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A surface engineering strategy for the stabilization of zinc metal anodes with montmorillonite layers toward long-life rechargeable aqueous zinc ion batteries

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Journal of Energy Chemistry 2025年第1期100卷 94-105页

作者： Wenbo Wang Ruifeng Xu Xu Zhang Peiyu Wang Bao Yang Bingjun Yang Juan Yang Kailimai Su Pengjun Ma Yanan Deng Xianfeng fan Wanjun Chen Key Laboratory for Electronic Materials College of Electrical Engineering Northwest Minzu University Resource Chemistry and Energy Materials Research Center State Key Laboratory of Solid Lubrication Lanzhou Institute of Chemical Physics Chinese Academy of Sciences University of Chinese Academy of Sciences Institute for Materials and Processes School of Engineering University of Edinburgh

Rechargeable aqueous zinc-ion batteries （AZIBs） exhibit appreciable potential in the domain of electrochemical energy ***,there are serious challenges for AZIBs,for instance zinc dendrite growth,hydrogen evolution reaction （HER）,and corrosion side ***,we propose a surface engineering modification strategy for coating the montmorillonite （MMT） layer onto the surface of the Zn anode to tackle these issues,thereby achieving high cycling stability for rechargeable *** results reveal that the MMT layer on the surface of the Zn anode is able to provide ordered zincophilic channels for zinc ions migration,facilitating the reaction kinetics of zinc *** functional theory（DFT） calculations and water contact angle （CA） tests prove that MMT@Zn anode exhibits superior adsorption capacity for Zn2+and better hydrophobicity than the bare Zn anode,thereby achieving excellent cycling ***,the MMT@Zn||MMT@Zn symmetric cell holds the stable cycling over 5600 h at 0.5 mA cm-2and 0.125 m A h cm-2,even exceeding 1800 h long cycling under harsh conditions of 5 m A cm-2and 1.25 m A h *** MMT@Zn||V2O5full cell reaches over 3000 cycles at 2 A g-1with excellent rate ***,this surface engineering modification strategy for enhancing the electrochemical performance of AZIBs represents a promising application.

关键词： Hydrogen evolution reaction

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Gyroscope Dynamic Balance Counterweight Prediction Based on Multi-Head ResGAT Networks

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Computer Modeling in Engineering & Sciences 2024年第6期139卷 2525-2555页

作者： Wuyang fan Shisheng zhong School of Mechanical Engineering Harbin Institute of TechnologyHarbin150000China

The dynamic balance assessment during the assembly of the coordinator gyroscope significantly impacts the guidance accuracy of precision-guided *** dynamic balance debugging,reliance on rudimentary counterweight empirical formulas persists,resulting in suboptimal debugging accuracy and an increased repetition *** mitigate this challenge,we present a multi-head residual graph attention network(ResGAT)model,designed to predict dynamic balance counterweights with high *** this research,we employ graph neural networks for interaction feature extraction from assembly graph *** SDAE-GPC model is designed for the assembly condition classification to derive graph data inputs for the ResGAT regression model,which is capable of predicting gyroscope counterweights under small-sample *** results of our experiments demonstrate the effectiveness of the proposed approach in predicting dynamic gyroscope counterweight in its assembly *** approach surpasses current methods in mitigating repetition rates and enhancing the assembly efficiency of gyroscopes.

关键词： Gyroscope counterweight assembly small-sample ResGAT repetition rate

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Renormalization group theory for temperature-driven first-order phase transitions in scalar models

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Frontiers of physics 2017年第6期12卷 79-96页

作者： Ning Liang fan zhong State Key Laboratory of Optoelectronic Materials and Technologies School of Physics Sun Yat-sen University Guangzhou 510275 China

