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Mechanism of cryorolling and aging treatment for enhancing corrosion properties of 2195 Al−Li alloy

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中国有色金属学报 2025年第1期35卷 13-29页

作者： Yue XIAO Wen-shuai WANG Waqas farid Li-hua ZHANG Charlie KONG Hai-liang YU State Key Laboratory of Precision Manufacturing for Extreme Service Performance Central South UniversityChangsha 410083China Light Alloy Research Institute Central South UniversityChangsha 410083China Mark Wainwright Analytical Centre University of New South WalesSydneyNSW 2052Australia

The impact of cryorolling(CR)and room temperature rolling(RTR)followed by artificial aging on the corrosion characteristics of 2195 Al−Li alloy(AA2195)was *** electron microscope,scanning electron microscope,optical microscope,intergranular corrosion experiment,and electrochemical experiment were *** different stages of aging treatment,the corrosion behavior of both CR and RTR samples exhibited a sequential progression of pitting corrosion,followed by intergranular corrosion,and then pitting corrosion *** corrosion rates of both samples initially showed an increase,followed by a gradual stabilization over *** size and density of T1 phase significantly influenced the corrosion performance of the *** the peak aging and over-aging stages,the CR sample exhibited superior corrosion resistance to the RTR sample,attributed to its finer T1 phase.

关键词： 2195 Al−Li alloy cryorolling aging treatment corrosion performance

Unleashing the Potential of Electroactive Hybrid Biomaterials and Self‑Powered Systems for Bone Therapeutics

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Nano-Micro Letters 2025年第2期17卷 463-497页

作者： Shichang Liu farid Manshaii Jinmiao Chen Xinfei Wang Shaolei Wang Junyi Yin Ming Yang Xuxu Chen Xinhua Yin Yunlei Zhou Honghui Hospital Xi’an Jiaotong UniversityXi’an 710018People’s Republic of China Department of Bioengineering Henry Samueli School of Engineering and Applied ScienceUniversity of California Los AngelesLos Angeles 90095USA Hangzhou Institute of Technology Xidian UniversityHangzhou 311231People’s Republic of China

The incidence of large bone defects caused by traumatic injury is increasing worldwide,and the tissue regeneration process requires a long recovery time due to limited self-healing *** bioelectrical phenomena have been well recognized as critical biophysical factors in bone remodeling and *** by bioelectricity,electrical stimulation has been widely considered an external intervention to induce the osteogenic lineage of cells and enhance the synthesis of the extracellular matrix,thereby accelerating bone *** ongoing advances in biomaterials and energy-harvesting techniques,electroactive biomaterials and self-powered systems have been considered biomimetic approaches to ensure functional recovery by recapitulating the natural electrophysiological microenvironment of healthy bone *** this review,we first introduce the role of bioelectricity and the endogenous electric field in bone tissue and summarize different techniques to electrically stimulate cells and ***,we highlight the latest progress in exploring electroactive hybrid biomaterials as well as self-powered systems such as triboelectric and piezoelectric-based nanogenerators and photovoltaic cell-based devices and their implementation in bone tissue ***,we emphasize the significance of simulating the target tissue’s electrophysiological microenvironment and propose the opportunities and challenges faced by electroactive hybrid biomaterials and self-powered bioelectronics for bone repair strategies.

关键词： Electroactive biomaterials Self-powered bioelectronics Bone regeneration Bone tissue

PtCu dendroframe octahedrons:Enhancing peroxidase-like activity and antibacterial efficiency through structural evolution

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Nano Research 2025年第1期18卷 100-106页

作者： Ri Feng Jiuyi Hu Liangjun Wang Jiayu Xu Jiajia Li Zeeshan Ahmad Shaohui Zheng Muhammad Farhan farid Wenjing Liu Faisal Saleem Key Laboratory of Flexible Electronics(KLOFE) Institute of Advanced Materials(IAM)and School of Flexible Electronics(Future Technologies)Nanjing Tech UniversityNanjing 211816China

