检索结果-南通市图书馆

Efficient and stable PtFe alloy catalyst for electrocatalytic methanol oxidation with high resistance to CO

Journal of Energy Chemistry 2024年第3期90卷 327-336,I0008页

作者： Qian Yang Sifan Zhang Fengshun Wu Lihua Zhu Guang Li Mingzhi Chen An pei Yingliang Feng Jiangxi Provincial Key Laboratory of Functional Molecular Materials Chemistry College of Chemistry and Chemical EngineeringFaculty of Materials Metallurgy and ChemistryJiangxi University of Science and TechnologyGanzhou 341000JiangxiChina College of Chemistry and Chemical Engineering Xiamen UniversityXiamen 361005FujianChina

Direct methanol fuel cells(DMFC) are widely considered to be an ideal green energy conversion device but their widespread applications are limited by the high price of the Pt-based catalysts and the instability in terms of surface CO toxicity in long-term ***,the PtFe alloy nanoparticles(NPs) with small particle size(~4.12 nm) supported on carbon black catalysts with different Pt/Fe atomic ratios(Pt_(1)Fe_(2)/C,Pt_(3)Fe_(4)/C,Pt_(1)Fe_(1)/C,and Pt_(2)Fe_(1)/C) are successfully prepared for enhanced anti-CO poisoning during methanol oxidation reaction(MOR).The optimal atomic ratio of Pt/Fe for the MOR is 1:2,and the mass activity of Pt_(1)Fe_(2)/C(5.40 A mg_(Pt)^(-1)) is 13.5 times higher than that of conventional commercial Pt/C(Pt/C-JM)(0.40 A mg_(Pt)^(-1)).The introduction of Fe into the Pt lattice forms the PtFe alloy phase,and the electron density of Pt is reduced after forming the PtFe ***-situ Fourier transform infrared results indicate that the addition of oxyphilic metal Fe has reduced the adsorption of reactant molecules on Pt during the *** doping of Fe atoms helps to desorb toxic intermediates and regenerate Pt active sites,promoting the cleavage of C-O bonds with good selectivity of CO_(2)(58.1%).Moreover,the Pt_(1)Fe_(2)/C catalyst exhibits higher CO tolerance,methanol electrooxidation activity,and long-term stability than other Pt_(x)Fe_(y)/C catalysts.

关键词： Alloy catalyst PtFe Methanol oxidation In-situ FTIR CO resistance

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Hybridization-mediated quasiparticle and phonon dynamics in single crystal cerium films

引用

Science China(Physics,Mechanics & Astronomy) 2024年第4期67卷 146-153页

作者： Yunhe pei Yi Wu Kai Hu Zhengxing Wei YiFeng Yang Yang Liu Jingbo Qi State Key Laboratory of Electronic Thin Films and Integrated Devices University of Electronic Science and Technology of ChinaChengdu 611731China Center for Correlated Matter and Department of Physics Zhejiang UniversityHangzhou 310058China Beijing National Laboratory for Condensed Matter Physics Institute of PhysicsChinese Academy of SciencesBeijing 100190China University of Chinese Academy of Sciences Beijing 100049China Songshan Lake Materials Laboratory Dongguan 523808China Collaborative Innovation Center of Advanced Microstructures Nanjing UniversityNanjing 210093China

We report the ultrafast optical pump-probe spectroscopy measurements on the single-crystal cerium *** experimental results of temperature-dependent quasiparticle dynamics reveal development of the hybridization between localized f moments and conduction electrons,i.e.,evolving from fluctuating hybridization to collective *** phonon renormalization is discovered to appear at the emerging temperature(T^(+))of fluctuating hybridization apart from its known presence at the coherent temperature(T^(*)),and can hardly be explained by the mean-field *** quasiparticle relaxation at high temperatures indicates coexistence of nonthermal electron-electron scattering and inelastic Kondo scattering,while its behavior at low temperatures suggests onset ofαphase in theγ-phase dominated *** also extract the indirect gap below T^(*),representing the appearance of collective *** findings provide novel information about the hybridization and phase evolution in the heavy fermion systems.

