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GaAs-chip-based mid-infrared supercontinuum generation

Light(Science & Applications) 2023年第11期12卷 2443-2450页

作者： geoffroy granger Myriam Bailly Hugo Delahaye Cristian Jimenez Idris Tiliouine Yann Leventoux Jean-Christophe Orlianges Vincent Couderc Bruno Gérard Rezki Becheker Said Idlahcen Thomas Godin Ammar Hideur Arnaud Grisard Eric Lallier Sébastien Février Universitéde Limoges XLIM UMR CNRS 7252 123 Av.A.Thomas87060 LimogesFrance Thales Research&Technology 1 Av.Augustin Fresnel91767 Palaiseau CedexFrance III-V Lab 1 Av.Augustin Fresnel91767 Palaiseau CedexFrance CORIA(UMR 6614) CNRS-INSA Rouen-Universitéde Rouen NormandieNormandie UniversitéSaint-Etienne du RouvrayFrance

The mid-infrared spectral region opens up new possibilities for applications such as molecular spectroscopy with high spatial and frequency *** example,the mid-infrared light provided by synchrotron sources has helped for early diagnosis of several ***,alternative light sources at the table-top scale would enable better access to these state-of-the-art characterizations,eventually speeding up research in biology and *** supercontinuum generation in highly nonlinear waveguides pumped by compact fiber lasers represents an appealing alternative to ***,we introduce orientation-patterned gallium arsenide waveguides as a new versatile platform for mid-infrared supercontinuum *** and fiber-based pump lasers are optimized in tandem to allow for the group velocities of the signal and the idler waves to match near the degeneracy *** configuration exacerbates supercontinuum generation from 4 to 9μm when waveguides are pumped at 2750 nm with few-nanojoule energy *** brightness of the novel mid-infrared source exceeds that of the thirdgeneration synchrotron source by a factor of *** also show that the nonlinear dynamics is strongly influenced by the choice of waveguide and laser parameters,thus offering an additional degree of freedom in tailoring the spectral profile of the generated *** an approach then opens new paths for high-brightness mid-infrared laser sources development for high-resolution spectroscopy and ***,thanks to the excellent mechanical and thermal properties of the waveguide material,further power scaling seems feasible,allowing for the generation of watt-level ultra-broad frequency combs in the mid-infrared.

关键词： waveguide pumped pump

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Do DBPs swim in salt water pools? Comparison of 60 DBPs formed by electrochemically generated chlorine vs. conventional chlorine

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Journal of Environmental Sciences 2022年第7期34卷 232-241页

作者： Caroline O.granger Susan D.Richardson Department of Chemistry and Biochemistry University of South Carolina631 Sumter St.ColumbiaSC 29208USA

Disinfectants are added to swimming pools to kill harmful pathogens. Although liquid chlorine(sodium hypochlorite) is the most commonly used disinfectant, alternative disinfection techniques like electrochemically generated mixed oxidants or electrochemically generated chlorine, often referred to as salt water pools, are growing in popularity. However, these disinfectants react with natural organic matter and anthropogenic contaminants introduced to the pool water by swimmers to form disinfection byproducts(DBPs). DBPs have been linked to several adverse health effects, such as bladder cancer, adverse birth outcomes, and asthma. In this study, we quantified 60 DBPs using gas chromatography-mass spectrometry and assessed the calculated cytotoxicity and genotoxicity of an indoor community swimming pool before and after switching to a salt water pool with electrochemically generated chlorine. Interestingly, the total DBPs increased by 15% upon implementation of the salt water pool, but the calculated cytotoxicity and genotoxicity decreased by 45% and 15%, respectively. Predominant DBP classes formed were haloacetic acids, with trichloroacetic acid and dichloroacetic acid contributing 57% of the average total DBPs formed. Haloacetonitriles, haloacetic acids, and haloacetaldehydes were the primary drivers of calculated cytotoxicity, and haloacetic acids were the primary driver of calculated genotoxicity. Diiodoacetic acid, a highly toxic iodinated DBP, is reported for the first time in swimming pool water. Bromide impurities in sodium chloride used to electrochemically generate chlorine led to a 73% increase in brominated DBPs, primarily driven by bromochloroacetic acid. This study presents the most extensive DBP study to-date for salt water pools.

