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Degradation of indomethacin in river water under stress and non-stress laboratory conditions:degradation products,long-term evolution and adsorption to sediment

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Journal of environmental Sciences 2017年第1期29卷 13-20页

作者： Juan J.Jimenez Maria i.Sanchez Rafael Pardo Beatriz e.Munoz Department of Analytical Chemistry Faculty of SciencesCampus Miguel DelibesUniversity of ValladolidPaseo de Belen 747012 ValladolidSpain i.U.CiNQUiMA Campus Miguel DelibesUniversity of ValladolidPaseo de Belen 547011 ValladolidSpain Department of Analytical Chemistry School of Industrial EngineersUniversity of ValladoliclFrancisco Mendizdbal 147014 ValladolidSpain

The pharmaceutical compound indomethacin is not totally removed in wastewater treatment plants,whose effluents flow into aquatic environments;concentrations in the 0.1-100 ng/L range are commonly found in surface waters,and its fate is ***,biological,photochemical and thermal degradation assays were conducted under stress and non-stress conditions to estimate its degradation rate in river water and establish its degradation products over *** results revealed that direct sunlight irradiation promoted the complete degradation of indomethacin（2 μg/L） in less than 6 hr,but indomethacin was detected over a period of 4 months when water was kept under the natural day-night cycle and the exposure to sunlight was partially limited,as occurs inside a body of *** biological degradation in water was negligible,while the hydrolysis at pH 7.8 was *** were monitored by ultra-pressure liquid chromatography/quadrupole time-of-flight/mass spectrometry after solid-phase extraction,and six degradation products were found;their structures were proposed based on the molecular formulae and fragmentation observed in high-resolution tandem mass spectra.4-Chlorobenzoic and 2-acetamido-5-methoxybenzoic acids were the long-term transformation products,persisting for at least 30 weeks in water kept under non-stress ***,the degradation in the presence of sediment was also monitored over time,with some differences being *** adsorption coefficients of indomethacin and degradation products on river sediment were calculated;long-term degradation products did not have significant adsorption to sediment.

关键词： indomethacin Degradation products River water Adsorption coefficients High-resolution mass spectrometry

Physicochemical regeneration of high silica zeolite Y used to clean-up water polluted with sulfonamide antibiotics

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Journal of environmental Sciences 2016年第5期28卷 302-312页

作者： i.Braschi S.Blasioli e.Buscaroli D.Montecchio A.Martucci Department of Agricultural Sciences University of Bologna NanoSiSTeMi interdisciplinary Centre Università del Piemonte Orientale A.Avogadro Department of Physics and earth Sciences University of Ferrara

High silica zeolite Y has been positively evaluated to clean-up water polluted with sulfonamides, an antibiotic family which is known to be involved in the antibiotic resistance evolution. To define possible strategies for the exhausted zeolite regeneration,the efficacy of some chemico-physical treatments on the zeolite loaded with four different sulfonamides was evaluated. The evolution of photolysis, Fenton-like reaction, thermal treatments, and solvent extractions and the occurrence in the zeolite pores of organic residues eventually entrapped was elucidated by a combined thermogravimetric（TGA–DTA）, diffractometric（XRPD）, and spectroscopic（FT-iR） approach. The chemical processes were not able to remove the organic guest from zeolite pores and a limited transformation on embedded molecules was observed. On the contrary, both thermal treatment and solvent extraction succeeded in the regeneration of the zeolite loaded from deionized and natural fresh water. The recyclability of regenerated zeolite was evaluated over several adsorption/regeneration cycles, due to the treatment efficacy and its stability as well as the ability to regain the structural features of the unloaded material.