关键词： cerium quasiparticle dynamics hybridization phonon renormalization

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Hyperbranched polymer hollow-fiber-composite membranes for pervaporation separation of aromatic/aliphatic hydrocarbon mixtures

引用

Chinese Journal of Chemical Engineering 2024年第5期69卷 13-22页

作者： Tong Liu Hao Sun Xiangqiong Wang Jie Li Zhanquan Zhang pei Wu Naixin Wang Quanfu An Beijing Key Laboratory for Green Catalysis and Separation Department of Chemical EngineeringCollege of Materials Science and EngineeringBeijing University of TechnologyBeijing 100124China Petrochemical Research Institute CNPCBeijing 102206China

The separation of aromatic/aliphatic hydrocarbon mixtures is crucial in the petrochemical *** is regarded as a promising approach for the separation of aromatic compounds from alkanes. Developing membrane materials with efficient separation performance is still the main task since the membrane should provide chemical stability, high permeation flux, and selectivity. In this study, the hyperbranched polymer(HBP) was deposited on the outer surface of a polyvinylidene fluoride(PVDF)hollow-fiber ultrafiltration membrane by a facile dip-coating method. The dip-coating rate, HBP concentration, and thermal cross-linking temperature were regulated to optimize the membrane *** obtained HBP/PVDF hollow-fiber-composite membrane had a good separation performance for aromatic/aliphatic hydrocarbon mixtures. For the 50%/50%(mass) toluene/n-heptane mixture, the permeation flux of optimized composite membranes could reach 1766 g·m^(-2)·h^(-1), with a separation factor of 4.1 at 60℃. Therefore, the HBP/PVDF hollow-fiber-composite membrane has great application prospects in the pervaporation separation of aromatic/aliphatic hydrocarbon mixtures.

关键词： Aromatic/aliphatic hydrocarbons Hyperbranched polymer Pervaporation Hollow fiber membrane Dip-coating

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Improvements in energy saving and thermal comfort for electric vehicles in summer through coupled electrochromic and radiative cooling smart windows

引用

Building Simulation 2024年第8期17卷 1231-1251页

作者： Zhoujie Duan Shuangdui Wu Hongli Sun Borong Lin pei Ding Tao Cui Jeremy To Xi Zhang College of Architectureand Environment Sichuan UniversityChengdu610065China Department of Building Science Tsinghua UniversityBejing 100084China KeyLaboratoryofEco Planning&Green Building MinistryofEducationTsinghua UniversityBeijing100084China State Key Laboratory of Hydraulics and Mountain River Engineering Sichuan UniversityChengdu 610065China School of EmergencyManagement Xihua UniversityChengdu 610039China Department of PSVD Mercedes-benz Group China Ltd.Beijing 100102China

In hot climates,the large amount of cooling load in electric vehicle(EV)results in a lot of battery energy consumption,leading the decrease of driving *** the widespread application of windows in EV,the electrochromic glass(EC)shows great prospect in lowering the cooling ***,researches on the application of EC in EV lack the consideration of both passive cooling measures and passenger comfort,which limits the further application of *** this paper,we proposed an idea combining the novel techniques of both electrochromism and radiative *** fluid dynamics(CFD)is modeled to simulate the application of electrochromic and radiative cooling coupled smart windows in hot parking conditions,exploring the improvement effect of the window on the thermal environment,comfort and energy saving of the *** results indicate that,under the intense sunlight with an outdoor temperature of 33℃,activating the air conditioning to maintain an average interior temperature of 26℃,the coupled windows reduced the cooling capacity of the air conditioning by 762 W compared to regular windows,which can further increase the range of ***,compared to simple electrochromic fully colored glass,the integration of radiative cooling technology can lower the window surface temperature by up to 10.7℃.Moreover,compared to regular windows,the coupled windows lowered the standard effective temperature(SET*)for passengers by approximately 7℃,significantly improving *** research findings are expected to provide guidance for optimizing window design and enhancing the performance of EV.

关键词： electrochromism radiative cooling smart windowel ectric vehicle cabin thermal comfort energy saving

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Very Short-Term Forecasting of Distributed PV Power Using GSTANN

引用

CSEE Journal of Power and Energy Systems 2024年第4期10卷 1491-1501页

作者： Tiechui Yao Jue Wang Yangang Wang pei Zhang Haizhou Cao Xuebin Chi Min Shi Computer Network Information Center of the Chinese Academy of Sciences Beijing 100190China University of Chinese Academy of Sciences Beijing 100190China School of Electrical Engineering Beijing Jiaotong UniversityBeijing 100044China State Grid Hebei Electric Power Co. Ltd.Shijiazhuang 050000China

Photovoltaic(PV)power forecasting is essential for secure operation of a power *** prediction of PV power can improve new energy consumption capacity,help power system planning,promote development of smart grids,and ultimately support construction of smart energy ***,different from centralized PV power forecasts,three critical challenges are encountered in distributed PV power forecasting:1)lack of on-site meteorological observation,2)leveraging extraneous data to enhance forecasting performance,3)spatial-temporal modelling methods of meteorological information around the distributed PV *** address these issues,we propose a Graph Spatial-Temporal Attention Neural Network(GSTANN)to predict the very short-term power of distributed ***,we use satellite remote sensing data covering a specific geographical area to supplement meteorological information for all PV ***,we apply the graph convolution block to model the non-Euclidean local and global spatial dependence and design an attention mechanism to simultaneously derive temporal and spatial ***,we propose a data fusion module to solve the time misalignment between satellite remote sensing data and surrounding measured on-site data and design a power approximation block to map the conversion from solar irradiance to PV *** conducted with real-world case study datasets demonstrate that the prediction performance of GSTANN outperforms five state-of-the-art baselines.