关键词： Disinfection byproducts Swimming pools Cytotoxicity Genotoxicity GC-MS

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How well does XAD resin extraction recover halogenated disinfection byproducts for comprehensive identification and toxicity testing?

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Journal of Environmental Sciences 2022年第7期34卷 264-275页

作者： Xiaobin Liao Joshua M.Allen Caroline O.granger Susan D.Richardson Department of Chemistry and Biochemistry University of South CarolinaColumbiaSouth Carolina 29208USA Institute of Municipal and Environmental Engineering College of Civil EngineeringHuaqiao UniversityFujian 361021China Currently at LanzaTech 535 Commerce DriveSopertonGeorgia 30457USA

Halogenated disinfection byproducts(DBPs) are an unintended consequence of drinking water disinfection, and can have significant toxicity. XAD resins are commonly used to extract and enrich trace levels of DBPs for comprehensive, nontarget identification of DBPs and also for in vitro toxicity studies. However, XAD resin recoveries for complete classes of halogenated DBPs have not been evaluated, particularly for low, environmentally relevant levels(ng/L to low μg/L). Thus, it is not known whether levels of DBPs or the toxicity of drinking water might be underestimated. In this study, DAX-8/XAD-2 layered resins were evaluated, considering both adsorption and elution from the resins, for extracting 66 DBPs from water. Results demonstrate that among the 7 classes of DBPs investigated, trihalomethanes(THMs), including iodo-THMs, were the most efficiently adsorbed, with recovery of most THMs ranging from 50%-96%, followed by halonitromethanes(40%-90%). The adsorption ability of XAD resins for haloacetonitriles, haloacetamides, and haloacetaldehydes was highly dependent on the individual species. The adsorption capacity of XAD resins for haloacetic acids was lower(5%-48%), even after adjusting to p H 1 before extraction. Recovery efficiency for most DBPs was comparable with their adsorption, as most were eluted effectively from XAD resins by ethyl acetate. DBP polarity and molecular weight were the two most important factors that determine their recovery. Recovery of trichloromethane, iodoacetic acid, chloro-and iodo-acetonitrile, and chloroacetamide were among the lowest, which could lead to underestimation of toxicity, particularly for iodoacetic acid and iodo-acetonitrile, which are highly toxic.

关键词： XAD resins Disinfection byproducts DBPs Recovery Toxicity

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Intestinal stasisassociated bowel in flam mation

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World Journal of Gastroenterology 1999年第6期5卷 518-521页

作者： Shunichiro Komatsu 1, Yuji Nimura 1 and D.Neil granger 2 Nagoya University School of Medicine 日本 Louislana State University Health Sciences Genter 美国

INTRODUCTIONAnatomical structures that create reservoirs for stagnant intestinal contents are a characteristic feature of common inflammatory disorders such as diverticulitis and appendicitis.

关键词： intestinal stasis bowel inflammation endothelial cell intercellular adhesion molecule 1

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Factors affecting healing after arthroscopic rotator cuff repair

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World Journal of Orthopedics 2015年第2期6卷 211-220页

作者： Amir M Abtahi Erin K granger Robert Z Tashjian Department of Orthopaedic Surgery University of Utah

Rotator cuff repair has been shown to have good longterm results. Unfortunately, a significant proportion of repairs still fail to heal. Many factors, both patient and surgeon related, can influence healing after repair. Older age, larger tear size, worse muscle quality, greater muscle-tendon unit retraction, smoking, osteoporosis, diabetes and hypercholesterolemia have all shown to negatively influence tendon healing. Surgeon related factors that can influence healing include repair construct-single vs double row, rehabilitation, and biologics including platelet rich plasma and mesenchymalstem cells. Double-row repairs are biomechanically stronger and have better healing rates compared with single-row repairs although clinical outcomes are equivalent between both constructs. Slower, less aggressive rehabilitation programs have demonstrated improved healing with no negative effect on final range of motion and are therefore recommended after repair of most full thickness tears. Additionally no definitive evidence supports the use of platelet rich plasma or mesenchymal stem cells regarding improvement of healing rates and clinical outcomes. Further research is needed to identify effective biologically directed augmentations that will improve healing rates and clinical outcomes after rotator cuff repair.