We study the scaling and universal behavior of temperature-driven first-order phase transitions in scalar models. These transitions are found to exhibit rich phenomena, though they are controlled by a single complex-conjugate pair of imaginary fixed points of φ3 theory. Scaling theories and renormalization group theories are developed to account for the phenomena, and three universality classes with their own hysteresis exponents are found： a field-like thermal class, a partly thermal class, and a purely thermal class, designated, respectively, as Thermal Classes I, II, and III. The first two classes arise from the opposite limits of the scaling forms proposed and may cross over to each other depending on the temperature sweep rate. They are both described by a massless model and a purely massive model, both of which are equivalent and are derived from φ3 theory via symmetry. Thermal Class III characterizes the cooling transitions in the absence of applied external fields and is described by purely thermal models, which include cases in which the order parameters possess different symmetries and thus exhibit different universality classes. For the purely thermal models whose free energies contain odd-symmetry terms, Thermal Class III emerges only at the mean-field level and is identical to Thermal Class II. Fluctuations change the model into the other two models. Using the extant three- and two- loop results for the static and dynamic exponents for the Yang-Lee edge singularity, respectively, which falls into the same universality class as φ3 theory, we estimate the thermal hysteresis exponents of the various classes to the same precision. Comparisons with numerical results and experiments are briefly discussed.

关键词： first-order phase transitions thermal phase transitions renormalization group theory φ3theory scaling and universality thermal classes instability exponents finite-time scaling scalar model,dynamics thermal hysteresis

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Genetic mechanisms of secondary pore development zones of Es_4~x in the north zone of the Minfeng Sag in the Dongying Depression,East China

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Petroleum Science 2016年第1期13卷 1-17页

作者： Yan-zhong Wang Ying-Chang Cao Shao-Min Zhang Fu-Lai Li fan-chao Meng School of Geosciences China University of Petroleum

The genetic mechanisms of the secondary pore development zones in the lower part of the fourth member of the Shahejie Formation（Es_4／6x） were studied based on core observations,petrographic analysis,fluid inclusion analysis,and petrophysical measurements along with knowledge of the tectonic evolution history,organic matter thermal evolution,and hydrocarbon accumulation *** secondary pore development zones exist in Es_4~x,the depths of which range from 4200 to 4500 m and from 4700 to 4900 m,*** reservoirs in these zones mainly consist of conglomerate in the middle fan braided channels of nearshore subaqueous fans,and the secondary pores in these reservoirs primarily originated from the dissolution of feldspars and carbonate *** reservoirs experienced ‘‘alkaline–acidic–alkaline–acidic–weak acidic＇＇,‘‘normal pressure–overpressure–normal pressure＇＇,and‘‘formation temperature increasing–decreasing–increasing＇＇ diagenetic *** diagenetic evolution sequences were ‘‘compaction/gypsum cementation/halite cementation/pyrite cementation/siderite cementation–feldspar dissolution/quartz overgrowth–carbonate cementation/quartz dissolution/feldspar overgrowth–carbonate dissolution/feldspar dissolution/quartz overgrowth–pyrite cementation and asphalt filling＇＇.Many secondary pores（fewer than the number of primary pores） were formed by feldspar dissolution during early acidic geochemical systems with organic acid when the burial depth of the reservoirs was relatively ***,the pore spaces wereslightly changed because of protection from early hydrocarbon charging and fluid overpressure during deep ***,the present secondary pore development zones were formed when many primary pores were filled by asphalt and pyrite from oil cracking in deeply buried paleoreservoirs.

关键词： reservoirs dissolution Depression carbonate hydrocarbon pores quartz porosity buried pyrite

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On the Drinfeld-Sokolov hierarchy of type E_(6)^((1))and its topological solution

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Science China Mathematics 2021年第6期64卷 1245-1262页

作者： Weiqiang He Hua-zhong Ke chao-zhong Wu School of Mathematics Sun Yat-sen UniversityGuangzhou 510275China

In this paper we report some explicit evolutionary PDEs of the Drinfeld-Sokolov hierarchy of type E_(6)^((1)),and show how the unknown functions in these PDEs are related to the tau ***,for this hierarchy we compute its topological solution of formal series up to a certain degree,whose coefficients of monomials give the fan-Jarvis-Ruan-Witten invariants for the E_(6) simple *** on such results we also derive several explicit evolutionary PDEs and some low-degree terms of the topological solution for the Drinfeld-Sokolov hierarchy of type F_(4)^((1)).

