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Structural,dielectric and magnetic properties of terbium doped strontium spinel ferrite（SrFe2O4） synthesized by sol-gel method

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Journal of Rare Earths 2025年第2期43卷 337-344页

作者： Rifat shaheen Hafeez Ullah m.m.moharam Ahmad m.Saeedi Ebraheem Abdu musad Saleh muhammad Ijaz Adel A.El-Zahhar Gamil A.A.m.Al-Hazmi Sana Ullah Asif Hafiz muhammad Tahir Institute of Physics Gomal University Department of Chemistry College of Arts and SciencesPrince Sattam Bin Abdulaziz University Chemical and Electrochemical Processing Department Central Metallurgical Research and Development Institute (CMRDI) Department of Physics Faculty of Applied ScienceUmm AL-Qura University Department of Chemistry College of ScienceKing Khalid University School of materials and Energy Yunnan University Department of Physics Govt. Graduate College Taunsa

In this research work,sol-gel technique was employed to prepare the strontium based spinel ferrite nanoparticles（SrFe2O4） with different ratios of terbium（Tb）.Different characterization techniques were used to investigate the structural,morphological,dielectric and magnetic properties of the prepared samples.X-ray diffraction（XRD） result suggests that face-centered cube spinel nanocrystalline structure is *** size of the SrFe2O4decreases with rising of Tb *** morphology,shape and size of the SrFe2O4were examined by scanning electron microscopy（SEm） analysis and results reveal inhomogeneous distributions of the nanostructures with high *** electrical resistivity of the SrFe2O4increases with rising of Tb ratio,which is confirmed from the cyclic *** is observed that dielectric constant of all the samples decreases with the increasing frequency *** is determined that the dielectric constants of the spinel ferrites are frequency dependent and decrease with increasing the frequency of applied electric *** magnetic behavior of SrFe2O4with different ratios of Tb was studied and it is found that the saturation magnetization values of samples decrease with increase in the substitution of Tb3+at octahedral sites for Fe3+.This decrease in the values of msis also attributed to spin at surface of nanoparticles.

关键词： Dielectric properties magnetic properties Rare earths Sol-gel Spinel ferrites Structural properties

Regular perturbation solution of Couette flow(non-Newtonian)between two parallel porous plates: a numerical analysis with irreversibility

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Applied mathematics and mechanics(English Edition) 2021年第1期42卷 127-142页

作者： m.NAZEER m.I.KHAN S.KADRY Yuming CHU F.AHmAD W.ALI m.IRFAN m.shaheen Department of mathematics Institute of Arts and SciencesGovernment College UniversityChiniot CampusFaisalabad 35400Pakistan Department of mathematics and Statistics Riphah International University I-14Islamabad 44000Pakistan Department of mathematics and Computer Science Beirut Arab UniversityBeirut 11-5020Lebanon Department of mathematics Huzhou UniversityHuzhou 313000Zhejiang ProvinceChina Hunan Provincial Key Laboratory of mathematical modeling and Analysis in Engineering Changsha University of Science&TechnologyChangsha 410114China Department of Applied Sciences National Textile UniversityFaisalabad 38000Pakistan Chair of Production Technology Faculty of Engineering TechnologyUniversity of TwenteEnschede 7500 AEThe Netherlands Department of mathematics Riphah Inernational LniversityFaisalabad CampusFaiselabad 38000Pakistan

The unavailability of wasted energy due to the irreversibility in the process is called the entropy *** irreversible process is a process in which the entropy of the system is *** second law of thermodynamics is used to define whether the given system is reversible or ***,our focus is how to reduce the entropy of the system and maximize the capability of the *** are many methods for maximizing the capacity of heat *** constant pressure gradient or motion of the wall can be used to increase the heat transfer rate and minimize the *** objective of this study is to analyze the heat and mass transfer of an Eyring-Powell fluid in a porous *** this,we choose two different fluid models,namely,the plane and generalized Couette *** flow is generated in the channel due to a pressure gradient or with the moving of the upper *** present analysis shows the effects of the fluid parameters on the velocity,the temperature,the entropy generation,and the Bejan *** nonlinear boundary value problem of the flow problem is solved with the help of the regular perturbation *** validate the perturbation solution,a numerical solution is also obtained with the help of the built-in command NDSolve of mATHEmATICA *** velocity profile shows the shear thickening behavior via first-order Eyring-Powell *** is also observed that the profile of the Bejan number has a decreasing trend against the Brinkman ***ηi→0(i=1,2,3),the Eyring-Powell fluid is transformed into a Newtonian fluid.

