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Identifying the dynamic behaviors in complete reconstruction of Co-based complex precatalysts during electrocatalytic oxygen evolution

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Journal of Energy Chemistry 2025年第1期100卷 226-233页

作者： Jingfang Zhang Danyang Wu Linke Cai Youluan Lu Fanpeng Cheng Lijuan shi Qun Yi Yao liu Yi Huang Key Laboratory of Green Chemical Engineering Process of Ministry of Education Engineering Research Center of Phosphorus Resources Development and Utilization of Ministry of EducationHubei Key Laboratory of Novel Reactor and Green Chemical TechnologySchool of Chemical Engineering&PharmacyWuhan Institute of TechnologyWuhan 430205HubeiChina Key Laboratory of Pesticide&Chemical Biology of Ministry of Education Engineering Research Center of Photoenergy Utilization for Pollution Control and Carbon Reduction of Ministry of EducationCollege of ChemistryCentral China Normal UniversityWuhan 430079HubeiChina College of Materials Science and Engineering Fuzhou UniversityFuzhou 350108FujianChina

Transition metal-based nanomaterials have emerged as promising electrocatalysts for oxygen evolution reaction(OER).Considerable research efforts have shown that self-reconstruction occurs on these nanomaterials under operating conditions of OER ***,most of them undergo incomplete reconstruction with limited thickness of reconstruction layer,leading to low component utilization and arduous exploration of real catalytic ***,we identify the dynamic behaviors in complete reconstruction of Co-based complexes during *** hollow phytic acid(PA)cross-linked CoFe-based complex nanoboxes with porous nanowalls are designed because of their good electrolyte penetration and mass transport ability,in favor of the fast and complete reconstruction.A series of experiment characterizations demonstrate that the reconstruction process includes the fast substitution of PA by OH-to form Co(Fe)(OH)xand subsequent potential-driven oxidation to Co(Fe)*** obtained CoFeOOH delivers a low overpotential of 290 mV at a current density of 10 mA cm^(-2)and a long-term *** experiment results together with theory calculations reveal that the Fe incorporation can result in the electron rearrangement of reconstructed CoFeOOH and optimization of their electronic structure,accounting for the enhanced OER *** work provides new insights into complete reconstruction of metal-based complexes during OER and offers guidelines for rational design of high-performance electrocatalysts.

关键词： Complete reconstruction Co-based complex Precatalysts Oxygen evolution reaction

g-C_(3)N_(4)nanosheets coupled with CoSe_(2)as co-catalyst for efficient photooxidation of xylose to xylonic acid

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Green Energy & Environment 2025年第1期10卷 231-238页

作者： Qi Hao Yijun liu Ren Zou Ge shi shilian Yang Linxin Zhong Wu Yang Xiao Chi Yunpeng liu shimelis Admassie Xinwen Peng State Key Laboratory of Pulp and Paper Engineering South China University of TechnologyGuangzhou510641GuangdongChina Hainan Key Laboratory of Storage&Processing of Fruits and Vegetables Agricultural Products Processing Research InstituteChinese Academy of Tropical Agricultural SciencesZhanjiangGuangdong524001China Department of Chemistry and Centre for Advanced 2D Materials(CA2DM)National University of Singapore 3 Science Drive 3 Singapore117543Singapore School of Materials Science and Hydrogen Energy Foshan UniversityFoshan528231GuangdongChina Department of Chemistry Addis Ababa UniversityPO BOX 1176Addis AbabaEthiopia

Photocatalysis has emerged as an effective approach to sustainably convert biomass into value-added ***_(2)is a promising nonprecious,efficient cocatalyst for photooxidation,which can facilitate the separation of photogenerated electron–holes,increase the reaction rates,and enhance photocatalytic *** this work,we synthesized a stable and efficient photocatalysis system of CoSe_(2)/g-C_(3)N_(4)through attaching CoSe_(2)on g-C_(3)N_(4)sheets,with a yield of 50.12%for the selective photooxidation of xylose to xylonic *** light illumination,the photogenerated electrons were prone to migrating from g-C_(3)N_(4)to CoSe_(2)due to the higher work function of CoSe_(2),resulting in the accelerated separation of photogenerated electron–holes and the promoted ***,this study reveals the unique function of CoSe_(2),which can significantly promote oxygen adsorption,work as an electron sink and accelerate the generation of ·O_(2)^(-),thereby improving the selectivity toward xylonic acid over other *** work provides useful insights into the design of selective photocatalysts by engineering g-C_(3)N_(4)for biomass high-value utilization.

