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Magnetic properties and magnetocaloric effects in Eu(Ti,Nb,Mn)O_(3) perovskites

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Journal of Rare Earths 2024年第8期42卷 1560-1567,I0006页

作者： Junfeng Wang Huicai Xie Quanyi Liu Zhihong Hao Zhaojun Mo Qi fu Xinqiang gao Jun Shen Ganjiang Innovation Academy Chinese Academy of SciencesGanzhou341119China Faculty of Materials Metallurgy and Chemistry Jiangxi University of Science and TechnologyGanzhou341000China School of Rare Earth and New Materials Engineering Gannan University of Science and TechnologyGanzhou341000China Department of Energy and Power Engineering School of Mechanical EngineeringBeijing Institute of TechnologyBeijing100081China

In perovskite EuTiO_(3),the magnetic characteristics and magnetocaloric effect(MCE) can be flexibly regulated by converting the magnetism from antiferromagnetic to *** the present work,a series of Eu(Ti,Nb,Mn)O_(3) compounds,abbreviated as ETNMO for convenience of description,was fabricated and their crystallography,magnetism together with cryogenic magnetocaloric effects were systematically *** crystallographic results demonstrate the cubic perovskite structure for all the compounds,with the space group of *** magnetic phase transitions are observed in these second-order phase transition(SOPT) *** joint substitution of elements Mn and Nb can considerably manipulate the magnetic phase transition process and magnetocaloric performance of the ETNMO *** the Mn content increases,gradually widened-ΔS_(M)-T curves are obtained,and two peaks with a broad shoulder are observed in the-ΔS_(M)-T curves for Δμ_(0)H≤0-1 *** a field change of 0-5 T,the values of maximum magnetic entropy change(-ΔS_(M)^(max)) and refrigeration capacity(RC) are evaluated to be 34.7 J/(kg·K) and 364.9 J/kg for EuTi_(0.8625)Nb_(0.0625)Mn_(0.075)O_(3), 27.8 J/(kg·K) and367.6 J/kg for EuTi_(0.8375)Nb_(0.0625)Mn_(0.1)O_(3),23.2 J/(kg·K) and 369.2 J/kg for EuTi_(0.8125)Nb_(0.0625)Mn_(0.125)O_(3),17.1 J/(kg·K) and 357.6 J/kg for EuTi_(0.7875)Nb_(0.0625)Mn_(0.15)O_(3),*** co nsiderable MCE parameters make the ETNMO compounds potential candidates for cryogenic magnetic refrigeration.

关键词： ETNMO perovskites Cryogenic refrigeration Magnetic phase transition Magnetocaloric effect Rare earths

Long noncoding RNAs HAND2-AS1 ultrasound microbubbles suppress hepatocellular carcinoma progression by regulating the miR-873-5p/tissue inhibitor of matrix metalloproteinase-2 axis

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World Journal of Gastrointestinal Oncology 2024年第4期16卷 1547-1563页

作者： qiang Zou Hao-Wen Wang Xi-Liang Di Yuan Li Hui gao Department of Interventional Therapy Tianjin Medical University Cancer Institute and HospitalTianjin 300060China National Clinical Research Center for Cancer Key Laboratory of Cancer Prevention and TherapyTianjin’s Clinical Research Center for CancerTianjin 300060China College of Animal Science and Technology Northeast Agricultural UniversityHarbin 150030Heilongjiang ProvinceChina Department of Hematology and Oncology Linyi People’s HospitalLinyi 251500Shandong ProvinceChina Department of Comprehensive Oncology Baotou Cancer HospitalBaotou 014030Inner Mongolia Autonomous RegionChina

