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Journal of Energy Chemistry 2024年第3期90卷 600-609,I0013页

作者： Juntao gao Zhiyun Wei Mengke Yuan Zhe Wang Zhe Lü qiang Li Lingling Xu Bo Wei School of Physics Harbin Institute of TechnologyHarbin 150001HeilongjiangChina Key Laboratory of functional Inorganic Material Chemistry Ministry of EducationSchool of Chemistry and Materials ScienceHeilongjiang UniversityHarbin 150080HeilongjiangChina School of Physics and Electronic Engineering Harbin Normal UniversityHarbin 150025HeilongjiangChina

Developing efficient and stable cathodes for low-temperature solid oxide fuel cells(LT-SOFCs) is of great importance for the practical ***,we propose a series of Sm-modified Bi_(0.7-x)Sm_xSr_(0.3)FeO_(3-δ) perovskites as highly-active catalysts for *** doping can significantly enhance the electrocata lytic activity and chemical stability of *** 600℃,Bi_(0.675)Sm_(0.025)Sr_(0.3)FeO_(3-δ)(BSSF25) cathode has been found to be the optimum composition with a polarization resistance of 0.098 Ω cm^2,which is only around 22.8% of Bi_(0.7)Sr_(0.3)FeO_(3-δ)(BSF).A full cell utilizing BSSF25 displays an exceptional output density of 790 mW cm^(-2),which can operate continuously over100 h without obvious *** remarkable electrochemical performance observed can be attributed to the improved O_(2) transport kinetics,superior surface oxygen adsorption capacity,as well as O_(2)p band centers in close proximity to the Fermi ***,larger average bonding energy(ABE) and the presence of highly acidic Bi,Sm,and Fe ions restrict the adsorption of CO_(2) on the cathode surface,resulting in excellent CO_(2) *** work provides valuable guidance for systematic design of efficient and durable catalysts for LT-SOFCs.

关键词： Low-temperature solid oxide fuel cell Perovskite cathode DFT calculations CO_(2) tolerance

Tuning the local coordination environment of silver(Ⅰ) coordination networks with counterions for enhanced electrocatalytic CO_(2) reduction

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Science China Chemistry 2024年第5期67卷 1524-1530页

作者： Xiaofeng Cui Xueting Wang Cong fu Bing Liu Mei-Yan gao Tingting Kong Yujie Xiong Anhui Engineering Research Center of Carbon Neutrality The Key Laboratory of Functional Molecular SolidsMinistry of EducationAnhui Laboratory of Molecular-Based MaterialsCollege of Chemistry and Materials ScienceAnhui Normal UniversityWuhu 241002China Department of Chemical Sciences Bernal InstituteUniversity of LimerickLimerick V94 T9PXRepublic of Ireland School of Chemistry and Materials Science University of Science and Technology of ChinaHefei 230026China School of Chemical and Material Engineering Jiangnan UniversityWuxi 214122China

Very recently, the local coordination environment of active sites has been found to strongly influence their performance in electrocatalytic CO_(2) reduction by tuning the intrinsic kinetics of CO_(2) activation and intermediate stabilization. It is imperative to elucidate the mechanism for such an influence towards the rational design of efficient catalysts;however, the complex interactions between the multiple factors involved in the system make it challenging to establish a clear structure–performance relationship. In this work, we chose ion-intercalated silver(I)-based coordination networks(AgCNs) with a well-defined structure as a model platform, which enables us to understand the regulation mechanism of counterions as the counterions are the only tuning factor involved in such a system. We prepared two isostructural Ag CNs with different intercalation ions or counterions of BF_(4)^(-) and ClO_(4)^(-)(named as AgCNs-BF_(4) and AgCNs-ClO_(4)) and found that the former has a more competitive CO_(2) electroreduction performance than the latter. AgCNs-BF_(4) achieves the highest Faradaic efficiency for CO_(2) to CO of 87.1% at-1.0 V(vs. RHE) with a higher partial current density, while AgCNs-ClO_(4) exhibits only 77.2% at the same applied *** characterizations and theoretical calculation reveal that the presence of BF_(4)^(-)is more favorable for stabilizing the COOH^(*) intermediate by weakening hydrogen bonds, which accounts for the superior activity of Ag CNs-BF_(4).