Nanozymes,which possess enzyme-like catalytic activity,are attractive alternatives to natural *** activity is largely dependent on the structure of the ***,challenges remain in optimizing the structure-activity *** work explores the synthesis and utilization of PtCu nanostructures(NSs),focusing on their peroxidase(POD)-like properties and their potential as antibacterial *** developed PtCu dendrites that transform into unique dendroframe octahedrons(DFOs)and subsequently stabilize into solid octahedrons with unusual growth *** intermediate DFO,showed higher POD-like activity in comparison to other shapes of PtCu *** DFOs also have the better ability to consume glutathione,thus enhancing their sterilization ***,we demonstrate the effectiveness of these PtCu DFOs as powerful antibacterial *** work provides valuable information on shape dependent activities of PtCu NSs in the field of biomedicine.

关键词： nanozymes antibacterials peroxidase PtCu dendroframe octahedrons dendrites

Pressureless infiltration of Si_3N_4 preforms with an Al-2wt%Mg alloy

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Journal of University of Science and Technology Beijing 2005年第4期12卷 351-356页

作者： Akhtar farid Materials Science and Engineering School

The pressureless infiltration process to synthesize a silicon nitride composite was investigated. An Al-2wt%Mg alloy was infiltrated into silicon nitride preforms in the atmosphere of nitrogen. It is possible to infiltrate the Al-2wt%Mg alloy in silicon nitride preforms, The growth of the composite with useful thickness was facilitated by the presence of magnesium powder at the interface and by flowing nitrogen. The microstructure of the Si3N4-Al composite has been characterized using scanning electron microscope. During the infiltration of Si3N4 preforms, Si3N4 reacted with aluminium to form silicon and AIN. The silicon produced during the growth consumed in the formation of MgSiAIO, MgSiAlN and Al3.27Si0.47 type phases. The growth of the composite was found to proceed in two ways, depending on the oxide content in the initial preforms, First, less oxide content preforms gave rise to MgAlSiO and MgAlSiN type phases after infiltration. Second, more oxide content preforms gave rise to AlN-Al2O3 solid solution phase （AlON）, The AlON phase was only present in the composite, containing 10% aluminium in the silicon nitride preforms before infiltration.

关键词： Si3N4 composite infiltration AlON AlN-Al2O3 solid solution

Lubrication effectiveness of composite lubricants during P/M electrostatic die wall lubrication and warm compaction

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Journal of University of Science and Technology Beijing 2006年第6期13卷 528-531页

作者： farid Akhtar Materials Science and Engineering School University of Science and Technology BeijingBeijing 100083China

The lubrication effectiveness of the composite lubricants, 50wt% ethylene bis-stearamide （EBS） wax ＋50wt% graphite and 50wt% EBS wax ＋ 50wt% BN, during the powder metallurgy （P/M） electrostatic die wall lubrication and warm compaction was studied. The results show that the combination of 50wt% EBS wax and 50wt% graphite has excellent lubrication performance, resulting in fairly high green densities, but the mixture of 50wt% EBS wax and 50wt% BN has less beneficial effect. In addition, corresponding die temperatures should be applied when different die wall lubricants are used to achieve the highest green densities.

关键词： powder metallurgy composite lubricant electrostatic die wall lubrication warm compaction

Theoretical Study of Mechanism and Regioselectivity of 1,3-dipolar Cycloaddition of N-[methyl]-C-[5-nitro-2-furyl] Nitrilimine with Dimethyl 7-oxabicyclo[2,2,1]hepta-2,5-diene-2,3-dicarboxylate

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Chinese Journal of Chemical Physics 2010年第2期23卷 165-168,I0001页

作者： farid Moeinpour 伊斯兰阿扎德大学理学院化学系阿巴斯港***伊朗

The mechanism and regioselectivity of 1,3-dipolar cycloaddition of N-[methyl]-C-[5-nitro-2-furyl] nitrilimine with dimethyl 7-oxabicyclo[2,2,1]hepta-2,5-diene-2,3-dicarboxylate were investigated using activation energy calculations and density functional theory-based reactivity indexes. The reaction proceeds by an asynchronous concerted mechanism. The calculations are performed at the B3LYP/6-31G（d） level of theory and the obtained results are in agreement with experimental outcome.

