检索结果-南通市图书馆

Cable-like Au@SiO2 Janus composite nanorods

在线全文

学校读者我要写书评

暂无评论

Chinese Chemical Letters 2018年第3期29卷 353-356页

作者： Tian-Hao Han fu-xin liang Zhen-Zhong Yang State Key Laboratory of Polymer Physics and Chemistry Institute of Chemistry Chinese Academy of Sciences Beijing 100190 China University of Chinese Academy of Sciences Beijing 100190 China

Cable-like Au@SiO2 Janus composite nanorods with PS and PEG grafting on both ends respectively are fabricated by skiving in combination of a post favorable modification. The cable-like Au@SiO2 composite nanofibers are synthesized in the channel of porous anodic aluminium oxide （AAO） membrane. After skiving, the corresponding composite nanorods are obtained. Following, PEG-SH and PS-SH are conjugated onto the two ends of the nanorods by a selective partial modification, respectively. Length and diameter of the Au@SiO2 Janus composite nanorods can be tuned controllably. It can be extended to fabricate a variety of different Janus nanorods with different compositions and microstructures.

关键词： AAO membrane Janus Nanomds Skiving Selective modification

Ionic liquid functionalized polymer composite nanotubes toward dye decomposition

在线全文

学校读者我要写书评

暂无评论

Chinese Chemical Letters 2015年第8期26卷 942-945页

作者： Shu-Qin Cui Xu-Yang Ji fu-xin liang Zhen-Zhong Yang State Key Laboratory of Polymer Physics and Chemistry Institute of Chemistry Chinese Academy of Sciences

Poly（ionic liquid） functionalized composite nanotubes are achieved by ATRP grafting ionic liquid monomers for example ViEtIm^＋Br^- from the poly（DVB-co-VBC） nanotubes surface. PW12O40^3- anion is introduced through anion exchange. The PW12O40^3- based composite nanotubes can synchronously absorb and decompose water soluble dyes for example methyl orange（MO）. The cooperative interplay is promising in highly efficient decomposition of dyes.

关键词： nanotubes toward decompose ionic orange ATRP Ionic absorb dispersed ethanol

Polymer/Metal Segmental Janus Nanoparticles

在线全文

学校读者我要写书评

暂无评论

Chinese Journal of Polymer Science 2017年第7期35卷 799-808页

作者： Lin Tang fu-xin liang Qian Wang Xiao-zhong Qu Bing-yin Jiang 杨振忠 State Key Laboratory of Polymer Physics and Chemistry Institute of Chemistry Chinese Academy of Sciences Beijing 100190 China University of Chinese Academy ofSciences Beijing 100049 China

Polymer/metal composite segmental Janus nanoparticles （NPs） are synthesized by sequential growth against poly（4-vinylpyridine）（P4VP） crosslinked cP4VP-PS Janus NPs. A Janus cluster of poly（4-vinylpyridine）-block-polystyrene （P4VP-b-PS） diblock copolymer is self-organized after absorption onto a silica patchy sphere via hydrogen bonding. Selective crosslinking of P4VP leads to the formation of robust cP4VP-PS Janus NPs. Within the cP4VP domain, functional species such as metals are preferentially grown by in situ reduction. Other thiol-capped polymers, for example, thiol-capped poly（N-isopropylacrylamide）（PNIPAM-SH）, can be conjugated onto the opposite side to form polymer/metal triple segmental Janus NPs. The hyperthermia effect ofAu NP of PNIPAM-Au@cP4VP-PS by near infrared （NIR） irradiation can trigger a fast transition from amphiphilic to hydrophobic of the Janus NPs at low surrounding temperature. De-stabilization of the emulsion is NIR triggered although the system temperature is below LCST （-32 ℃）.

关键词： Janus Polymer Composite Nanoparticle Interactive performance

pH responsive Janus polymeric nanosheets

在线全文

学校读者我要写书评

暂无评论

Chinese Chemical Letters 2015年第6期26卷 657-661页

作者： Peng Zhou Qian Wang Cheng-liang Zhang fu-xin liang Xiao-Zhong Qu Jiao-Li Li Zhen-Zhong Yang State Key Laboratory of Polymer Physics and Chemistry Institute of ChemistryChinese Academy of Sciences

pH responsive polymeric Janus nanosheets with poly（maleic acid） moiety and crosslinked PS onto the corresponding sides have been synthesized by free radical polymerization. The Janus nanosheets can serve as solid emulsifier to stabilize an oil/water emulsion, whose stability is easily triggered by changing pH across pKa of the poly（maleic acid）.