关键词： electrocatalytic CO_(2) reduction coordination networks local environment counterions intercalation ions

Enhanced High-Temperature Energy Storage Performance of All-Organic Composite Dielectric via Constructing Fiber-Re in forced Structure

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Energy & Environmental Materials 2024年第2期7卷 299-307页

作者： Mengjia Feng Yu Feng Changhai Zhang Tiandong Zhang Xu Tong qiang gao Qingguo Chen Qingguo Chi Key Laboratory of Engineering Dielectrics and Its Application Ministry of EducationHarbin University of Science and TechnologyHarbin 150080China School of Electrical and Electronic Engineering Harbin University of Science and TechnologyHarbin 150080China

Optimizing the high-temperature energy storage characteristics of energy storage dielectrics is of great significance for the development of pulsed power devices and power control *** a polymer with a higher glass transition temperature(T_(g))as the matrix is one of the effective ways to increase the upper limit of the polymer operating ***,current high-T_(g)polymers have limitations,and it is difficult to meet the demand for high-temperature energy storage dielectrics with only one *** example,polyetherimide has high-energy storage efficiency,but low breakdown strength at high *** has high corona resistance,but low high-temperature energy storage *** this work,combining the advantages of two polymer,a novel high-T_(g)polymer fiber-reinforced microstructure is *** is designed as extremely fine fibers distributed in the composite dielectric,which will facilitate the reduction of high-temperature conductivity loss for *** the same time,due to the high-temperature resistance and corona resistance of polyimide,the high-temperature breakdown strength of the composite dielectric is *** the polyimide content with the best high-temperature energy storage characteristics is determined,molecular semiconductors(ITIC)are blended into the polyimide fibers to further improve the high-temperature ***,excellent high-temperature energy storage properties are *** 0.25 vol%ITIC-polyimide/polyetherimide composite exhibits high-energy density and high discharge efficiency at 150℃(2.9 J cm^(-3),90%)and 180℃(2.16 J cm^(-3),90%).This work provides a scalable design idea for high-performance all-organic high-temperature energy storage dielectrics.

关键词： all-organic energy storage density high-temperature high-temperature breakdown strength

Energy saving analysis for CO_(2)–O_(2)mixed injection technology in converter steelmaking

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Journal of Iron and Steel Research International 2024年第5期31卷 1095-1103页

作者： Bao-chen Han Chun-liang gao Ya-qiang Li Dan Liu Guang-sheng Wei Rong Zhu Hebei Key Laboratory of Material Near-Net Forming Technology School of Material Science and EngineeringHebei University of Science and TechnologyShijiazhuang050018HebeiChina Department of Automotive Engineering Hebei Vocational University of Technology and EngineeringXingtai054000HebeiChina School of Metallurgical and Ecological Engineering University of Science and Technology BeijingBeijing100083China

Energy-saving in China's iron and steel industry still relies on the development and improvement of short-term energy saving ***,a special converter smelting technology incorporating energy saving was *** evaluate the energy-saving potential of the CO_(2)–O_(2)mixed injection(COMI)technology,collected production data were used to develop an improved techno-economic *** reveal that the technology can save energy through auxiliary material consumption,sensible heat of solid by-product,iron loss reduction,and energy *** application of COMI technology in an enterprise is cost effective,involving the energy saving potential of 0.206 GJ/t,the cost of conserved energy of−48.83 yuan/GJ,and a simple payback period of 0.35 year for a 60-million-yuan *** analysis shows that the investment cost and discount rate primarily influence the cost of conserved energy of the *** the discount rate increased,the cost of conserved energy also gradually ***,the COMI technology is an energy-saving technology with good development prospects.

关键词： Converter steelmaking COMI technology Energy saving Techno-economic model Investment cost

Liquid-mediated Ostwald ripening of Ag-based clusters supported on oxides

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Nano Research 2024年第6期17卷 4971-4978页

作者： Conghui Liu Rongtan Li Yamei Fan Shiwen Li Xiaohui Feng Lu Feng Yanxiao Ning qiang fu School of Chemistry Dalian University of TechnologyDalian 116024China State Key Laboratory of Catalysis Chinese Academy of SciencesDalian Institute of Chemical PhysicsDalian 116023China

Reconstruction of supported nanocatalysts often occurs in gas-solid reactions and significantly affects the catalytic performance,yet it is much less explored in liquid-phase ***,we find that highly-dispersed Ag nanocatalysts,i.e.,AgOx clusters,supported on alumina,silica,and titania,can aggregate into larger Ag or Ag2O particles after immersing in liquid-phase media at room *** spontaneous aggregation of AgOx clusters in liquid water is attributed to liquid-phase Ostwald ripening through dissolution of AgOx clusters into water and subsequent redeposition to form Ag2O *** immersion into organic solvents such as ethanol leads to reduction of AgOx clusters and further growth into Ag *** work reveals that liquid-phase reaction media can induce substantial structural evolution of supported nanostructured catalysts,which should be carefully considered in liquid-solid interface catalytic reactions such as electrocatalysis,environmental catalysis,and organic synthesis in liquid phase.

