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Unravelling the ion transport and the interphase properties of a mixed olivine cathode for Na-ion battery

Journal of Energy Chemistry 2024年第9期96卷 300-317页

作者： Luca Minnetti Leonardo Sbrascini Antunes Staffolani Vittorio Marangon francesco Nobili Jusef Hassoun School of Sciences and Technologies–Chemistry Division University of CamerinoVia Madonna delle Carceri ChIP62032 CamerinoItaly Current affiliation:University of Bologna Department of Chemistry“Giacomo Ciamician”Via Francesco Selmi 240126 BolognaItaly Graphene Labs Istituto Italiano di Tecnologiavia Morego 30Genoa 16163Italy Department of Chemical Pharmaceutical and Agricultural SciencesUniversity of FerraraVia Fossato di Mortara 1744121 FerraraItaly GISEL−Centro di Riferimento Nazionale per i Sistemi di Accumulo Elettrochimico di Energia INSTMFirenze 50121Italy National Interuniversity Consortium of Materials Science and Technology(INSTM)University of Ferrara Research Unit University of FerraraVia Fossato di Mortara1744121 FerraraItaly

The replacement of Li by Na in an analogue battery to the commercial Li-ion one appears a sustainable strategy to overcome the several concerns triggered by the increased demand for the electrochemical energy ***,the apparently simple change of the alkali metal represents a challenging step which requires notable and dedicated ***,we investigate herein the features of a NaFe_(0.6)Mn_(0.4)PO_(4)(NFMP)cathode with triphylite structure achieved from the conversion of a LiFe_(0.6)Mn_(0.4)PO_(4)(LFMP)olivine for application in Na-ion *** work initially characterizes the structure,morphology and performances in sodium cell of NFMP,achieving a maximum capacity exceeding 100 mAh g^(−1)at a temperature of 55℃,adequate rate capability,and suitable retention confirmed by ex-situ ***,the study compares in parallel key parameters of the NFMP and LFMP such as Na^(+)/Li^(+)ions diffusion,interfacial characteristics,and reaction mechanism in Na/Li cells using various electrochemical *** data reveal that relatively limited modifications of NFMP chemistry,structure and morphology compared to LFMP greatly impact the reaction mechanism,kinetics and electrochemical *** changes are ascribed to the different physical and chemical features of the two compounds,the slower mobility of Na^(+)with respect to Li^(+),and a more resistive electrode/electrolyte interphase of sodium compared with ***,the study reveals analogue trends of the charge transfer resistance and the ion diffusion coefficient in NFMP and LFMP during the electrochemical process in ***,the NFMP achieved herein is suggested as a possible candidate for application in a low-cost,efficient,and environmentally friendly Na-ion battery.

关键词： NaFe_(0.6)Mn_(0.4)PO_(4)NFMP Olivine Na-ion lon transport Interphase

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Reconstructing hourly residential electrical load profiles for Renewable Energy Communities using non-intrusive machine learning techniques

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Energy and AI 2024年第1期15卷 217-235页

作者： Lorenzo Giannuzzo francesco Demetrio Minuto Daniele Salvatore Schiera Andrea Lanzini Energy Center Lab Polytechnic of Turinvia Paolo Borsellino 38/1610152TurinItaly Department of Energy(DENERG) Polytechnic of TurinCorso Duca degli Abruzzi 2410129TurinItaly