关键词： pH responsive Janus Nanosheets

在线全文

学校读者我要写书评

暂无评论

Janus复合材料调控界面

高分子学报 2017年第6期27卷 883-892页

作者：梁福鑫杨振忠中国科学院化学研究所高分子物理与化学国家重点实验室北京100190

Janus材料集成不同组成/功能于一体,具有明确的空间分区特征,是一类特殊的高分子复合功能材料.有机高分子链提供亲水/亲油及响应特性,无机组成提供丰富的光、电、磁、热等功能性.两亲性的Janus材料在高效稳定界面同时,还能赋予界面功能... 详细信息

Janus材料集成不同组成/功能于一体,具有明确的空间分区特征,是一类特殊的高分子复合功能材料.有机高分子链提供亲水/亲油及响应特性,无机组成提供丰富的光、电、磁、热等功能性.两亲性的Janus材料在高效稳定界面同时,还能赋予界面功能性并可在外场作用下实现操控.本文重点总结了不同结构和功能的Janus材料在稳定界面和调控界面的近期主要进展,包括聚集行为、固体乳化剂、界面增容、界面催化、功能涂层、细胞诊断与治疗等方面.

关键词： Janus 复合材料两亲性功能界面

Staged dendrite suppression for high safe and stable lithium-sulfur batteries

在线全文

学校读者我要写书评

暂无评论

Journal of Energy Chemistry 2025年第1期100卷 674-683页

作者： Jun Jiang Zhenjie Lu Yanwen Ding Shujun Liu Zhijie Qi Tian Tang Yunfan Zhang Zhiyuan Ma Jingwen Sun liang Xue Wenyao Zhang Pan Xiong xin Wang Junwu Zhu Yongsheng fu Key Laboratory for Soft Chemistry and functional Materials of Ministry of Education Nanjing University of Science and Technology Jiangsu Pylon Battery Co.Ltd

The unavoidable dendrite growth and shuttle effect have long been stranglehold challenges limiting the safety and practicality of lithium-sulfur ***,we propose a dual-action strategy to address the lithium dendrite issue in stages by constructing a multifunctional surface-negatively-charged nanodiamond layer with high ductility and robust puncture resistance on polypropylene （PP） *** uniformly loaded compact negative layer can not only significantly enhance electron transmission efficiency and promote uniform lithium deposition,but also reduce the formation of dendrite during early deposition *** importantly,under the strong puncture stress encountered during the deterioration of lithium dendrite growth under limiting current,the high ductility and robust puncture resistance（145.88 MPa） of as-obtained nanodiamond layer can effectively prevent short circuits caused by unavoidable lithium *** Li||Li symmetrical cells assembled with nanodiamond layer modified PP demonstrated a stable cycle of over 1000 h at 2 mA cm-2with a polarization voltage of only 29.3 ***,the negative charged layer serves as a physical barrier blocking lithium polysulfide ions,effectively mitigating capacity *** improved cells achieved a capacity decay of only 0.042%per cycle after 700 cycles at 3 C,demonstrating effective suppression of dendrite growth and capacity attenuation,showing promising prospect.

关键词： Ductility

Vector meson's spin alignments in high energy reactions

在线全文

同方期刊数据库

学校读者我要写书评

暂无评论

Science China(Physics,Mechanics & Astronomy) 2025年第1期Mechanics & Astronomy) .卷 5-20页

作者： Jin-Hui Chen Zuo-Tang liang Yu-Gang Ma xin-Li Sheng Qun Wang Key Laboratory of Nuclear Physics and Ion-beam Application (MoE) Institute of Modern PhysicsFudan University Institute of Frontier and Interdisciplinary Science Key Laboratory of Particle Physics and Particle Irradiation (MOE)Shandong University INFN-Firenze Department of Modern Physics University of Science and Technology of China School of Mechanics and Physics Anhui University of Science and Technology