关键词： Couette flow Eyring-Powell fluid entropy generation perturbation method Bejan number

Influence of fly ash and sewage sludge application on wheat biomass production,nutrients availability,and soil properties

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International Journal of Coal Science & Technology 2014年第2期1卷 221-226页

作者： Christos Tsadilas Vasilios Samaras E.Evangelou Sabry m.shaheen National Agricultural Research Foundation Institute of Soil Mapping and ClassificationLarissaGreece Faculty of Agriculture University of KafrelsheikhKafr El-SheikhEgypt

The influence of fly ash(FA)applied alone and/or with sewage sludge(SS)on wheat(Triticum vulgare)grain yield,biomass production and soil properties was studied in a field *** results showed that both FA and SS significantly increased grain yield and plant *** applied alone increased significantly soil pH and EC while FA applied together with SS did not significantly affect them compared to mono FA *** pH and EC values increased with time in FA and FA-SS *** increased soil organic matter and total N content and SS applied together with FA increased also available soil *** the plant nutrients tested only tissue N concentration was increased significantly in all treatments compared to ***,Zn,mn,Ni,and Pb at both available and total concentrations are significantly affected.

关键词： Fly ash Sewage sludge By-product of coal combustion Wheat biomass product Soil property

Removal of toxic elements from aqueous environments using nano zero-valent iron-and iron oxide-modified biochar:a review

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Biochar 2022年第1期4卷 779-799页

作者： Sabry m.shaheen Ahmed mosa Natasha Hamada Abdelrahman Nabeel Khan Niazi Vasileios Antoniadis muhammad Shahid Hocheol Song Eilhann E.Kwon Jörg Rinklebe Laboratory of Soil-and Groundwater-management Institute of Foundation EngineeringWater-and Waste-ManagementSchool of Architecture and Civil EngineeringUniversity of WuppertalPauluskirchstraße 742285 WuppertalGermany Department of Arid Land Agriculture Faculty of MeteorologyEnvironmentand Arid Land AgricultureKing Abdulaziz UniversityJeddah 21589Saudi Arabia Department of Soil and Water Sciences Faculty of AgricultureUniversity of KafrelsheikhKafr El-Sheikh 33516Egypt Soils Department Faculty of AgricultureMansoura UniversityMansoura 35516Egypt Department of Environmental Sciences COMSATS University IslamabadVehari CampusVehari 61100Pakistan Soil Science Dept. Faculty of AgricultureCairo UniversityGiza 12613Egypt Institute of Soil and Environmental Sciences University of Agriculture FaisalabadFaisalabad 38040Pakistan Department of Agriculture Crop Production and Rural Environment University of ThessalyFytokou Street38446VolosGreece Department of Environment Energy and GeoinformaticsUniversity of SejongGuangjin-GuSeoul 05006Republic of Korea Department of Earth Resources and Environmental Engineering Hanyang UniversitySeoul 04763Republic of Korea

Biochar(BC)has gained attention for removal of toxic elements(TEs)from aqueous media;however,pristine biochar often exhibits low adsorption ***,various modification strategies in BC have been developed to improve its removal capability against *** zero-valent iron(nZVI)and iron oxides(FeOx)have been used as sorbents for TE ***,these materials are prone to agglomeration and also expensive,which make their usage limited for large-scale *** nZVI technical demerits could be resolved by the development of BC-based composite sorbents through the loading of nZVI or FeOx onto BC *** zero-valent iron modified BC(nZVIBC),FeOx-modified BC(FeOxBC)have attracted attention for their capability in removing pollutants from the aqueous ***,a potential use of nZVIBC and FeOxBC for TE removal from aqueous environments has not been well-realized or *** such,this article reviews:(i)the preparation and characterization of nZVIBC and FeOxBC;(ii)the capacity of nZVIBC and FeOxBC for TE retention in line with their physicochemical properties,and(iii)TE removal mechanisms by nZVIBC and *** nZVI and FeOx in BC increases its sporptive capability of TEs due to surface modifications in morphology,functional groups,and elemental *** combined effects of BC and nZVI,FeOx or Fe salts on the sorption of TEs are complex because they are very specific to *** review identified significant opportunities for research and technol-ogy advancement of nZVIBC and FeOxBC as novel and effective sorbents for the remediation of TEs contaminated water.

