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SOME INTERESTING REACTIONS OF AN N-BROMOMETHYL QUATERNARY AMMONIUM SALT WITH HALOPHILIC REAGENTS

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Chinese Chemical Letters 1994年第8期5卷 663-666页

作者： guo feng huang Xiao Tian LIANG Institute of Materia Medica Chinese Academy of Medical Sciences and Peking Union Medical CollegeBeijing 100050 Department of Organic Synthesis Institute of Applied Pharmaceutical ResearchBeijing Medical UniversityBejing 100083

N-Bromomethyl-N-methyl- 1,2, 3,4-tetrahydro-iso-quinolinium bromide(1)reacted with sodium 2, 6-di-tert-butylphenoxide to afford compound 2a. 3a. 4 and 5 via the benzylic N-ylide intermediate. Meanwhile, when compound 1 reacted with tri-n-butylphosphine the coupling compound 7 was obtained via demethylation reaction. The reaction mechanisms were discussed.

关键词：澹?

Dynamic simulation analysis of molten salt reactor-coupled air-steam combined cycle power generation system

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Nuclear Science and Techniques 2024年第2期35卷 222-233页

作者： Jing-Lei huang guo-Bin Jia Li-feng Han Wen-Qian Liu Li huang Zheng-Han Yang Shanghai Institute of Applied Physics Chinese Academy of SciencesShanghai 201800China University of Chinese Academy of Sciences Beijing 100049China

A nonlinear dynamic simulation model based on coordinated control of speed and flow rate for the molten salt reactor and combined cycle systems is proposed here to ensure the coordination and stability between the molten salt reactor and power *** model considers the impact of thermal properties of fluid variation on accuracy and has been validated with *** study reveals the capability of the control system to compensate for anomalous situations and maintain shaft stability in the event of perturbations occurring in high-temperature molten salt tank outlet ***,the control system’s impact on the system’s dynamic characteristics under molten salt disturbance is also *** results reveal that after the disturbance occurs,the controlled system benefits from the action of the control,and the overshoot and disturbance amplitude are positively correlated,while the system power and frequency eventually return to the initial *** simulation model provides a basis for utilizing molten salt reactors for power generation and maintaining grid stability.

关键词： Molten salt reactor Combined cycle Dynamic characteristic Control

Ultrafast laser-chemical modification hybrid fabrication of hydrostatic bearings with a superhydrophobicity solid-liquid interface

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Science China(Technological Sciences) 2024年第3期67卷 696-708页

作者： guo MingHui RONG YouMin huang Yu feng XiaoLin HU HaiDong WU CongYi ZHANG guoJun State Key Laboratory of Intelligent Manufacturing Equipment and Technology Huazhong University of Science and Technology Wuhan 430074China School of Mechanical Science and Engineering Huazhong University of Science and TechnologyWuhan 430074China Faculty of Engineering and Life Sciences Universiti Selangor Bestari JayaSelangor 45600Malaysia

Oil film vortex severely reduces the stability of hydrostatic bearings. A solid-liquid interface with drag and slip properties can weaken the oil film vortex of the bearing. Here, a combined picosecond laser ablation and chemical modification method is proposed to prepare surfaces with microbulge array structure on 6061 aluminum alloy substrates. Because of the low surface energy of the perfluorododecyltriethoxysilane modification and the bulge geometry of the microbulge array structure, the surface shows excellent superhydrophobicity. The optimum contact angle in air for water is 164°, and that for oil is 139°. Two surfaces with “lotus-leaf effect” and “rose-petal effect” were obtained by controlling the processing parameters. The drag reduction properties of superhydrophobic surfaces were systematically investigated with slip lengths of 22.26 and 36.25 μm for deionized water and VG5 lubricant, respectively. In addition, the superhydrophobic surface exhibits excellent mechanical durability and thermal stability. The proposed method provides a new idea for vortex suppression in hydrostatic bearings and improves the stability of bearings in high-speed operation.