关键词： Zeolite recyclability Water depollution Sulfa drugs Thermal regeneration Solvent extraction

Three subspecies of Black-tailed Godwit share non-breeding sites in the world's largest river delta

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Avian Research 2025年第1期16卷 1-10页

作者： Das, Delip K. Vansteelant, Wouter M.G. Zhu, Bingrun islam, Shariful Khandakar, Naim van der Velde, Marco Hassell, Chris J. Conklin, Jesse R. Bocher, Pierrick Hooijmeijer, Jos C.e.W. Verkuil, Yvonne i. Piersma, Theunis Department of Zoology Faculty of Life and Earth Sciences Jagannath University Dhaka 1100 Bangladesh Conservation ecology Group Groningen Institute for Evolutionary Life Sciences University of Groningen PO Box 11103 Groningen 9700 CC Netherlands Birdeyes Centre for Global Ecological Change at the Faculties of Science & Engineering and Campus Fryslân University of Groningen Zaailand 110 Leeuwarden 8911 BN Netherlands Theoretical and Computational ecology Institute for Biodiversity and Ecosystem Dynamics University of Amsterdam Science Park 904 Amsterdam 1098 XH Netherlands Hunan Global Messenger Technology Co. Ltd Changsha 410205 China Behavioural & Physiological ecology Groningen Institute for Evolutionary Life Sciences University of Groningen PO Box 11103 Groningen 9700 CC Netherlands Global Flyway Network PO Box 3089 Broome WA 6725 Australia Littoral environnement et Sociétés UMR LieNSs 7266 CNRS La Rochelle University 2 rue Olympe de Gouges La Rochelle 17000 France NiOZ Royal Netherlands institute for Sea Research Department of Coastal Systems PO Box 59 Den Burg Texel 1790 AB Netherlands

During the non-breeding season (September–April), Black-tailed Godwits (Limosa limosa) are commonly seen in coastal and inland wetlands of the Ganges-Brahmaputra-Meghna Delta in Bangladesh. We hypothesize that the Ganges-Brahmaputra-Meghna Delta, at the overlap between the Central Asian and east Asian–Australasian flyways, may host three subspecies that breed in disjunct areas of temperate and northern Asia: L. l. limosa, L. l. melanuroides, and L. l. bohaii. We used mitochondrial DNA (mtDNA) haplotype network and biometric analysis to determine subspecies in captured individuals, and deployed GPS–GSM transmitters to verify breeding areas of individuals with subspecies assignments. To test for differential habitat preferences, we sampled birds at two ecologically distinct habitats known to host the largest concentrations of non-breeding Black-tailed Godwits in Bangladesh: Nijhum Dweep National Park, a tidal coastal habitat with brackish water on the south-central coast, and Tanguar Haor (‘backmarsh’), a seasonal freshwater floodplain in the north. During the non-breeding seasons of 2021–2022 and 2022–2023, we sampled and measured 93 Black-tailed Godwits, 54 of which were equipped with GPS–GSM transmitters. Our mtDNA haplotype network analysis confirmed the presence of limosa, melanuroides, and bohaii subspecies at the study sites. Thus, indeed, Black-tailed Godwits subspecies, despite having distinct breeding ranges, exhibit (partially) overlapping non-breeding ranges in Asia. The subspecies composition differed significantly between sites, with limosa and bohaii dominating in Tanguar Haor and melanuroides in Nijhum Dweep. Of the 21 individuals that were tracked to their breeding grounds, 18 migrated to the expected breeding range of their respective subspecies. However, one bird with a limosa haplotype migrated to a known breeding area of bohaii, whereas two birds with melanuroides haplotypes migrated to the supposed breeding range of limosa. Therefore, while ecolo

关键词： Black-tailed godwits Central Asian flyway Ganges-Brahmaputra-Meghna Delta GPS–GSM tracking Migration mtDNA Subspecies

effects of V and Cr Addition on the Structural and Sensing Properties of Titania

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稀有金属材料与工程 2006年第A3期35卷 113-115页

作者： e.Comini i.Alessandri G.Faglia e.Bontempi L.e.Depero G.Sberveglieri Sensor Laboratory INFMUniversita'di Brescia25133 BRESCIAItaly Laboratorio di Chimica perle Tecnoiogie Universita'di Brescia25133 BRESCIAItaly

We have comparatively studied the addition of Cr and V in *** and V content were changed by means of insets placed in the Ti ***,compositional and electrical analyses of different series of thin films,made by XRF, XRD,are *** characterization not only showed that Cr doped layers were very sensitive to ethanol within a useful range for applications,but also allowed to verify that the electrical behaviour is dependent on the structure of film. Finally,the Cr and V concentrations that gives the best results in terms of sensing performances has been determined and a correlation between structural and electrical measurement has been evidenced.