关键词： Regioselectivity 1 3-dipolar cycloaddition Nitrilimine DFT-based reactivity index B3LYP calculation

Development of Si_3N_4/Al composite by pressureless melt infiltration

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中国有色金属学会会刊：英文版 2006年第3期16卷 629-632页

作者： Akhtar farid Institute of Powder Metallurgy University of Scien ce and Technology Beijing Beijing 100083 China

Pressureless infiltration process to synthesize Si3N4/Al composite was investigated. Al-2%Mg alloy was infiltrated into Si3N4 and Si3N4 containing 10% Al2O3 preforms in the atmosphere of nitrogen. It is possible to infiltrate Al-2%Mg alloy in Si3N4 and Si3N4 containing 10% Al2O3 preforms. The growth of the dense composite of useful thickness was facilitated by the presence of magnesium powder at the interface and by flowing nitrogen. During infiltration Si3N4 reacted with aluminium to form Si and AlN, the growth of composite was found to proceed in two ways, depending on the Al2O3 content in the initial preform. Firstly, preform without Al2O3 content gives rise to AlN, Al3.27Si0.47 and Al type phases after infiltration. Secondly, perform with 10% Al2O3 content gives rise to AlN-Al2O3 solid solution phase (AlON), MgAl2O4, Al and Si type phases. AlON phase was only present in composite, containing 10% Al2O3 in the Si3N4 preforms before infiltration.

关键词： Si3N4 无压渗透铝复合材料

Effect of inner oxidant on self-propagating high-temperature synthesis of MnZn-ferrite powder

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Rare Metals 2006年第z1期25卷 553-556页

作者： AKHTAR farid School of Materials Science and Engineering University of Science and Technology Beijing

Using KClO3 as an inner oxidant, MnZn-ferrite powder was synthesized by a self-propagating high-temperature synthesis (SHS) process in normal air atmosphere. The effects of the inner oxidant on combustion temperature, combustion velocity, microstructure and the phase of the product were investigated by XRD and SEM,respectively. The results show that a highly ferritized powder can be obtained as well as the highest combustion temperature and the highest combustion velocity when the inner oxidant content m equals 54(k-16).

关键词： inner oxidant self-propagating high-temperature synthesis (SHS) MnZn-ferrite powder

Stainless steel binder for the development of novel TiC-reinforced steel cermets

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Journal of University of Science and Technology Beijing 2006年第6期13卷 546-550页

作者： Akhtar farid Materials Science and Engineering School University of Science and Technology BeijingBeijing 100083 China

Steel reinforced TiC composites are an attractive choice for wear resistance and corrosion resistance applications. TiC- reinforced 17-4PH maraging stainless matrix composites were processed by conventional powder metallurgy （P/M）. TiC-reinforced maraging stainless steel composites with 〉97% of theoretical density were fabricated. The microstructure, mechanical and wear properties of the composites were evaluated. The microstructure of these composites consisted of spherical and semi-spherical TiC particles. A few microcracks appeared in the composites, showing the presence of tensile stress in the composites produced during sintering. Typical properties, namely, hardness and bend strength were reported for the sintered composites. After heat treatment and aging, the increase of hardness was observed. The increase of hardness was attributed to the aging reaction in the 17-4PH stainless steel. The precipitates appeared in the microstructure and were responsible for the increase in hardness. The specific wear behavior of the composites was strongly dependent on the content of TiC particles, the interparticle spacing, and the presence of hard precipitates in the binder phase.

关键词： TiC-based cermets binder phase maraging stainless steel aging microcracks