关键词： superhydrophobicity surface ultrafast laser drag reduction solid-liquid interface microbulge array structure

Stability analysis of longwall top-coal caving face in extra-thick coal seams based on an innovative numerical hydraulic support model

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International Journal of Mining Science and Technology 2024年第4期34卷 491-505页

作者： Jun guo Wenbo huang guorui feng Jinwen Bai Lirong Li Zi Wang Luyang Yu Xiaoze Wen Jie Zhang Wenming feng College of Mining Engineering Taiyuan University of TechnologyTaiyuan 030024China Key Laboratory of Shanxi Province for Mine Rock Strata Control and Disaster Prevention Taiyuan University of TechnologyTaiyuan 030024China Shanxi Coking Coal Group Co. Ltd.Taiyuan 030024China Shanxi-Zheda Institute of Advanced Materials and Chemical Engineering Taiyuan 030024China

The relationship between support and surrounding rock is of great significance to the control of surrounding rock in mining *** view of the fact that most of the existing numerical simulation methods construct virtual elements and stress servo control to approximately replace the hydraulic support problem,this paper establishes a new numerical model of hydraulic support with the same working characteristics as the actual hydraulic support by integrating numerical simulation software Rhino,Griddle and FLAC3D,which can realize the simulation of different working *** on this model,the influence mechanism of the supporting strength of hydraulic support on surrounding rock stress regulation and coal stability in front of the top coal caving face in extra thick coal seam were ***,under different support intensity,the abutment pressure of the bearing coal and the coal in front of it presents the “three-stage”evolution *** influence range of support intensity is 15%–30%.Secondly,1.5 MPa is the upper limit of impact that the support strength can have on the front coal failure ***,within a displacement range of 2.76 m from the coal wall,a support strength of1.5 MPa provides optimal control of the horizontal displacement of the coal.

关键词： Extremely thick coal seam Fully mechanized top coal caving Support strength Support-surrounding rock interaction

Rim^(18)F-fluorodeoxyglucose uptake of hepatic cavernous hemangioma on positron emission tomography/computed tomography:A case report

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World Journal of Clinical Cases 2024年第13期12卷 2243-2247页

作者： Yong-An Hu Ya-Xin guo Qi-feng huang Department of Nuclear Medicine Jinhua Hospital of Zhejiang UniversityJinhua Municipal Central HospitalJinhua 321000Zhejiang ProvinceChina

BACKGROUND Peripheral FDG accumulation in a hepatic hemangioma presenting in a patient with prolonged fever is ***,clinicians should pay close attention to patients with hepatic *** SUMMARY A 54-year-old woman with a 4-wk history of daily fevers was admitted to our hospital.A whole body^(18)-Fluordesoxyglucose(PET-FDG)positron emission tomography/computed tomography(PET/CT)was performed to elucidate the source of the ***,whole body^(18)-FDG PET/CT raised the suspicion of a malignant lesion because of peripheral FDG accumulation(SUVmax 3.5 g/mL)higher than that of the normal liver parenchyma(SUVmax 1.6 g/mL)surrounding a hypoactive area,and no other abnormalities were ***,the patient underwent liver mass *** showed a hepatic cavernous hemangioma with fatty infiltration around the *** fever disappeared four days after surgery and the patient did not present any complications during *** Fatty infiltration in the peripheral parts of hepatic cavernous hemangioma may lead to subacute inflammation which further activate the Kupffer *** may cause prolonged fever and peripheral rim FDG accumulation on PET/CT.

关键词： ^(18)-Fluordesoxyglucose positron emission tomography/computed tomography Hepatocellular carcinoma Fever Fatty infiltration Case report

Average Secrecy Capacity of the Reconfigurable Intelligent Surface-Assisted Integrated Satellite Unmanned Aerial Vehicle Relay Networks

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Computer Modeling in Engineering & Sciences 2024年第2期138卷 1849-1864页

作者： Ping Li Kefeng guo feng Zhou XuelingWang Yuzhen huang School of Information Technology Yancheng Institute of TechnologyYancheng224051China School of Space Information Space Engineering UniversityBeijing101407China Space E-Star Communication Technology Co. LtdNanjing210007China Academy of Military Sciences of PLA Beijing100097China

Integrated satellite unmanned aerial vehicle relay networks(ISUAVRNs)have become a prominent topic in recent *** paper investigates the average secrecy capacity(ASC)for reconfigurable intelligent surface(RIS)-enabled ***,an eve is considered to intercept the legitimate information from the considered secrecy ***,we get detailed expressions for the ASC of the regarded secrecy system with the aid of the reconfigurable ***,to gain insightful results of the major parameters on the ASC in high signalto-noise ratio regime,the approximate investigations are further gotten,which give an efficient method to value the secrecy *** last,some representative computer results are obtained to prove the theoretical findings.