关键词： titania V Cr ethanol sensors thin films

effect of Crystallization Conditions on Polymorphic Diversity of Malic Acid RS-Racemate

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Transactions of Tianjin University 2013年第2期19卷 86-91页

作者： isakov A i kotelnikova e N Kryuchkova L Yu Lorenz H St.Petersburg State University St.Petersburg 199034Russia Max Planck institute for Dynamics of Complex Technical Systems Magdeburg 39106Germany

enantiomers （R （＋） and S（-））, RS-racemate mixture of enantiomers） of malic acid C4H605 have been （double compound） and （R ＋ S） -conglomerate （mechanical investigated by means of X-ray diffractometry and high tern- perature X-ray diffraction method. The RS-racemate was found to be able to form three polymorphic modifications, which we denominated as M1 （monoclinic, space group P21/c）, M2 （monoclinic, space group Cc）, and Tc （triclinic, space group P-l ）, the latter modification having been unknown before. Modification Tc was also described, and its X- ray diffraction characteristics, including interplanar spacings d, hkl indices, unit cell parameters, were defined. in addi- tion, X-ray diffraction characteristics for both reported earlier M1 and M2 monoclinic polymorphic modifications were measured with higher accuracy. The ability of RS-racemate to form one of the above three modifications （Mi, M2, and Tc） or their mixtures containing various proportions and combinations of the components （M1 ＋ M2, M1 ＋ Tc, or M2 ＋ Tc） was found to depend on the type of crystallization medium （a melt, aqueous medium, ethanol or acetone solu- tion）, crystallization rate （from 2--3 minutes to 4 months）, and crystallization temperature. Heating S-enantiomer and M1 RS-racemate up to their respective melting points （100 ℃ and 124 ℃, correspondingly） only made them undergo thermal deformations, while heating （R ＋ S） -conglomerate in the temperature range of 96--110 ℃ resulted in its homogenization to form M2 RS-racemate, which, near the melting point （118 ℃）, namely, in the range of 112-116 ℃, was transformed into Mi RS-racemate. Keywords： polvmorDhism; racemic, chiral

关键词： polymorphism racemic chiral

Climate variation, reproductive frequency and acorn yield in english Oaks

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Journal of Plant ecology 2019年第3期12卷 542-549页

作者： Mick e.Hanley Benjamin i.Cook Michael Fenner School of Biological and Marine Sciences University of PlymouthPlymouthUK NASA Goddard institute for Space Studies New YorkNYUSA Ocean and Climate Physics Lamont-Doherty Earth ObservatoryPalisadesNYUSA Centre for Biological Sciences University of SouthamptonSouthamptonUK

Aims Annually variable but synchronous production of large seed crops(‘masting’)is a widespread phenomenon in temperate *** concerns about the impacts of anthropogenic climate change(ACC)on plant reproduction gives urgency to our need to understand better the role of climate on tree reproduction,and in particular,mast *** our understanding of reproductive phenology however,there is little consensus regarding how climate affects plant reproductive effort or indeed the actual environmental triggers that underpin masting *** We used a 27-year record of acorn yield from a population of 12 Quercus robur trees located in southern england to compare mast-ing frequency and post-dispersal acorn yield each year for each tree,with long-term weather data over the same *** focussed on discrete or sequential climate cues(temperature,precipitation and frost days)as likely predictors of oak *** Findings Annual post-dispersal acorn crop varied greatly;*** acorns in 14 of the 27 years,but there was no sequential pattern of crop ver-sus non-crop years indicating that weather,rather than resource limitation alone,dictated the timing of *** years were instead most closely associated with relatively cool late sum-mer conditions in the preceding year,followed by anomalous sum-mer warmth within crop *** yield increased following dry April and above-average May and June temperatures within crop *** our results support a general association between warm late spring and summer conditions,and crop frequency and yield,respectively,the influence of cooler later summer conditions in the year prior to masting highlights how a combination of weather cues may dictate the occurrence of mast ***,our results corroborate not only the hypothesis that temperature differ-entials between consecutive years,not absolute temperatures,may be the better predictor of mast seeding events but lend support al

关键词： anthropogenic climate change environmental veto Moran effect Quercus robur reproductive effort

