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Magnesium oxide(MgO)nanoadsorbents in wastewater treatment:A comprehensive review

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Journal of Magnesium and Alloys 2024年第5期12卷 1709-1773页

作者： H.c.S.Perera V.gurunanthanan Anoop Singh M.M.M.g.P.g.Mantilaka g.das Sandeep Arya Department of Physics Khalifa UniversityAbu Dhabi12788United Arab Emirates Postgraduate Institute of Science University of PeradeniyaPeradeniyaSri Lanka Department of Humanities and Sciences Guru Nanak Institutions Technical CampusIbrahimpatnamHyderabad501506India centre for global Health Research Saveetha Medical College and HospitalsSaveetha Institute of Medical and Technical SciencesChennai602105Tamil NaduIndia Department of Physics University of JammuJammu and Kashmir180006India

Wastewater contamination by heavy metals and synthetic dyes presents a significant environmental challenge,necessitating effective and sustainable separation *** review article provides a detailed examination of magnesium oxide(MgO)nanoparticles as an innovative nanoadsorbent for wastewater treatment,with a specific focus on heavy metal and dye *** review comprehensively explores various aspects of MgO nanoparticles,including their structural characteristics and synthesis *** article delves into the morphology and crystallographic arrangement of MgO nanoparticles,offering insights into their structural *** the complexity of adsorption processes,the review identifies and analyzes parameters influencing the adsorption efficiency of MgO nanoparticles,such as temperature,pH,contact time,initial concentration,and co-existing *** interplay between these parameters and the adsorption capability of MgO nanoparticles emphasizes the importance of optimizing operational ***,the review assesses various synthesis methods for MgO nanoparticles,including sol-gel,hydrothermal,precipitation,green synthesis,solvothermal,and template-assisted *** discusses the advantages,limitations,and resulting nanoparticle characteristics of each method,enabling readers to grasp the implications of synthesis processes on adsorption *** comprehensive review consolidates current insights into the effectiveness of MgO nanoparticles as a potent nanoadsorbent for removing heavy metals and dyes from wastewater covering a wide spectrum of aspects related to MgO ***,there is a need to investigate the use of MgO in the treatment of actual wastewater or river water,in order to leverage its cost-effectiveness and high efficiency for practical water treatment applications in real-time.

关键词： MgO nanoparticles Nanoadsorbent Wastewater treatment Heavy metals Dye separation Adsorption Synthesis methods

Boulder-induced form roughness and skin shear stresses in a gravel-bed stream

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Journal of Mountain Science 2024年第1期21卷 346-360页

作者： das Ratul DATTA Akash civil Engineering Department National Institute of Technology AgartalaAgartala-799046India

Boulder spacing in mountain rivers and near-wake flow zones within the boulder array is very useful for fish habitat and growth of aquatic *** present study aims to investigate how the boulder array and spacing influence the near-bed flow structures in a gravel-bed *** are staggered over a gravel-bed stream with three different inter-boulder spacing namely(a)large(b)medium and(c)small *** acoustic Doppler velocimeter was used for flow measurements in a rectangular channel and the results were compared with those acquired from numerical *** time-averaged velocity profiles at the near-wake flow zones of boulders experience maximum flow retardation which is an outcome of the boulder-induced form *** ratio of velocity differences associated to form and skin roughness and its positive magnitude reveals the dominance of form roughness closest to the *** roughness computed is 1.75 to 2 times higher than the skin roughness at the near-wake flow *** particular,the collective immobile boulders placed at different inter-boulder spacings developed high and low bed shear stresses closest to the *** low bed shear stresses characterised by a secondary peak developed at the trough location of the boulders is attributed to the skin shear ***,the spatial averaging of time-averaged flow quantities gives additional impetus to present an improved illustration of fluid shear *** formation of form-induced shear stress is estimated to be 17%to 23%of doubleaveraged Reynolds shear stress and partially compensates for the damping of time-averaged Reynolds shear stress in the interfacial *** quadrant analysis of spatial velocity fluctuations depicts that the form-induced shear stresses are dominant in the interfacial sub-layer and have no significance above the gravel-bed surface.