BACKGROUND Increasing data indicated that long noncoding RNAs(lncRNAs)were directly or indirectly involved in the occurrence and development of tumors,including hepatocellular carcinoma(HCC).Recent studies had found that the expression of lncRNA HAND2-AS1 was downregulated in HCC tissues,but its role in HCC progression is *** targeted microbubble destruction mediated gene transfection is a new method to overexpress *** To study the role of ultrasound microbubbles(UTMBs)mediated HAND2-AS1 in the progression of HCC,in order to provide a new reference for the treatment of *** In vitro,we transfected HAND2-AS1 siRNA into HepG2 cells by UTMBs,and detected cell proliferation,apoptosis,invasion and epithelial-mesenchymal transition(EMT)by cell counting kit-8 assay,flow cytometry,Transwell invasion assay and Western blotting,*** addition,we transfected miR-837-5p mimic into UTMBs treated cells and observed the changes of cell ***,the UTMBs treated HepG2 cells were transfected together with miR-837-5p mimic and tissue inhibitor of matrix metalloproteinase-2(TIMP2)overexpression vector,and we detected cell proliferation,apoptosis,invasion and *** vivo,we established a mouse model of subcutaneous transplantation of HepG2 cells and observed the effect of HAND2-AS1 silencing on tumor formation *** We found that UTMBs carrying HAND2-AS1 restricted cell proliferation,invasion,and EMT,encouraged apoptosis,and HAND2-AS1 silencing eliminated the effect of ***,miR-873-5p targets the gene HAND2-AS1,which also targets the 3’UTR of *** miR-873-5p mimic counteracted the impact of ***,miR-873-5p mimic solely or in combination with pcDNA-TIMP2 had been transformed into HepG2 cells exposed to *** discovered that TIMP2 reversed the effect of miR-873-5p mimic caused by the blocked signalling cascade for matrix metalloproteinase(MMP)2/*** vivo results showed that HAND2-AS1 silencing sig

关键词： Hepatocellular carcinoma Ultrasound microbubbles Long noncoding RNA HAND2-AS1 miR-873-5p Tissue inhibitor of matrix metalloproteinase-2

Performance of the Multilayer Film for Infrared Stealth based on VO_(2) Thermochromism

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Journal of Thermal Science 2024年第4期33卷 1312-1324页

作者： LI Yaru WANG fuqiang ZHANG Aoyu fu Zhichang SU Ronghua gao Tengfei WANG Zhen GUO Jicheng ORDOS Institute of Technology Ordos017000China School of Energy Science and Engineering Harbin Institute of TechnologyHarbin150001China School of New Energy Harbin Institute of Technology at WeihaiWeihai264209China Defense Engineering Institute AMSPLABeijing100850China

With the development of detection and identification technology,infrared stealth is of great value to realize anti-reconnaissance detection of military *** present,infrared stealth materials generally have deficiency,such as complex structure,inconvenient radiation regulation and cumbersome preparation steps,which greatly limit the practical application of infrared stealth *** view of the above deficiency of infrared stealth materials,we proposed a kind of multilayer film for infrared stealth using VO2thermochromism based on the temperature response mechanism of tuna to adjust its color,and through the intelligent reversible radiation regulation mechanism to meet the infrared stealth requirements of tanks in different actual *** results show that when the temperature increases from 300 K to 373 K,the peak emissivity of the film decreases from 94%to 20%in the 8-14μm band after structural optimization,which can realize the infrared stealth of the high temperature target in the 8-14μm *** average emissivity of the multilayer film for infrared stealth at3-5μm and 8-14μm band can be reduced to 34%and 27%at 373 K,and the peak emissivity at 5-8μm band can reach 65%,realizing dual-band infrared stealth in the 3-5μm and 8-14μm bands and heat dissipation in the 5-8μm *** multilayer film for infrared stealth based on VO2thermochromism designed by the authors can meet the characteristics of simple film structure,convenient radiation regulation and simple preparation.

