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Geochemical constraints from hydrothermal fluid inclusions of altered deformation zone type Au(Ag)deposits in Yunkai area, South china

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chinese Science Bulletin 1999年第S2期44卷 230-232页

作者： WANG Zuwei~1, ZHANG Haihua~2. YAO Dongliang~2.and ZHOU Yongzhang~3 1. Department of Geography, Tianjin Normal University, Tianjin 300071, china 2. guangzhou Institute of {2., chinese academy of sciences, guangzhou 510640, china 3. Department of Earth sciences, Zhongshan University, guangzhou 5102.5, china eeszhou@*** Department of Geography Tianjin Normal University Tianjin 300071 China guangzhou Institute of geochemistry Chinese Academy of Sciences Guangzhou 510640 China Department of Earth sciences Zhongshan University Guangzhou 510275 China

THE altered deformation zone type Au (Ag) deposits share an important part from the precious metallicore deposits in the Yunkai area, South china. Their formation is a history of poly-stage evolution. Pre- liminary source strata, Calidoniam metamorphism, Indosinian-Yanshanian ductile shear deformation andassociated hydrotheraml alteration all play certain roles in the history. This note discusses the geochemical conditional of the hydrothermal fluids during mineralization. Two representative ore deposits, the Pangxidong Ag(Au) deposit and Hetai Au deposits are selectedfor this study. They are hosted in altered ductile shear zones. Wall-rock hydrothermal alteration is bothspatially and temporally associated with the development of the ductile shear system. Silicification occurred throughout the whole alteration process. There are three groups of quartz: thepredeformational quartz, the early stage hydrothermal quartz, and the late stage hydrothermal quartz asso-

关键词： precious metallic deposit fluid inclusions mineralizing fluid South china.

Gas hydrate fast nucleation from melting ice and quiescent growth along vertical heat transfer tube

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Science china Chemistry 2005年第1期48卷 75-82页

作者： XIE Yingming1,2. GUO Kaihua2. LIANG Deqing2. FAN Shuanshi2. GU Jianming1 & CHEN Jinggui2.1. Institute of Refrigeration and Cryogenics, Shanghai Jiaotong University, Shanghai 2.0030, china 2. guangzhou Institute of Energy Conversion, The {2., guangzhou 510640, china 1. Institute of Refrigeration and Cryogenics Shanghai Jiaotong University 200030 Shanghai China 2. guangzhou Institute of Energy Conversion The Chinese Academy of Sciences 510640 Guangzhou China

During the observation of HCFC141b gas hydrate growth processes outside a ver- tical heat transfer tube, two exciting phenomena were found: fast nucleation of gas hydrate from melting ice, and the spontaneous permeation of water into the guest phases along the surface of heat transfer tube to form gas hydrate continuously. These two phenomena were explained with Zhou & Sloan’s hypothesis and the theory of surface free energy respectively, and a novel method of gas hydrate formation was presented——gas hydrate fast nucleation from melting ice and quiescent growth along heat transfer tube. There is no mechanic stirring in this method, the formed gas hydrates are compact, the ratio of unreacted interstitial water is little, which overcome the drawback of high energy cost and high ratio of unreacted interstitial water among the formed gas hydrates in the system with mechanic stirring. This finding will benefit the gas hydrate ap- plication technologies such as natural gas storage technology or cool storage technology with gas hydrate.

关键词： gas hydrate, natural gas storage, cool storage, fast nucleation from melting ice, permeation, surface free energy.

Determination of paleo-pressure for a natural gas pool formation based on PVT characteristics of fluid inclusions in reservoir rocks——A case study of Upper-Paleozoic deep basin gas trap of the Ordos Basin

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Science china Earth sciences 2004年第6期47卷 507-513页

作者： MI Jingkui1,2.XIAO Xianming1,LIU Dehan1,& SHEN Jiagui1 1.State Key Laboratory of Organic geochemistry,guangzhou Institute of geochemistry,chinese academy of sciences,guangzhou 510640,china 2.Institute of Sedimentary Mineral and Resources,Department of Civil Engineering,Xiangtan Polytechnic University,Xiangtan 4112.1,china 1. State Key Laboratory of Organic geochemistry Guangzhou Institute of Geochemistry Chinese Academy of Sciences 510640 Guangz China 2. Institute of Sedimentary Mineral and Resources Department of Civil Engineering Xiangtan Polytechnic University 411 Xiangtan China