关键词： Distributed photovoltaic power forecasting graph convolutional networks satellite images spatial-temporal attention

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Fungal residues were more sensitive to nitrogen addition than bacterial residues in a meadow grassland soil

引用

Soil Ecology Letters 2024年第3期6卷 61-70页

作者： Zhifu pei Mei Hong Inner Mongolia Key Laboratory of Soil Quality and Nutrient Resources Key Laboratory of Agricultural Ecological Security and Green Development at Universities of Inner Mongolia Autonomous RegionInner Mongolia Agricultural UniversityHohhot 010018China

Nitrogen(N)addition can significantly affect the amount of soil carbon(C)pools through biological routes,and microbial residues are important components of soil carbon ***,it remains unclear how N addition affects the accumulation of soil microbial residues in meadow *** study analyzed the effects of N addition on microbial residues in a meadow grassland soil,and the key factors affecting the accumulation of microbial residues under N addition were analyzed in combination with soil physicochemical properties and microbial community *** results showed that N addition significantly changed the structure of the microbial communities and the accumulation of microbial residues,mainly manifested by a significant decrease in fungal biomass and the fungal/bacterial ratio(F/B),but had no significant effect on bacterial or total microbial biomass(PLFAs).N addition significantly increased the accumulation of fungal residues(7.45%),but had no significant effect on the accumulation of bacterial residues or total amino sugar(TAS).We found that fungal residues were more affected by soil environmental factors than bacterial *** results of the random forest analysis showed that bacterial biomass under N addition was the most important predictor of soil bacterial residues,whereas total N(TN),pH and F/B were the most important predictors of soil fungal *** summary,our results indicate that fungal communities and residues accumulation play important roles in regulating the response of grassland soil C to N addition,further enhancing our understanding of the mechanisms of soil carbon pool to N addition.

关键词： nitrogen addition microbial residues microbial community composition soil organic carbon

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Four centrosome-related genes to predict the prognosis and drug sensitivity of patients with colon cancer

引用

World Journal of Gastrointestinal Oncology 2024年第5期16卷 1908-1924页

作者： Hui-Yan Wang Yan Diao pei-Zhu Tan Huan Liang Department of Clinical Laboratory Harbin Medical University Cancer HospitalHarbin 150086Heilongjiang ProvinceChina Department of Clinical Laboratory Heilongjiang Province HospitalHarbin 150000Heilongjiang ProvinceChina Translational Medicine Center of Northern China Harbin Medical UniversityHarbin 150081Heilongjiang ProvinceChina

BACKGROUND As the primary microtubule organizing center in animal cells,centrosome abnormalities are involved in human colon *** To explore the role of centrosome-related genes(CRGs)in colon *** CRGs were collected from public *** clustering analysis was performed to separate the Cancer Genome Atlas *** Cox and least absolute shrinkage selection operator regression analyses were performed to identify candidate prognostic CRGs and construct a centrosome-related signature(CRS)to score colon cancer patients.A nomogram was developed to evaluate the CRS risk in colon cancer *** integrated bioinformatics analysis was conducted to explore the correlation between the CRS and tumor immune microenvironment and response to immunotherapy,chemotherapy,and targeted ***-cell transcriptome analysis was conducted to examine the immune cell landscape of core prognostic *** A total of 726 CRGs were collected from public databases.A CRS was constructed,which consisted of the following four genes:TSC1,AXIN2,COPS7A,and *** cancer patients with a high-risk signature had poor *** with a high-risk signature exhibited decreased levels of plasma cells and activated memory CD4+T *** treatment response,patients with a high-risk signature were resistant to immunotherapy,chemotherapy,and targeted ***7A expression was relatively high in endothelial cells and ***1 expression was high in endothelial cells,fibroblasts,and malignant *** We constructed a centrosome-related prognostic signature that can accurately predict the prognosis of colon cancer patients,contributing to the development of individualized treatment for colon cancer.

关键词： Colon cancer Centrosome Signature Prognostic Immune microenvironment Therapy

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

The relationship between indoor air quality(IAQ)and perceived air quality(PAQ)-a review and case analysis of Chinese residential environment

引用

Energy and Built Environment 2024年第2期5卷 230-243页

作者： Jingjing pei Meinan Qu Luyao Sun Xueyong Wang Yihui Yin Tianjin Key Laboratory of Indoor Air Environmental Quality Control School of Environmental Science and EngineeringTianjin UniversityTianjin 300072China

Due to the majority of time people spent indoors,indoor air quality is not only critical to people’s health,comfort,but can also significantly influence occupants perception on indoor *** quality is closely related to many factors including thermal parameters,pollutant concentrations,and ventilation ***,the current building indoor air quality evaluation method is based the objective measurement of indoor parameters,without considering occupants’subjective *** paper is aimed at summarizing a profound review on the PAQ evaluation *** among various PAQ evaluating methods with advantages,similarities and differences were *** of literatures about indoor air quality in Chinese residential buildings field is also summarized,and discussion on the subjective influence of temperature and relative humidity,venti-lation performance,volatile organic compounds(VOCs)concentration,and particulate matters on perceived air quality is carried out.