关键词： Biomass photooxidation Hemicelluloses Xylose g-C_(3)N_(4) Xylonic acid

Boosting hydrocarbon conversion via Cu-doping induced oxygen vacancies on CeO_(2) in CO_(2)electroreduction

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Journal of Energy Chemistry 2025年第1期100卷 66-76页

作者： Lei Xue Tong shi Chenhui Han Heng Zhang Fenrong liu Haorun Li Yan Wang Xiaojun Gu Shanghong Zeng Inner Mongolia Key Laboratory of Chemistry and Physics of Rare Earth Materials School of Chemistry and Chemical EngineeringInner Mongolia UniversityHohhot 010021Inner MongoliaChina State Key Laboratory of Coal Conversion Institute of Coal ChemistryChinese Academy of SciencesTaiyuan 030001ShanxiChina Institute of Catalysis Department of ChemistryZhejiang UniversityHangzhou 310058ZhejiangChina National Key Laboratory of Baiyunobo Rare Earth Resource Research and Comprehensive Utilization Baotou Research Institute of Rare EarthsBaotou 014030Inner MongoliaChina

Conversion of CO_(2)back to hydrocarbons is the most direct way of closing the“carbon cycle”,and its significance is further enlarged if this process is driven by renewable energies such as ***,precisely controlling the product selectivity towards hydrocarbons against the competitive hydrogen evolution remains challenging,especially for Cu-based ***,we report a novel defect engineering strategy,by which Cu-doping-induced oxygen vacancies on CeO_(2)nanorods were effectively created,with adjustable vacancy/Cu *** resulting optimum catalyst shows up to 79%catalytic current density to hydrocarbons(excluding CO),with 49%faradaic efficiency to *** and density functional theory unveil that the ratio between oxygen vacancy and Cu affects significantly the formation of*CHO and activation of H2O,which leads to the following deep hydrogenation to *** findings may spur new insights for designing and developing more controllable chemical process relevant to CO_(2)utilization.

关键词： Cu/CeO_(2)-x Oxygen vacancy Hydrocarbon production Reaction mechanism

Targeting vulnerable microcircuits in the ventral hippocampus of male transgenic mice to rescue Alzheimer‑like social memory loss

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Military Medical Research 2025年第1期12卷 48-71页

作者： Hui-Yang Lei gui-Lin Pi Ting He Rui Xiong Jing-Ru Lv Jia-Le liu Dong-Qin Wu Meng-Zhu Li Kun shi shi-Hong Li Na-Na Yu Yang Gao Hui-Ling Yu Lin-Yu Wei Xin Wang Qiu-Zhi Zhou Pei-Lin Zou Jia-Yang Zhou Ying-Zhou liu Nai-Ting Shen Jie Yang Dan Ke Qun Wang Gong-Ping liu Xi-Fei Yang Jian-Zhi Wang Ying Yang Department of Pathophysiology School of Basic MedicineKey Laboratory of Education Ministry of China/Hubei Province for Neurological DisordersTongji Medical CollegeHuazhong University of Science and TechnologyWuhan 430030China Department of Traditional Chinese Medicine the Central Hospital of WuhanTongji Medical CollegeHuazhong University of Science and TechnologyWuhan 430014China Key Laboratory of Modern Toxicology of Shenzhen Shenzhen Center for Disease Control and PreventionShenzhen 518055GuangdongChina Co‑Innovation Center of Neuroregeneration Nantong UniversityNantong 226000JiangsuChina