关键词： Drinfeld-Sokolov hierarchy tau function topological solution

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Trimetallic mesoporous PdCuRu for efficient formate electrosynthesis from polyethylene terephthalate recycling

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Science China Chemistry 2025年

作者： Yuting Li Huiqin Yao Lizhi Sun Shu Han Xiaoxiang Xu Guangyin fan Ben Liu College of Chemistry and Materials Science Sichuan Normal University Key Laboratory of Green Chemistry and Technology of Ministry of Education College of Chemistry Sichuan University School of Basic Medical Sciences Ningxia Medical University Department of Otorhinolaryngology-Head and Neck Surgery Zhongnan Hospital of Wuhan University

Electrochemical recycling of waste polyethylene terephthalate（PET） plastics represents a green and sustainable route to produce valuable fuels and address serious environmental issues. Despite some encouraged achievements, their progress is still slower because of the lack of highly active and selective electrocatalysts. Here, we reported an efficient PET recycling route with trimetallic PdCuRu mesoporous nanospheres（MSs） as a high-performance electrocatalyst that achieved selective electrosynthesis of valuable formate from PET hydrolysate（PETH） electrooxidation. Penetrated metal mesopores and trimetallic compositions of PdCuRu MSs synergistically optimized electronic structures of Pd sites and changed chemisorption properties of intermediates, which disclosed a high formate Faradic efficiency of 97% and impressive yield rate of 0.49 mmol h-1cm-2in an alkaline solution. Meanwhile, this electrocatalyst held good electrocatalytic stability, retaining high formate Faradic efficiency and yield rate even being performed for 10 cycles, which highlighted its potential applications for practical PET recycling. Our study provides a powerful strategy for designing high-performance electrocatalysts toward selective electro-synthesis of valuable fuels from various waste plastics.

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Synthetic control of chiral pore surfaces in covalent organic frameworks for enantioselective separation of chiral drugs

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Science China Chemistry 2025年

作者： Shiguo Fu Xiaofeng Zhang Kaixuan Wang Linfeng Chen fan Xia Yong Cui Yan Liu School of Chemistry and Chemical Engineering Frontiers Science Center for Transformative Molecules and State Key Laboratory of Metal Matrix Composites Shanghai Jiao Tong University Faculty of Materials Science and Chemistry China University of Geosciences

Enantioselective separations of racemates using porous materials are highly attractive and significant in both fundamental research and technological applications. However, achieving controlled chiral pore surfaces to create the necessary driving force for enantiomer discrimination poses a fundamental challenge. Herein, we demonstrate that chiral covalent organic frameworks(COFs) possess the essential characteristics for effective enantioseparations through synthetic control over pore surfaces. We synthesized three 3D chiral COFs (CCOFs) featuring abundant chiral recognition sites on the pore walls via the condensation of enantiopure dialdehyde of 2,2′-dihydroxy-1,1′-binaphthyl and tetraamine. All CCOFs with high stability exhibit an 11-fold interpenetrated framework with tubular open channels, decorated with dihydroxyl or diethoxyl groups. The CCOFs with dihydroxyl groups serve as solid adsorbents for the adsorptive separation and solid-phase extraction of various chiral 1-phenylethanol-derived enantiomers, particularly racemic drugs, achieving up to 98%enantiomeric excess. In contrast, the CCOF with diethoxy groups is unable to resolve the racemates. These CCOF materials can be recycled and reused without any apparent loss of performance. Density functional theory (DFT) calculations reveal that the enantiospecific recognition arises from the well-organized chiral inner sphere and multiple chiral host-guest interactions.

