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Influence of mechanical reduction amount on internal quality of continuous casting billets by thermal and numerical simulation

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Journal of Iron and Steel Research International 2023年第6期30卷 1234-1243页

作者： Dan-qing Jiang Shu-jian Sun Han Wu Yang-jian Xu fu-hai zhu Zhen-qiang Zhang Jiang Wang Zhong-ming Ren School of Materials Science and Engineering Shanghai UniversityShanghai 200444China State Key Laboratory of Advanced Special Steel Shanghai UniversityShanghai 200444China

With establishment of thermal and numerical simulation models,the influence of reduction amount on solidification structure,segregation and shrinkage porosity of continuous casting(CC)billets was *** thermal–mechanical coupled simulation results indicated that with an increase in reduction amount,the temperature in the central area decreases,and the reduction efficiency firstly increases and then decreases,reaching the maximum value at reduction amount of 6 *** analysis showed that increasing the reduction amount is beneficial for the refinement of central solidification ***,the internal cracks are more likely to appear at higher reduction *** X-ray computerized tomography results revealed that a higher reduction amount can significantly reduce the volume fraction and equivalent diameter of the central shrinkage porosities of CC billets and increase the sphericity of ***,the macrosegregation of carbon along the central line is improved as the reduction amount increases;while the reduction amount exceeds 8 mm,the segregation degree will not change any more.

关键词： Mechanical reduction Solidification structure Porosity Thermal simulation Continuous casting billet

Unconditional and Conditional QTL Mapping for Tiller Numbers at Various Stages with Single Segment Substitution Lines in Rice(Oryza sativa L.)

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Agricultural Sciences in China 2008年第3期7卷 257-265页

作者： ZHAO Fang-ming LIU Gui-fu zhu hai-tao DING Xiao-hua ZENG Rui-zhen ZHANG Ze-min LI Wen-tao ZHANG Gui-quan Guangdong Key Laboratory of Plant Molecular Breeding South China Agricultural University Guangzhou 510642 P.R.China

Tiller is one of the most important agronomic traits which influences quantity and quality of effective panicles and finally influences yield in rice. It is important to understand ＂static＂ and ＂dynamic＂ information of the QTLs for tillers in rice. This work was the first time to simultaneously map unconditional and conditional QTLs for tiller numbers at various stages by using single segment substitution lines in rice. Fourteen QTLs for tiller number, distributing on the corresponding substitution segments of chromosomes 1, 2, 3, 4, 6, 7 and 8 were detected. Both the number and the effect of the QTLs for tiller number were various at different stages, from 6 to 9 in the number and from 1.49 to 3.49 in the effect, respectively. Tiller number QTLs expressed in a time order, mainly detected at three stages of 0-7 d, 14-21 d and 35-42 d after transplanting with 6 positive, 9 random and 6 negative expressing QTLs, respectively. Each of the QTLs expressed one time at least during the whole duration of rice. The tiller number at a specific stage was determined by sum of QTL effects estimated by the unconditional method, while the increasing or decreasing number in a given time interval was controlled by the total of QTL effects estimated by the conditional method. These results demonstrated that it is highly effective and accurate for mapping of the QTLs by using single segment substitution lines and the conditional analysis methodology.

关键词： single segment substitution line unconditional QTL mapping conditional QTL mapping tiller number rice

Staged dendrite suppression for high safe and stable lithium-sulfur batteries

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Journal of Energy Chemistry 2025年第1期100卷 674-683页

作者： Jun Jiang Zhenjie Lu Yanwen Ding Shujun Liu Zhijie Qi Tian Tang Yunfan Zhang Zhiyuan Ma Jingwen Sun Liang Xue Wenyao Zhang Pan Xiong Xin Wang Junwu zhu Yongsheng fu Key Laboratory for Soft Chemistry and functional Materials of Ministry of Education Nanjing University of Science and Technology Jiangsu Pylon Battery Co.Ltd