LiMiT CYCLeS AND iNVARiANT PARABOLA iN A KUKLeS SYSTeM OF DeGRee THRee

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Acta Mathematica Scientia 2008年第4期28卷 865-869页

作者：刘振海 e.Sáez i.Szántó Department of Mathematics Changsha University of Sciences and Techndogy Departamento de Matemática Universidad Tcnica Federico Santa MariaCasilla 110-VValparaisoChile

in this article,the authors consider a class of Kukles planar polynomial differential system of degree three having an invariant *** this class of second-order differential systems,it is shown that for certain values of the parameters the invariant parabola coexists with a *** other values it can coexist with one,two or three small amplitude limit cycles which are constructed by Hopf *** result gives an answer for the question given in[4],about the existence of limit cycles for such class of system.

关键词： Kukles system limit cycles invariant algebraic curves

Different paths to sexual size dimorphism in two praying mantids, Pseudomantis albofimbriata and Hierodula majuscula

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insect Science 2014年第2期21卷 227-233页

作者： Louise e. Allen Katherine L. Barry Gregory i. Holwell Department of Biological Sciences Macquarie University North Ryde NSW 2109 Australia School of Biological Sciences The University of Auckland Auckland New Zealand

Sexual size dimorphism （SSD） is widespread among diverse animal taxa and has attracted the attention of evolutionary biologists for over a century. SSD is likely to be adaptive and the result of divergent selection on different size optima for males and females, given their different roles in reproduction. The developmental trajectory leading to SSD may help us to understand how selection acts on male and female size. Here, we describe the growth and development of two Australian praying mantids, Pseudomantis albofimbriata and Hierodula majuscula including the number of moults, time to adulthood, size at each moult, and the degree of SSD. While both species exhibit the common pattern of female-biased SSD, the number of moults required for individuals to reach adulthood differed between males and females and between species. Despite their larger adult size, P. albofimbriata females require fewer moults and less time than males to reach adulthood, but are significantly larger than males from the second instar onwards. in contrast, H. majuscula males reached adulthood in fewer moults, and less time than females, however males and females did not differ in size until females went through their final moult into adulthood. H. majuscula also required more time and more moults to reach adulthood than 17. albofimbriata. We discuss these different developmental pathways in light of the existing knowledge of reproductive biology for each species. We also suggest that these differences may relate to the different phenologies that occur in strongly seasonal temperate environments compared with those in the tropics. This study provides evidence that SSD can result from two different patterns of growth and development in closely related species.

关键词： developmental trajectories Mantodea sexual size dimorphism

Tree regeneration in gap-understory mosaics in a subtropical Shorea robusta(Sal) forest

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Journal of Forestry Research 2019年第6期30卷 2061-2068页

作者： L.N.Sharma K.B.Shrestha i.e.Maren Forest Action Nepal GPO-12207 LalitpurNepal Department of Biological Sciences University of BergenThormoensgate 53B5007 BergenNorway

Spatial variation in tree-regeneration density is attributed to the specialization of tree species to light availability for germination and *** availability,in turn,varies across the gap-understorey *** gaps provide an important habitat for the regeneration of tree species that would otherwise be suppressed in the *** subtropical forests,there is still a knowledge-gap relating to how canopy disturbances influence tree-regeneration patterns at local scale,and if they disproportionately favor regeneration of certain *** aim to analyze whether canopy gaps promote tree regeneration,and tree species are specialized to gaps or understory for germination and *** sampled vegetation in 128 plots(0.01 ha),equally distributed in gaps and below canopy,in two subtropical Shorea robusta Gaertn.(Sal)forests in Nepal,recording the number of tree seedlings and saplings in each *** compared the regeneration density of seedlings and saplings separately between gaps and the *** mean densities of seedlings and saplings were higher in the gaps at both sites;although there was no difference in the seedling density of the majority of the species between the *** species were confined to either gap or understorey at the seedling *** conclude that gaps are not critical for the germination of tree species in Sal forests but these are an important habitat for enabling seedlings to survive into *** classification of trees into regeneration guilds mainly based on germination does not apply to the majority of tree species in subtropical Sal *** results reaffirm that gap creation promotes tree regeneration by favouring seedling survival and growth and can influence forest management for conservation,as well as for plantations.

关键词： Canopy-gap Density Regeneration Saplings Seedlings Shade tolerance