and a sequential extraction *** as-prepared carbon microsphere featured aspherical micron particles of a uniform size(0.6-1.6㎛),abundant O-functional groups,excellent thermal stability,high SBET(415.5-983.2 m^(2)/g),and plentiful ultra-micropores(63.15-72.72%).The coal-based carbon microsphere exhibited a noteworthy CO_(2)uptake(3.19-4.97 mmol/g at 273 K and 1.0 bar),acceptable CO_(2)/N_(2)selectivity(IAST:23-46)and moderate isosteric heats(20-32 kJ/mol).This synthetic strategy is important for the preparation of ultramicroporous carbon microspheres using coal,and the synthetic carbon microspheres have promising prospects for highly efficient CO_(2)capture.

关键词： Coal Ultramicroporous Carbon microspheres Ethanolysis Sequential extraction CO_(2)capture

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Privacy-Preserving Consensus-Based Distributed Economic Dispatch of Smart Grids via State Decomposition

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IEEE/CAA Journal of Automatica Sinica 2024年第5期11卷 1250-1261页

作者： Wei Chen guo-Ping Liu The authors are with the Center for Control Science and Technology Southern University of Science and TechnologyShenzhen 518055China

This paper studies the privacy-preserving distributed economic dispatch(DED)problem of smart *** autonomous consensus-based algorithm is developed via local data exchange with neighboring nodes,which covers both the islanded mode and the grid-connected mode of smart *** prevent power-sensitive information from being disclosed,a privacy-preserving mechanism is integrated into the proposed DED algorithm by randomly decomposing the state into two parts,where only partial data is *** objective is to develop a privacy-preserving DED algorithm to achieve optimal power dispatch with the lowest generation cost under physical constraints while preventing sensitive information from being *** this end,a comprehensive analysis framework is established to ensure that the proposed algorithm can converge to the optimal solution of the concerned optimization problem by means of the consensus theory and the eigenvalue perturbation *** particular,the proposed autonomous algorithm can achieve a smooth transition between the islanded mode and the grid-connected ***,rigorous analysis is given to show privacy-preserving performance against internal and external ***,case studies illustrate the feasibility and validity of the developed algorithm.

关键词： preserving autonomous mode

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Improving mathematical model of burden distribution and correcting chute angle to cope with fluctuation of stock line

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Journal of Iron and Steel Research International 2024年第2期31卷 342-356页

作者： Jian-sheng Chen Wen-guo Liu Hao guo Wang Ding Qing-guo Xue Jing-song Wang Hai-bin Zuo State Key Laboratory of Advanced Metallurgy University of Science and Technology BeijingBeijing100083China MCC Capital Engineering&Research Incorporation Limited Beijing100176China Hunan Valin Xiangtan Iron and Steel Co. Ltd.Xiangtan411101HunanChina

Accurate evaluations of the burden distribution are of critical importance to stabilize the operation of blast *** mathematical model and discrete element method(DEM)are two attractive methods for predicting burden *** on DEM,the initial velocities of the pellet,sinter,and coke were calculated,and the velocity attenuations of the above three particles between the burden and the chute were *** initial velocity and velocity attenuation were applied to a mathematical model for improving the ***,based on the improved model,a scheme for rectifying the chute angles was proposed to address the fluctuation of the stock line and maintain a stable burden *** validity of the scheme was confirmed via a stable burden distribution under different stock *** mathematical model has been successfully applied to evaluate the online burden distribution and cope with the fluctuation of the stock line.

关键词： Burden distribution Mathematical model Discrete element method Velocity attenuation Stock line fluctuation

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Predicting torsional capacity of reinforced concrete members by data-driven machine learning models

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Frontiers of Structural and Civil Engineering 2024年第3期18卷 444-460页

作者： Shenggang CHEN Congcong CHEN Shengyuan LI Junying guo Quanquan guo Chaolai LI School of Mechanics and Civil Engineering China University of Mining and TechnologyXuzhou 211116China Jiangsu Key Laboratory Environmental Impact and Structural Safety in Engineering China University of Mining and TechnologyXuzhou 211116China China Nuclear Power Design Co.Ltd. Shenzhen 518031China School of transportation and science engineering Beihang UniversityBeijing 100191China China Construction First Group Corporation Limited Beijing 100161China

Due to the complicated three-dimensional behaviors and testing limitations of reinforced concrete(RC)members in torsion,torsional mechanism exploration and torsional performance prediction have always been *** the present paper,several machine learning models were applied to predict the torsional capacity of RC *** results of a total of 287 torsional specimens were collected through an overall literature *** of extreme gradient boosting machine(XGBM),random forest regression,back propagation artificial neural network and support vector machine,were trained and tested by 10-fold cross-validation *** performances of proposed machine learning models were evaluated and compared,both with each other and with the calculated results of existing design codes,i.e.,GB 50010,ACI 318-19,and Eurocode *** results demonstrated that better predictive performance was achieved by machine learning models,whereas GB 50010 slightly overestimated the torsional capacity,and ACI 318-19 and Eurocode 2 underestimated it,especially in the case of ACI *** XGBM model gave the most favorable predictions with R^(2)=0.999,RMSE=1.386,MAE=0.86,andλ=***,strength of concrete was the most sensitive input parameters affecting the reliability of the predictive model,followed by transverse-to-longitudinal reinforcement ratio and total reinforcement ratio.

关键词： RC members torsional capacity machine learning models design codes

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一种双层圆孔阵列全介质超表面完美吸收器

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电子元件与材料 2023年第7期42卷 849-854页

作者：许瑞星吕晓龙郭云胜内蒙古科技大学理学院内蒙古包头014000

入射电磁波在刻有周期性圆孔阵列的介质基板上激发的电偶极子和磁偶极子处于简并临界耦合状态时,能够实现全介质惠更斯超表面的完美吸收。然而,完美吸收需要介质基板的损耗处于一个临界值,这在由同一种组分构成的基板材料中很难实现。... 详细信息

入射电磁波在刻有周期性圆孔阵列的介质基板上激发的电偶极子和磁偶极子处于简并临界耦合状态时,能够实现全介质惠更斯超表面的完美吸收。然而,完美吸收需要介质基板的损耗处于一个临界值,这在由同一种组分构成的基板材料中很难实现。本文提出材料损耗相差较大的两种介质基板的叠层组合结构实现惠更斯超表面的完美吸收。实验结果表明,1 mm厚的磁性复合材料吸波片叠放在4 mm厚的聚四氟乙烯陶瓷复合材料基板上形成的双层结构,当其上刻有周期和直径分别为20 mm和17 mm的圆孔阵列时,能够吸收频率为9.68 GHz入射电磁能量的92.4%,与吸收率为99.6%的电磁仿真结果基本一致。双层圆孔阵列全介质完美吸收超表面具有重量轻、结构简单以及金属超表面不可比拟的诸多特性,在电磁隐身和屏蔽的应用中能发挥重要作用。

关键词：圆孔阵列全介质超表面完美吸收器

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