关键词： vanadium dioxide multilayer film infrared stealth thermal management

Multi-Objective Optimization Algorithm for Grouping Decision Variables Based on Extreme Point Pareto Frontier

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Computers, Materials & Continua 2024年第4期79卷 1281-1299页

作者： JunWang Linxi Zhang Hao Zhang funan Peng Mohammed A.El-Meligy Mohamed Sharaf qiang fu College of Computer Science and Technology Shenyang University of Chemical TechnologyShenyang110142China Key Laboratory of Intelligent Technology for Chemical Process Industry of Liaoning Province Shenyang University of Chemical TechnologyShenyang110142China Industrial Engineering Department College of EngineeringKing Saud UniversityP.O.Box 800Riyadh11421Saudi Arabia

The existing algorithms for solving multi-objective optimization problems fall into three main categories:Decomposition-based,dominance-based,and *** multi-objective optimization problemsmainly focus on objectives,treating decision variables as a total variable to solve the problem without consideringthe critical role of decision variables in objective *** seen,a variety of decision variable groupingalgorithms have been ***,these algorithms are relatively broad for the changes of most decisionvariables in the evolution process and are time-consuming in the process of finding the Pareto *** solvethese problems,a multi-objective optimization algorithm for grouping decision variables based on extreme pointPareto frontier(MOEA-DV/EPF)is *** algorithm adopts a preprocessing rule to solve the Paretooptimal solution set of extreme points generated by simultaneous evolution in various target directions,obtainsthe basic Pareto front surface to determine the convergence effect,and analyzes the convergence and distributioneffects of decision *** the later stages of algorithm optimization,different mutation strategies are adoptedaccording to the nature of the decision variables to speed up the rate of evolution to obtain excellent individuals,thusenhancing the performance of the *** validation of the test functions shows that this algorithmcan solve the multi-objective optimization problem more efficiently.

关键词： Multi-objective evolutionary optimization algorithm decision variables grouping extreme point pareto frontier

Ginsenoside Rk3 modulates gut microbiota and regulates immune response of group 3 innate lymphoid cells to against colorectal tumorigenesis

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Journal of Pharmaceutical Analysis 2024年第2期14卷 259-275页

作者： Xue Bai Rongzhan fu Yannan Liu Jianjun Deng qiang Fei Zhiguang Duan Chenhui Zhu Daidi Fan Shaanxi Key Laboratory of Degradable Biomedical Materials School of Chemical EngineeringNorthwest UniversityXi'an710069China Biotech&Biomed Research Institute Northwest UniversityXi'an710069China School of Chemical Engineering and Technology Xi'an Jiaotong UniversityXi'an710069China

The gut microbiota plays a pivotal role in the immunomodulatory and protumorigenic microenvironment of colorectal cancer(CRC).However,the effect of ginsenoside Rk3(Rk3)on CRC and gut microbiota remains ***,the purpose of this study is to explore the potential effect of Rk3 on CRC from the perspective of gut microbiota and immune *** results reveal that treatment with Rk3 significantly suppresses the formation of colon tumors,repairs intestinal barrier damage,and regulates the gut microbiota imbalance caused by CRC,including enrichment of probiotics such as Akkermansia muciniphila and Barnesiella intestinihominis,and clearance of pathogenic *** metabolomics data demonstrate that Rk3 can modulate the metabolism of amino acids and bile acids,particularly by upregulating glutamine,which has the potential to regulate the immune ***,we elucidate the regulatory effects of Rk3 on chemokines and inflammatory factors associated with group 3 innate lymphoid cells(ILC3s)and T helper 17(Th17)signaling pathways,which inhibits the hyperactivation of the Janus kinase-signal transducer and activator of transcription 3(JAK-STAT3)signaling *** results indicate that Rk3 modulates gut microbiota,regulates ILC3s immune response,and inhibits the JAK-STAT3 signaling pathway to suppress the development of colon *** importantly,the results of fecal microbiota transplantation suggest that the inhibitory effect of Rk3 on colon tumors and its regulation of ILC3 immune responses are mediated by the gut *** summary,these findings emphasize that Rk3 can be utilized as a regulator of the gut microbiota for the prevention and treatment of CRC.