The global spin alignment of vector mesons has been observed by the STAR collaboration at the Relativistic Heavy Ion Collider （RHIC） at Brookhaven National Laboratory （BNL）.It provides a unique opportunity to probe the correlation between the polarized quark and antiquark in the strongly coupled quark-gluon plasma （sQGP） produced in relativistic heavy ion collisions,opening a new window to explore the properties of s *** addition,spin alignments of vector mesons have also been observed in other high-energy particle collisions such as e+e-annihilations at high energies where hadron production is dominated by quark fragmentation *** results obtained are quite different from those obtained in heavy ion collisions where quark coalescence/combination mechanism dominates suggesting strong dependence on hadronization *** comprehensive studies in different hadronization processes are *** this article,we present a brief review of theoretical and experimental advances in the study of vector meson’s spin alignments in a variety of high-energy particle collisions,with emphasis on hadronization mechanisms.

关键词： vector meson spin alignment global polarization relativistic heavy ion collisions fragmentation

From waste to wealth:Coal tar residue derived carbon materials as low-cost anodes for potassium-ion batteries

在线全文

同方期刊数据库

学校读者我要写书评

暂无评论

International Journal of Minerals,Metallurgy and Materials 2025年第2期32卷 464-475页

作者： Zhonghua Lu Jun Shen xin Zhang Lingcong Chao liang Chen Ding Zhang Tao Wei Shoudong Xu College of Chemical Engineering and Technology Taiyuan University of TechnologyTaiyuan 030024China College of Chemistry Taiyuan University of TechnologyTaiyuan 030024China School of Chemical Engineering and Pharmacy Wuhan Institute of TechnologyWuhan 430205China School of Energy and Power Jiangsu University of Science and TechnologyZhenjiang 212003China

Carbon materials are widely recognized as highly promising electrode materials for various energy storage system *** tar residues(CTR),as a type of carbon-rich solid waste with high value-added utilization,are crucially important for the development of a more sustainable *** this study,we employed a straightforward direct carbonization method within the temperature range of 700-1000℃to convert the worthless solid waste CTR into economically valuable carbon materials as anodes for potassium-ion batteries(PIBs).The effect of carbonization temperature on the microstructure and the potassium ions storage properties of CTR-derived carbons(CTRCs)were systematically explored by structural and morphological characterization,alongside electrochemical performances *** on the co-regulation between the turbine layers,crystal structure,pore structure,functional groups,and electrical conductivity of CTR-derived carbon carbonized at 900℃(CTRC-900H),the electrode material with high reversible capacity of 265.6m Ah·g^(-1)at 50 m A·g^(-1),a desirable cycling stability with 93.8%capacity retention even after 100 cycles,and the remarkable rate performance for PIBs were ***,cyclic voltammetry(CV)at different scan rates and galvanostatic intermittent titration technique(GITT)have been employed to explore the potassium ions storage mechanism and electrochemical kinetics of *** indicate that the electrode behavior is predominantly governed by surface-induced capacitive processes,particularly under high current densities,with the potassium storage mechanism characterized by an“adsorption-weak intercalation”*** work highlights the potential of CTR-based carbon as a promising electrode material category suitable for high-performance PIBs electrodes,while also provides valuable insights into the new avenues for the high value-added utilization of CTR.

关键词： coal tar residue carbon materials anode potassium-ion batteries high value-added

在线全文

学校读者我要写书评

暂无评论

基于视线的智能碰撞检测方法

计算机工程 2012年第18期38卷 178-181,185页

作者：王雪光付新良河北工程大学信息与电气工程学院河北邯郸056038

针对在虚拟漫游系统中运动物体的碰撞检测问题,提出一种基于视线的智能碰撞检测方法。分析虚拟现实漫游环境中碰撞检测的基本原理和基于视线的碰撞检测,采用模糊控制隶属函数提高碰撞检测效率。实验结果表明,该方法的运算效率和检测精... 详细信息

针对在虚拟漫游系统中运动物体的碰撞检测问题,提出一种基于视线的智能碰撞检测方法。分析虚拟现实漫游环境中碰撞检测的基本原理和基于视线的碰撞检测,采用模糊控制隶属函数提高碰撞检测效率。实验结果表明,该方法的运算效率和检测精度有所提高,能避开墙体和障碍物。

关键词：智能碰撞检测虚拟现实虚拟漫游视线检测模糊控制包围盒