关键词： Array of boulders Near wake flow zones Velocity distributions Skin roughness Form induced shear stresses

Effect of in ovo feeding of xylobiose and xylotriose on plasma immunoglobulin, cecal metabolites production, microbial ecology, and metabolic pathways in broiler chickens

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Journal of Animal Science and Biotechnology 2024年第4期15卷 1578-1589页

作者： Razib das Pravin Mishra Birendra Mishra Rajesh Jha Department of Human Nutrition Food and Animal SciencesCollege of Tropical Agriculture and Human ResourcesUniversity of Hawaii at ManoaHonoluluHI 96822USA

Background Dietary supplementation of xylooligosac charides(XOS) has been found to influence gut health by manipulating cecal microbiota and producing microbe-origin *** no study investigated and compared the effect of in ovo feeding of xylobiose(XOS2) and xy lotriose(XOS3) in *** study investigated the effect of in ovo feeding of these XOS compounds on post-hatch gut health parameters in chickens.A total of 144 fertilized chicken eggs were divided into three groups:a) non-injected control(cON),b) XOS2,and c) *** the 17^(th) embryonic day,the eggs of the XOS2 and XOS3 groups were injected with 3 mg of XOS2 and XOS3 diluted in 0.5 mL of 0.85% normal saline through the amniotic *** hatching,the chicks were raised for 21 *** was collected on d 14 to measure plasma *** digests were collected for measuring short-chain fatty acids(ScFA) on d 14 and 21,and for microbial ecology and microbial metabolic pathway analyses on d 7 and *** The results were considered significantly different at PgA and Igg on d 14chickens,revealing no differences among the *** chromatography results showed no significant differences in the concentrations of cecal ScFAs on d 14 but significant differences on d ***;the ScFA concentrations were lower in the XOS3 than in the cON group on d *** cecal metagenomics data showed that the abundance of the family clostridiaceae significantly decreased on d 7,and the abundance of the family Oscillospiraceae increased on d 21 in the XOS2 compared to the *** was a reduction in the relative abundance of genus clostridium sense stricto 1 in the XOS2 compared to the cON on d 7 and the genus Ruminococcus,torques in both XOS2 and XOS3 groups compared to the cON on d *** XOS2 and XOS3 groups reduced the genes for chondroitin sulfate degradation Ⅰ and L-histidine degradation Ⅰpathways,which contribute to improved gut health,respectivelyc in the micr

关键词： Broiler In ovo Metagenomics Prebiotic Xylooligosaccharides

肝脏影像报告和数据系统局部治疗反应标准的诊断准确性：系统回顾和荟萃分析

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国际医学放射学杂志 2021年第6期 747-747页

作者： P.gupta A.Bansal g.c.das P.Kumar-M S.B.chaluvashetty H.Bhujade 郭虹

目的肝脏成像报告和数据系统(LI-RADS)治疗反应(LR-TR)采用的标准日益增加。然而,仍相对缺乏评估这些标准效能的证据。本研究目的是评估LI-RADS LR-TR

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Molecular mechanism of nanomaterials induced liver injury:A review

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World Journal of Hepatology 2024年第4期16卷 566-600页

作者： Sanjib Kumar das Koushik Sen Biswatosh ghosh Nabanita ghosh Krishnendu Sinha Parames c Sil Department of Zoology Jhargram Raj CollegeJhargram 721507India Department of Zoology Bidhannagar CollegeKolkata 700064India Department of Zoology Maulana Azad CollegeKolkata 700013India Department of Molecular Medicine Bose InstituteCalcutta 700054India

The unique physicochemical properties inherent to nanoscale materials have unveiled numerous potential applications,spanning beyond the pharmaceutical and medical sectors into various consumer industries like food and ***,humans encounter nanomaterials through diverse exposure routes,giving rise to potential health *** among these materials are silica and specific metallic nanoparticles,extensively utilized in consumer products,which have garnered substantial attention due to their propensity to accumulate and induce adverse effects in the *** review paper aims to provide an exhaustive examination of the molecular mechanisms underpinning nanomaterial-induced hepatotoxicity,drawing insights from both in vitro and in vivo ***,the most frequently observed manifestations of toxicity following the exposure of cells or animal models to various nanomaterials involve the initiation of oxidative stress and ***,we delve into the existing in vitro models employed for evaluating the hepatotoxic effects of nanomaterials,emphasizing the persistent endeavors to advance and bolster the reliability of these models for nanotoxicology research.