Background:Episodic memory loss is a prominent clinical manifestation of Alzheimer’s disease(AD),which is closely related to tau pathology and hippocampal *** to the heterogeneity of brain neurons,the specific roles of different brain neurons in terms of their sensitivity to tau accumulation and their contribution to AD-like social memory loss remain ***,further investigation is ***:We investigated the effects of AD-like tau pathology by Tandem mass tag proteomic and phosphoproteomic analysis,social behavioural tests,hippocampal electrophysiology,immunofluorescence staining and in vivo optical fibre recording of GCaMP6f and ***,we utilized optogenetics and administered ursolic acid(UA)via oral gavage to examine the effects of these agents on social memory in ***:The results of proteomic and phosphoproteomic analyses revealed the characteristics of ventral hippocampal CA1(vCA1)under both physiological conditions and AD-like tau *** tau progressively accumulated,vCA1,especially its excitatory and parvalbumin(PV)neurons,were fully filled with mislocated and phosphorylated tau(p-Tau).This finding was not observed for dorsal hippocampal CA1(dCA1).The overexpression of human tau(hTau)in excitatory and PV neurons mimicked AD-like tau accumulation,significantly inhibited neuronal excitability and suppressed distinct discrimination-associated firings of these neurons within *** excitatory and PV neurons in vCA1 at specific rhythms and time windows efficiently ameliorated tau-impaired social ***,1 month of UA administration efficiently decreased tau accumulation via autophagy in a transcription factor EB(TFEB)-dependent manner and restored the vCA1 microcircuit to ameliorate tau-impaired social ***:This study elucidated distinct protein and phosphoprotein networks between dCA1 and vCA1 and highlighted the susceptibility of the vCA1 microcircuit to AD-like tau

关键词： Alzheimer’s disease Tau protein Ventral hippocampus Social memory Ursolic acid Transcription factor EB(TFEB)

Territorial Ecological Restoration with a High-carbon Storage Focus in the Beibu Gulf Urban Agglomeration of China:Insights from Carbon Metabolism Spatial Security Patterns

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Chinese Geographical Science 2025年第1期35卷 73-91页

作者： QIN Menglin liu Yuting TAN Qianxi ZHU Ziming WU Xinyu JIANG Hongbo LI Hang shi Qianqian School of Civil Engineering and Architecture Guangxi UniversityNanning 530004China School of Forestry Guangxi UniversityNanning 530004China Ecosystem Science and Management Program University of Northern British ColumbiaPrince George V2N 4Z9Canada Zhuhai Institute of Planning and Design Zhuhai 519000China

This study focuses on urgent research on restoring and enhancing carbon storage capacity in the Beibu Gulf Urban Agglomer-ation of China,a key area in the‘Belt and Road’Initiative,which aligns with carbon peaking and neutrality *** research ana-lyzes the spatial characteristics of carbon metabolism from 2000 to 2020 and uses models to identify stable carbon sink areas,positive carbon flow corridors,and carbon sequestration *** goal is to construct a carbon metabolism spatial security pattern(CMSSP)and propose territorial ecological restoration strategies under different development demand *** results show the following:1)in 2020,the study area’s carbon sink decreased by 8.29×10^(4) t C/yr compared with that in 2010 and by 10.83×10^(4) t C/yr compared with that in ***-carbon sinks were found mainly in mountainous areas,whereas low-carbon sinks are concentrated in urban con-struction land,rural residential areas,and land margins.2)From 2000 to 2020,the spatial security pattern of carbon metabolism tended to be‘high in the middle of the east and west and low in the gulf.’In 2000,2010,and 2020,16 stable carbon sinks were *** carbon energy flow density in Guangxi was greater than that in Guangdong and Hainan,with positive carbon flow corridors located primarily in Guangxi and *** number of carbon sequestration nodes remained stable at approximately 15,mainly in Guangxi and Hainan.3)Scenario simulations revealed that under the Nature-based mild restoration scenario,the carbon sink rate will reach 611.85×10^(4) t C/yr by 2030 and increase to 612.45×10^(4) t C/yr by 2060,with stable carbon sinks increasing to *** the restora-tion scenario based on Anti-globalization,the carbon sink will decrease from 610.24×10^(4) t C/yr in 2030 to 605.19×10^(4) t C/yr in 2060,with the disappearance of some positive carbon flow corridors and stable carbon *** the Human-based sustainable restoration scenario,the carbon sink area wil