It has been proved to be a difficult problem to determine directly trapping pressure of fluid inclusions. Recently, PVT simulation softwares have been applied to simulating the trapping pressure of petroleum inclusions in reservoir rocks, but the reported methods have many limita- tions in practice. In this paper, a method is suggested to calculating the trapping pressure and temperature of fluid inclusions by combining the isochore equations of a gas-bearing aqueous inclusion with its coeval petroleum inclusions. A case study was conducted by this method for fluid inclusions occurring in the Upper-Paleozoic Shanxi Formation reservoir sandstones from the Ordos Basin. The results show that the trapping pressure of these inclusions ranges from 2. to 32.MPa, which is 6─7 MPa higher than their minimum trapping pressure although the trapping temperature is only 2.3℃ higher than the homogenization temperature. The trapping pressure and temperature of the fluid inclusions decrease from southern area to northern area of the basin. The trapping pressure is obviously lower than the state water pressures when the inclusions formed. These data are consistent with the regional geological and geochemical conditions of the basin when the deep basin gas trap formed.

关键词： Ordos Basin, fluid inclusion,PVTsim,trapping pressure.

On deposits controlled by tectonic lenses

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Science china Earth sciences 2004年第12期47卷 1095-1101页

作者： WANG Jincao 1 ,XIA Bin 1 & JI Shaocheng 2.1.guangzhou Institute of geochemistry,{2.,guangzhou 510640,china 2.Department of Civil,Geological and Mining Engineering,Montreal Institute of Technology,P.O.Box6079,Station Centre-ville Montreal,Canada 1. chinese academy of sciences Guangzhou Institute of Geochemistry 510640 Guangzhou China 2. Department of Civil Geological and Mining Engineering Montreal Institute of Technology Station Centre-ville Montreal P. O. Box 6079 Canada

By study of the typical tectonic lenses controlling some ore deposits, the tectonic lens boundaries may be classified into fuzzy boundaries, sharp boundaries and complex boundaries, and the metallostructures in tectonic lenses may be classified into vein-type, stock- work-type and breccia-type. After studying their metallostructures, we suggest the conception on tectonic lenses as an ore-forming system, realizing that the compact-function ore-forming system is made up of the lenticular weak-strain domain(Q) and its outside linear strong-strain belt(P). The ore-forming system, which is composed of four subsystems that coupled with each other and exert their system functions to the full, includes the dual-dynamical system made up of tectonic and fluid dynamics, the metallotectonic system controlled by hydrofracturing, the ore-source system made up of multi-substances and the mineral transportation system contacted by tectonic network. Deformational partitioning, hydrofracturing and tectonic pumping operate the consid- erable function while the system function practises. Finally, the significance of metallotectonics on the tectonic lenses is discussed in the paper.

关键词： tectonic lenses, boundary type of tectonic lenses, type of metallostructures, tectonic lens as an ore-forming system.

Experimental Study of Partial Melting of Mantle Peridotite -A Discussion about the Genesis of Sih'ca-rich Fluids (Melts)

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Acta Geologica Sinica(English Edition) 1999年第4期73卷 395-403页

作者： LI Jianping guangzhou Institute of geochemistry, {2., guangzhou, 510640, chinaand Kornprobst JACQUES Departement des sciences de la Terre, Universite Blaise Pascal, 610038 Clermont-Ferrand, France chinese Acad Sci Guangzhou Inst Geochem Guangzhou 510640 Peoples R China Univ Blaise Pascal Dept Sci Terre F-610038 Clermont Ferrand France