关键词： Nanoparticles Hepatotoxicity Oxidative stress Inflammation Autophagy

Resistance and resilience of soil biological indicators:A case study with multi-walled carbon nanotube

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Pedosphere 2024年第3期34卷 664-675页

作者： Shagufta YASMEEN Nintu MANDAL Anupam das Pritam gANgULY Sanjay KUMAR Rajiv RAKSHIT Department of Soil Science and Agricultural chemistry Bihar Agricultural UniversitySabourBhagalpur 813210(India) Department of Agronomy Bihar Agricultural UniversitySabourBhagalpur 813210(India)

Soil ecosystem is experiencing stresses due to climate change,and soil inhabitants try to demonstrate their inherent resistance and resilience against those *** of nanomaterials as agricultural inputs could bring shifts in resistance and resilience patterns of soil microbes and associated enzymes,especially under short-term heat *** this background,the impacts of multi-walled carbon nanotube(MWcNT)on the resistance and resilience of soil biological indicators were *** incubation experiment was conducted with varied MWcNT concentrations(0,50,100,250,and 500 mg kg-1soil)for 90 d after 24-h heat stress at 48±2?c to assess the impacts of MWcNT on soil enzyme activities and microbial populations vis-à-vis their resistance and resilience indices under short-term exposure to heat *** activities were reduced after exposure to heat *** indices of enzyme activities were enhanced by MWcNT application on day 1 after heat stress,whereas there was no recovery of enzyme activities after 90-d *** soil enzyme activities,resistance index values of soil microbial populations followed the similar trend and were improved by MWcNT ***-walled carbon nanotube has the potential to improve resistance indices of soil enzyme activities and microbial populations under heat stress,although they could not recover to their original state during periodical incubation after heat *** study helps to understand the relative changes of biological indicators under MWcNT and their ability to withstand heat stress.

关键词： enzyme activity heat stress microbial population nanomaterial recovery

Hybrid ion/electron interfacial regulation stabilizes the cobalt/oxygen redox of ultrahigh-voltage lithium cobalt oxide for fast-charging cyclability

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Science Bulletin 2024年第13期69卷 2071-2079页

作者： Zhihong Bi Anping Zhang gongrui Wang cong Dong Pratteek das Xiaoyu Shi Zhong-Shuai Wu State Key Laboratory of catalysis Dalian Institute of Chemical PhysicsChinese Academy of SciencesDalian 116023China University of chinese Academy of Sciences Beijing 100049China Dalian National Laboratory of clean Energy Chinese Academy of SciencesDalian 116023China

High-voltage and fast-charging LicoO_(2)(LcO)is key to high-energy/power-density Li-ion ***,unstable surface structure and unfavorable electronic/ionic conductivity severely hinder its high-voltage fast-charging ***,we construct a Li/Na-B-Mg-Si-O-F-rich mixed ion/electron interface network on the 4.65 V LcO electrode to enhance its rate capability and long-term cycling ***,the resulting artificial hybrid conductive network enhances the reversible conversion of co^(3+)/^(4+)/O_(2)/nredox by the interfacial ion–electron cooperation and suppresses interface side reactions,inducing an ultrathin yet compact cathode electrolyte ***,the derived near-surface Na+/Mg2+/Si^(4+)-pillared local intercalation structure greatly promotes the Li^(+)diffusion around the 4.55 V phase transition and stabilizes the cathode ***,excellent 3 c(1 c=274 mA g1)fast charging performance is demonstrated with 73.8%capacity retention over 1000 *** findings shed new insights to the fundamental mechanism of interfacial ion/electron synergy in stabilizing and enhancing fast-charging cathode materials.