The unavoidable dendrite growth and shuttle effect have long been stranglehold challenges limiting the safety and practicality of lithium-sulfur ***,we propose a dual-action strategy to address the lithium dendrite issue in stages by constructing a multifunctional surface-negatively-charged nanodiamond layer with high ductility and robust puncture resistance on polypropylene （PP） *** uniformly loaded compact negative layer can not only significantly enhance electron transmission efficiency and promote uniform lithium deposition,but also reduce the formation of dendrite during early deposition *** importantly,under the strong puncture stress encountered during the deterioration of lithium dendrite growth under limiting current,the high ductility and robust puncture resistance（145.88 MPa） of as-obtained nanodiamond layer can effectively prevent short circuits caused by unavoidable lithium *** Li||Li symmetrical cells assembled with nanodiamond layer modified PP demonstrated a stable cycle of over 1000 h at 2 mA cm-2with a polarization voltage of only 29.3 ***,the negative charged layer serves as a physical barrier blocking lithium polysulfide ions,effectively mitigating capacity *** improved cells achieved a capacity decay of only 0.042%per cycle after 700 cycles at 3 C,demonstrating effective suppression of dendrite growth and capacity attenuation,showing promising prospect.

关键词： Lithium-sulfur batteries Staged dendrite suppression Shuttle effect Surface-negatively-charged nanodiamond

CNKSR2 interactome analysis indicates its association with the centrosome/microtubule system

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Neural Regeneration Research 2025年第8期20卷 2420-2432页

作者： Lin Yin Yalan Xu Jie Mu Yu Leng Lei Ma Yu Zheng Ruizhi Li Yin Wang Peifeng Li hai zhu Dong Wang Jing Li Institute for Translational Medicine The Affiliated Hospital of Qingdao UniversityMedical CollegeQingdao UniversityQingdaoShandong ProvinceChina School of Basic Medicine Qingdao UniversityQingdaoShandong ProvinceChina College of Life Sciences and School of PharmacyMedical CollegeQingdao UniversityQingdaoShandong ProvinceChina Department of Urology Qingdao Municipal Hospital Affiliated to Qingdao UniversityQingdaoShandong ProvinceChina

The protein connector enhancer of kinase suppressor of Ras 2(CNKSR2),present in both the postsynaptic density and cytoplasm of neurons,is a scaffolding protein with several protein-binding *** of the CNKSR2 gene have been implicated in neurodevelopmental disorders,particularly intellectual disability,although the precise mechanism involved has not yet been fully *** has demonstrated that CNKSR2 plays a role in facilitating the localization of postsynaptic density protein complexes to the membrane,thereby influencing synaptic signaling and the morphogenesis of dendritic ***,the function of CNKSR2 in the cytoplasm remains to be *** this study,we used immunoprecipitation and high-resolution liquid chromatography-mass spectrometry to identify the interactors of *** a combination of bioinformatic analysis and cytological experiments,we found that the CNKSR2 interactors were significantly enriched in the proteome of the *** also showed that CNKSR2 interacted with the microtubule protein DYNC1H1 and with the centrosome marker *** colocalization analysis confirmed the centrosomal localization of *** we downregulated CNKSR2 expression in mouse neuroblastoma cells(Neuro 2A),we observed significant changes in the expression of numerous centrosomal *** manipulation also affected centrosome-related functions,including cell size and shape,cell proliferation,and ***,we found that CNKSR2 interactors were highly enriched in de novo variants associated with intellectual disability and autism spectrum *** findings establish a connection between CNKSR2 and the centrosome,and offer new insights into the underlying mechanisms of neurodevelopmental disorders.