关键词： Shoulder Repair Healing Tendon Rotator cuff tear

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Role of the endothelium in inflammatory bowel diseases

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World Journal of Gastroenterology 2011年第5期17卷 578-593页

作者： Walter E Cromer J Michael Mathis Daniel N granger Ganta V Chaitanya J Steven Alexander Department of Cellular Biology and Anatomy LSU Health Sciences Center-Shreveport1501 Kings HighwayShreveportLA 71130-3932United States Department of Cellular and Molecular Physiology LSU Health Sciences Center-Shreveport1501 Kings HighwayShreveportLA 71130-3932United States

Inflammatory bowel diseases(IBD) are a complex group of diseases involving alterations in mucosal immunity and gastrointestinal physiology during both initiation and progressive phases of the *** the core of these alterations are endothelial cells,whose continual adjustments in structure and function coordinate vascular supply,immune cell emigration,and regulation of the tissue *** of the endothelium in IBD(angiogenesis),mediated by inflammatory growth factors,cytokines and chemokines,is a hallmark of active gut disease and is closely related to disease *** endothelium in newly formed or inflamed vessels differs from that in normal vessels in the production of and response to inflammatory cytokines,growth factors,and adhesion molecules,altering coagulant capacity,barrier function and blood cell recruitment in *** review examines the roles of the endothelium in the initiation and propagation of IBD pathology and distinctive features of the intestinal endothelium contributing to these conditions.

关键词： Microvasculature Endothelium Inflamma-tion Nitric oxide Adhesion molecules Crohn's disease Ulcerative colitis Cytokines Chemokines Growth factors

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A balancing act: Optimizing free chlorine contact time to minimize iodo-DBPs, NDMA, and regulated DBPs in chloraminated drinking water

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Journal of Environmental Sciences 2022年第7期34卷 315-325页

作者： Matthew A.Bloodgood Sridevi Anduri Chowdary Eric J.Daiber Honglan Shi Caroline O.granger Susan D.Richardson Student Services Authority U.S.Environmental Protection AgencyNational Exposure Research LaboratoryAthensGA 30605USA Department of Chemistry Missouri University of Science and TechnologyRollaMO 65409USA Department of Chemistry and Biochemistry University of South CarolinaColumbiaSC 29208USA

Many drinking water treatment plants in the U.S. have switched from chlorination to chloramination to lower levels of regulated trihalomethane(THM) and haloacetic acid(HAA) disinfection byproducts(DBPs) in drinking water and meet the current regulations. However, chloramination can also produce other highly toxic/carcinogenic, unregulated DBPs: iodoacids, iodo-THMs, and N-nitrosodimethylamine(NDMA). In practice, chloramines are generated by the addition of chlorine with ammonia, and plants use varying amounts of free chlorine contact time prior to ammonia addition to effectively kill pathogens and meet DBP regulations. However, iodo-DBPs and nitrosamines are generally not considered in this balancing of free chlorine contact time. The goal of our work was to determine whether an optimal free chlorine contact time could be established in which iodo-DBPs and NDMA could be minimized, while keeping regulated THMs and HAAs below their regulatory limits. The effect of free chlorine contact time was evaluated for the formation of six iodo-trihalomethanes(iodo-THMs), six iodo-acids, and NDMA during the chloramination of drinking water. Ten different free chlorine contact times were examined for two source waters with different dissolved organic carbon(DOC) and bromide/iodide. For the low DOC water at pH 7 and 8, an optimized free chlorine contact time of up to 1 h could control regulated THMs and HAAs, as well as iodo-DBPs and NDMA. For the high DOC water, a free chlorine contact time of 5 min could control iodo-DBPs and NDMA at both p Hs, but the regulated DBPs could exceed the regulations at pH 7.