关键词： carbon metabolism spatial security pattern(CMSSP) territorial ecological restoration carbon sink carbon storage capacity Beibu Gulf Urban Agglomeration,China

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Multi-scenario simulation of land use change and its impact on ecosystem services in the northeastern edge of the Qinghai-Xizang Plateau,China

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Journal of Arid Land 2025年第2期17卷 145-166页

作者： ZHANG Xuebin liu Yanni YIN Junfeng shi Peiji FENG Haoyuan shi Jing College of Geography and Environmental Science Northwest Normal UniversityLanzhou 730070China Faculty of Geographic Sciences Beijing Normal UniversityBeijing 100875China State Key Laboratory of Herbage Improvement and Grassland Agro-ecosystems College of EcologyLanzhou UniversityLanzhou 730000China

The Qinghai-Xizang Plateau(QXP)serves as a crucial ecological barrier in China and Asia,exerting profound influences on global climate and biodiversity *** Tibetan Autonomous Prefecture(hereinafter referred as Gannan Prefecture),located on the northeastern edge of the QXP,represents a fragile alpine ecosystem in which land use change significantly impacts ecosystem services(ESs).This study established a comprehensive framework,utilizing the Patch-generating Land-Use Simulation(PLUS)model coupled with the Integrated Valuation of Ecosystem Services and Tradeoffs(InVEST)model to predict land use patterns under the natural development scenario,cultivated land protection scenario,and ecological protection scenario for Gannan Prefecture by 2030 and evaluated four critical ESs:habitat quality(HQ),water yield(WY),soil retention(SR),and carbon storage(CS).The primary aim is to elucidate the impacts of dynamic land use change on *** results revealed that,from 2000 to 2020,HQ exhibited minimal variation,whereas CS experienced a slight ***,WY and SR showed significant *** the natural development scenario,construction land was projected to increase by 4247.74 hm^(2),primarily at the expense of forest *** cultivated land protection scenario anticipated an increase in farmland by 2634.36 hm^(2),which was crucial for maintaining food *** ecological protection scenario predicted a notable expansion of forest land,accompanied by a restrained development rate of construction *** ecological protection scenario also showed an increase in the ecosystem service index(ESI),encompassing 26.07%of the *** land and grassland emerged as the primary contributors to ESs,while construction land substantially impacted *** bodies exhibited minimal contribution to *** study enhanced the understanding of land use change impacts on ESs in fragile and high-altitude ecosystems,offering essential theoretical framework

关键词： PLUS-InVEST model ecosystem service habitat quality water yield soil retention carbon storage Qinghai-Xizang Plateau

CMOS direct conversion X-ray detector coupled with fluorinated liquid

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Nuclear Science and Techniques 2025年第1期36卷 59-68页

作者： shi-Hua liu Chao-Song Gao Xin Zhang Xiang-Ming Sun Meng Wu Zhi-Hui Han Tong Wan Yong-Shuai Ge Key Laboratory of Quark&Lepton Physics(MOE) Central China Normal UniversityWuhan 430079China guizhou Education University Guiyang 550018China Research Center for Medical Artificial Intelligence Chinese Academy of SciencesShenzhen Institutes of Advanced TechnologyShenzhen 518055China