关键词： Ag catalysts Ostwald ripening liquid phase media dissolution-deposition process

A Tri-Salt Composite Electrolyte with Temperature Switch function for Intelligently Temperature-Controlled Lithium Batteries

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ENERGY & ENVIRONMENTAL MATERIALS 2024年第6期7卷 84-93页

作者： fu, Ende Wang, Huimin Zhang, Yating Xiao, Zhenxue Zheng, Xiu Hao, Shuai gao, Xueping Nankai Univ Inst New Energy Mat Chem Sch Mat Sci & Engn Tianjin 300350 Peoples R China

The intense research of lithium-ion batteries has been motivated by their successful applications in mobile devices and electronic vehicles. The emerging of intelligent control in kinds of devices brings new requirements for battery systems. The high-energy lithium batteries are expected to respond or react under different environmental conditions. In this work, a tri-salt composite electrolyte is designed with a temperature switch function for intelligently temperature-controlled lithium batteries. Specifically, the halide Li3YBr6 together with LiTFSI and LiNO3 works as active fillers in a low-melting-point polymer matrix (polyethyleneglycol dimethyl ether (PEGDME) and polyethylene oxide (PEO)), which is further filled into the pre-lithiated alumina fiber skeleton. Above 60 degrees C, the composite electrolyte exists in the liquid state and fully contacts with the working electrodes on the liquid-solid interface, effectively minimizing the interfacial resistance and leading to high discharge capacity in the cell. The electrolyte is changed into a solid state below 30 degrees C so that the ionic conductivity is significantly reduced and the interface resistance is increased dramatically on the solid-solid interface. Therefore, by simply adjusting the temperature, the cell can be turned "ON" or "OFF" intentionally. This novel function of the composite electrolyte has enlightening significance in developing intelligently temperature-controlled lithium batteries. A tri-salt composite electrolyte is developed by adding Li3YBr6, LiTFSI, and LiNO3 into PEGDME/PEO. It reversibly transforms between solid and liquid through adjusting the temperature, with lithium-ion conductivity and interfacial contact dramatically changed. Correspondingly, the cells are blocked or conductive as turning "off" and "on" reversibly and flexibly. This switch function shows great potential for developing intelligently temperature-controlled lithium batteries. image

关键词： composite electrolyte halide electrolyte low melting point solid-state battery temperature switch function SOLID POLYMER ELECTROLYTES IONIC-CONDUCTIVITY RECENT PROGRESS COMPATIBILITY INTERFACE NANOWIRES CATHODE SIO2

Development of SV2A Ligands for Epilepsy Treatment:A Review of Levetiracetam,Brivaracetam,and Padsevonil

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Neuroscience Bulletin 2024年第5期40卷 594-608页

作者： Peng-Peng Wu Bi-Rong Cao fu-Yun Tian Zhao-Bing gao Center for Neurological and Psychiatric Research and Drug Discovery Shanghai Institute of Materia MedicaChinese Academy of SciencesShanghai201203China University of Chinese Academy of Sciences Beijing100049China Zhongshan Institute for Drug Discovery Shanghai Institute of Materia MedicaChinese Academy of SciencesZhongshan528400China

Epilepsy is a common neurological disorder that is primarily treated with antiseizure medications(ASMs).Although dozens of ASMs are available in the clinic,approximately 30%of epileptic patients have medically refractory seizures;other limitations in most traditional ASMs include poor tolerability and drug-drug ***,there is an urgent need to develop alternative ***(LEV)is a first-line ASM that is well tolerated,has promising efficacy,and has little drug-drug *** it is widely accepted that LEV acts through a unique therapeutic target synaptic vesicle protein(SV)2A,the molecular basis of its action remains *** so,the next-generation SV2A ligands against epilepsy based on the structure of LEV have achieved clinical *** review highlights the research and development(R&D)process of LEV and its analogs,brivaracetam and padsevonil,to provide ideas and experience for the R&D of novel ASMs.