Experiments on partial melting of mantle lherzolite have been realized at 0.6 and 1.0 GPa and the chemical compositional variations of melts during different melting stages have been first discussed. The results show that the trends of variations in SiO2. CaO, Al2.3, Na2. and TiO2.are different at different melting stages. The melts produced at lower pressure are richer in SiO2.than those at higher pressure. The mantle-derived silica-rich fluids (silicate melts) are polygenetic, but the basic and intermediate-acid silicate melts in mantle peridotite xenoliths from the same host rocks, which have equivalent contents of volatile and alkali components and different contents of other components, should result from in-situ (low-degree) partial melting of mantle peridotite under different conditions (e.g. at different depths, with introduction of C-O-H fluids or in the presence of metasomatic minerals). The intermediate-acid melts may be the result of partial melting (at lower pressure) Opx + Sp + K-Na-rich fluid ±(Am-phi) ± (Phlog) = OI + melt. But the intermediate-acid magmas cannot be produced from the partial melting of normal mantle peridotite unless the crustal materials are introduced to some extent.

关键词： mantle peridotite in-situ partial melting compositional variation of melt genesis of silica-rich fluid (stlicate melt)

geochemistry CONSTRAIN ON TECTONIC EVOLUTION OF PALEO-TETHYS IN SE YUNNAN,china

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地学前缘 2000年第S1期7卷 276-277页

作者： Dong Yunpeng 1,2., Zhu Bingquan 2. Zhang Guowei 1,Yao Anping 1[WT5,5”BX](1 Department of Geology, Northwest University, Xi’an 710069, china 2.guangzhou Institute of {2., chinese academy of sciences, guangzhou 510640, china)

There has been a long\|term debate about the Paleo\|Tethyan Ocean in South china continent. Based on the geological and geochemical studies, it is suggested that there exist two tectonic belts in SE Yunnan, SW china called Ailao Shan zone and Shizong—Mile zone, which separate Yangtze Block, Cathysian Block and Indo\|china Block from each other. The evolutionary history and its geodynamics of these suture zones are correlated with the Paleo\|Tethyan Ocean. Both of the zones are keys to understanding whether the Paleo\|Tethyan Ocean extended from Western Yunnan area to east of the South china continent. The Ailao Shan belt consists of Red River fault, Ailao Shan fault, Shuanggou fault and Huashan—Yayi fault, which are the boundaries of the Ailao Shan basement metamorphic belt, ophiolitic melange belt and Island\|arc volcanic\|sediments belt, *** ophiolitic melange belt is characterized by the existence of the ophiolite in Shuanggou area, which represents the relicts of the oceanic crust of the Ailao Shan Ocean. In addition, there exist volcanic rocks in west of the ophiolitic melange belt in Jingdong area. The geochemical characteristics of basalts in Jingdong are similar to that of the E\|MORB. Synthesized studies on geochemistry and tectonics suggest that the basalts in Jingdong area were formed in an extensional rift setting in Devonian.

关键词： SE Yunnan Paleo\|Tethys tectonic evolution geochemistry ge odynamics

Loss of energetic particles due to feedback control of resistive wall mode in HL-3

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Plasma Science and Technology 2024年第10期26卷 17-28页

作者： Yifei ZHAO Yueqiang LIU guangzhou HAO Zhengxiong WANG Guanqi DONG Shuo WANG Chunyu LI Guanming YANG Yutian MIAO Yongqin WANG Dalian University of Technology Dalian 116024People’s Republic of China General Atomics San Diego CA 92186-5608United States of America Southwestern Institute of Physics Chengdu 610041People’s Republic of China

Effects of three-dimensional(3D)magnetic field perturbations due to feedback control of an unstable n=1(n is toroidal mode number)resistive wall mode(RWM)on the energetic particle(EP)losses are systematically investigated for the HL-3 *** MARS-F(Liu et al 2.00 *** 73681)code,facilitated by the test particle guiding center tracing module REORBIT,is utilized for the *** RWM is found to generally produce no EP loss for cocurrent particles in *** the same perturbation level at the sensor location for the close-loop system,feedback produces nearly the same loss of counter-current EPs compared to the open-loop *** however that the sensor signal is ten times smaller in the close-loop system than the open-loop counter part(reflecting the fact that the RWM is more stable with feedback),the counter-current EP loss is found significantly reduced in the *** of EP losses occur only for particles launched close to the plasma edge,while particles launched further away from the plasma boundary experience much less *** strike points of lost EPs on the HL-3 limiting surface become more scattered for particles launched closer to the plasma *** into account the full gyro-orbit of particles while approaching the limiting surface,REORBIT finds slightly enhanced loss fraction.