关键词： Colorectal cancer Ginsenoside Immune cells Gut microbiota

Cryptic diversity and rampant hybridization in annual gentians on the Qinghai-Tibet Plateau revealed by population genomic analysis

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Plant Diversity 2024年第2期46卷 194-205页

作者： Peng-Cheng fu Qiao-Qiao Guo Di Chang Qing-Bo gao Shan-Shan Sun School of Life Science Luoyang Normal UniversityLuoyang 471934PR China Key Laboratory of Adaptation and Evolution of Plateau Biota Northwest Institute of Plateau BiologyChinese Academy of SciencesXining 810001PR China

Understanding the evolutionary and ecological processes involved in population differentiation and speciation provides critical insights into biodiversity formation. In this study, we employed 29,865 single nucleotide polymorphisms(SNPs) and complete plastomes to examine genomic divergence and hybridization in Gentiana aristata, which is endemic to the Qinghai-Tibet Plateau(QTP) region. Genetic clustering revealed that G. aristata is characterized by geographic genetic structures with five clusters(West, East, Central, South and North). The West cluster has a specific morphological character(i.e., blue corolla) and higher values of FSTcompared to the remaining clusters, likely the result of the geological barrier formed by the Yangtze River. The West cluster diverged from the other clusters in the Early Pliocene;these remaining clusters diverged from one another in the Early Quaternary. Phylogenetic reconstructions based on SNPs and plastid data revealed substantial cyto-nuclear conflicts. Genetic clustering and D-statistics demonstrated rampant hybridization between the Central and North clusters,along the Bayankala Mountains, which form the geological barrier between the Central and North clusters. Species distribution modeling demonstrated the range of G. aristata expanded since the Last Interglacial period. Our findings provide genetic and morphological evidence of cryptic diversity in G. aristata, and identified rampant hybridization between genetic clusters along a geological *** findings suggest that geological barriers and climatic fluctuations have an important role in triggering diversification as well as hybridization, indicating that cryptic diversity and hybridization are essential factors in biodiversity formation within the QTP region.

关键词： Gentiana aristata Hybrid zone Qinghai-Tibet Plateau Plastome Nuclear SNPs

Theoretical analysis and engineering application of controllable shock wave technology for enhancing coalbed methane in soft and low‑permeability coal seams

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International Journal of Coal Science & Technology 2024年第2期11卷 123-142页

作者： Guodong Qiao Zegong Liu Yongmin Zhang Changping Yi Kui gao Shigui fu Youzhi Zhao School of Safety Science and Engineering Anhui University of Science and TechnologyHuainan 232001AnhuiChina Institute of Energy Hefei Comprehensive National Science CenterHefei 230031AnhuiChina School of Electrical Engineering Xi’an Jiaotong UniversityXi’an 710049ShanxiChina Division of Mining and Geotechnical Engineering LuleåUniversity of TechnologyLuleåSweden

Coalbed methane(CBM)is a significant factor in triggering coal and gas outburst disaster,while also serving as a clean *** the increasing depth of mining operations,coal seams that exhibit high levels of gas content and low permeability have become increasingly *** controllable shockwave(CSW)technology has proven effective in enhancing CBM in laboratory settings,there is a lack of reports on its field applications in soft and low-permeability coal *** study establishes the governing equations for stress waves induced by *** numerical inversion was employed to analyse the dynamic response of the coal seam during CSW ***,quantitative calculations were performed for the crushed zone,fracture zone,and effective CSW influence range,which guided the selection of field test *** results of the field test unveiled a substantial improvement in the gas permeability coefficient,the average rate of pure methane flowrate,and the mean gas flowrate within a 10 m radius of the antireflection *** enhancements were notable,showing increases of 3 times,13.72 times,and 11.48 times,***,the field test performed on the CSW antireflection gas extraction hole cluster demonstrated a noticeable improvement in CBM *** antireflection,the maximum peak gas concentration and maximum peak pure methane flow reached 71.2%and 2.59 m^(3)/min,*** findings will offer valuable guidance for the application of CSW antireflection technology in soft and low-permeability coal seams.