关键词： Iodo-DBPs NDMA Disinfection byproducts Chloramine Drinking water Free chlorine contact time

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Functional outcomes assessment in shoulder surgery

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World Journal of Orthopedics 2014年第5期5卷 623-633页

作者： James D Wylie James T Beckmann Erin granger Robert Z Tashjian Department of Orthopaedic Surgery University of Utah

The effective evaluation and management of orthopaedic conditions including shoulder disorders relies upon understanding the level of disability created by the disease process. Validated outcome measures are critical to the evaluation process. Traditionally, outcome measures have been physician derived objective evaluations including range of motion and radiologic evaluations. However, these measures can marginalize a patient's perception of their disability or outcome. As a result of these limitations, patient self-reported outcomes measures have become popular over the last quarter century and are currently primary tools to evaluate outcomes of treatment. Patient reported outcomes measures can be general health related quality of life measures, health utility measures, region specific health related quality of life measures or condition specific measures. Several patients self-reported outcomes measures have been developed and validated for evaluating patients with shoulder disorders. Computer adaptive testing will likely play an important role in the arsenal of measures used to evaluate shoulder patients in the future. The purpose of this article is to review the general health related quality-of-life measures as well as the jointspecific and condition specific measures utilized in evaluating patients with shoulder conditions. Advancesin computer adaptive testing as it relates to assessing dysfunction in shoulder conditions will also be reviewed.

关键词： Shoulder Functional outcome Quality-oflife Health utility measure Patient reported outcome

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宇宙成因核素^(10)Be揭示的北祁连山侵蚀速率特征

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地球科学进展 2015年第2期30卷 268-275页

作者：胡凯方小敏赵志军 Darryl granger 中国科学院青藏高原研究所北京100101 南京师范大学地理科学学院江苏南京210023 普度大学地球大气与行星科学系美国印第安纳州47907

山脉侵蚀速率的大小和时空分布信息是研究山脉构造—气候相互作用和地貌演化的关键切入点,其大小是受气候还是构造控制争论已久。宇宙成因核素10Be方法为从千年至万年尺度上定量研究流域平均侵蚀速率提供了一种先进和快捷的技术手段,为... 详细信息

山脉侵蚀速率的大小和时空分布信息是研究山脉构造—气候相互作用和地貌演化的关键切入点,其大小是受气候还是构造控制争论已久。宇宙成因核素10Be方法为从千年至万年尺度上定量研究流域平均侵蚀速率提供了一种先进和快捷的技术手段,为揭示侵蚀速率与现代气候和构造地貌因子的关系并进行相关分析提供了基础。利用该方法对北祁连山近现代侵蚀速率进行了研究。所采集的9个流域现代河沙样品,结合前人数据进行共同分析,结果显示该区侵蚀速率的变化范围为18.7~833 mm/ka,北祁连山中段的侵蚀速率约为323 mm/ka,该区侵蚀速率与降雨量没有明显的对应关系,但与流域平均坡度呈现很好的非线性关系,揭示坡度是该区侵蚀速率的最主要控制因素。通过对比北祁连山地表平均侵蚀速率和该区域的断层垂直滑动速率发现整体上该区域地表侵蚀速率要低于祁连山北缘断层的垂直滑动速率,反映了北祁连山正处于地形抬升和生长的过程之中。

关键词：宇宙成因核素流域平均侵蚀速率坡度降水量祁连山

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Enhancing the Resilience of Electricity Systems

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Engineering 2017年第5期3卷 580-582页

作者： Ben A. Wender M. granger Morgan K. John Holmes Board on Energy and Environmental Systems Division on Engineering and Physical Sciences The National Academies of Sciences Engineering and Medicine Washington DC20001 USA Department of Engineering and Public Policy Carnegie Mellon University Pittsburgh PA 15213 USA

1.引言经过超级飓风桑迪和飓风哈维、厄玛、何塞、玛利亚、卡特里娜等重大干扰事件的影响,以及2003年美国东北部的大停电事件,美国对具备恢复力的电力系统的需求越加凸显,也更加意识到电力基础设施对恶意物理和网络攻击的脆弱性。尽管... 详细信息

1.引言经过超级飓风桑迪和飓风哈维、厄玛、何塞、玛利亚、卡特里娜等重大干扰事件的影响,以及2003年美国东北部的大停电事件,美国对具备恢复力的电力系统的需求越加凸显,也更加意识到电力基础设施对恶意物理和网络攻击的脆弱性。尽管事后新闻媒体立即对事件进行了大量的报道。

关键词：恢复力 resilience 电力系统停电事件电力基础设施网络攻击 electricity 干扰事件卡特里娜美国东北部

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