关键词： High-voltage Fast-charging LicoO_(2) Interfacial ion-electron cooperation Local intercalation

2.4 V ultrahigh-voltage aqueous MXene-based asymmetric micro-supercapacitors with high volumetric energy density toward a self-sufficient integrated microsystem

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Fundamental Research 2024年第2期4卷 307-314页

作者： Yuanyuan Zhu Shuanghao Zheng Jieqiong Qin Jiaxin Ma Pratteek das Feng Zhou Zhong-Shuai Wu State Key Laboratory of catalysis Dalian Institute of Chemical PhysicsChinese Academy of SciencesDalian 116023China University of chinese Academy of Sciences Shijingshan DistrictBeijing 100049China college of Science Henan Agricultural UniversityZhengzhou 450002China Dalian National Laboratory for clean Energy Chinese Academy of SciencesDalian 116023China Key Laboratory of Spin Electron and Nanomaterials of Anhui Higher Education Institutes Suzhou UniversitySuzhou 234000China

Two-dimensional MXenes are key high-capacitance electrode materials for micro-supercapacitors(MScs)catering to integrated ***,the narrow electrochemical voltage windows of conventional aqueous electrolytes(≤1.23 V)and symmetric MXene MScs(typically≤0.6 V)substantially limit their output voltage and energy *** concentrated aqueous electrolytes exhibit lower water molecule activity,which inhibits water splitting and consequently widens the operating voltage ***,we report ultrahigh-voltage aqueous planar asymmetric MScs(AMScs)based on a highly concentrated Licl-gel quasi-solid-state electrolyte with MXene(Ti3c2Tx)as the negative electrode and MnO_(2) nanosheets as the positive electrode(MXene//MnO_(2)-AMScs).The MXene//MnO_(2)-AMScs exhibit a high voltage of up to 2.4 V,attaining an ultrahigh volumetric energy density of 53 mWh cm−***,the in-plane geometry and the quasi-solid-state electrolyte enabled excellent mechanical flexibility and performance uniformity in the serially/parallel connected packs of our ***,the MXene//MnO_(2)-AMSc-based integrated microsystem,in conjunction with solar cells and consumer electronics,could efficiently realize simultaneous energy harvesting,storage,and *** findings of this study provide insights for constructing high-voltage aqueous MXene-based AMScs as safe and self-sufficient micropower sources in smart integrated microsystems.

关键词： Asymmetric micro-supercapacitors MXene MnO_(2) Aqueous electrolyte High voltage Integrated microsystem

New method for rekindling the explosive waves in Maxwellian space plasmas

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Plasma Science and Technology 2020年第12期22卷 48-58页

作者： g.c.das Kalikadas Road Byelane HazraparaCoochbehar-736101West BengalIndia

Our interest is to study the nonlinear wave phenomena in complex plasma constituents with Maxwellian electrons and ions. The main aim is to use a new method known as the(g′/g)method to exhibit the effects of dust charge fluctuations on the evolution of nonlinear waves. The coherent features of the shock and solitary waves along with the generation of high-energy waves have been amplified through the solution of the Korteweg–de Vries–Burgers equation,and the different natures of the waves were found successfully. Results are discussed graphically with the thoughtful choice of typical plasma parameters from different space plasma environments, exactly those found in cosmic dusty plasmas laden in ionospheric auroral region,radial spokes of Saturn's rings, planetary nebulae and solar F-corona region. All conclusions are in good accordance with the actual occurrences and could be of interest to further investigations of space. Moreover, the applicability of the present method is hoped to be a great enhancement by its use as ingenious mechanism used to evaluate the soliton dynamics and Burgers shock waves.

关键词： Maxwellian complex plasma nonlinear waves soliton and shock propagation (g′/g)method space plasmas