关键词： Feedstock Engineered biochar Toxic metal(loid)s Biosorption Wastewater remediation

Arsenic removal from water and soils using pristine and modified biochars

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Biochar 2022年第1期4卷 255-280页

作者： Wei Zhang Yoora Cho meththika Vithanage Sabry m.shaheen Jörg Rinklebe Daniel S.Alessi Chia-Hung Hou Yohey Hashimoto Piumi Amasha Withana Yong Sik Ok Korea Biochar Research Center APRU Sustainable Waste Management and Division of Environmental Science and Ecological EngineeringKorea UniversitySeoul 02841South Korea School of Environmental Science and Engineering Guangzhou UniversityGuangzhou 510006China Ecosphere Resilience Research Center Faculty of Applied SciencesUniversity of Sri JayewardenepuraNugegoda 10250Sri Lanka Sustainability Cluster University of Petroleum and Energy StudiesUttarkhandDehradunIndia The Institute of Agriculture The University of Western AustraliaCrawleyAustralia School of Architecture and Civil Engineering Institute of Foundation EngineeringWater-and Waste-ManagementLaboratory of Soil-and Groundwater-ManagementUniversity of WuppertalPauluskirchstraße742285 WuppertalGermany Department of Earth and Atmospheric Sciences University of AlbertaEdmontonAB T6G 2E3Canada Graduate Institute of Environmental Engineering National Taiwan UniversityTaipei 10617TaiwanChina Department of Bioapplications and Systems Engineering Tokyo University of Agriculture and TechnologyTokyoJapan Department of Arid Land Agriculture Faculty of MeteorologyEnvironmentand Arid Land AgricultureKing Abdulaziz University21589 JeddahSaudi Arabia Department of Soil and Water Sciences Faculty of AgricultureUniversity of Kafrelsheikh33516 Kafr El-SheikhEgypt

Arsenic(As)is recognized as a persistent and toxic contaminant in the environment that is harmful to ***,a porous carbonaceous material with tunable functionality,has been used widely as an adsorbent for remediating As-contaminated water and *** types of pristine and modified biochar are available,and significant efforts have been made toward modifying the surface of biochars to increase their adsorption capacity for *** capacity is influenced by multiple factors,including biomass pyrolysis temperature,pH,the presence of dissolved organic carbon,surface charge,and the presence of phosphate,silicate,sulfate,and microbial *** As adsorption in modified biochars is attributed to several mechanisms including surface complexation/precipitation,ion exchange,oxidation,reduction,electrostatic interactions,and surface functional groups that have a relatively higher affinity for *** biochars show promise for As adsorption;however,further research is required to improve the performance of these *** example,modified biochars must be eco-friendly,cost-effective,reliable,efficient,and sustainable to ensure their widespread application for immobilizing As in contaminated water and *** relevant research to address these issues relies on a thorough understanding of biochar modifications to *** study presents an in-depth review of pristine and modified biochars,including their production,physicochemical properties,and As adsorption ***,a comprehensive evaluation of biochar applications is provided in As-contaminated environments as a guide for selecting suitable biochars for As removal in the field.

关键词： Engineered biochar Removal mechanisms Arsenic pollution Water pollution Soil pollution

Effects of Plasticizers,Antioxidants and Burning Rate modifiers on Aging Performance of the HTPB/HmDI Composite Solid Propellant

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含能材料 2019年第1期27卷 21-27,90页

作者： Ahmed m Enew ehab Abadir Sahar Elmarsafy Karim K Elsharkawy Chemical Department Faculty of EngineeringCairo University School of Chemistry and Environment Beijing University of Aeronautics and Astronautics