The successful implementation of Renewable Energy Communities(RECs)involves maximizing the self-consumption within a community,particularly in regulatory contexts in which shared energy is *** many countries,the absence of a metering infrastructure that provides data at an hourly or sub-hourly resolution level for low-voltage users(e.g.,residential and commercial users)makes the design of a new energy community a challenging *** study proposes a non-intrusive machine learning methodology that can be used to generate residential electrical consumption profiles at an hourly resolution level using only monthly consumption data(i.e.,billed energy),with the aim of estimating the energy shared by *** proposed methodology involves three phases:first,identifying the typical load patterns of residential users through k-Means clustering,then implementing a Random Forest algorithm,based on monthly energy bills,to identify typical load patterns and,finally,reconstructing the hourly electrical load profile through a data-driven rescaling *** effectiveness of the proposed methodology has been evaluated through an REC case study composed by 37 residential users powered by a 70 kWp photovoltaic *** Normalized Mean Absolute Error(NMAE)and the Normalized Root Mean Squared Error(NRMSE)were evaluated over an entire year and whenever the energy was shared within the *** Relative Absolute Error was also measured when estimating the shared energy at both a monthly(MRAE)and at an annual basis.(RAE).A comparison between the REC load profile reconstructed using the proposed methodology and the real load profile yielded an overall NMAE of 20.04%,an NRMSE of 26.17%,and errors of 18.34%and 23.87%during shared energy timeframes,***,our model delivered relative absolute errors for the estimation of the shared energy at a monthly and annual scale of 8.31%and 0.12%,respectively.

关键词： Renewable Energy Community Load profiling Non-intrusive machine learning Data-driven models Data analytics Shared energy estimation

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Valorisation of industrial hemp (Cannabis sativa L.) residues and cheese whey into volatile fatty acids for single cell protein production

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Environmental Science and Ecotechnology 2024年第5期21卷 369-380页

作者： Carlo Moscariello Silvio Matassa francesco Pirozzi Giovanni Esposito Stefano Papirio Department of Civil Architectural and Environmental EngineeringUniversity of Napoli Federico IIvia Claudio 2180125NapoliItaly

The production of single cell protein(SCP)using lignocellulosic materials stands out as a promising route in the circular bioeconomy ***,multiple steps are necessary for lignocellulosics-to-SCP processes,involving chemical pretreatments and specific aerobic *** there are no studies that investigated the SCP production from lignocellulosics by using only biological processes and microbial biomass able to work both anaerobically and *** this view,the valorisation of industrial hemp(Cannabis sativa L.)biomass residues(HBRs),specifically hurds and a mix of leaves and inflorescences,combined with cheese whey(CW)was investigated through a semi-continuous acidogenic co-fermentation process(co-AF).The aim of this study was to maximise HBRs conversion into VFAs to be further used as carbon-rich substrates for SCP *** process conditions were tested by either removing CW or increasing the amount of HBRs in terms of VS(i.e.,two and four times)to evaluate the performance of the co-AF *** HBRs resulted in a proportional increase in VFA production up to 3115 mg HAc L^(-1),with experimental production nearly 40%higher than theoretical *** synergy between HBRs and CW was demonstrated,proving the latter as essential to improve the biodegradability of the *** produced VFAs were subsequently tested as substrates for SCP synthesis in batch aerobic tests.A biomass concentration of 2.43 g TSS L^(-1) was achieved with a C/N ratio of 5.0 and a pH of 9.0 after two days of aerobic fermentation,reaching a protein content of 42%(g protein per g TSS).These results demonstrate the overall feasibility of the VFA-mediated HBR-to-SCP valorisation process.

关键词： Hemp biomass residues Cheese whey Volatile fatty acids Acidogenic fermentation Single cell protein

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The sea bass Dicentrarchus labrax as a marine model species in immunology:Insights from basic and applied research

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Aquaculture and Fisheries 2024年第2期9卷 136-143页

作者： Andrea Miccoli francesco Buonocore Simona Picchietti Giuseppe Scapigliati Department for Innovation in Biological Agro-food and Forest SystemsUniversity of TusciaViterbo01100Italy

This review summarizes the current knowledge on immune defence activities of the European sea bass Dicentrarchus labrax by reporting the consistent amount of work done on this economically-important species.A draft genome sequence is available for this species,together with whole transcriptomes from lymphoid and non-lymphoid *** full-length coding sequences of many immunoregulatory and immune-related genes allow for targeted quantitative PCR analysis,nowadays needed for-omics data verification,ex vivo and in *** first anti-T cells monoclonal antibody teleost-wise was obtained in sea bass,followed by several monoclonal and polyclonal markers of lymphocyte populations,namely T cells(pan-T,CD3ε,TcRγ,CD45),and B cells(IgM,IgT,IgD).The combined use of molecular and biochemical tools enabled investigations on innate and acquired immune responses of sea bass in unstimulated/stimulated fish,along the development and under variable environmental conditions and food *** overview of sea bass viral and bacterial pathogens and available vaccines against these microorganisms is also *** knowledge accumulated in the past 25 years validates the European sea bass as a reference marine model in the field of fish immunology.