关键词： CSW antireflection in coal seams CBM extraction enhancement Soft and low-permeability coal seams Field test

Exact Convergence Rate of the Local Limit Theorem for a Branching Random Walk in Zd with a Random Environment in Time

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Chinese Annals of Mathematics,Series B 2024年第5期 805-822页

作者： Jian-xin LIU Zhi-qiang gao School of Mathematical Sciences Beijing Normal University Laboratory of Mathematics and Complex Systems (Ministry of Education) School of Mathematical Sciences Beijing Normal University

Abstract Consider a branching random walk with a random environment in time in the d-dimensional integer *** branching mechanism is governed by a supercritical branching process,and the particles perform a lazy random walk with an independent,non-identical increment *** A?Zd,let Z_n（A） be the number of offsprings of generation n located in *** exact convergence rate of the local limit theorem for the counting measure Zn（·） is *** partially extends the previous results for a simple branching random walk derived by gao （2017,*** Appl.）.

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Efficient and Stable Inverted Perovskite Solar Modules Enabled by Solid-Liquid Two-Step Film Formation

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Nano-Micro Letters 2024年第9期16卷 571-582页

作者： Juan Zhang Xiaofei Ji Xiaoting Wang Liujiang Zhang Leyu Bi Zhenhuang Su Xingyu gao Wenjun Zhang Lei Shi Guoqing Guan Abuliti Abudula Xiaogang Hao Liyou Yang qiang fu Alex K.‑Y.Jen Linfeng Lu Graduate School of Science and Technology Hirosaki University3‑BunkyochoHirosaki 036‑8561Japan Department of Materials Science and Engineering Department of ChemistryHong Kong Institute for Clean EnergyCity University of Hong Kong KowloonHong Kong 999077People’s Republic of China The Interdisciplinary Research Center Shanghai Advanced Research InstituteChinese Academy of SciencesShanghai 201210People’s Republic of China Shanghai Synchrotron Radiation Facility(SSRF) Zhangjiang LabShanghai Advanced Research InstituteChinese Academy of SciencesShanghai201204People’s Republic of China JINNENG Clean Energy Technology Ltd. Jinzhong 030300ShanxiPeople’s Republic of China Hangzhou Zhongneng Photoelectricity Technology Co. Ltd.Hangzhou 310018People’s Republic of China College of Chemical Engineering and Technology Taiyuan University of TechnologyTaiyuan 030024People’s Republic of China Institute of Regional Innovation Hirosaki University3‑BunkyochoHirosaki 036‑8561Japan

A considerable efficiency gap exists between large-area perovskite solar modules and small-area perovskite solar *** control of forming uniform and large-area film and perovskite crystallization is still the main obstacle restricting the efficiency of *** this work,we adopted a solid-liquid two-step film formation technique,which involved the evaporation of a lead iodide film and blade coating of an organic ammonium halide solution to prepare perovskite *** method possesses the advantages of integrating vapor deposition and solution methods,which could apply to substrates with different roughness and avoid using toxic solvents to achieve a more uniform,large-area perovskite ***,modification of the NiO_(x)/perovskite buried interface and introduction of Urea additives were utilized to reduce interface recombination and regulate perovskite *** a result,a large-area perovskite film possessing larger grains,fewer pinholes,and reduced defects could be *** inverted PSM with an active area of 61.56 cm^(2)(10×10 cm^(2)substrate)achieved a champion power conversion efficiency of 20.56%and significantly improved *** method suggests an innovative approach to resolving the uniformity issue associated with large-area film fabrication.

关键词： Inverted perovskite solar cells Perovskite solar modules Two-step film formation Crystallization Defect passivation