关键词： Integrated satellite unmanned aerial vehicle relay networks reconfigurable intelligent surface average secrecy capacity(ASC) asymptotic ASC

Nanotechnology’s frontier in combatting infectious and inflammatory diseases:prevention and treatment

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Signal Transduction and Targeted Therapy 2024年第3期9卷 998-1047页

作者： Yujing huang Xiaohan guo Yi Wu Xingyu Chen Lixiang feng Na Xie guobo Shen Department of Biotherapy Cancer Center and State Key Laboratory of BiotherapyWest China Hospitaland West China School of Basic Medical Sciences and Forensic MedicineSichuan Universityand Collaborative Innovation Center for BiotherapyChengdu 610041China

Inflammation-associated diseases encompass a range of infectious diseases and non-infectious inflammatory diseases,which continuously pose one of the most serious threats to human health,attributed to factors such as the emergence of new pathogens,increasing drug resistance,changes in living environments and lifestyles,and the aging *** rapid advancements in mechanistic research and drug development for these diseases,current treatments often have limited efficacy and notable side effects,necessitating the development of more effective and targeted anti-inflammatory *** recent years,the rapid development of nanotechnology has provided crucial technological support for the prevention,treatment,and detection of inflammation-associated *** types of nanoparticles(NPs)play significant roles,serving as vaccine vehicles to enhance immunogenicity and as drug carriers to improve targeting and *** can also directly combat pathogens and *** addition,nanotechnology has facilitated the development of biosensors for pathogen detection and imaging techniques for inflammatory *** review categorizes and characterizes different types of NPs,summarizes their applications in the prevention,treatment,and detection of infectious and inflammatory *** also discusses the challenges associated with clinical translation in this field and explores the latest developments and *** conclusion,nanotechnology opens up new possibilities for the comprehensive management of infectious and inflammatory diseases.

关键词： prevention inflammatory treatment

SYNTHESIS　OF　POLYSUBSTITUTED　AROMATIC　COMPOUNDS　***　DIELS-ALDER　REACTION　OF　PHENYLSELENO　SUBSTITUTED　DIENES　WITH　DIMETHYL　ACETYLENEDICARBOXYLATE

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Chinese Chemical Letters 1995年第9期6卷 769-770页

作者： Guang Dlan HAN guo feng huang(Institute of Materia Medica, Peking Union Medical College, Chinese Academy of Medical Sciences, Beijing 100060) Chinese Acad Med Sci Inst Mat Med Peking Union Med Coll Beijing 100050 Peoples R China

Abstract: The phenylseleno substituted aromatlc compounds were prepared via the Diels-Alder reaction of phenylseleno substituted dlenes with dimethyl acetylenedicarboxylate followed by DDQ dehydrogenation.

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Quantum phase transition of the Jaynes-Cummings model

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Science China(Physics,Mechanics & Astronomy) 2024年第1期67卷 1-9页

作者： Cheng Liu Jin-feng huang Key Laboratory of Low-Dimensional Quantum Structures and Quantum Control of Ministry of Education Key Laboratory for Matter Microstructure and Function of Hunan ProvinceDepartment of Physics and Synergetic Innovation Center for Quantum Effects and ApplicationsInstitute of Interdisciplinary StudiesHunan Normal UniversityChangsha 410081China

Herein,we propose an experimentally feasible scheme to show the quantum phase transition of the Jaynes-Cummings(JC)model by modulating the transition frequency of a two-level system in a quantum Rabi model with strong *** tuning the modulation frequency and amplitude,the ratio of the effective coupling strength of the rotating terms to the effective cavity(atomic transition)frequency can enter the deep-strong coupling regime,while the counter-rotating terms can be ***,a deep-strong JC model is *** ratio of the coupling strength to resonance frequencies in the deep-strong JC model is two orders of magnitude larger than the corresponding ratio in the original quantum Rabi *** scheme can be employed in atom-cavity resonance and off-resonance cases,and it is valid over a broad *** nonzero average cavity photons of the ground state indicate the emergence of a quantum phase ***,we demonstrate the dependence of the phase diagram on the atom-cavity detuning and modulation *** the parameters used in our scheme are within the reach of current experimental *** scheme provides a new mechanism for investigating the critical phenomena of finite-sized systems without requiring classical field limits,thereby opening a door for studying fundamental quantum phenomena occurring in the ultrastrong and even deep-strong coupling regimes.

关键词： Jaynes-Cummings model quantum phase transition frequency modulation