The effects of plasticizers,antioxidants and burning rate modifiers on the aging performance of the composite solid propellant based on hydroxyl-terminated polybutadiene(HTPB)/hexamethylene diisocyanate(HmDI)were explored by apply-ing an accelerated aging program for 90 day at 70 ℃. The HTPB propellant matrix with the diisooctyl sebacate(DOS)as plasti-cizers and diisooctyl azelate(DOZ), antioxidants as N,N ′-Diphenyl-p-phenylenediamine(AO) and 2,2′-methylenebis(4-methyl-6-tert-butylphenol)(cyanox 2246)and burning rate modifiers as barium ferrite(BF),copper chromites(CC)and fer-ric oxide(FO)were varied. Results show that sample(S1)which based on DOS decreases the stress value and increases the strain value which considered to be an excellent start for aging program. Sample(S3)containing AO presents the higher resis-tance to oxidation showing the better performance that reflects on increasing the shelf life of the composite solid propellant mo-tor. Sample(S5)which based on BF enhances the ballistic performance among over the other tested two samples. The accelerat-ed aging program allowed us to estimate the motor in-service lifetime.

关键词： polybutadiene(HTPB)/hexamethylene diisocyanate(HmDI)composite solid propellant plasticizers antioxidants burning rate modifiers aging program

Simulation of Water-Soil-Structure Interactions Using Incompressible Smoothed Particle Hydrodynamics

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Computers, materials & Continua 2020年第10期65卷 205-224页

作者： Abdelraheem m.Aly mitsuteru Asai ehab mahmoud mohamed Department of mathematics College of ScienceKing Khalid UniversityAbha62529Saudi Arabia Department of mathematics Faculty of ScienceSouth Valley UniversityQena83523Egypt Civil Engineering Department Kyushu UniversityFukuoka819-0395Japan Electrical Engineering Department College of EngineeringPrince Sattam Bin Abdulaziz UniversityWadi Addwasir11991Saudi Arabia Electrical Engineering Department Faculty of EngineeringAswan UniversityAswan81542Egypt

In the present work,an incompressible smoothed particle hydrodynamic(SPH)method is introduced to simulate water-soil-structure *** the current calculation,the water is modelled as a Newtonian *** soil is modelled in two different *** the first case,the granular material is considered as a fluid where a Bingham type constitutive model is proposed based on mohr-Coulomb yield-stress criterion,and the viscosity is derived from the cohesion and friction *** addition,the fictitious suspension layers between water and soil depending on the concentration of soil are *** the second case,Hooke’s law introduces elastic *** ISPH,the pressure is evaluated by solving the pressure Poisson equation using a semi-implicit algorithm based on the projection method and an eddy viscosity for water is modelled by a large eddy simulation with the Smagorinsky *** the proposed ISPH method,the pressure is stabilized to simulate the multiphase flow between soil and *** experiments for water-soil suspension flow of Louvain erosional dam break with flat soil foundation,is simulated and validated using 3D-ISPH *** between water-soil interactions with different solid structures are *** results revealed that,the suspension layers with the Bingham model of soil gives more accurate results in the experiment as compared to the case of the Bingham model without suspension *** addition,the elastic soil model by the Hooke’s law can simulate soil hump accurately as compared to the Bingham *** the simulations,avoiding erosion behind the structure for preventing the structure break during flood are investigated by using an extended structure or a wedge structure.

关键词： Bingham model ISPH method rigid body water-soil interactions

Effect of corn pre-puffing on the efficiency of mgO-engineered biochar for phosphorus recovery from livestock wastewater:mechanistic investigations and cost benefit analyses