关键词： energetic particles resistive wall mode HL-3

Petrology and mineral chemistry of new ureilites found in Grove Mountains, Antarctica

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Progress in Natural Science:Materials International 2008年第4期18卷 431-439页

作者： Bingkui Miaoa,b,, Yangting Linb, Guiqin Wangc, Daode Wangc, Ziyuan Ouyangd a Key Laboratory of Geological Engineering Center of Guangxi Province, Guilin University of Technology, Guilin 541004, china b State Key Laboratory of Lithospheric Evolution, Institute of Geology and Geophysics, chinese academy of sciences, Beijing 10002., china c Key Laboratory of Isotope Geochronology and geochemistry, guangzhou Institute of geochemistry, chinese academy of sciences, guangzhou 510640, chinad National Astronomical Observatories, chinese academy of sciences, Beijing 100012. china Key Laboratory of Geological Engineering Center of Guangxi Province Guilin University of Technology Guilin 541004 China State Key Laboratory of Lithospheric Evolution Institute of Geology and Geophysics Chinese Academy of Sciences Beijing 100029 China Key Laboratory of Isotope Geochronology and geochemistry Guangzhou Institute of Geochemistry Chinese Academy of Sciences Guangzhou 510640 China National Astronomical Observatories Chinese Academy of Sciences Beijing 100012 China

Petrography and mineral chemistry of two new ureilites, GRV 02.512.and 02.931, from the Grove Mountains, Antarctica, are reported in this paper. GRV 02.512.exhibits a typical ureilite texture, and consists of 48.3% olivine, 9.4% pigeonite and 38.1% carbo- naceous interstitial material and/or reduction product. GRV 02.931 has a cataclastic porphyritic texture, and consists of 19.1% olivine and 14.1% pigeonite embedded in 66.3% carbonaceous interstitial material and/or reduction product. The coarse-grained olivine and pigeonite in both meteorites have homogeneous cores, and they are FeO-rich within the range of the ferroan subgroup (subgroup I) of olivine-pigeonite ureilites. All olivine grains of the meteorites show reduction zones along boundaries and cracks. Abundant diamond coexists with graphite as graphite-rich patches and veins in the carbonaceous interstitial material. Petrogenesis of both meteorites and the origin of diamond are discussed.

关键词： Meteorite Achondrite Ureilite Diamond Antarctica

Lincang Superlarge Germanium Deposit in Yunnan Province,china: Sedimentation,Diagenesis,Hydrothermal Process and Mineralization

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Journal of Earth Science 1998年第2期17卷 37-44页

作者： Zhuang Hanping Lu Jialan Fu Jiamo Liu Jinzhong guangzhou Institute of geochemistry, {2., guangzhou 510640

The mineralization is related closely to sedimentation, diagenesis and hydrothermal processes. In this paper, investigations are carried out on coal occurrence, maceral composition, inorganic minerals, trace elements and huminite reflectance. It is concluded that the source of Lincang superlarge deposit is mainly the muscovite granite in the west edge of the basin. During sedimentation, Ge (germanium) was leached out and entered the basin. Ge was adsorbed by lower organism and humic substances in water. Lincang lignite underwent three thermal processes: peatification, early diagenesis and hydrothermal transformation. During peatification, Ge was adsorbed or complexed by humic colloids. During early diagenesis, the Ge associated with humic acids was hard to mobilize or transport. Most of Ge entered the structure of huminite while a small amount of Ge was associated with residual humic acids as complex or humate. During hydrothermal transformation, the heated natural water or deep fluid from basement encountered the coal layer within tectonic weak zone. SO 2. 4 was reduced by coal organic matter. Pyrite and calcite formed. Hydrothermal process did not contribute significantly to mineralization.

关键词： Lincang superlarge germanium deposit sedimentation diagenesis hydrothermal process mineralization.