关键词： autism spectrum disorder centrosome CNKSR2 intellectual disability interactome mass spectrometry microtubule neurodevelopmental disease protein complexes protein-protein interactions

Superior ligand for Pd(Ⅱ)-catalyzed enantioselective arylation of C(sp^3)-H bonds:chiral acetyl protected aminoethyl quinoline

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Science China Chemistry 2017年第2期60卷 165-166页

作者： Zheng-Yang Xu hai-zhu Yu Yao fu Collaborative Innovation Centre of Chemistry for Energy Materials CAS Key Laboratory of Urban Pollutant Conversion Department of Chemistry University of Science and Technology of ChinaHefei 230026China Department of Chemistry and Centre for Atomic Engineering of Advanced Materials Anhui UniversityHefei 230601China

Enantioselective functionalization of prochiral C-H bonds is a highly attractive strategy for the construction of chiral *** extensive efforts[1],enantioselective C（sp3）-H functionalization still remains challenging at *** instance,although enantioselective C-H functionalization via desymmetrization of two carbon centers has been accomplished with Pd catalysis and a directing group,differenciation of the prochiral C-H bonds on one methylene carbon center has rarely been *** a different front,introduction of a transient chiral directing group is expected to be useful in enantioselective C-H arylation of C（sp2）-H ***,

关键词： Aromatic compounds Catalysis Chemical reactions Computation theory Density functional theory Enantioselectivity Ligands

Formation mechanism of multi-functional black silicon based on optimized deep reactive ion etching technique with SF_6/C_4F_8

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Science China(Technological Sciences) 2015年第2期58卷 381-389页

作者： zhu fu Yun ZHANG Xiao Sheng ZHANG hai Xia National Key Laboratory of Nano/Micro Fabrication Technology Institute of Microelectronics Peking University

This paper reports a controllable multi-functional black silicon surface with nanocone-forest structures fabricated by an optimized deep reactive ion etching(DRIE)technique using SF6/C4F8 in cyclic etching-passivation process,which is maskless,effective and *** process conditions are investigated by systematically comparative experiments and core parameters have been figured out,including etching process parameters,pre-treatment,patterned silicon etching and inclined surface *** on the experimental data,the formation mechanism of nanocone shape is developed,which provides a novel view for in-depth understanding of abnormal phenomena observed in the experiments under different process *** the optimization of the process parameters,the black silicon surfaces exhibit superhydrophobicity with tunable ***,the quantitative relationship between nanocones aspect ratio and surface reflectance and static contact angle is obtained,which demonstrates that black silicon surfaces with unique functional properties(i.e.,cross-combination of reflectance and wettability)can be achieved by controlling the morphology of nanostructures.

关键词： formation mechanism black silicon nanocone-forest deep reactive ion etching (DRIE) properties characterization

Simulation of three-phase flow and lance height effect on the cavity shape

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International Journal of Minerals,Metallurgy and Materials 2014年第6期21卷 523-530页

作者： Kai Dong Rong zhu Wei Gao fu-hai Liu School of Mechanical Engineering University of Science and Technology Beijing School of Metallurgical and Ecological Engineering University of Science and Technology Beijing Beijing Shougang Design Institute

A three-dimensional computational fluid dynamics （CFD） model was developed to simulate a 150-t top-blown converter. The ef-fect of different lance heights on the cavity shape was investigated using the volume of fluid （VOF） method. Numerical simulation results can reflect the actual molten bath surface waves impinged by the supersonic oxygen jets. With increasing lance height, the cavity depth de-creases, and the cavity area, varying like a parabola, increases and then decreases. The cavity area maximizes at the lance height of 1.3 m. Under the three different lance heights simulated in this study, all of the largest impact velocities at the molten bath surface are between 50 m/s and 100 m/s.