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Co@C-N as an electronic mediator anchored with Cu2O nanoparticles enables efficient photoreduction of CO2 to CO with nearly 100% selectivity

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Science China Chemistry 2025年

作者： Xingbin Pan Xiuzheng Deng Jingshan fan Jiangchuan Liu Changhai Liu zhongyu Li Qian Liang Jiangsu Key Laboratory of Advanced Catalytic Materials and Technology CNPC-CZU Innovation Alliance School of Petrochemical Engineering Changzhou University School of Materials Science & Engineering Changzhou University

Solar-driven CO2conversion into value-added chemical provides an attractive strategy for sustainable development. However,the enhanced CO2photoreduction performance with target product selectivity remains a major challenge. Here, we develop a novel strategy involving Cu2O nanoparticles in situ grown on the surface of ZIF-67-derived Co@C-N nanocages （CC） to create abundant active sites and appropriate heterointerfaces. A remarkable CO selectivity of 95.7%with a yield of 117.39μmol g-1h-1and an apparent quantum efficiency as high as 1.88%at 420 nm was obtained over CC-60 catalyst in pure water, which was 87.6times higher than that of pure Cu2O. Theoretical calculations and experiments indicated that Co@C-N nanocages as charge mediator not only rapidly trap photogenerated electrons to promote charge separation efficiency, but also regulate the d-band center of Cu atoms to move to the Fermi energy level, thereby optimizing the reaction kinetics to facilitate the highly selective conversion of the key intermediate *CO desorption to CO.

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Analytical long-term evolution and perturbation compensation models for BeiDou MEO satellites

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Chinese Journal of Aeronautics 2018年第2期31卷 330-338页

作者： Li fan Min HU chao JIANG School of Aerospace Engineering Tsinghua University Beijing 100084 China Space Engineering University Beijing 101416 China College of Aerospace Science and Engineering National University of Defense Technology Changsha 410073 China

The current paper establishes the analytical models of the long-term evolution and perturbation compensation strategy for Medium Earth Orbits（MEO）shallow-resonant navigation constellation,with application to the Chinese Bei Dou Navigation Satellite System（BDS）.The long-term perturbation model for the relative motion is developed based on the Hamiltonian model,and the long-term evolution law is *** relationship between the control boundary of the constellation and the offset of the orbital elements is analyzed,and a general analytical method for calculating the offset of the orbit elements is *** analytical model is further improved when the luni-solar perturbations are *** long-term evolutions of the BDS MEO constellation within 10 years are illustrated,and the effectiveness of the proposed analytical perturbation compensation calculation approach is compared with the traditional numerical *** found the fundamental reason for the nonlinear variations of the relative longitude of ascending node and the mean argument of latitude is the long-periodic variations of the orbital inclination due to the luni-solar *** proposed analytical approach can avoid the numerical iterations,and reveal the essential relationship between the orbital element offsets and the secular drifts of the constellation ***,there is no need for maintaining the BDS MEO constellation within 10 years while using the perturbation compensation method.

关键词： BeiDou Navigation Satellite System (BDS) Long-term evolution Luni-solar perturbations Medium Earth Orbits(MEO) Perturbation compensation

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Universality of Competitive Networks in Complex Networks

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Journal of Systems Science & Complexity 2015年第3期28卷 546-558页

作者： GUO Jinli fan chao JI Yali Business School University of Shanghai for Science and Technology

The paper proposes a model which helps to investigate the competitive aspect of real networks in quantitative terms. Through theoretical analysis and numerical simulations, it shows that the competitive model has the universality for a weighted network. The relation between parameters in the weighted network and the competitiveness in the competitive network is obtained by theoretical analysis. Based on the expression of the degree distribution of the competitive network, the strength and degree distributions of the weighted network can be calculated. The analytical solution reveals that the degree distribution of the weighted network is correlated with the increment and initial value of edge weights, which is verified by numerical simulations. Moreover, the evolving pattern of a clustering coefficient along with network parameters such as the size of a network, an updating coefficient, an initial weight and the competitiveness are obtained by further simulations.

关键词： Competitive network complex network scale-free network weighted network.

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