关键词： Perceived air quality Temperature and relative humidity Volatile organic compound Ventilation Particulate matter

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

A harmonic-wave bio-thermal method for continuous monitoring skin thermal conductivity and capillary perfusion rate

引用

Nano Research 2024年第5期17卷 4420-4427页

作者： Yuxin Ouyang Jie Lin Jiajing pei Rui Sui Di Liu Yanhui Feng Lin Qiu School of Energy and Environmental Engineering University of Science and Technology BeijingBeijing 100083China Ningbo Institute of Materials Technology and Engineering Chinese Academy of SciencesNingbo 315201China Beijing Synchrotron Radiation Facility Institute of High Energy PhysicsChinese Academy of SciencesBeijing 100049China Department of Chemistry Tsinghua UniversityBeijing 100084China Institute of Analysis and Testing Beijing Academy of Science and TechnologyBeijing 100089China

The revelation of thermal energy exchange mechanism of human body is challenging yet worthwhile,because it can clearly explain the changes in human symptoms and health ***,the heat transfer of the skin is significant because the skin is the foremost organ for the energy exchange between the human body and the *** order to diagnose the physiological conditions of human skin without causing any damage,it is necessary to use a non-invasive measurement technique by means of a conformal flexible *** harmonic method can minimize the thermal-induced injury to the skin due to its low heat generating properties.A novel type of computational theory assessing skin thermal conductivity,blood perfusion rate of capillaries in the dermis,and superficial subcutaneous tissues was formed by combining the multi-medium thermal diffusion model and the bio-thermal model(Pennes equation).The skins of the hand back of six healthy subjects were *** was found that the results revealed no consistent changes in thermal conductivity were observed across genders and *** measured blood perfusion rates were within the range of human capillary *** was found that female subjects had a higher perfusion rate range(0.0058-0.0061 s^(-1))than male subjects(0.0032-0.0049 s^(-1)),which is consistent with invasive medical studies about the gender difference in blood flow rates and stimulated effects in relaxation situations.

关键词： thermal conductivity blood perfusion rate harmonic method Pennes equation

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Reliability-BasedModel for Incomplete Preventive ReplacementMaintenance of Photovoltaic Power Systems

引用

Energy Engineering 2024年第1期121卷 125-144页

作者： Wei Chen Ming Li Tingting pei Cunyu Sun Huan Lei School of Electrical Engineering and Information Engineering Lanzhou University of TechnologyLanzhou730050China

At present,the operation and maintenance of photovoltaic power generation systems mainly comprise regular maintenance,breakdown maintenance,and condition-based maintenance,which is very likely to lead to over-or under-repair of ***,a preventive maintenance and replacement strategy for PV power generation systems based on reliability as a constraint is ***,a hybrid failure function with a decreasing service age factor and an increasing failure rate factor is introduced to describe the deterioration of PV power generation equipment,and the equipment is replaced when its reliability drops to the replacement threshold in the last ***,based on the reliability as a constraint,the average maintenance cost and availability of the equipment are considered,and the non-periodic incomplete maintenance model of the PV power generation system is established to obtain the optimal number of repairs,each maintenance cycle and the replacement cycle of the PV power generation system ***,the inverter of a PV power plant is used as a research *** model in this paper is compared and analyzed with the equal cycle maintenance model without considering reliability and the maintenance model without considering the equipment replacement threshold,Through model comparison,when the optimal maintenance strategy is(0.80,4),the average maintenance cost of this paper’s model are decreased by 20.3%and 5.54%and the availability is increased by 0.2395% and 0.0337%,respectively,compared with the equal-cycle maintenance model without considering the reliability constraint and the maintenance model without considering the equipment replacement ***,this maintenance model can ensure the high reliability of PV plant operation while increasing the equipment availability to improve the system economy.

关键词： Reliability photovoltaic power system average maintenance cost availability incomplete preventive maintenance hybrid failure rate

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

欢迎您,

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

请选择保存的检索档案：

请选择收藏分类：

通借通还

欢迎您,

建议与咨询 留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

请选择保存的检索档案： 新增检索档案 确定 取消

请选择收藏分类： 新增自定义分类 确定 取消

通借通还

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

请选择保存的检索档案：

请选择收藏分类：