关键词： Sea bass Dicentrarchus labrax Fish immunology Acquired immunity Innate immunity Evolutionary immunology

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Chestnut tannin:New use,research and bioeconomy

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Journal of Bioresources and Bioproducts 2024年第3期9卷 246-252页

作者： Rosaria Ciriminna francesco Meneguzzo Giovanna Li Petri Cosimo Meneguzzo Giuseppe Angellotti Mario Pagliaro Istituto per lo Studio dei Materiali Nanostrutturati CNRvia U.La Malfa 15390146 PalermoItaly Istituto per la Bioeconomia CNRvia Madonna del Piano 1050019 Sesto Fiorentino(FI)Italy HyRes Srl via Salvator Rosa 1882100 BeneventoItaly

Chestnut tannin,extracted from the bark or wood of chestnut trees,possesses unique properties that make it valuable in various *** serves as a natural source of tannins,which are widely used in the production of leather,textiles,and wood *** research continues to explore its potential applications,chestnut tannin remains a promising resource with diverse industrial *** new use,research and bioeconomy aspects,this study provides a unified perspective on chestnut *** advanced applications will likely emerge shortly.

关键词： Tannin Chestnut Bioeconomy Tannin market Hydrolysable tannin

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Investigating epithelial-neuronal signaling contribution in visceral pain through colon organoid-dorsal root ganglion neuron co-cultures

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Neural Regeneration Research 2024年第6期19卷 1199-1200页

作者： francesco Margiotta Lorenzo Di Cesare Mannelli Antonino Morabito Carla Ghelardini Elena Lucarini Department of Neuroscience PsychologyDrug Research and Child Health-NEUROFARBA-Pharmacology and Toxicology SectionUniversity of FlorenceFlorenceItaly Department of Neuroscience PsychologyDrug Research and Child Health-NEUROFARBAUniversity of FlorenceFlorenceItaly Meyer Children’s Hospital IRCCS FlorenceItaly

Abdominal pain is a common symptom associated with irritable bowel syndrome and inflammatory bowel diseases(IBDs),affecting about 20%of the global population(Grundy et al.,2019).Current pain therapies are poorly effective on visceral pain of intestinal origin and present several side effects,hence the need to identify novel molecular and cellular targets for drug development.

关键词： pain visceral colon

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Single-cell pan-omics, environmental neurology, and artificial intelligence:the time for holistic brain health research

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Neural Regeneration Research 2025年第6期20卷 1703-1704页

作者： Paolo Abondio francesco Bruno IRCCS Istituto delle Scienze Neurologiche di Bologna BolognaItaly Association for Neurogenetic Research(ARN) Lamezia TermeCatanzaroItaly

The brain,with its trillions of neural connections,different cellular types,and molecular complexities,presents a formidable challenge for researchers aiming to comprehend the multifaceted nature of neural *** traditional methods have provided valuable insights,emerging technologies offer unprecedented opportunities to delve deeper into the underpinnings of brain *** the everevolving landscape of neuroscience,the quest to unravel the mysteries of the human brain is bound to take a leap forward thanks to new technological improvements and bold interpretative frameworks.