关键词： metallurgical furnaces basic oxygen converters lance height cavity shape computational fluid dynamics computer simulation

miRNA-21-5p is an important contributor to the promotion of injured peripheral nerve regeneration using hypoxia-pretreated bone marrow-derived neural crest cells

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Neural Regeneration Research 2025年第1期20卷 277-290页

作者： Meng Cong Jing-Jing Hu Yan Yu Xiao-Li Li Xiao-Ting Sun Li-Ting Wang Xia Wu Ling-Jie zhu Xiao-Jia Yang Qian-Ru He Fei Ding hai-Yan Shi School of Medicine Nantong UniversityNantongJiangsu ProvinceChina Key Laboratory of Neuroregeneration of Jiangsu and Ministry of Education and Coinnovation Center of Neuroregeneration Nantong UniversityNantongJiangsu ProvinceChina Department of Physiology Jiangsu Health Vocational CollegeNanjingJiangsu ProvinceChina Department of Pathology Affiliated Hospital of Nantong UniversityNantongJiangsu ProvinceChina Jiangsu Clinical Medicine Center of Tissue Engineering and Nerve Injury Repair Affiliated Hospital of Nantong UniversityNantongJiangsu ProvinceChina

Our previous study found that rat bone marrow–derived neural crest cells(acting as Schwann cell progenitors)have the potential to promote long-distance nerve ***-based therapy can enhance peripheral nerve repair and regeneration through paracrine bioactive factors and intercellular ***,the complex contributions of various types of soluble cytokines and extracellular vesicle cargos to the secretome remain *** investigate the role of the secretome and extracellular vesicles in repairing damaged peripheral nerves,we collected conditioned culture medium from hypoxia-pretreated neural crest cells,and found that it significantly promoted the repair of sensory neurons damaged by oxygen-glucose *** mRNA expression of trophic factors was highly expressed in hypoxia-pretreated neural crest *** performed RNA sequencing and bioinformatics analysis and found that miR-21-5p was enriched in hypoxia-pretreated extracellular vesicles of neural crest ***,to further clarify the role of hypoxia-pretreated neural crest cell extracellular vesicles rich in miR-21-5p in axonal growth and regeneration of sensory neurons,we used a microfluidic axonal dissociation model of sensory neurons in vitro,and found that hypoxia-pretreated neural crest cell extracellular vesicles promoted axonal growth and regeneration of sensory neurons,which was greatly dependent on loaded ***,we constructed a miR-21-5p-loaded neural conduit to repair the sciatic nerve defect in rats and found that the motor and sensory functions of injured rat hind limb,as well as muscle tissue morphology of the hind limbs,were obviously *** findings suggest that hypoxia-pretreated neural crest extracellular vesicles are natural nanoparticles rich in ***-21-5p is one of the main contributors to promoting nerve regeneration by the neural crest cell *** helps to explain the mechanism of action of the secretome and e

关键词： axotomy cell-free therapy conditioned medium extracellular vesicles hypoxic preconditioning microRNA oxygen-glucose deprivation peripheral nerve injury Schwann cell precursors

A self-catalytic role of methanol in PNP-Ru pincer complex catalysed dehydrogenation

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Science China Chemistry 2016年第6期59卷 724-729页

作者： Yuan-Ye Jiang Zheng-Yang Xu hai-zhu Yu Yao fu Department of Chemistry and Center for Atomic Engineering of Advanced Materials Anhui University Hefei 230601 China Collaborative Innovation Center of Chemistry for Energy Materials CAS Key Laboratory of Urban Pollutant Conversion Department of Chemistry University of Science and Technology of China Hefei 230026 China

Extracting hydrogen from methanol is a safe and cost-efficient strategy for fuel supply. This process was realized recently at a mild condition with excellent efficiency by ruthenium pincer catalysts. Despite the experimental success, the associated mechanism remains under debate. With the aid of density functional theory(DFT) calculations, an updated and self-consistent mechanism which involves Me OH-catalysed dehydrogenation of ruthenium hydride intermediate and pre-protonation of the pincer ligand was present herein. This mechanism is kinetically favoured over the previously-proposed water- or formic- acid-participated ones and more consistent with the optimal experimental condition where strong base and neat methanol solvent are used.

关键词： dehydrogenation ruthenium pincer ligand methanol density functional theory