X-ray detectors show potential applications in medical imaging,materials science,and nuclear *** achieve high detection efficiency and spatial resolution,many conventional semiconductor materials,such as amorphous selenium,cadmium telluride zinc,and perovskites,have been utilized in direct conversion X-ray ***,these semiconductor materials are susceptible to temperature-induced performance degradation,crystallization,delamination,uneven lattice growth,radiation damage,and high dark *** study explores a new approach by coupling an FC40 electronic fluorinated liquid with a specialized high-resolution and high-readout-speed complementary metal-oxide-semiconductor(CMOS)pixel array,specifically the Topmetal II−chip,to fabricate a direct conversion X-ray *** fluorinated liquid FC40(molecular formula:C_(21)F_(48)N_(2))is an electronic medium that is minimally affected by temperature and displays no issues with uniform *** exhibits a low dark current and minimal radiation damage and enables customizable thickness in X-ray *** addresses the limitations inherent in conventional semiconductor-based *** this study,simple X-ray detector imaging tests were conducted,demonstrating the excellent coupling capability between FC40 electronic fluorinated liquid and CMOS chips by the X-ray detector.A spatial resolution of 4.0 lp/mm was measured using a striped line par card,and a relatively clear image of a cockroach was displayed in the digital radiography imaging *** test results indicated the feasibility of fabricating an X-ray detector by combining FC40 electronic fluorinated liquid and CMOS *** to the absence of issues related to chip-material coupling,a high spatial resolution could be achieved by reducing the chip pixel *** method presents a new avenue for studies on novel liquid-based direct conversion X-ray detectors.

关键词： FC40 electronic fluorinated liquid CMOS pixel chip X-ray detector Spatial resolution

SYNTHESIS OF AZA-CROWN-ETHER CHOLESTERIC LIQUID CRYSTALS

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Chinese Chemical Letters 1992年第10期3卷 779-782页

作者： Ming gui XIE~a,shi Kui liu~b, Gang liu~c and Jiang Ling LI~d ~aDepartment of Chemistry, Sichuan University, Chengdu, 610064. ~bChengdu Institute of Organic Chemistry, Academia Sinica, 610015. ~cChengdu Institute of Chemical Engineering Research and Design, Chengdu, 610061 ~dEnviromental Monitoring Station of Wuhou District, Chengdu, 610041.

Five aza-crown-ethers were synthesized and four of them shown to have cholesteric liquid crystalline properties. Their properties relevant to cholesteric liquid crystal were determined by DSC and the textures. The typ... 详细信息

关键词： IR SYNTHESIS OF AZA-CROWN-ETHER CHOLESTERIC LIQUID CRYSTALS KBr

Climate changes drive phytoplankton community through complementarity and selection effects in a large mesotrophic reservoir

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Journal of Oceanology and Limnology 2025年第1期43卷 119-133页

作者： Yue WU Qi YE Siwen CHEN Lei JIANG Kaining CHEN Shuzhan MA Yiheng CHANG Jie liu Xiaoli shi State Key Laboratory of Lake Science and Environment Nanjing Institute of Geography and LimnologyChinese Academy of SciencesNanjing 210008China University of Chinese Academy of Sciences Beijing 100049China College of Nanjing University of Chinese Academy of SciencesNanjing 211135China China State Environmental Protection Key Laboratory of Aquatic Ecosystem Health in the Middle and Lower Reaches of Yangtze River Jiangsu Provincial Academy of Environmental ScienceNanjing 210036China School of Geography and Ocean Science Nanjing UniversityNanjing 210023China

Understanding the response of the phytoplankton community to climate change is essential for reservoir *** analyzed a long-term data series(2009–2020)on the phytoplankton community in a large mesotrophic reservoir in the wet season to investigate the impacts of temperature and precipitation increases caused by climate change on the functioning and trait composition of the phytoplankton *** the last twelve years,the 3-month accumulative precipitation increased from 291.03 mm to 590.91 mm,and the surface water temperature increased from 25.06℃to 26.49℃in wet season,*** changes caused a higher water level,stronger thermal stratification and lower nitrogen concentration in Daxi *** dynamic equilibrium model indicated that the increased precipitation and water temperature-related environmental changes would result in a more diverse and productive phytoplankton *** effects of increasing water temperature and precipitation on the niche complementarity and selection effects within the phytoplankton community were analyzed using structural equation model by means of the functional divergence index and functional evenness index,respectively,elucidating the reasons for the increase in cyanobacteria in the absence of a significant increase in nutrient *** on these results,it is advisable that more stringent phosphorus control standards might be conducted to reduce the risks of cyanobacteria proliferation in the context of global warming.

关键词： global warming climate change reservoir trait-based phytoplankton functional group cyanobacteria