关键词： function artificial landscape

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Mechanisms behind elevated serum levels of plasminogen activator inhibitor-1 in frontotemporal lobar degeneration

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Neural Regeneration Research 2025年第8期20卷 2317-2318页

作者： francesco Angelucci Jakub Hort Memory Clinic Department of NeurologySecond Faculty of MedicineCharles University and Motol University HospitalPragueCzech Republic International Clinical Research Centre St.Anne’s University HospitalBrnoCzech Republic

Frontotemporal lobar degeneration(FTLD)is a form of progressive dementia characterized by degeneration of the frontal and temporal lobes of the *** pathology involves a series of cognitive,behavioral,and neurological ... 详细信息

关键词： degeneration elevated pathology

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Therapeutic advances in neural regeneration for Huntington’s disease

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Neural Regeneration Research 2024年第9期19卷 1991-1997页

作者： francesco D’Egidio Vanessa Castelli Giorgia Lombardozzi Fabrizio Ammannito Annamaria Cimini Michele d’Angelo Department of Life Health and Environmental SciencesUniversity of L’AquilaL’AquilaItaly

Huntington’s disease is a neurodegenerative disease caused by the expansion mutation of a cytosine-adenine-guanine triplet in the exon 1 of the HTT gene which is responsible for the production of the huntingtin (Htt) protein. In physiological conditions, Htt is involved in many cellular processes such as cell signaling, transcriptional regulation, energy metabolism regulation, DNA maintenance, axonal trafficking, and antiapoptotic activity. When the genetic alteration is present, the production of a mutant version of Htt (mHtt) occurs, which is characterized by a plethora of pathogenic activities that, finally, lead to cell death. Among all the cells in which mHtt exerts its dangerous activity, the GABAergic Medium Spiny Neurons seem to be the most affected by the mHtt-induced excitotoxicity both in the cortex and in the striatum. However, as the neurodegeneration proceeds ahead the neuronal loss grows also in other brain areas such as the cerebellum, hypothalamus, thalamus, subthalamic nucleus, globus pallidus, and substantia nigra, determining the variety of symptoms that characterize Huntington’s disease. From a clinical point of view, Huntington’s disease is characterized by a wide spectrum of symptoms spanning from motor impairment to cognitive disorders and dementia. Huntington’s disease shows a prevalence of around 3.92 cases every 100,000 worldwide and an incidence of 0.48 new cases every 100,000/year. To date, there is no available cure for Huntington’s disease. Several treatments have been developed so far, aiming to reduce the severity of one or more symptoms to slow down the inexorable decline caused by the disease. In this context, the search for reliable strategies to target the different aspects of Huntington’s disease become of the utmost interest. In recent years, a variety of studies demonstrated the detrimental role of neuronal loss in Huntington’s disease condition highlighting how the replacement of lost cells would be a reasonable strategy to o

关键词： cell therapy exosomes extracellular vesicles Huntingtin Huntington’s disease medium spiny neurons neurodegenerative disease neurogenesis neuronal loss stem cells

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An integrated computational method for calculating dynamic thermal bridges of building facades in tropical countries

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Frontiers of Architectural Research 2024年第1期13卷 201-218页

作者： Miktha Farid Alkadri Muhammad Rafif Cahyadi Agung francesco De Luca Research Cluster of Architectural Sciences and Building Technology Department of ArchitectureFaculty of EngineeringUniversitas IndonesiaDepok 16425Indonesia Department of Civil Engineering and Architecture Tallinn University of TechnologyTallinn 19086Estonia

Identifying thermal bridges on building façades has been a great challenge for architects,especially during the conceptual design *** is not only due to the complexity of parameters when calculating thermal bridges,but also lack of feature integration between building energy simulation(BES)tools and the actual building *** example,existing BES tools predominantly calculate thermal bridges only in steady state without considering the temperature dynamic behaviour of building ***,relevant features such as thermal delay,decrement factor,and operative temperature are often neglected,and this can lead to miscalculation of energy *** study then proposes an integrated method to calculate dynamic thermal bridges under transient conditions by incorporating field observations and computational simulations of thermal *** specifically,the proposed method employs several measurement tools such as HOBO data logger to record the actual conditions of indoor and outdoor room temperature and thermal cameras to identify the surface temperature of selected building *** actual datasets are then integrated with the simulation workflow developed in BES *** study ultimately enables architects not only to identify potential thermal bridges on existing building façades but also to support material and geometric exploration in early design phase.

关键词： Thermal bridges Dynamic calculation Thermal delay Cooling load Computational design method

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