关键词： Levetiracetam Epilepsy Antiseizure medications Synaptic vesicle protein 2A Brivaracetam Padsevonil

Structural insights into the Oryza sativa cation transporters HKTs in salt tolerance

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Journal of Integrative Plant Biology 2024年第4期66卷 700-708页

作者： Ran gao Yutian Jia Xia Xu Peng fu Jiaqi Zhou Guanghui Yang State Key Laboratory of Plant Environmental Resilience Frontiers Science Center for Molecular Design BreedingCollege of Biological SciencesChina Agricultural UniversityBeijing 100193China

The high-affinity potassium transporters(HKTs),selectively permeable to either Na^(+)alone or Na^(+)/K^(+),play pivotal roles in maintaining plant Na^(+)/K^(+)*** their involvement in salt tolerance is widely reported,the molecular underpinnings of Oryza sativa HKTs remain *** this study,we elucidate the structures of OsHKT1;1 and OsHKT2;1,representing two distinct classes of rice *** dimeric assembled OsHKTs can be structurally divided into four *** the dimer interface,a half-helix or a loop in the third domain is coordinated by the C-terminal region of the opposite ***,we present the structures of OsHKT1;5 salt-tolerant and salt-sensitive variants,a key quantitative trait locus associated with salt *** salt-tolerant variant of OsHKT1;5 exhibits enhanced Na^(+)transport capability and displays a more flexible *** findings shed light on the molecular basis of rice HKTs and provide insights into their role in salt tolerance.

关键词： HKT salt-tolerant structure

Three dimensional discrete element modelling of the conventional compression behavior of gas hydrate bearing coal

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International Journal of Coal Science & Technology 2024年第1期11卷 61-77页

作者： Xia gao Nannan Wang Baoyong Zhang Qiqi Lin qiang Wu Wei Meng Xia Liu Department of Architecture and Civil Engineering Heilongjiang University of Science and TechnologyHarbin150022China School of Qilu Transportation Shandong UniversityJinan250061China Department of Safety Engineering Heilongjiang University of Science and TechnologyHarbin150022China Jining Hongxiang Highway Survey Design and Research Institute Co.Ltd Jining272000China

To analyze the relationship between macro and meso parameters of the gas hydrate bearing coal(GHBC)and to calibrate the meso-parameters,the numerical tests were conducted to simulate the laboratory triaxial compression tests by PFC3D,with the parallel bond model employed as the particle contact constitutive ***,twenty simulation tests were conducted to quantify the relationship between the macro–meso ***,nine orthogonal simulation tests were performed using four meso-mechanical parameters in a three-level to evaluate the sensitivity of the meso-mechanical ***,the calibration method of the meso-parameters were then ***,the contact force chain,the contact force and the contact number were examined to investigate the saturation effect on the meso-mechanical behavior of *** results show that:(1)The elastic modulus linearly increases with the bonding stiffness ratio and the friction coefficient while exponentially increasing with the normal bonding strength and the bonding radius *** failure strength increases exponentially with the increase of the friction coefficient,the normal bonding strength and the bonding radius coefficient,and remains constant with the increase of bond stiffness ratio;(2)The friction coefficient and the bond radius coefficient are most sensitive to the elastic modulus and the failure strength;(3)The number of the force chains,the contact force,and the bond strength between particles will increase with the increase of the hydrate saturation,which leads to the larger failure strength.

关键词： Gas hydrate bearing coal Discrete element method Triaxial compression test Macro-meso mechanical propertie

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预应力在锚杆支护中的作用

煤炭学报 2007年第7期32卷 680-685页

作者：康红普姜铁明高富强煤炭科学研究总院开采研究分院北京100013 晋城无烟煤矿业集团公司技术中心山西晋城048006

在分析目前复杂困难条件下锚杆支护存在问题的基础上,论述锚杆支护系统刚度,特别是预应力对支护效果的重要性.采用有限差分数值计算软件分析了不同预应力下锚杆、锚索产生的应力场分布特征,以及钢带对锚杆预应力扩散的作用.提出锚杆主... 详细信息

在分析目前复杂困难条件下锚杆支护存在问题的基础上,论述锚杆支护系统刚度,特别是预应力对支护效果的重要性.采用有限差分数值计算软件分析了不同预应力下锚杆、锚索产生的应力场分布特征,以及钢带对锚杆预应力扩散的作用.提出锚杆主动支护系数、强度利用系数、预应力长度系数、有效压应力区、预应力扩散系数、有效压应力区骨架网状结构及临界支护刚度等概念.井下试验表明,大幅度提高锚杆预应力可显著减小巷道围岩变形,有效控制顶板离层;钢带在预应力支护系统中起非常重要的作用;锚杆预应力存在临界值,达到或超过临界值后锚杆支护可有效控制围岩变形与破坏.

关键词：预应力锚杆支护支护刚度应力场