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Biochar 2023年第1期5卷 462-478页

作者： Yaru Peng Yuan Luo Yimeng Li muhammad Azeem Ronghua Li Chuchu Feng Guangzhou Qu Esmat F.Ali mohamed A.Hamouda Peter S.Hooda Jörg Rinklebe Ken Smith Zengqiang Zhang Sabry m.shaheen College of Natural Resources and Environment Northwest A&F UniversityYangling 712100Shaanxi ProvinceChina Key Laboratory of Urban Environment and Health Ningbo Observation and Research StationInstitute of Urban EnvironmentChinese Academy of SciencesXiamen 361021China Institute of Soil and Environmental Sciences Pir Mehr Ali Shah Arid Agriculture University RawalpindiRawalpindi 46300PunjabPakistan Department of Biology College of ScienceTaif UniversityP.O.Box 11099Taif 21944Saudi Arabia Department of Civil and Environmental Engineering Faculty of EngineeringUnited Arab Emirates UniversityAl AinAbu DhabiUnited Arab Emirates School of Engineering and the Environments Kingston University LondonKingston University LondonKingston Upon Thames KT12EELondonUK University of Wuppertal School of Architecture and Civil EngineeringLaboratory of Soil and Groundwater ManagementInstitute of Foundation EngineeringWater-and Waste-ManagementPauluskirchstraße 742285 WuppertalGermany The Department of Environmental Science The University of ArizonaShantz Building Rm 4291177 E 4Th St.TucsonTucsonArizona 85721USA Department of Arid Land Agriculture Faculty of MeteorologyEnvironmentand Arid Land AgricultureKing Abdulaziz UniversityJeddah 21589Saudi Arabia Department of Soil and Water Sciences Faculty of AgricultureUniversity of KafrelsheikhKafr El-Sheikh 33516Egypt

To improve the phosphorus(P)recovery efficiency from livestock wastewater,a novel mgO doped mildewed corn biochar with thermal pre-puffing treatment(mg-PBC)and without pre-puffing(mg-BC)was synthesized and *** thermal-puffing pretreatment improved the effectiveness of metal soaking and mgO dispersion.P recovery time with mg-PBC(7 h)was significantly shorter than that with mg-BC(12 h).moreover,mg-PBC showed significantly higher P recovery capacity(241 mg g^(−1))than mg-BC(96.6 mg g^(−1)).P recovery capacity of the mg-PBC fitted to the Thomas model was 90.7 mg g^(−1),which was 4 times higher than that of mg-BC(22.9 mg g^(−1))under column test *** mechanisms involved in P recovery included precipitation,surface complexation,and electrostatic *** adsorption,both mg-BC and mg-PBC showed relatively low regeneration *** P loaded mg-BC(mg-BC-P)and mg-PBC(mg-PBC-P),the later particularly,obviously increased the available P content and promoted plant *** release of P increased with time in the mg-PBC-P treated soil,while it decreased with time in the P fertilizer treated soil.A cost-benefit analysis revealed that thermal-puffing pretreatment greatly increased the profit of mgO doped biochar from−0.66 to 5.90 US$kg^(−1).These findings highlight that biomass pre-puffing is a feasible treatment to produce mgO modified biochar and to recover P from livestock wastewater,and that the mg-PBC-P can be used as a slow-release P fertilizer.

关键词： Engineered biochar Biomass pre-puffing Nutrient recovery Wastewater engineering Cost-benefit analysis

metachronal propulsion of non-Newtonian viscoelastic mucus in an axisymmetric tube with ciliated walls

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Communications in Theoretical Physics 2021年第3期73卷 43-54页

作者： S shaheen K maqbool R Ellahi Sadiq m Sait Department of mathematics and Statistics International Islamic UniversityIslamabadPakistan Fulbright Fellow Department of Mechanical EngineeringUniversity of California RiversideCAUnited States of America Center for Communications and IT Research Research InstituteKing Fahd University of Petroleum&MineralsDhahran-31261Saudi Arabia

Cilia-induced flow of viscoelastic mucus through an idealized two-dimensional model of the human trachea is *** cilia motion is simulated by a metachronal wave pattern which enables the mobilization of highly viscous mucus even at nonzero Reynolds *** viscoelastic mucus is analyzed with the upper convected maxwell viscoelastic formulation which features a relaxation time and accurately captures normal stress generation in shear *** governing equations are transformed from fixed to wave(laboratory)frame with appropriate variables and resulting differential equations are perturbed about wave *** trachea is treated as an axisymmetric ciliated *** and axial distributions in axial velocity are calculated via the regular perturbation method and pressure rise is computed with numerical integration using symbolic software mATHEmATICA^(‘Tm’).The influence of selected parameters which is cilia length,and maxwell viscoelastic material parameter *** time for prescribed values of wave number are visualized *** rise is observed to increase considerably with elevation in both cilia length and relaxation time whereas the axial velocity is markedly *** simulations provide some insight into viscous-dominated cilia propulsion of rheological mucus and also serve as a benchmark for more advanced modeling.

关键词： viscoelastic mucus ciliated surface trachea inertial flow axisymmetric tube rheology flow